• Title/Summary/Keyword: 중금속 분석

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Response of Benthic Foraminifera to Sedimentary Pollution in Masan Bay, Korea (마산만 퇴적환경 오염에 따른 저서성 유공충 분포 변화)

  • Woo, Han-Jun;Kim, Hyo-Young;Jeong, Kap-Sik;Chun, Jong-Hwa;Kim, Seong-Eun;Chu, Yong-Shik
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.4 no.2
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    • pp.144-154
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    • 1999
  • Masan Bay is highly polluted by the discharge of large quantities of effluents from the industrial complex and domestic sewage of Masan City, Southeast Korea. Surface sediments from 9 stations were used for geochemical and foraminiferal analyses in order to investigate foraminiferal response to sedimentary pollution in the Bay. The heavy metal concentrations in sediments are relatively higher than those in Kyeonggi Bay and Daesan area, west coastal region of Korea. Zn, Cd, Pb, and As are more concentrated than in world average shale, indicating that the municipal and industrial effluents cause sediment contamination. Responses of benthic foraminifera to the sedimentary pollution effect document a degree of pollution in Masan Bay. The species number and diversity in Masan Bay had lower values than those in Gadeog Channel. In Masan Bay, agglutinated foraminifera are abundant and calcareous foraminiferal tests were frequently pyritized. Eggerella advena and Trochammina pacifica dominated at levels of pollution and could be opportunistic species. These data will provide a baseline for future assessments of environmental quality in Masan Bay.

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Determination on the component arrangement of a hybrid rain garden system for effective stormwater runoff treatment (강우유출수 처리를 위한 하이브리드 빗물정원 시스템의 구성요소 배열 연구)

  • Flores, Precious Eureka D.;Geronimo, Franz Kevin F.;Alihan, Jawara Christian P.;Kim, Lee-Hyung
    • Journal of Wetlands Research
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    • v.19 no.3
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    • pp.271-278
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    • 2017
  • Low impact development (LID) technology has been recently applied for the treatment of nonpoint source pollutants. Rain garden is one of the widely used LIDs since it utilizes various mechanisms such as biological and physico-chemical treatment to reduce pollutants. However, problem such as clogging has been one of the issues encountered by the rain garden that do not undergo constant maintenance. Therefore, this research was conducted to develop and determine the component arrangement of a rain garden system for a more efficient volume and pollutant reduction. Two hybrid rain garden systems having different characteristics were developed and evaluated to determine the optimum design and arrangement of the system. The results showed that the components arranged in a series manner showed a volume reduction of 93% and a pollutant reduction efficiency of approximately 99%, 93% and 95% was observed for particulates, nutrients and heavy metals, respectively. While when the system is connected in a combined series-parallel, the volume and average pollutant reduction efficiency for the TSS, nutrients and heavy metals are 65%, 94%, 80% and 85%, respectively. Moreover, the component arrangement in the order of sedimentation tank, infiltration tank and plant bed exhibited a high pollutant reduction efficiency compared when the infiltration tank and plant bed were interchanged. The findings of this research will help in the further development and optimization of rain garden systems.

Environmental Contamination and Best Management of Stone-dust from Quarry Mine (석산개발에 따른 주변 환경오염 및 석분토 처리를 위한 연구)

  • Lee, Pyeong-Koo;Youm, Seung-Jun;Kang, Min-Ju
    • Economic and Environmental Geology
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    • v.43 no.4
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    • pp.315-332
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    • 2010
  • All of the water and stone-dust samples with or without flocculant, in and around quarry mines, were analyzed for total concentrations of heavy metals, cyanide(CN), toxic organic compounds and organic phosphorus. Extraction experiments on stone-dust by EDTA and various pH solutions were also carried out, in order to evaluate the contaminant leaching from the long-term heaped stone-dust within quarry mines. The concentrations of $Cr^{6+}$, Hg, CN, TCE/PCE and total phosphorus in all samples (water and stone-dust) were under detection limits, confirming no environmental contamination from stone-dust in quarry mine areas. Lead and cadmium were not detected in all water samples. Copper and zinc were found in some water samples, and arsenic was detected in a few water samples. But they also showed levels much lower than the drinking water standard. Results of the extraction experiments by EDTA and pH solutions showed that Pb, Cr, Cd, Cu and Zn were leached out in less amounts or under detection limits. Arsenic was detected only at pH 3. From above results, we suggested that environmental contamination by quarry mine development is likely to be minor or negligible.

Physio-chemical and Mineralogical Characterization of the Tailings in the Guryoung Mining Area (구룡광산 광미층의 심도변화에 따른 물리.화학적 및 광물학적 특성)

  • Moon, Yong-Hee;Kim, Jeong-Yeon;Song, Yun-Goo;Moon, Hi-Soo
    • Economic and Environmental Geology
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    • v.41 no.2
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    • pp.183-199
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    • 2008
  • This study is focused on characterization of the physio-chemical and mineralogical properties, investigation of their vertical changes in the tailing profile of the Guryoung mining area, classification of the profile into distinct zones, and condition conceptual model of physio-chemical conditions and phases-water relationships controlling the element behaviors in the tailings. The upper part of the groundwater is characterized by the high contents of $Fe_2O_3$ and $SO_3$ for whole rock analysis, low pH, and the occurrence of jarosite, schwertmannite and Fe-oxyhydroxide as the secondary mineral phases. The tailing profile can be divided into the covering soil, jarosite zone, Fe-sulfate zone, Fe-oxyhydroxide and gypsum-bearing pyrite zone, calcite-bearing pyrite zone, soil zone, and weathered zone on the based of the geochemical and mineralogical characteristics. The profile can be sampled into the oxidized zone and the carbonate-rich primary zone with the dramatic changes in pH and the secondary mineral phases. The conceptual model proposed for the tailing profile can be summarized that the oxidation of pyrite is the most important reaction controlling the changes in pH, the dissolution of the primary silicates and carbonates, the precipitation of secondary mineral phases, acid-neutralizing, and heavy metal behaviors through the profile.

Chemical Components and Physiological Activities of Bamboo (Phyllostachys bambusoides Starf) Extracts Prepared with Different Methods (추출방법에 따른 대나무(왕대) 추출물의 화학성분 및 생리활성)

  • Ju, In-Ok;Jung, Gi-Tai;Ryu, Jeong;Choi, Joung-Sik;Choi, Yeong-Geun
    • Korean Journal of Food Science and Technology
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    • v.37 no.4
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    • pp.542-548
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    • 2005
  • Chemical components and physiological activities Bamboo (Phyllostachys bambusoides Starf) extracts obtained by burning, dry heating or extracting with water or 70% ethanol and were investigated. Contents of soluble solid and total phenolic compounds were highest in the ethanol extract. Contents of polyphenols such as catechin, chlorogenic acid, caffeic acid, 3-hydroxy benzoic acid and ferulic acid were determined. Free sugars consisted of galactose, glucose, fructose, and sucrose. Organic acids including citric, tartaric, malic, succinic, and acetic acid were present in the bamboo extracts. Antioxidant activities of dry heat and ethanol extracts were higher than those of BHA or ${\delta}-tocopherol$. Nitrite- scavenging effect of extracts ranged from 84.7 to 99.6% at pH 1.2 ana 3.0. Tyrosinase-inhibitory activity was higher in the water extract, and SOD-like and ACE-inhibitory activity were highest in tile dry kent extract. Antimicrobial activities of the bamboo extracts were strong against Bacillus subtilis, Escherichia coli O157, and Staphylococcus aureus.

In-situ Precipitation of Arsenic and Copper in Soil by Microbiological Sulfate Reduction (미생물학적 황산염 환원에 의한 토양 내 비소와 구리의 원위치 침전)

  • Jang, Hae-Young;Chon, Hyo-Taek;Lee, Jong-Un
    • Economic and Environmental Geology
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    • v.42 no.5
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    • pp.445-455
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    • 2009
  • Microbiological sulfate reduction is the transformation of sulfate to sulfide catalyzed by the activity of sulfate-reducing bacteria using sulfate as an electron acceptor. Low solubility of metal sulfides leads to precipitation of the sulfides in solution. The effects of microbiological sulfate reduction on in-situ precipitation of arsenic and copper were investigated for the heavy metal-contaminated soil around the Songcheon Au-Ag mine site. Total concentrations of As, Cu, and Pb were 1,311 mg/kg, 146 mg/kg, and 294 mg/kg, respectively, after aqua regia digestion. In batch-type experiments, indigenous sulfate-reducing bacteria rapidly decreased sulfate concentration and redox potential and led to substantial removal of dissolved As and Cu from solution. Optimal concentrations of carbon source and sulfate for effective microbial sulfate reduction were 0.2~0.5% (w/v) and 100~200 mg/L, respectively. More than 98% of injected As and Cu were removed in the effluents from both microbial and chemical columns designed for metal sulfides to be precipitated. However, after the injection of oxygen-rich solution, the microbial column showed the enhanced long-term stability of in-situ precipitated metals when compared with the chemical column which showed immediate increase in dissolved As and Cu due to oxidative dissolution of the sulfides. Black precipitates formed in the microbial column during the experiments and were identified as iron sulfide and copper sulfide. Arsenic was observed to be adsorbed on surface of iron sulfide precipitate.

Generation Characteristics and Prediction of Acid Rock Drainage(ARD) of Cut Slopes (건설현장 절취사면의 산성암반배수 발생특성과 잠재적 산발생능력 평가)

  • Lee, Gyoo-Ho;Kim, Jae-Gon;Lee, Jin-Soo;Chon, Chul-Min;Park, Sam-Gyu;Kim, Tack-Hyun;Ko, Kyung-Seok;Kim, Tong-Kwon
    • Economic and Environmental Geology
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    • v.38 no.1
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    • pp.91-99
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    • 2005
  • Acid Rock Drainage(ARD) is the product formed by the atmospheric(i.e. by water, oxygen and carbon dioxide) oxidation of the relatively common iron-sulphur mineral pyrite($FeS_2$). ARD causes the acidification and heavy metal contamination of water and soil and the reduction of slope stability. In this paper the generation characteristics and the prediction of ARD of various cut slopes were studied. An attempt to classify the rocks into several groups according to their acid generation potentials was made. Acid Base Accounting(ABA) tests, commonly used as a screening tool in ARD predictions, were performed. Fourteen rock samples were classified into PAF(potentially acid forming) group and four rock samples into NAF(non-acid forming) group. The chemical analysis of water samples strongly suggested that ARD with high content of heavy metals and low pH could pollute the ground water and/or stream water.

Properties Evaluation and flowability of Controlled Low Strength Materials Utilizing Industrial By-Products (산업부산물을 활용한 저강도 고유동 채움재의 유동성 및 물성평가)

  • Cho, Yong-Kwang;Kim, Chun-Sik;Nam, Seong-Young;Cho, Sung-Hyun;Lee, Hyoung-Woo;Ahn, Ji-Whan
    • Journal of Energy Engineering
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    • v.27 no.4
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    • pp.64-69
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    • 2018
  • The purpose of this study is to expand the use of coal ash and coal slag in thermal power plants. In addition, controlled low strength materials was developed to prevent mine settlement. Bottom ash and KR slag are mixed at ratio of 7:3 to expand the use of industrial by-products through carbonate reaction and inhibit the exudation of heavy metals. In order to efficiently fill the abandon mine, workability and physical properties were evaluated according to flow. As a result of elution of harmful substance experiment, it was confirmed that the carbonation reaction inhibited the elution of heavy metals. It was confirmed that the difference in water ratio was the difference in specific surface area of the controlled low strength materials. It was confirmed that the working efficiency is excellent when the flowability is 300mm compared to 260mm. compressive strength measurement result was relatively high at 260mm compared to 300mm because the number of pores due to decrease of water ratio was small.

Change in Physical Properties depending on Contaminants and Introduction to Case Studies of Geophysical Surveys Applied to Contaminant Detection (오염원에 따른 오염지역 물성 변화 및 물리탐사 적용 사례 소개)

  • Yu, Huieun;Kim, Bitnarae;Song, Seo Young;Cho, Sung Oh;Caesary, Desy;Nam, Myung Jin
    • Geophysics and Geophysical Exploration
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    • v.22 no.3
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    • pp.132-148
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    • 2019
  • Recently, safety and environmental concerns have become major social issues. Especially, a special underground-safety law has been made and enacted to prevent ground subsidence around construction sites. For environmental problems, several researches have started or will start on characterization of contaminated sites, in-situ environmental remediation in subsurface, and monitoring of remediation results. As a part of the researches, geophysical surveys, which have been mainly applied to explore mineral resources, geological features or ground, are used to characterize not only contaminated areas but also fluid flow paths in subsurface environments. As a basic study for the application of geophysical surveys to detect contamination in subsurface, this paper analyzes previous researches to understand changes in geophysical properties of contaminated zones by various contaminants such as leachate, heavy metals, and non-adequate phase liquid (NAPL). Furthermore, this paper briefly introduces how geophysical surveys like direct-current electrical resistivity, induced polarization and ground penetration radar surveys can be applied to detect each contamination, before analyzing case studies of the applications in contaminated areas by NAPL, leachate, heavy metal or nitrogen oxides.

Development of Skin Health Promoting Materials Using Leuconostoc mesenteroides (중금속 흡착능 Leuconostoc mesenteroides CJNU 0705 균주를 활용한 피부 건강기능성 소재 개발)

  • Han, Min-Hui;Moon, Gi-Seong
    • Microbiology and Biotechnology Letters
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    • v.48 no.4
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    • pp.455-462
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    • 2020
  • Leuconostoc mesenteroides CJNU 0705 was isolated from a breast milk sample and identified by 16S rRNA gene sequencing and confirmed by its ability to produce dextran from tryptic soy agar plates supplemented with 2% sucrose. This strain can absorb various heavy metals including lead (Pb) and cadmium (Cd) which are both found in fine dust and have been shown to be harmful to human skin. In addition, Leu. mesenteroides CJNU 0705 has demonstrated antimicrobial activity against Propionibacterium acnes, the primary causative agent of acne. Given these traits it was natural to evaluate the use of this strain in the fermentation of several natural extracts from green tea, carrot, annual wormwood, parsley, broccoli, and corn silk, which are known to improve skin health, to see if it could increase their dextran content when supplemented with no sucrose, 2% sucrose, or 2% sucrose and 3% yeast extract. The extracts supplemented with both yeast and sucrose were found to produce the most dextran, which was confirmed by the scanning electron microscope (SEM) images. These results suggest that Leu. mesenteroides CJNU 0705 and its fermented natural extracts could be used as functional materials for improving human skin health.