• Proceedings of the Korea Water Resources Association Conference
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• 2012.05a
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• pp.759-759
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• 2012

하수처리수의 농업용수 재이용 사업은 물 재이용 기본계획의 일환으로 수행되고 있다. 재이용방식은 직접재이용과 간접재이용으로 구분할 수 있으며 2020년까지 56개 하수처리시설에서 총 106,388 천$m^3$/년의 농업용수를 직접재이용할 계획이다. 하지만 대부분의 경우 간접재이용의 형식으로 하수처리수를 농업용수로 이용하고 있는 실정이다. 따라서 본 연구의 목적은 하수처리수의 농업용수 간접재이용에 따른 작물생육, 수질, 그리고 토양환경에 미치는 영향을 평가하는데 있다. 본 연구를 위해 수원시 환경사업소와 오산시 환경사업소 하류 지역을 간접재이용 사례지구로 선정하고, 용인 이동저수지를 관개용수로 하는 청정지역을 대비구로 선정하였다. 각 지구별로 수량 구성요소 및 수확량 특성, 그리고 벼의 영양염류 및 중금속 함량 등의 유해성분을 분석하였으며, 관개수질과 논토양의 성분을 모니터링 하였다. 모니터링 결과를 통해 간접재이용 사례지구의 환경영향을 평가하여 수질기준을 정립하고 간접재이용시스템을 개발하는데 있어 기초적인 자료를 제공할 것이라 사료된다.

• Proceedings of the Korea Water Resources Association Conference
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• 2012.05a
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• pp.588-592
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• 2012

저수지에서 퇴사가 저수지에 미치는 영향으로는 저수용량의 감소로 인한 용수공급량 저하, 상류하천 수위 상승에 따른 홍수소통능력 감소로 인한 배수위 상승, 퇴적토의 용출에 의한 부영양화 촉진 및 중금속 퇴적 등의 수질변화, 퇴사로 인한 어류서식처 환경의 변화 등이 있다. 또한, 저수지로 유입되는 유사에 대한 정확한 예측은 댐의 계획 및 운영과 관련된 저수지 퇴사관계를 이해하는데 필수 요소이다. 즉, 저수지 퇴사에 관한 예측 자료는 댐 설계시에 장래 50년 및 100년 후의 저수위-저수용량 관계곡선을 결정하고, 댐의 사수위를 결정하는데 중요한 기본자료이며, 또한 댐 건설후의 저수지내로 유입되는 유사의 공간적 퇴적분포를 예측하고, 기능별 저수지 용량배분, 본체 및 취수구 등 각종 수리구조물의 안정, 저수지 상류 퇴사로 인한 홍수위의 상승 등 저수지 제 기능의 적정 관리를 계획하는데 필요한 기본자료이기 때문이다. 본 연구에서는 저수지 내에서의 2차원적 하상변동을 해석하기 위한 퇴사 모델링 방법으로 2차원 정상 및 동수역학적인 유사이송과 하상변동을 모의할 수 있으며, 침식과 포착 및 이송 그리고 퇴적의 각 단계에 따라 세부모의가 가능할 뿐만 아니라 RMA2와 SMS 프로그램과 상호 연계가 자유로운 SED-2D 모형을 이용하여 댐 축조로 인한 저수지내의 퇴사거동을 모의한 후 하상변동을 분석하였다.

• Elastomers and Composites
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• v.30 no.3
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• pp.229-234
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• 1995

Membrane process has been applied widely to petroleum chemistry, fine chemistry, polymer, electronics, food, bioprocessing, and wastewater treatment process. Membrane process has advantage that there's no phase change through separation, energy consumption is smaller than other separation processes. And equipment investment and operation cost are inxpensive too. We prepared the silicone rubber membrane and then separated the heavy metal ion from wastewater. Silicone rubber membrane was prepared using a superitical fluid process and heavy metal ions were separated from the chromium nitrate, ferric sulfate, cupric sulfate, nickel sulfate aqueous solution. The pressure difference between top and bottom of separation apparatus was preserved by vacuum pump, and the removal amount of heavy metal at each separation step were analyzed by instrumental analysis, AAS. The surface and pore of silicone rubber membrane was investigated using SEM, and the capability of wastewater treatment using a silicone rubber membrane was proposed as calculated removal rate of heavy metal after comparing removal amount of heavy metal to amount of heavy metal in mother solution by AAS analysis.

• Analytical Science and Technology
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• v.28 no.6
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• pp.385-397
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• 2015

Harmful and potentially harmful constituents (HPHCs) are chemical compounds in tobacco smoke that cause harm to smokers and non-smokers. This study established and validated methods for the analysis of HPHCs from mainstream cigarette smoke. The analyzed HPHCs were categorized into seven groups: aromatic amines, volatile organic compounds (VOCs), heavy metals, tobacco specific nitrosamines (TSNAs), benzo[a]pyrene (B[a]P), ammonia, and carbonyl compounds. The methods were validated by specificity, linearity, limit of detection (LOD), accuracy, precision, and recovery. These validated methods were then applied to the reference cigarettes (1R5F, 3R4F). The correlation coefficients (r²) for the calibration curves of the seven groups were over 0.995. The LODs showed values of 0.01-0.04 ng/cig cig for aromatic amines, 0.01-0.16 μg/cig for VOCs, 0.01-1.27 ng/cig for heavy metals, 0.06-0.28 ng/cig for TSNAs, 0.04 ng/cig for benzo[a]pyrene, 0.08 μg/cig for ammonia, and 0.78-1.77 μg/cig for carbonyl compounds. The precisions obtained from the intra and inter-day batches were less than 15%. The accuracy and the recovery range were less than 15% and 79.2-117.5%, respectively. The proposed methods can therefore be applied for determining HPHCs in tobacco mainstream smoke.

• Food Science and Preservation
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• v.22 no.2
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• pp.218-224
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• 2015

Crickets have been used as crude drug for treating fever and hypertension in East Asia. This study was carried out to investigate the quality characteristics such as the microbial and nutrient contents of crickets (Gryllus bimaculatus) prepared with various processing conditions for use as food. These conditions included the lyophilization process (LP), hot-air process (HP, $90^{\circ}C$ for 7 hr), roasting process (RP, $160^{\circ}C$ for 40 min), and frying process (FP, $180^{\circ}C$ for 30 sec). The total bacterial population of the crickets was 5~7 log CFU/g, but Coliform and E. coli were not detected. The major fatty acids in all the samples were palmitic acid (C16:0), oleic acid (C18:1), and linoleic acid (C18:2). The level of polyunsaturated fatty acids was highest (63.55 g/100 g) in the LP-processed crickets. As for the amino acid content, the glutamic acid level was highest in all the samples, and the RP and FP decreased by 12.01% and 53.88%, respectively, compared to that of the LP. The mineral contents were highest in the LP-processed crickets. Hg was detected at about 1.0 ppb in all the samples, but its level was lower than the residue tolerance level in the Korean Food Code. Such conditions should be considered to better understand the quality characteristics of crickets in food processing.

• Korean Journal of Soil Science and Fertilizer
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• v.29 no.2
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• pp.150-157
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• 1996

This study was conducted to observe the heavy matal contents of paddy soil and brown rice under long term fertilization with different soil amelioration materials. The contents of 0.1N HCl extractable Cu and Zn of surface soil increased in the plots of long term application with urea, ammonium sulfate, compost, lime and silicate fertilizers. The Cu and Zn contents of brown rice showed decreasing trends in same treatments of fertilizers and soil amelioration materials. But the contents of Cd and Pb in soil and brown rice were not affected in long term fertilization with soil amelioration materials.

• Journal of the Korean Chemical Society
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• v.31 no.4
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• pp.308-314
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• 1987

The adsorption behavior of some chelating agents on the Amberlite XAD-7 resin was studied to obtain the optimum conditions for the preparation of chelating agent-XAD-7 resins. The chosen chelating agents are cupferron (CP), diphenylcarbazone (DPC), salicylaldoxime (SAO), thiosalicylic acid (TSA), and dimethylglyoxime (DMG), which have been well known chelating agents to Cu(Ⅱ) and Ni (Ⅱ) ions. Among the chelating agent-XAD-7 resins, SAO-XAD-7 and DMG-XAD-7 resins were evaluated as appropriate impregnated resins by investigating their stabilities in the wide pH range and high abilities to adsorb Cu(Ⅱ) and Ni(Ⅱ) ions. The selective adsorption of Cu(Ⅱ) from Ni(Ⅱ) was possible by changing pH condition by SAO-XAD-7 resin. The adsorption capacities of SAO-XAD-7 and DMG-XAD-7 for Cu(Ⅱ) were $7{\times}10^{-3}mmol$ Cu(Ⅱ) per gram of resin and $2{\times}10^{-3}mmol$ Cu(Ⅱ) per gram of resin, respectively. The quantitative recovery of Cu(Ⅱ) adsorbed by the resin was demonstrated. The adsorption behavior of Cu(Ⅱ) and Ni(Ⅱ) by the single and mixed bed of chelating agent-XAD-7 resin was discussed.

• Applied Chemistry for Engineering
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• v.26 no.4
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• pp.477-482
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• 2015

This study examined the adsorption characteristics of heavy metal ions ($Cr^{6+}$, $As^{3+}$) in an aqueous solution using recycled aggregate (RA) and recycled aggregate (RA)/steel slag (SS) composites. The RA and SS are favorable for the absorbent because it contains about 91% and 86.9%, respectively, which are some of the major adsorbent ingredients (CaO, $SiO_2$, $Al_2O_3$ and $Fe_2O_3$) for heavy metal. Kinetic equilibrium of $Cr^{6+}$ and $As^{3+}$ in RA and RA/SS composites reached within 180 min and 360 min, respectively. The kinetic data presented that the slow course of adsorption follows the Pseudo first and second order models. The equilibrium data were well fitted by the Freundlich model and showed the affinity order of $As^{3+}$ > $Cr^{6+}$. The results of $As^{3+}$ also showed that the adsorption capacity slightly increased with increasing pH from 6 to 10. Meanwhile, the adsorption capacity of $Cr^{6+}$ was slightly decreased. From these results, it was concluded that the RA and RA/SS composites can be successfully used for removing the heavy metals ($Cr^{6+}$ and $As^{3+}$) from aqueous solutions.

• The Korean Journal of Ecology
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• v.25 no.5
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• pp.335-339
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• 2002

Concentrations of Fe, Zn, Mn, Cd and Pb were determined in the tissues of sixty adult pigeons collected at six colonies in Korea, and examined correlations between elements, and between tissues in feral pigeons. As the results, we found many significant correlations between elements, and between tissues in them, A negative correlation between Cd and Fe concentrations was observed in the kidney, Cd depresses the absorption of Fe from the intestine and, in this way, affects the levels of Fe in particular tissues. This tendency could be expressed in terms of lower hemoglobin and hematocrit values because hematocrit is one of the most sensitive indicators of Cd intoxication. Zn concentrations are strongly associated with higher Cd levels in the kidney and liver. This is thought to be a reflection of the interaction known to occur between these two metals. Zn induction has been shown to antagonize a number of toxic effects of Cd. A positive correlation between Pb and Fe concentrations was detected in the livers at the Busan colony with relatively high Pb and Fe concentrations. Pb has been shown to co-accumulate with Fe in the liver by inhibiting the heme synthesis. Significant correlations, especially in toxic elements, Pb and Cd, were observed for many pairs of tissues. We suggest that these correlations between elements, and between tissues should be considered in biomonitoring for heavy metal pollution.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.21 no.6
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• pp.259-265
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• 2011

This research was performed to stabilize heavy metals in mine tailing using fly ash and clay. Fly ash-clay-mine tailing system were investigated using XRD (X-ray diffractometer), XRF (X-ray fluorescence spectrometer), TG-DTA, SEM (Scanning Electron Microscope), Dilatometer and UTM with various mine tailing contents (~15 wt%). The fly ash used in this research was mainly composed of $SiO_2$ (33.01 wt%), $Al_2O_3$ (28.54 wt%), $K_2O$ (3.32 wt%), $Fe_2O_3$ (1.47 wt%), CaO(9.97 wt%). $SiO_2$ and $Al_2O_3$ composition of the clay was over 61 wt%. And the mine tailing have high composition of $SiO_2$ (26.91 wt%), CaO (24.25 wt%), $Fe_2O_3$ (22.97 wt%). Therefore, it was estimated that fly ash-clay-mine tailing have enough sintering characteristics. The shrinkage of specimens started at around $850^{\circ}C$ and changed little up to $1100^{\circ}C$, but increased markedly at above $1100^{\circ}C$. The shrinkage rate is strongly related to the decarbonization amount of coal fly ash. As the result of SEM, structure of the specimens with mine tailing addition showed more close than the one without mine tailing. Compressive strength of the specimens with mine tailing was highly increased to approximately 200~420 kgf/$cm^2$, it satisfied the first grade criterion for clay brick by KS L 4201. The specification of leaching characteristics of the sintered specimens were within the Korean regulation standard.