• Journal of Conservation Science
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• v.32 no.3
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• pp.313-320
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• 2016

The aim of this study was to obtain information on the ancient material of cast bronze through an investigation of the microstructure and impurity characteristics of the casting. Three Koryo bronze coins were analyzed using an optical microscope, scanning electron microscope, and electron dispersive X-ray analyses were used to determine the composition of the specimens. The three coins had 4 phases: ${\alpha}phase$, ${\delta}phase$, Pb, and impurities ($Cu_2S$). $Cu_2S$ was found to exist near Pb or in ${\delta}phase$. $Cu_2S$ is the inter mediate product of copper ore refining. Therefore, the copper ore was not completely refined. To find out the characteristic of $Cu_2S$, we melt 1)Koryo bronze coin and 2)$Cu_2S$ and Pb powder at 1273 K. The reaction between $Cu_2S$ and Pb at 1273 K yielded fine Cu and black gas, which was identified to be PbS and is presented below: $Cu_2S+Pb{\rightarrow}PbS{\uparrow}+2Cu$.

• Korean Journal of Materials Research
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• v.10 no.2
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• pp.111-116
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• 2000

Fracture mode and carbide reactions of cast alloy 738LC during thermal exposure and creep at 816$^{\circ}C$/440MPa and 982$^{\circ}C$/152MPa were investigated. Crystallographic transgranular failure was observed in the specimen crept at 816$^{\circ}C$ due to shearing on the slip plane. Because selective oxidation at the grainboundaries which was exposed at the surface leads reduction in surface energy, however, early initiation of crack at the grainboundaries and intergranular failure were observed in the specimen crept at 982$^{\circ}C$/152MPa. As a result of decomposition of MC carbide at the tested temperatures, M(sub)23C(sub)6 carbide precipitated either on the grainboundaries or on the deformation band. The applied stress enhanced decomposition of MC. $\sigma$phase nucleated from Cr(sub)23C(sub)6 then grew to the ${\gamma}$+${\gamma}$\\` matrix. Precipitation of $\sigma$was accelerated by increasing temperature and applied stress.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.03a
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• pp.205-205
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• 2003

우리나라에서는 많은 양의 폐분진이 발생하며 경남지역에서는 연간 3만톤의 폐분진이 발생한다. 매년 폐기물의 발생량은 증가하고 있으며 폐분진류의 주성분은 실리카와 알루미나가 주성분을 이룬다. 특히 주조, 제강 등 금속공업에서 발생하는 분진은 입자가 미세한 다량의 실리카와 알루미나로 이루어져 있어 탄화규소(SiC) 및 알루미나-탄화규소-탄소(A1$_2$O$_3$-SiC-C)계 내화물 제조에 분쇄공정 없이 세라믹스의 원료로 활용할 수 있다. 현재 알루미나-탄화규소-탄소(Al$_2$O$_3$-SiC-C)계 내화물 제조를 위해 제조공정이 간단한 연소합성법을 이용하지만 분말제조 공정 중 분위기 조절에 많은 비용이 요구되고 있어 시급한 대안이 필요한 상태이다.

• Proceedings of the KAIS Fall Conference
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• 2005.05a
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• pp.58-60
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• 2005

기존의 금속조형물은 만드는 공정으로 주조-후처리 또는 정밀 기계가공방법은 많은 시간과 노력이 필요한 단점이 있었다. 최근에 귀금속 성형점토 (PMC)라는 마이크로 크기의 분말과 바인더가 혼합되어 마치 점토와 같이 직접 수공 또는 치공구를 이용하여 완성하고 $650-850^{\circ}C$ 정도의 저온에서 소결하여 단시간 안에 최종 조형물을 만들 수 있는 신공정이 개발된 바 있다. 본 연구에서는 선진사와 비슷한 $1{\~}3{\mu}$m급은 분말을 1:1로 혼합하고 고형 바인더를 첨부하여 기존 선진사와 동등하거나 우수한 미세조직과 표면경도를 확보하고 조형비가 있는 시작품을 만드는데 성공하였다.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.13 no.4
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• pp.320-324
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• 2008

In order to identify the change of tidal characteristics on average in the Asan Bay due to the construction of the Hwaong (Namyang Bay) tidal barrier (HTB), the tide data at Pyongtack (PT) and Anheung (AH) for the periods from 1993 to 2006 were analyzed using the harmonic analysis method, and major and shallow water tidal constituents were compared. The semidiurnal tidal amplitudes at PT increased while those at AH decreased after the tidal barrier construction. In particular, the amplitudes at PT increased abruptly during the period of $2002{\sim}2003$ when HTB was completed. On the other hand, the amplitudes of the diurnal tides at PT and AH showed minimal change. This suggests that the tidal characteristics change in the Asan Bay may be related to the construction of HTB. The cause of this change is different from either blocking the tidal wave propagation by the Keum River tidal barrier or removing 'choking effect' by the Yeongsan River tidal barrier. The $M_4/M_2$ ratio increased and their phase difference decreased after the completion of HTB. Accordingly, these changes may result in increase of tidal range, decrease of the flood duration and increase of the flood current velocity, inducing more sediments into the Asan Bay.

• Proceedings of the Materials Research Society of Korea Conference
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• 2009.11a
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• pp.19.2-19.2
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• 2009

금속을 용해 응고시킬 때 생성되는 소위, 주조 결함이나 소결금속 내의 기공은 재료의 성능이나강도를 현저하게 낮추는 결함으로서 예전부터 기피되어 왔다. 또한, 재료공정에있어서도 여하의 기공이나 기포가 없는 치밀한 고강도 및 고기능성 재료를 개발하는 것에 최대한의 주의와 관심을 기울여 왔다. 그렇지만, 우리가 자연계의 천연물이나 인공물을 둘러보면 그 대부분이다공질임을 쉽게 눈치챌 수 있다. 예를 들어 목재, 지엽등의 생물을 시작해서 콘크리트 등의 인공물, 우리 체내의 뼈도 전형적인 다공질구조로 구성되어 있다. 이러한 구조로부터 재료의 재질제어 이외에 구조제어라는 새로운 어프로치를 고려할 수 있고, 최근 들어, 금속재료에 있어서도 이러한 다공질구조에 관한 연구가활성화되어 충격흡수재, 생체재료, 베어링재료 등의 다양한응용이 전개되고 있다. 특히, 원주상의 방향성 기공을 갖는 로터스금속은 기존의 복잡한구조의 다공질금속보다 뛰어난 기계적 성질을 갖는다. 이러한 다공질금속은 일방향응고할 때 생성하는 과포화가스원자를 석출시켜 기공을 일방향으로 성장시킨다. 즉, 융점에서의 고상과 액상의 가스 용해도 차를 이용하는 것으로서 응고시에 고용할 수 없는 가스원자가 기공을 형성한다. 이와같이 제조한 방향성 다공질금속은 BT (인플란트, 생체적합성, 저탄성, 경량), ST (초음속기엔진부품, 경량), IT (고성능수냉모듈), ET(고온촉매, 필터)의 분야로의 응용이 기대된다. 본 강연에서는 방향성 다공질금속의 제조법, 특성 및 응용을 포함하여그 동안의 연구성과 및 앞으로의 과제 등을 소개하고자 한다.

• Applied Microscopy
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• v.7 no.1
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• pp.45-49
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• 1977

For obtaining high manganese steel plates, the study has been made on the optimum conditions in melting, forging, rolling and water toughning treatment practices. The optimum water toughning temperature and time was found to be $1030^{\circ}C$ and 30 min. respectively for the plates of 1 mm thickness. The argon atmosphere is very effective for the prevention of decarburization which can be easily occured in open air. There is a close relation between the degree of c 이 d working and the hardess. The greater the cold reduction ratio is, the smaller the grain size is and it results in the increase of hardness. The improvement of tensile and bending properties can be made by the addition of small amount of nickel, chromium and vanadium.

• Applied Chemistry for Engineering
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• v.29 no.1
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• pp.112-116
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• 2018

In this study, the mixing characteristics of water glass and additives (Si, alkali metal), which are one of the main raw materials of silicate based binder used in the production of molds during casting process, were examined. Molecular structures of water glass, additives and mixtures were analyzed FT-IR and viscosity measurements and their correlation were compared. The addition of Si source to the water glass accelerated the Si networking in the material and increased the viscosity. When the alkali metal was added, the viscosity of the water glass decreased by suppressing the Si networking of the water glass. Viscosities of the water glass and lithium silicate (LS) mixtures increased when the content of LS was less than 20 wt% and gradually decreased when the content was more than 20 wt%. By adding KOH to the water glass, the viscosity could be lowered and it could be used effectively to mix with colloidal silica (CS) or potassium methyl siliconate (PMS).

• Korean Journal of Materials Research
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• v.7 no.2
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• pp.129-135
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• 1997

This study has investigated the effects of aging treatment on thc nlechanical propcrries of blg-iiAl-x%nix - 0.1.2) alloys fabricated by the squeeze castmg process. The microstructurcs of as-squeeze cast were composed of pro eurectic $\alpha$ magnesium solid solution, super saturated $\alpha$ solid solution and $\beta(Mg_{17}AI_{12}$) compund. Agcd at both $200^{\circ}C$ and $240^{\circ}C$, Mg--6AixZn alloys showed the peak hardness due to the formation of $\beta(Mg_{17}AI_{12}$) precipitates. The tiiscontinuous precipitates of the lamella r\.pe are predominant at $200^{\circ}C$ aging tredrment. tvhilc. the finely dispersed continu ous precipitates were major type at $240^{\circ}C$ treatment. Mg-- GAI-xZn a1loi.s fabricated hy the squeeze casting process had the hetter combination of tensile strength and elongation compared to the conventionally cast alloys. As increascci zinc: contents. the tensile strength was increased 11y the soiid solutirin strengthening effect of zinc,.

• Conservation Science in Museum
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• v.8
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• pp.49-69
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• 2007

This is about the scientific analysis of the 10 items of the gilt-bronze Panbul excavated from Anapji, Gyeongju. First, the composition of the Panbul was confirmed, using X-ray fluorescence spectrometer (XRF), and the patinas covering the surface of the Panbul were analyzed, using X-ray diffractometer (XRD). And the micro structures and gilt layer of the Panbul were investigated, using microscope and scanning electron microscope with energy dispersive spectrometer (SEM/EDS), and in order to investigate the internal conditions of the Panbul, X-radiography was conducted. As the result, it is found out that the material of the Panbul excavated from Anapji was the bronze of copper (86~95%) and tin (4~12%), and coated with gold. And cuprite (Cu₂O) was detected from red patina of the gilt-bronze Panbul, and chalcocite(Cu₂S) also was detected from the black patina. As the result of the observation of the micro structure through microscope, it is estimated that it was manufactured, using the wax molding method, and, judging from the fact that the thickness of gilt layer was not even, and that the groove had been filled, it was presumed that the amalgam coating method had been used, but some questions still remain, because mercury was not detected. Lastly, through the X-radiography, it was observed that the tiny round spots existed, which was presumed to have been generated during the casting.