• Journal of the Korean earth science society
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• v.34 no.4
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• pp.289-302
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• 2013

In order to determine the provenance of the Huksan Mud Belt sediments in the southeastern Yellow Sea, the major and rare earth elements of the same sediments were analyzed. The surface sediments were sampled from top of piston-cores and box-cores taken at 51 sites within the Huksan Mud Belt. With the mean grain size of $5-6{\phi}$, the sediments of the study area are mud-dominated. The spatial distribution patterns show that silt content is high in the northern Mud Belt, whereas clay content increases as it moves toward the southern Mud Belt. Interestingly, the geochemical compositions both of major and rare earth elements have resulted in differences of sediment provenance. Among the major elements, plots of Fe/Al vs. Mg/Al ratios, $Al_2O_3$ vs. MgO ratios, and $Al_2O_3$ vs. $K_2O$ reveal that the Huksan Mud Belt sediments are dominated by the Korean river-derived sediments. However, the characteristics of rare earth elements infer sediments originating from the Chinese rivers. This discrepancy between the above provenances is attributed to the different contributory factors in the content of chemical elements. Considering strong correlation between major elements with grain sizes, the contents of the major elements are thought to be influenced by the grain size. However, there is a weak correlation between rare earth elements and grain sizes. The behaviour of rare earth elements may be controlled by heavy minerals, rather than grain sizes. Further study requires to solve the discrepancy arose from the difference in applied chemical tracers.

• Proceedings of the Optical Society of Korea Conference
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• 2000.02a
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• pp.222-223
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• 2000

희토류 (또는 란탄족) 원소들은 주기율표상에 원자 번호 57번부터 71번까지 15종의 원소들의 총칭이다. 일부 희토류 원소는 감속재를 비롯한 원자로의 재료로 사용되고 있으며, 대부분의 희토류 원자 스펙트럼은 원자력 발전소에서 사용한 연료의 폐기물 처리에 관련된 각종 연구에 이용되고 있다. 따라서 이 원소들에 대한 원자 분광학적 연구는 원자력 산업 응용 분야에서 중요하게 인식되고 있다. 특히, 레이저를 이용한 분광학적 기술은 이 원소들의 정량 분석에 있어 주성분과 비교적 적은 양 및 극미량 수준의 시료 분석에 가장 유용하게 이용되고 있다. (중략)

• Economic and Environmental Geology
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• v.37 no.2
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• pp.153-171
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• 2004

This study was carried out to define the geochemical and mineralogical relationship between stream sediments and regional geology on upstream of Hahn river area. Geochemical characteristic including for major elements, trace elements and rare earth elements of the South and North Hahn river bed sediments are similar to those of acid igneous rocks which are distributed around both Hahn river basin. The chemical variation of major elements against SiO$_2$ and trace elements contents between South and North Hahn river bed sediments doesn't show the difference. REE patterns of both area show a distinct negative Eu anomaly, but total contents of rare earth elements are higher in North Hahn river sediments than South Hahn river sediments. The heavy minerals in the river bed sediments in this study area are identified as tremolite-actinolite, hematiteㆍmagnetite, common hornblende, ilmenite, garnet, epidote, rutile and sphene. In conclusion, it is elucidated that South and North Hahn river bed sediments are being originated from igneous rocks or metamorphic rocks which contains medium-high grade metamorphic minerals and components of originated from sedimentary rocks those of politic or calcareous rocks are eroded away as solution or suspended load.

• Journal of the Korean earth science society
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• v.26 no.8
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• pp.800-808
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• 2005

Elemental mobility during the weathering of granite in the Gwangju Hyangdeung area was investigated using ICP-MS analysis. It appeared that Al, Fe, Ti, K were lost from the profile, whereas Si, Ca, Na Mg, P and Mn were immobile during chemical weathering. In less weathered soil, large enrichment of K and Ti were found relative to Al, whereas other elements such as Si, Ca, Na, Mg and P are deplete. Fe content is constant throughout the weathered profiles. Amounts of Rb, Sr, Y, Cs, Pb, Th and U increased toward the surface. Nb, and Co have accumulated in the deepest parts of the weathered soil profile. These results agree with similar published studies. In addition, the analytical data shows that Ba and Ga increased, while Cu, Zn, Cr and Ni were relatively constant in this area. REE tend to increase in most samples, while LREEs, relative to Al, were enriched in the lower and upper saprolite. HREEs were enriched in the lower and upper saprolite.

• The Journal of the Petrological Society of Korea
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• v.5 no.1
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• pp.66-83
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• 1996

We report petrography, mineral chemistry, and major and trace element chemistry for rare tholeiites in Cheju island where alkalic rocks predominate. Available age data indicate that the tholeiitic magmatism was younger than 0.49Ma, possibly younger than 0.17 Ma. The tholeiites are generally fine-grained, porphyritic rock and show intergranular texture with lath-shaped plagioclase ($An_{61-46}$), orthopyroxene (bronzite) and olivine ($Fo_{78-67}$). Characteristically, two kinds of clinopyroxene (pigeonite and augite) occur only in groundmass. The tholeiites have normative quartz and show limited compositional variations ($SiO_2$=51.0-52.5 wt%; Mg＃=54-60). Major and transitional metal element variations of tholeiites are distinct from those of alkaline rocks in MgO diagram, suggestingthat the two rock types cannot be simply related to differentiation process from the same magma. The ratios among $K_2O$, Rb, Ba, Nb and La are similar for both tholeiites and alkali basalts, however the ratios between the elements (P, Y and Yb) having an affinity with garnet and the above elements are higher for tholeiites than for alkali basalts. These trace element ratios suggest that the tholeiites and alkali basalts were produced by different degrees of partial melting from a similar sources material (garnet lherzolite mantle).

• Proceedings of the Korean Society of Applied Pharmacology
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• 1994.04a
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• pp.204-204
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• 1994

Ganoderma lucidum의 균사체로 부터 얻어진 G009의 이화학적 특성을 규명하였다. G009는 넓은 범위의 분자량 분포를 가지고 있는 다당체로 분자량 9.4kD의 물질이 주성분이었다 G009의 당의 함량은 약 70%이었고 단백질은 약 2.4%인 것으로 나타났다. G009의 주요 구성당은 glucose, xylose, mannose, galactose 등이었고, glycine, leucine, alanine, valine, isoleucine, proline 등 17종의 아미노산이 확인되었다. 유기원소 분석 결과 G009는 탄소 약 40%, 수소 5.7%, 질소 1.8%의 구성비를 보였으며, 무기원소 분석결과 Ca, Mg, Zn 등이 확인되었다. 이상의 결과로 부터 G009는 9.4 kD의 분자량을 갖는 단백다당체를 주성분으로 하는 당화합물로 추정된다.

• Journal of Conservation Science
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• v.21
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• pp.89-100
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• 2007

This study analyze concentration of minor and trace elements on 47 white porcelains excavated from Dudong-ri, Baekryeon-ri, Sachon-ri kilns in Gyeonsangnam-do by NAA(neutron activation analysis) and try to classify the provenance and characteristics according to the analytical result. Each kilns are divided into the group by PCA(principal component analysis) and LDA(linear discrimination analysis) using 17 elements; Ba Ce, Co, Cr, Cs, Dy, Eu, Hf, La Lu, Rb, Sc, Sm, Ta, Th, V, Yb. The contribution elements are Dy, Sm, La, Ce, Lu, Sc. And soft and hard white porcelains are similar with the chemical composition of the use materials therefore the difference of the chemical composition not confirmed a cause. The analytical results of the fine(I) and poor(II) quality white porcelains presume the difference of the povenance of clay materials or the poduction process such as difference purify and additive materials.

• The Journal of the Petrological Society of Korea
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• v.4 no.1
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• pp.20-30
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• 1995

We report major element chemistry of the Chuncheon amphibolite in the Precambrian Kyonggi massif and discuss its origin. On the basis of areal distribution and chemical difference, the Chuncheon amphibolite can be divided into the Gubongsan arnphibolite in the Gubongsan Group east of Chuncheon city and the Sangguli amphibolite in the Yongduri gneiss complex occurring to the southeast of the Gubongsan Group. Overall major element characteristics of the Chuncheon amphibolite indicate an igneous precursor, although it shows concordant relationship with metasedimentary rocks in many cases. The parental rock of the amphibolite has tholeiitic composition with 45-53wt% $SiO_2$. The Sangguli amphibolite has lower MgO than the Gubongsan one. The difference in $TiO_2$/P_2O_5 ratio between the two amphibolites suggests that they are not genetically related. In MgO variation diagrams, $Na_2O$, $Fe_2O_3$ and $Al_2O_3$ show scattered pattern, while MgO has positive correlation with CaO and negative one with $SiO_2$, $TiO_2$, $P-2O_5$ and $K_2O$. These variations can be interpreted as the result of differentiation of basaltic magma with fractionation of olivine, pyroxene, and plagioclase. Tectonic discrimination using major elements generally suggest withinplate environment for the Chuncheon amphibolite which is similar to that of the amphibolite in the Ogcheon belt.

• Korean Journal of Materials Research
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• v.4 no.2
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• pp.166-176
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• 1994

Ni base superalloys are composed of solid sohltion hardening elements(Co, Cr. Mo. W and so on) and $\gamma '$ precipitation hardening elements(A1, Ti, Nb, Ta and so on). To Improve the mechanical properties and oxidation resistanre of superalloys, rare earth elements(%r, Hf, Y and so on) are added to the inner substrate, or are used as coating materials. Their pffects on the growth rate and adhes~on of oxide are changed according to the kinds of oxides such as $AI_2O_3$ and $Cr_2O_3$. The effect of yttrium on the oxidation rate, grain size of oxide, internal structure, and crack resistance was investigated for two kinds of Ni-base superalloys. One in AF'115 superalloy containing Hf and the other is MA6000 superalloy containing $Y_2O_3$. They werr owid~zed at high temperature after yttrium surface modification using ion coater. Yttrium coating on the AF115 and MA6000 superalloys results in a marked change in the growth of the inner oxide. For AF115 superalloy, the degree of gram boundary segregation of $Cr_2O_3$, and prefer en^ tial oxidation of Hf are decreased, and the shape of inner oxidation layer was changed from triangle to plate type. For MA6000 superalloy, $Cr_2O_3$ oxide scale was transformed as outer oxidation layer of CrZOI and inner oxidation layer of $Cr_2O_3$.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.6 no.1
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• pp.27-34
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• 2001

To investigate the processes governing the distribution of elements in the tidal flat, thirty-eight sediment samples collected from the Saemangeum tidal flat of the Korean west coast were analyzed for their contents of major (Al, Fe, Mg, Ca, Na, K, Ti) and trace (P, Mn, Ba, Sr, V, Cr, Co, Cu, Ni, Zn, Pb) elements. Most elements showed generally lower contents compared to data published for other tidal flats of Korea, and the effect of anthropogenic input could not be recognized in the sediments. The relative abundance and distribution of most of the elements varied significantly with the grain size of sediments. High contents of Al, Fe, Mg, Ti, P, Mn, V, Co, Cr, Cu, Ni and Zn were found in the finer sediments in the upper tidal flat of the study area, suggesting that tidal sedimentation processes play an important role in controlling the distribution of these elements. However, sediment grain size does not impose any significant effect on the abundance and distribution of Ca, Na, K, Ba, Sr and Pb. It appears that the clastic mineralogy in the coarse-grained fractions is the dominant factor determining the distribution of these elements in the study area.