• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2004.05a
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• pp.53-58
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• 2004

동제련 공정중 고품질의 전기동을 효율적으로 생산하기 위해서는 Anode중에 적정량의 비소(As)가 필요하다. 그러나 Cu가 약30% 함유되어 있는 동정광에 함유된 비소는 Smelting Furnace 용련과정에서 비소 특성상 약 70%가 Offgas로 휘발되어 황산공장으로 유입 처리되고, 나머지 30%만 아노드(Anode)로 유입되므로 별도로 전련공정에서 발생된 Cu-Cement(비소 함유)를 정제로에 Recycle 하고 있으며, 부족시 추가로 비소 Source를 구입하여 정제로에 투입하고 있다. 이를 효과적으로 해결하기 위하여 현재 위탁처리를 하고있는 As가 함유된 폐수처리 2차 중화시 발생된 2차 Cake 60W.T/D중 30W.T/D를 기존 Converter Slag 건조용 Rotary Dryer를 이용하여 Converter Furnace에 Recycle 함으로써 전련 Anode에 필요한 비소를 공급하고, 또한 2차 Cake에 혼입되어 있는 CaO 활용으로 부재료 절감, 유가금속(Cu등) 회수등 및 2차 Cake 위탁처리비용을 절감하며, Cu-Cement는 Smelting Furnace에 투입하여 정제로 투입시 발생되는 문제점들을 동시에 해결코자 한다.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2003.11a
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• pp.426-430
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• 2003

Fissionable uranium will be separated from long-lived nuclear materials in pyroprocess for transmutation. This study was measured decomposition voltage and deposition rate on cathode of uranium in $LiF-BeF_2$ molten salt by electrowinning. The result of experimental is that decomposition voltage of $UF_4$ and $LiF-BeF_2$ molten salt is -1.4 and -1.5 volt at $500^{\circ}C$ Deposition rate of uranium on cathode increases with increase of uranium concentration in molten salt.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2007.11a
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• pp.289-290
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• 2007

본 연구에서 제시된 모델을 기반으로 KCl-LiCl/Cd의 전해제련 시스템 해석을 통하여 다성분 금속염의 전해 분리의 기본 특성을 이해할 수 있었으며, 주어진 정전류 전해제련 모사에서 전해거동을 예측할 수 있었다. 또한 시간에 따른 용융염 전극반응에 참여하는 각 원소들의 전류 및 전극반응에 가해지는 전위를 예측할 수 있는 모델로써 전해장치의 설계 및 운전시 전해 변수들이 전해성능에 미치는 영향을 판단하는데 유용하게 활용될 것이 기대된다.

• Resources Recycling
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• v.2 no.2
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• pp.22-26
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• 1993

The flowsheet for the recovery of gallium and indium from zinc residues has been established based on the sulfuric acid treatment. In comparison with the alkali treatment, the method proposed in this work allowed the recovery of indium together with gallium. The majority of iron contained in leach liquor could be removed through the two-stage neutrallization under oxidative or reductive atmosphere. Crude gallium and indium could be obtained through the alkali and/or acid leaching of the products generated from the above treatment. In addition, cementation of indium with zinc powders could also be used for the concentration of it from weak acid solutions.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2013.11a
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• pp.74-75
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• 2013

The paper study on the mechanical properties of reactive powder concrete using copper slag. A change in the replacement ratio s of copper slag was measured compressive strength and slump flow. As a results, slump flow using copper slag tend to increase slump flow with replacement ratio. As the concrete with a replacement ratio of copper slag up to 30% was found to have a compressive strength superior to that of plain.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.05a
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• pp.69-72
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• 2011

The purpose of this study is to identify basic property of porous concrete using cooper slag as fine aggregate. The specimens were made with cooper slag with various mixing ratio(10, 20, 30, 50%), porous concrete and porous concrete containing river fine aggregate and crushed fine aggregate, which W/B ratio fixed 0.25. Compressive strength, Flexural strength, coefficient of permeability. From the test results, various fine aggregate mixing ratio improves compressive strength and flexural strength, but cooper slag fine aggregate mixing ratio over 20%, concrete indicates trend to decrease performance of permeability. Concrete containing fine aggregate is improved the performance of permeability and strength compared to other specimen, when age 28days, and cooper slag mixing ratio less than 20% concrete indicates better performance than cooper slag mixing ratio 20% over.

• Journal of Institute of Convergence Technology
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• v.1 no.1
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• pp.13-17
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• 2011

The car industry is one of the technological applications which more rare earth metals employes as three-way catalysts. Therefore, the recovery of rare earth metals from the used automotive three-way catalysts could be important source to obtain these metals. This work presents the analysis of market and demand for rare earth metal in automotive three-way catalyst and introduces the dry and the wet processes for the recovery of rare earth metals from used three-way catalyst. Finally, the alternative methods to conventional wet processes was simply suggested based on the economic and ecological point of view.

• Korean Journal of Metals and Materials
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• v.47 no.3
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• pp.182-187
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• 2009

The molten salt electrolysis is applied to reduce titanium dioxide to titanium metal using calcium chloride as an electrolyte and the reaction mechanism of the reduction process is examined by analyzing the reaction products. The process conditions to obtain titanium metal for $900^{\circ}C$ correspond to 2.9~3.2 V and 24 hours. The reaction products for 2.9 V at $900^{\circ}C$ include irregular-shaped titanium oxides such as $Ti_4O_7$, $Ti_3O_5$ and $Ti_2O_3$ and polyhedral $CaTiO_3$. Using these microstructure analysis, the sequential reaction mechanism for the electrochemical reduction of titanium dioxide to titanium is proposed.

• 산업보건소식
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• no.28
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• pp.3-10
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• 1986

• 한국전기화학회:학술대회논문집
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• 1998.10a
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• pp.36-36
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• 1998