• Proceedings of the Korean Radioactive Waste Society Conference
• /
• 2004.06a
• /
• pp.339-339
• /
• 2004

원자로를 이용하여 장수명핵종(long lived nucleus)을 소멸처리하는 과정에서 초우라늄(TRU, transuranium)과 희토류(RE, rare earth) 금속에 포함되어 있는 소량의 핵분열성(fissile) 물질인 우라늄을 제거할 필요가 있다. 본 실험은 LiCl-KCl 용융염계에서 전해제련법(Electrowinning)을 이용하여 용융염욕에 존재하는 우라늄을 제거하기 위하여 필요한 Cd-Li 양전극 물질을 제조하였고, 제조된 금속을 이용하여 우라늄 및 란탄족(Dy, Ce, Y, Nd, Gd) 금속의 환원 특성을 파악하였다.(중략)

• Resources Recycling
• /
• v.9 no.3
• /
• pp.22-28
• /
• 2000

A study on the recovery of gallium from zinc residues is carried out by alkali leaching using NaOH. The results show that in case of alkali leaching of zinc residues, Zn, K and Si are mainly leached out and Fe and other base metals are scarcely leached out, which results in that gallium is easily recovered by solvent extraction. The leaching efficiency of gallium increases with increasing alkali concentration and solid density. Especially, alkali consumption is considerably reduced by washing the zinc residues with water before leaching in order to eleminate the soluble zinc compounds. The gallium from zinc residues is found to be leached out with a recovery of 80% or higher for 2hrs leaching with 1~1.25 M/L NaOH solution and solid density 333 g/L at $25^{\circ}C$.

• Journal of Conservation Science
• /
• v.32 no.3
• /
• pp.313-320
• /
• 2016

The aim of this study was to obtain information on the ancient material of cast bronze through an investigation of the microstructure and impurity characteristics of the casting. Three Koryo bronze coins were analyzed using an optical microscope, scanning electron microscope, and electron dispersive X-ray analyses were used to determine the composition of the specimens. The three coins had 4 phases: ${\alpha}phase$, ${\delta}phase$, Pb, and impurities ($Cu_2S$). $Cu_2S$ was found to exist near Pb or in ${\delta}phase$. $Cu_2S$ is the inter mediate product of copper ore refining. Therefore, the copper ore was not completely refined. To find out the characteristic of $Cu_2S$, we melt 1)Koryo bronze coin and 2)$Cu_2S$ and Pb powder at 1273 K. The reaction between $Cu_2S$ and Pb at 1273 K yielded fine Cu and black gas, which was identified to be PbS and is presented below: $Cu_2S+Pb{\rightarrow}PbS{\uparrow}+2Cu$.

• Resources Recycling
• /
• v.29 no.2
• /
• pp.62-68
• /
• 2020

In new millennium, wide-reaching demands for selective catalytic reduction (SCR) catalyst have been increased gradually in new millennium. SCR catalyst can prevent the NO_x emission to protect the environment. In SCR catalyst the main composition of the catalyst is typically TiO₂ (70~80%), WO₃ (7~10%), V₂O₅ (~1%) and others. When the SCR catalysts are used up and disposed to landfills, it is problematic that those should exist in the landfill site permanently due to their extremely low degradability. A new advanced technology needs to be developed primarily to protect environment and then recover the valuable metals. Hydrometallurgical techniques such as leaching and liquid-liquid extraction was designed and developed for the spent SCR catalyst processing. In a first stage, V and W selectively leached from spent SCR catalyst, then both the metals were processed by liquid-liquid extraction process. Various commercial extractants such as D2EHPA, PC 88A, TBP, Cyanex 272, Aliquat 336 were tested for selective extraction of title metals. Scrubbing and stripping studies were tested and optimized for vanadium and tungsten extraction and possible separation. 3^rd phase studies were optimized by using iso-decanol reagent.

• Journal of Conservation Science
• /
• v.34 no.1
• /
• pp.39-50
• /
• 2018

This study replicated traditional smelting methods to produce iron blooms from sand iron. The metallurgical properties of the slag and the iron blooms were analyzed. The sand iron materials used in the smelting experiments, which were based on ancient documents, were collected from Gyeong-Ju and Pohang. Analysis by WD-XRF and XRD showed that Gyeong-Ju's sand iron contains a high-titanium, with magnetite, and Pohang's sand iron contains a low-titanium, which magnetite and ilmenite were mixed. Analysis of the slag with XRD, and the micro-structure with metal microscopes and SEM-EDS, confirmed that the major compounds in the slag of the Gyeong-Ju's sand iron were fayalite and $w\ddot{u}stite$, and those in the slag of the Pohang's sand iron were titanomagnetite and fayalite. The differences in the main constituents were confirmed according to the Ti quantity. Finally, we observed the microstructures of the iron blooms. In the case of the iron bloom produced from Gyeong-Ju's sand iron, the outside was found to be dominantly a pearlite of eutectoid steel, while the inside was a hypo-eutectoid steel where ferrite and pearlite were mixed together. While, the major component of the iron bloom produced from Pohang's sand iron was ferrite, which is almost like pure iron. However, there were many impurities inside the iron blooms. Therefore, this experiment confirmed that making ironware required a process that involved removing internal impurities, refining, and welding. It will be an important data to identify the characteristics of iron by-products and the site through traditional iron-making experiments under various conditions.

• Resources Recycling
• /
• v.27 no.4
• /
• pp.29-35
• /
• 2018

In this study, the electrochemical redox behavior of neodymium in non-aqueous electrolytes was investigated to confirm the possibility of neodymium metallurgy at room temperature. The non-aqueous electrolytes include ionic liquids such as $[C_4mim]PF_6$, $[C_4mim]Cl$, and $[P_{66614}]PF_6$, ethanol which are highly soluble in neodymium salts, and mixed electrolytes based on carbonate with highly electrochemical stability. The electrochemical redox properties of neodymium were better than those of other electrolytes in the case of the mixed electrolyte based on ethylene carbonate (EC)/di-ethylene carbonate (DEC). Ethanol was added to improve the physical properties of the mixed electrolyte. Thorough the analysis about ionic conductivity of EC/DEC ratio, ethanol content and $NdCl_3$ concentration, the best electrolyte composition was 50 vol% content of ethanol and 0.5 M of $NdCl_3$. Using cyclic voltametry and linear sweep voltametry, a current peak estimated at -3.8 V (vs. Pt-QRE) was observed as a limiting current of neodymium reduction. Potentiostatic electrolysis for 18 hours at room temperature at -6 V (vs. Pt-QRE) confirmed that metallic neodymium was electrodeposited.

• Corrosion Science and Technology
• /
• v.11 no.6
• /
• pp.213-217
• /
• 2012

The amount of spent fuel from nuclear power plants has been increasing. An effective management plan of the spent fuel becomes a critical issue, because the storage capacity of each plant will reach its storage limit in a few years. The volume of high toxic spent fuel can be reduced through a fuel processing. Advanced Fuel Cycle (AFC) system is considered to be one of the options to reduce the toxicity and volume of the spent fuel. It is necessary to set up a test facility to demonstrate the feasibility of the process at the engineering scale. The objective of the work is a development of the safety evaluation technology for the AFC system. The evaluation technology of the AFC structural integrity and processes were surveyed and reviewed. Key evaluation parameters for the main processes such as electrolytic reduction, electrorefining, and electrowinning were obtained. The survey results may be used for the establishment of the AFC regulatory licensing procedure. The establishment of the licensing criteria minimizes the trials and errors of the AFC facility design. Issues taken from the survey on the regulatory procedure and design safety features for the AFC facility provide a chance to resolve potential issues in advance.

• Resources Recycling
• /
• v.24 no.4
• /
• pp.12-21
• /
• 2015

Almost all copper slags contain a considerable amount of Cu (0.5 - 3.7%) close to or even higher than copper ores. A number of methods for metal recovery from copper slag were reported These methods can be classified into three categories, flotation, leaching and roasting. Sulfide flotation method for the recovery of copper from Kazahstan copper furnace slag is discussed in this investigation. 50% of copper from the slag was recovered by sulfide flotation at pH 4. meanwhile 67% of copper from the slag was recovered at pH 11. Higher copper recovery result at pH 11 rather than that at pH 4 was caused by the fact that copper sulfides were floated in particle size fraction over $100{\mu}m$ in concentrates at pH 11. When the slag were ground below $74{\mu}m$by ball milling, the recovery of copper by floation in slag improved to 78 - 83% because of copper liberation effect.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2001.05a
• /
• pp.319-324
• /
• 2001

Recently new practical use way of industry product is required. In this study, to find flowing property of slump, unit weight, the air amount, compressive strength etc. Compressive strength 240, 270kgf/$cm^{2}$, slump 8$\pm$2.5(I), 152$\pm$.5(II)cm, mixing ratio of copper smelting slag decided by 0, 25, 50, 75, 100% gradually, The result of this study was follows ; 1. Unit weight increased 2.2%~4.4% according as mixing ratio of copper smelting slag increases. 2. Slump increased about 2~5% as the mixing ratio increased gradually 3. Compressive strength was increased about 4~28% in copper smelting slag mixing ratio 25~50% and 8~20% decreased more than mixing ratio 75%.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2002.05a
• /
• pp.317-322
• /
• 2002

In modern times, the environment preservation is global tendency and self social awareness is arise. Measures to the environment preservation and pollution is going on study. One measure is recycling and reuse of by product and it is already developed in some advanced country. There is 7 hundred thousand tons of copper slag production from copper refining process in domestic. The purpose of this study is reusing copper slag -by product which produced L cooperation in domestic-as fine aggregate for producing high strength concrete and investigating the fundamental characteristics.