• Journal of the Korean Chemical Society
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• v.44 no.3
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• pp.184-189
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• 2000

ab initio molecular orbitaI calculation is performed to estimate the substituent effects for meta-substituted pyridines. Electrostatic potentials are obtained from ab initio wavefunctions of the optimized structures for the meta-substituted pyridines. Electrostatic potenhals are shown to be minimum at nitrogen atom of pyridines. The potenttial minima are good correlated with the substituent constants, ${\sigma}_m$ and with the ${\Delta}pK_a$, respectively. It is found that the electrostatic potential minima can be used as a useful measure of substituent effects.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.130-130
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• 2015

플라즈마를 이용한 cleaning, etching, sputtering 공정에서 발생하는 마이크로아크방전이나 turn-off후의 잔류정전기는 공정대상물의 절연파괴나 전자소자에 전기적 손상을 유발함으로서 공정의 불량률을 증가시키는 중요한 요인이 된다. 본 연구에서는 잔류정전기를 관찰하기위하여 실린더형 챔버구조의 평행평판 전극구조를 지닌 용량결합형 플라즈마에서 powered electrode에 부착된 유전체 기판 표면의 잔류 정전기의 변화 양상을 planar type probe로 측정해보았다. 300mtorr 압력에서 아르곤가스로 발생시킨 플라즈마가 존재할 때 낮은 음전위 평균값을 가지던 기판표면 전위가 전력인가가 중지되었을때 20V 가량의 양전위를 가질 수 있음을 측정 하였고, 이것을 COMSOL MULTIPHYSICS TOOL을 활용한 시뮬레이션과 비교하였다. 이 현상이 파워인가 전극이 플라즈마 영역에 노출되느냐에 따라 발생할 수 있음을 알게 되었고, 그 크기와 지속시간은 입력전력 및 블로킹 커패시터와 유전체 기판의 정전용량에 의존함을 확인 하였다.

• Journal of the Korean Chemical Society
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• v.43 no.4
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• pp.378-383
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• 1999

Ab initio calculation is performed to estimate the substituent effects for Para-substituted pyridines. Electrostatic potentials are obtained from ab initio molecular orbital wavefunctions of optimized structures for substituted pyridines. Electrostatic potentials are computed to be minimum at nitrogen atom of pyridines. The potential minima are good correlated with the substituent constants, ${\sigma}_p$ and with the ${\Delta}pKa$. It is shown that the electrostatic potential minima can be used as a measure of substituent effects.

• Journal of the Korean Chemical Society
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• v.39 no.5
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• pp.329-337
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• 1995

Energetic oxetane derivatives which undergo cationic polymerizations have been investigated theoretically by using ab initio HF/3-21G calculations. We have examined structures, charges, and molecular electrostatic potentials. The ring structure of oxetane has changed significantly due to (1) the introduction of large substituents in the ring or (2) the addition of either proton or BF3. This structural change is attributed to electrostatic interactions and/or steric repulsions. The nucleophilicity and basicity of oxetane derivatives can be explained by the negative charge and the minimum electrostatic potential value of O atom. The reactivity in the polymerization can be rationalized by (1) the basicity of O atom and (2) the difference between HOMO energy of oxetanes and LUMO energy of activated oxetane polymeric chains. Our calculations predict that 3-azidomethyl-3-methyl oxetane (AMMO) is more basic than 3-nitratomethyl-3-methyl oxetane (NMMO), and AMMO is more reactive toward both AMMO and NMMO polymeric chains. Our results are in good agreement with previous experimental data.

• Fire Science and Engineering
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• v.25 no.3
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• pp.107-112
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• 2011

We have considered the fire hazard by the static in anti-static film manufacturing factory on this study. Solvents that the flash point as ethanol, methanol and iso-propyl alcohol is low are used on the manufacturing process of anti-static film, and the minimum ignition energy of these solvents is ignited easily despite less discharge energy form 0.16 mJ to 0.65 mJ. After the static electric potential produced on each of the manufacturing plants was measured, electric potential on films of paste board is measured form 17 kV to 20 kV. But this exceeds 5 kV, which is electrifiable of objective of nonconductor for fire & explode protection. Therefore, We figure out the fire hazard was high by a static discharge in anti-static film manufacturing factory.

• Aerospace Engineering and Technology
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• v.7 no.2
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• pp.67-75
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• 2008

The electrostatic charging/discharging mechanism and its effects, and the system design considerations in the space plasma environment are studied in this paper. The electrostatic discharge (ESD) effects are carefully taken into account for a design of the satellite system at the early stage of the development. Generally, the electrical design requirements are specified to protect the satellite system from the ESD effects in the electromagnetic compatibility specifications. Those requirements are included the grounding, the bonding, the shielding, the conductive coating, the electric interfacing and so on. The space charging is caused by the increasing of the voltage difference between the each locations on the satellite surface. If the space charging is continued up to threshold, it may be occurred the system failure. This phenomenon is depended on the mission of system, electrical and mechanical configuration, system operation, and orbit condition. Therefore the related requirements are properly tailored and concentrated into the safety design.

• JOURNAL OF ELECTRICAL WORLD
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• s.335
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• pp.37-52
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• 2004

접지설비는 다른 설비에 비해서 단지 부속설비처럼 안이하게 취급하는 경우가 많다. 그러나 접지설비는 전로의 이상전압을 억제하고 지락시의 고장전류를 안전하게 대지로 흘려 인체의 보호나 화재, 기기의 손상 등의 재해를 방지하는 것뿐만 아니라 제어기기를 안정하게 동작시키는 등의 역할을 위한 필수불가결한 설비이다. 특히 최근 전자기기의 급격한 증가에 따라 안정된 신호계를 확보하기 위한 접지설비가 다양화, 혼재화하고 있다. 접지를 하여야 할 설비에는 전력설비, 정보$\cdot$통신설비(신호, 제어, 유무선통신, 컴퓨터 등), 피뢰설비(피뢰침, 피뢰도선, 가공지선 등)를 비롯하여 정전기 제거설비, 유도장해 방지설비 등 여러 가지 설비가 있다. 접지는 기본적으로 대지에 전기적 단자를 접속하는 것으로 즉, 금속 등의 도전성 물체를 대지와 전기적으로 접속하여 도전성물체의 전위를 대지와 같은 전위 또는 전위차를 최소화시키는 것을 말한다. 금속체와 대지를 접속하는 단자의 역학을 하는 것이 접지전극(Grounding electrode)이라고 하며 보통은 지중에 매설되어 있는 도체가 사용된다. 접지전극과 접지를 하는 설비를 연결하는 도선을 접지도선 또는 접지선(Grounding conductor)이라고 한다. 따라서 접지설비를 설계하기 위해서는 접지의 목적, 기능, 종류를 정확하게 이해하여 접지시스템을 구축함과 동시에 적절한 접지개소, 접지선, 접지극을 선정하고 시공하여야 한다.

• Journal of the Korea Institute of Military Science and Technology
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• v.11 no.3
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• pp.154-160
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• 2008

We investigated molecular polarity by using theoretical means and comparing empirical solvent polarity. Our approach employed electrostatic potentials at the molecular surface calculated by density functional methods. A number of molecular descriptors related to molecular polarities were computed from molecular surface electrostatic potentials. Among computed molecular descriptors, the most positive electrostatic potential provided the best correlation with the empirical solvent polarities. A regression equation was developed in order to predict molecular polarities of molecules whose experimental solvent polarities were unknown. The new regression equations were utilized in estimating solvent polarities of cubane derivatives which are considered important precusors of high-energy density meterials.

• Journal of the Korean Magnetics Society
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• v.12 no.5
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• pp.168-173
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• 2002

Electrostatic discharge characteristics were studied by connecting human body model (HBM) with tunneling magnetoresistance (TMR) device in this research. TMR samples were converted into electrical equivalent circuit with HBM and it was simulated utilizing PSPICE. Discharge characteristics were observed by changing the component values of the junction model in this equivalent circuit. The results show that resistance and capacitance of the TMR junction were determinative components that dominate the sensitivity of the electrostatic discharge(ESD). Reducing the resistance oi the junction area and lead line is more profitable to increase the recording density rather than increasing the capacitance to improve the endurance for ESD events. Endurance at DC state was performed by checking breakdown and failure voltages for applied DC voltage. HBM voltage that a TMR device could endure was estimated when the DC failure voltage was regarded as the HBM failure voltage.

• Applied Biological Chemistry
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• v.43 no.1
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• pp.52-56
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• 2000

The influence of the 2-(4-(6-chloro-2-benzoxazolyloxy)phenoxy)-N-phenyl- propionamide derivatives on the herbicide activities against rice plant with pre-emergence and post-emergence in down land were examined and the structure activity relationship (SAR) were analyzed by Free-Wilson and Hansch method. In pre-emergence, the SAR approach is shown that the optimal, $({\pi})_{opt}=0.91$, hydrophobicity with electron donating effect of the ortho substituted mono substituents and 2,3,4-substituted three substituents were found to be contribute the herbicidal activity. Whereas, in post-emergence, the optimal, ({\pi})_{opt}=0.50$, hydrophobicity with electron withdrawing effect of meta substituted mono subsituents and 2,3-substituted two substituents were found to be contribute the herbicide activity. The herbicide activities with post-emergence more increase than that of pre-emergence. It is assumed from the SAR equations that the 2-methyl-3-methoxy-4-cyano group substituent is selected as the most lowest herbicide activity against rice plant with post-emergence in green house. The hydrolysis reaction was proceeded through nucleophilic addition-elimination (Ad_{Nu-E})$ with the orbital control between LUMO of substrate and HOMO of water molecule. And molecular electrostatic potential (MEP) of none (H) substituent was discussed.