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다양한 활성제 이온이 치환 고용된 MgNb2O6 형광체의 특성

  • Kim, Ji-Seon;Jo, Sin-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.167-167
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    • 2013
  • 최근에 산화물 형광체는 황화물 형광체에 비해 높은 화학적 안정성을 나타내기 때문에 백색 발광 다이오드, 전계방출 디스플레이와 플라즈마 디스플레이 패널에 그 응용성을 넓히고 있다. 마그네슘 니오베이트(magnesium niobate, MgNb2O6)는 우수한 유전 특성(상대 유전상수=18.4)을 나타내기 때문에 마이크로파 유전체로 응용 가능하며, 단일상 릴랙서 페라브스카이트(relaxor perovskite) Pb(Mg1/3Nb2/3)O3을 합성하기 위한 전구체 (precursor)로 널리 사용되고 있으며, 나이오븀산염 이온에서 다양한 색상을 방출하는 활성제 이온으로 효율적인 에너지 전달이 일어남으로써 Sm3+, Dy3+, Eu3+와 같은 희토류 이온의 좋은 모체 격자로 개발할 수 있다. 본 연구에서는 마그네슘 니오베이트 MgNb2O6 모체 결정에 다양한 활성제 이온, 즉 Eu3+, Sm3+, Dy3+, Tb3+를 선택적으로 주입하여 발광 효율이 높은 천연색 형광체를 합성하고자 한다. 특히, 모체 결정에 주입되는 활성제 이온 주위의 국소적인 환경이 반전 대칭에서 변형되는 척도를 조사하여 활성제의 주 발광 파장의 세기가 최대가 되는 최적의 조건을 결정하고자 한다. Mg1-1.5xNb2O6:REx3+ 형광체 분말 시료는 초기 물질 MgO, Nb2O5와 희토류 이온을 화학 반응식에 맞게 정밀 저울로 측량하여 플라스틱 용기에 ZrO2 볼과 함께 넣고, 소정의 에탄올을 채운 뒤 밀봉하고서, 300 rpm의 속도로 20시간 볼밀 (ball-mill) 작업을 수행하였다. 그 후, 체(sieve)로 ZrO2 볼을 걸러낸 다음에 혼합된 용액을 각 비커에 담아서 $40^{\circ}C$의 건조기에서 24시간 건조하였고, 건조된 시료를 막자 사발에 넣고 잘게 갈고 80 ${\mu}m$의 체로 걸러낸 후에, 알루미나 도가니에 활성제 이온별로 각각 담아, 전기로에 장입하여 매분당 $5^{\circ}C$의 비율로 온도를 상승시켜 $350^{\circ}C$에서 5시간 동안 하소 공정을 실시한 후에, 온도를 계속 일정한 율로 증가시켜 $1,200^{\circ}C$에서 5시간 동안 소성하여 합성하였다. 합성된 형광체 분말의 결정 구조는 $Cu-K{\alpha}$ 복사선(파장: 1.5406)을 사용하여 X-선회절장치로 측정하였으며, 형광체의 표면 형상은 전계형 주사전자현미경으로 관측하였다. 흡광와 발광스펙트럼은 제논 램프를 광원으로 갖는 형광 광도계를 사용하여 측정하였다. 모체 결정에 활성제 이온 Eu3+, Sm3+, Dy3+, Tb3+가 도핑된 형광체 분말은 각각 적색, 주황색, 황색, 녹색 발광이 관측되었다. 각 발광 스펙트럼과 결정 입자의 크기와 형상 사이의 상호 관계를 조사하였다. 실험 결과로부터, 각 형광체의 발광 파장은 활성제 이온의 종류 와 서로 밀접하게 관련되어 있으며, 형광체 시료 합성시 활성제 이온의 농도를 선택적으로 조절함으로써 발광의 세기를 제어할 수 있음을 확인하였다.

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Intertidal DEM Generation Using Waterline Extracted from Remotely Sensed Data (원격탐사 자료로부터 해안선 추출에 의한 조간대 DEM 생성)

  • 류주형;조원진;원중선;이인태;전승수
    • Korean Journal of Remote Sensing
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    • v.16 no.3
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    • pp.221-233
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    • 2000
  • An intertidal topography is continuously changed due to morphodynamics processes. Detection and measurement of topographic change for a tidal flat is important to make an integrated coastal area management plan as well as to carry out sedimentologic study. The objective of this study is to generate intertidal DEM using leveling data and waterlines extracted from optical and microwave remotely sensed data in a relatively short period. Waterline is defined as the border line between exposed tidal flat and water body. The contour of the terrain height in tidal flat is equivalent to the waterline. One can utilize satellite images to generate intertidal DEM over large areas. Extraction of the waterline in a SAR image is a difficult task to perform partly because of the presence of speckle and partly because of similarity between the signal returned from the sea surface and that from the exposed tidal flat surface or land. Waterlines in SAR intensity and coherence map can effectively be extracted with MSP-RoA edge detector. From multiple images obtained over a range of tide elevation, it is possible to build up a set of heighted waterline within intertidal zone, and then a gridded DEM can be interpolated. We have tested the proposed method over the Gomso Bay, and succeeded in generating intertidal DEM with relatively high accuracy.

Improvement of Ortho Image Quality by Unmanned Aerial Vehicle (UAV에 의한 정사영상의 품질 개선 방안)

  • Um, Dae-Yong;Park, Joon-Kyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.11
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    • pp.568-573
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    • 2018
  • UAV(Unmanned Aerial Vehicle) is widely used in space information construction, agriculture, fisheries, weather observation, communication, and entertainment fields because they are cheaper and easier to operate than manned aircraft. In particular, UAV have attracted much attention due to the speed and cost of data acquisition in the field of spatial information construction. However, ortho image images produced using UAVs are distorted in buildings and forests. It is necessary to solve these problems in order to utilize the geospatial information field. In this study, fixed wing, rotary wing, vertical take off and landing type UAV were used to detect distortions of ortho image of UAV under various conditions, and various object areas such as construction site, urban area, and forest area were captured and analysed. Through the research, it was found that the redundancy of the unmanned aerial vehicle image is the biggest factor of the distortion phenomenon, and the higher the flight altitude, the less the distortion phenomenon. We also proposed a method to reduce distortion of orthoimage by lowering the resolution of original image using DTM (Digital Terrain Model) to improve distortion. Future high-quality unmanned aerial vehicles without distortions will contribute greatly to the application of UAV in the field of precision surveying.

A Study on Point Cloud Generation Method from UAV Image Using Incremental Bundle Adjustment and Stereo Image Matching Technique (Incremental Bundle Adjustment와 스테레오 영상 정합 기법을 적용한 무인항공기 영상에서의 포인트 클라우드 생성방안 연구)

  • Rhee, Sooahm;Hwang, Yunhyuk;Kim, Soohyeon
    • Korean Journal of Remote Sensing
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    • v.34 no.6_1
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    • pp.941-951
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    • 2018
  • Utilization and demand of UAV (unmanned aerial vehicle) for the generation of 3D city model are increasing. In this study, we performed an experiment to adjustment position/orientation of UAV with incomplete attitude information and to extract point cloud data. In order to correct the attitude of the UAV, the rotation angle was calculated by using the continuous position information of UAV movements. Based on this, the corrected position/orientation information was obtained by applying IBA (Incremental Bundle Adjustment) based on photogrammetry. Each pair was transformed into an epipolar image, and the MDR (Multi-Dimensional Relaxation) technique was applied to obtain high precision DSM. Each extracted pair is aggregated and output in the form of a single point cloud or DSM. Using the DJI inspire1 and Phantom4 images, we can confirm that the point cloud can be extracted which expresses the railing of the building clearly. In the future, research will be conducted on improving the matching performance and establishing sensor models of oblique images. After that, we will continue the image processing technology for the generation of the 3D city model through the study of the extraction of 3D cloud It should be developed.

Cause of Rockfall at Natural Monument Pohang Daljeon-ri Columnar Joint (천연기념물 포항 달전리 주상절리의 낙석 발생원인)

  • Kim, Jae Hwan;Kong, Dal-Yong
    • Economic and Environmental Geology
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    • v.55 no.5
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    • pp.497-510
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    • 2022
  • Monthly monitoring, 3D scan survey, and electrical resistivity survey were conducted from January 2018 to August 2022 to identify the cause of rockfall occurring in Daljeon-ri Columnar Joint (Natural Monument No. 415), Pohang. A total of 3,231 rocks fell from the columnar joint over the past 5 years, and 1,521 (47%) of the falling rocks were below 20 cm in length, 978 (30.3%) of 20-30 cm, and 732 (22.7%) of rocks over 30 cm. While the number of rockfalls by year has decreased since 2018, the frequency of rockfalls bigger than 30 cm tends to increase. Large-scale rockfalls occurred mainly during the thawing season (March-April) and the rainy season (June-July), and the analysis of the relationship between cumulative rainfall and rockfall occurrence showed that cumulative rainfall for 3 to 4 days is also closely related to the occurrence of rockfall. Smectite and illite, which are expansible clay minerals, were observed in XRD analysis of the slope material (filling minerals) in the columnar joint, and the presence of a fault fracture zone was confirmed in the electrical resistivity survey. In addition, the confirmed fault fracture zone and the maximum erosion point analyzed through 3D precision measurement coincided with the main rockfall occurrence point observed by the BTC-6PXD camera. Therefore, the main cause of rockfall at Daljeon-ri columnar joint in Pohang is a combination of internal factors (development of fault fracture zones and joints, weathering of rocks, presence of expansive clay minerals) and external factors (precipitation, rapid thawing phenomenon), resulting in large-scale rockfall. Meanwhile, it was also confirmed that the Pohang-Gyeongju earthquake, which was continuously raised, was not the main cause.

Performance evaluation of hyperspectral image for morphological mapping (초분광 영상을 활용한 하상 측정 성능 평가 )

  • Youngcheol Seo;Dongsu Kim;Hojun You;Yeonghwa Gwon
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.225-225
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    • 2023
  • 하상 측정은 하천 유지관리, 수공구조물 설계 및 보수, 수생태 조사의 필수적인 자료이다. 최근 4대강 대규모 사업 이후 자연적 안정화로 인해 침식 및 재퇴적이 진행되어 정밀 하상 모니터링이 요구되고 있다. 통상적인 하상 조사 기법은 레벨측량 및 RTK-GPS 등을 활용하여 점단위로 직접 계측하는 기법과 수심이 깊을 경우 ADCP와 같은 음향측심기법을 통해 하상변동을 계측하고 있다. 하지만 점단위 직접 측정은 사구와 사련과 같은 하상 구조 교란 및 계측 시 위험을 동반하고 수심자료의 측정오차가 크게 발생하는 한계점이 존재한다. 또한 초음파 방식의 경우 막음길이와 바닥면 노이즈 등의 한계점으로 50 cm 미만의 저수심부 하상 측정이 불가능한 실정이다. 이러한 한계점을 극복하기 위해 최근 드론의 보급으로 수심라이다(Bathymetry LiDAR), SFM, 드론 탑재 초분광 영상을 활용한 초분광수심법과 같은 저고도, 고해상도의 비접촉식 면단위 하상 측정 기법이 대안으로 각광받고 있고 최근 관심은 해당 최신 기술의 성능 점검 및 적용성 평가에 있다. 따라서 본 연구에서는 초분광수심법 중 보편적으로 적용할 수 있는 최적밴드비분석(OBRA)의 성능 점검과 실무 적용성을 국내 하천을 대상으로 검토하였다. 해당 기술의 실무 적용성 평가항목 중 수심 적용 범위가 경제적이고 효율적인 성능 평가의 주된 항목이다. 선행 연구에 따르면 감천을 대상으로 저수심부의 성능 평가를 진행한 결과 상세한 하상계측이 가능하다고 제시하였다. 따라서 본 연구는 낙동강-황강 합류부를 대상으로 전형적인 평수기 탁도 조건에서 초분광수심법을 적용할 경우 최대측정가능수심의 범위를 결정하는 방법 및 결과를 제시하려고 한다. 또한 현장실험 당시 합천댐 방류로 인하여 황강의 탁도가 높아진 상태에 기인하여 고탁도 조건에서 초분광수심법의 적용성 평가도 추가 검토하였다. 해당 연구는 수심과 밴드비의 비선형성을 통해 최적 밴드비 분석의 결과로 도출될 수 있는 상관계수와 평균 제곱근 오차(RMSE)의 동향을 보아 다양한 시나리오의 배제수심을 통해 최대측정가능수심을 산정하였으며 그 이상의 범위는 수심맵 산정에서 제외하였다. 그 결과로 낙동강 본류에서 2.5 m 이하, 황강 지류에서 1.25 m 이하의 최대측정가능수심이 나타났고 해당 범위 이하에서는 상세한 하상이 나타났다. 또한 고탁도 조건인 황강에서는 낙동강에 비해 절반 수준의 최대측정가능수심 범위가 나타나 탁도 조건에 따른 초분광수심법의 한계가 있는 것을 확인하였다.

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Prediction of the Static Deflection Profiles on Suspension Bridge by Using FBG Strain Sensors (FBG 변형률센서를 이용한 현수교의 정적 처짐형상 추정)

  • Cho, Nam-So;Kim, Nam-Sik
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.5A
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    • pp.699-707
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    • 2008
  • For most structural evaluation of bridge integrity, it is very important to measure the geometric profile, which is a major factor representing the global behavior of civil structures, especially bridges. In the past, because of the lack of appropriate methods to measure the deflection profile of bridges on site, the measurement of deflection has been restricted to just a few discrete points along the bridge, and the measuring points have been limited to the locations installed with displacement transducers. Thus, some methods for predicting the static deflection by using fiber optic strain sensors has been applied to simply supported bridges. In this study, a method of estimating the static deflection profile by using strains measured from suspension bridges was proposed. Based on the classical deflection theory of suspension bridges, an equation of deflection profile was derived and applied to obtain the actual deflection profile on Namhae suspension bridge. Field load tests were carried out to measure strains from FBG strain sensors attached inside the stiffening girder of the bridge. The predicted deflection profiles were compared with both precise surveying data and numerical analysis results. Thus, it is found that the equation of predicting the deflection profiles proposed in this study could be applicable to suspension bridges and the FBG strain sensors could be reliable on acquiring the strain data from bridges on site.

A Simulation of a Small Mountainous Chachment in Gyeoungbuk Using the RAMMS Model (RAMMS 모형을 이용한 경북 소규모 산지 유역의 토석류 모의)

  • Hyung-Joon Chang;Ho-Jin Lee;Seong-Goo Kim
    • Journal of Korean Society of Disaster and Security
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    • v.17 no.1
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    • pp.1-8
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    • 2024
  • In Korea, mountainous areas cover 60% of the land, leading to increased factors such as concentrated heavy rainfall and typhoons, which can result in debris flow and landslide. Despite the high risk of disasters like landslides and debris flow, there has been a tendency in most regions to focus more on post-damage recovery rather than preventing damage. Therefore, in this study, precise topographic data was constructed by conducting on-site surveys and drone measurements in areas where debris flow actually occurred, to analyze the risk zones for such events. The numerical analysis program RAMMS model was utilized to perform debris flow analysis on the areas prone to debris flow, and the actual distribution of debris flow was compared and analyzed to evaluate the applicability of the model. As a result, the debris flow generation area calculated by the RAMMS model was found to be 18% larger than the actual area, and the travel distance was estimated to be 10% smaller. However, the simulated shape of debris flow generation and the path of movement calculated by the model closely resembled the actual data. In the future, we aim to conduct additional research, including model verification suitable for domestic conditions and the selection of areas for damage prediction through debris flow analysis in unmeasured watersheds.

The 2009-based detailed distribution pattern and area of Phragmites communis-dominant and Suaeda japonica-dominant communities on the Suncheon-bay and Beolgyo estuarine wetlands (순천만과 벌교 하구 연안습지의 2009년 기준 갈대 및 칠면초 우세 군집 분포양상과 면적 제시)

  • Hong, Seok Hwi;Chun, Seung Soo;Eom, Jin Ah
    • Journal of Wetlands Research
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    • v.17 no.1
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    • pp.26-37
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    • 2015
  • Halophyte distribution pattern and area in the Suncheon-bay and Beolgyo estuary coastal wetlands were analyzed using KOMPSAT-2 landsat images were taken in 2008 and 2009, and field investigations were fulfilled for confirming the precise boundaries of individual halophyte areas. The salt-marsh vegetation in those areas can be classified mainly into two dominant communities: Suaeda japonica-dominant and Phragmites communis-dominant communities. In order to identify sedimentary characteristics, tidal-flat surface leveling and sedimentary facies analysis had been conducted. The sedimentary facies of marsh area are mostly silty clayey and clay facies with a little seasonal change and its slope is very gentle (0.0007~0.002 in gradient). Phragmites communis and Suaeda japonica communities were distributed in the mud-flat zone between 0.7 m and 1.8 m higher than MSL (mean sea level): zone of 1.1~1.8 m in the former and zone of 0.7~1.3 m in the latter. In the Suncheon-bay estuarine wetland, on the basis of 2009 distribution, Phragmites communis-dominant and Suaeda japonica-dominant communities are about $0.79km^2$ and $0.22km^2$ in distribution area, respectively. On the other hand, Bulgyo estuarine marsh shows that the distribution areas of Phragmites communis-dominant and Suaeda japonica-dominant communities are about $0.31km^2$ and 0.031km2 in distribution area, respectively. Individual 105 and 60 dominant community areas and their distribution patterns can be well defined and indicated in the Suncheon-bay and Bulgyo estuarine marshes, respectively. The distribution pattern and area of hylophyte communities analyzed in this study based on 2008/2009 satellite images would be valuable as a base of future monitoring of salt-marsh related studies in the study area which is the most important salt-marsh research site in Korea.

Three dimensional GPR survey for the exploration of old remains at Buyeo area (부여지역 유적지 발굴을 위한 3차원 GPR 탐사)

  • Kim Jung-Bo;Son Jeong-Sul;Yi Myeong-Jong;Lim Seong-Keun;Cho Seong-Jun;Jeong Ji-Min;Park Sam-Gyu
    • 한국지구물리탐사학회:학술대회논문집
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    • 2004.08a
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    • pp.49-69
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    • 2004
  • One of the important roles of geophysical exploration in archeological survey may be to provide the subsurface information for effective and systematic excavations of historical remains. Ground Penetrating Radar (GPA) can give us images of shallow subsurface structure with high resolution and is regarded as a useful and important technology in archeological exploration. Since the buried cultural relics are the three-dimensional (3-D) objects in nature, the 3-D or areal survey is more desirable in archeological exploration. 3-D GPR survey based on the very dense data in principle, however, might need much higher cost and longer time of exploration than the other geophysical methods, thus it could have not been applied to the wide area exploration as one of routine procedures. Therefore, it is important to develop an effective way of 3-D GPR survey. In this study, we applied 3-D GPR method to investigate the possible historical remains of Baekje Kingdom at Gatap-Ri, Buyeo city, prior to the excavation. The principal purpose of the investigation was to provide the subsurface images of high resolution for the excavation of the surveyed area. Besides this, another purpose was to investigate the applicability and effectiveness of the continuous data acquisition system which was newly devised for the archeological investigation. The system consists of two sets of GPR antennas and the precise measurement device tracking the path of GPR antenna movement automatically and continuously Besides this hardware system, we adopted a concept of data acquisition that the data were acquired arbitrary not along the pre-established profile lines, because establishing the many profile lines itself would make the field work much longer, which results in the higher cost of field work. Owing to the newly devised system, we could acquire 3-D GPR data of an wide area over about $17,000 m^2$ as a result of the just two-days field work. Although the 3-D GPR data were gathered randomly not along the pre-established profile lines, we could have the 3-D images with high resolution showing many distinctive anomalies which could be interpreted as old agricultural lands, waterways, and artificial structures or remains. This case history led us to the conclusion that 3-D GPR method can be used easily not only to examine a small anomalous area but also to investigate the wider region of archeological interests. We expect that the 3-D GPR method will be applied as a one of standard exploration procedures to the exploration of historical remains in Korea in the near future.

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