• Journal of the Korean Applied Science and Technology
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• v.35 no.1
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• pp.141-150
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• 2018

Mussel byssal protein has strong adhesive capability even in wet surface. It has been reported that nine proteins in marine blue mussel, often referred to a representative mussel, contribute to form mussel byssal threads and plaques. DOPA containing two hydroxy groups called cathecol is recognized that it plays a major role in adhesion as well as cohesion process within byssal structure. In this paper, adhesion and cohesion mechanisms were introduced and evaluated by supportive literature published during last decade. Diverse applications of cathecol chemicals were also examined in terms of innovative adhesive, bioadhesive and challenging material for tissue engineering. It is noticeable that reconsideration of mussel proteins could provide the various opportunities as biomaterials.

• Journal of Adhesion and Interface
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• v.4 no.1
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• pp.18-27
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• 2003

Interfacial properties and microfailure degradation mechanisms of the oxygen-plasma treated biodegradable poly(p-dioxanone) (PPDO) fiber/poly(L-lactide) (PLLA)composites were investigated for the orthopedic applications as implant materials using micromechanical technique and surface wettability measurement. PPDO fiber reinforced PLLA composite can provide good mechanical performance for long hydrolysis time. The degree of degradation for PPDO fiber and PLLA matrix was measured by thermal analysis and optical observation. IFSS and work of adhesion, $W_a$ between PPDO fiber and PLLA matrix showed the maximum at the plasma treatment time, at 60 seconds. Work of adhesion was lineally proportional to the IFSS. PPDO fiber showed ductile microfailure modes at We initial state, whereas brittle microfailure modes appeared with elapsing hydrolysis time. Interfacial properties and microfailure degradation mechanisms can be important factors to control bioabsorbable composites performance because IFSS changes with hydrolytic degradation.

• Journal of Adhesion and Interface
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• v.3 no.2
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• pp.17-29
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• 2002

Interfacial properties and microfailure degradation mechanisms of the bioabsorbable composites for implant materials were investigated using micromechanical technique and measurement of surface wettability. As hydrolysis time increased, the tensile strength, the modulus and the elongation of poly(ester-amide) (PEA) and bioactive glass fibers decreased, whereas those of chitosan fiber almost did not change. Interfacial shear strength (IFSS) between bioactive glass fiber and poly-L-lactide (PLLA) was much higher than PEA or chitosan fiber/PLLA systems using dual matrix composite (DMC) specimen. The decreasing rate of IFSS was the fastest in bioactive glass fiber/PLLA composites whereas that of chitosan fiber/PLLA composites was the slowest. Work of adhesion, $W_a$ between bioactive glass fiber and PLLA was the highest, and the wettability results were consistent with the IFSS. Interfacial properties and microfailure degradation mechanisms can be important factors to control bioabsorbable composite performance.

• Journal of Adhesion and Interface
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• v.2 no.2
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• pp.11-19
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• 2001

The phase-transfer catalyzed radical polymerization of styrene was carried out using tricaprylylmethylammonium chloride as a phase-transfer catalyst in a two-phase system of an aqueous $Na_2S_2O_8$ solution and toluene at $60^{\circ}C$ under nitrogen atmosphere. The initial rate of radical polymerization was expressed as the combined terms of concentrations of quaternary onium cation and peroxydisulfate anion in the aqueous phase rather than the fed concentrations of catalyst and $Na_2S_2O_8$. The observed initial rate of radical polymerization was used to analyze the radical polymerization mechanism with a cycle phase-transfer initiation step in the heterogeneous liquid-liquid system. The viscosity average molecular weight of polystyrene was inversely proportional to concentration of $Na_2S_2O_8$ expressed as $[Q^+]([S_2O{_8}^{2-}]{\alpha}_2)^{1/2}$ derived by the radical polymerization mechanism.

• Journal of the Korea Concrete Institute
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• v.13 no.2
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• pp.168-174
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• 2001

Carbon fiber sheet(CFS) has been widely used for strengthening of the concrete building structures due to its excellent physical properties such as high strength, light weight and high durability. Bond strength or behavior, on the other hands, between carbon fiber sheet and concrete is very important in strengthening the concrete member using CFS. Therefore the bond failure mechanism between CFS and concrete should be fully verified and understood. This study is to investigate the bond strength of CFS to the concrete by the direct pull-out test and the tensile-shear test. In the direct pull-out tests, the bond strength under the various environmental conditions such as curing temperature, surface condition on concrete and water content of concrete are evaluated. Also, the effective bond length, lu and the average bond stress, $\tau$y are examined in the tensile-shear tests. Based on the test results, it is concluded that the curing temperature is the most critical element for the bond strength between CFS and concrete. And, the proper value of lu and $\tau$y is recommended with 15 cm and 9.78∼ 11.88 kgf/$\textrm{cm}^2$ respectively.

• Tunnel and Underground Space
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• v.20 no.4
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• pp.267-276
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• 2010

In modern rock engineering practice, fully grouted rock bolting is actively employed as a major supporting system, so that understanding the behavior of fully grouted rock bolts is essential for the precise design of rock bolting. Despite its importance, the supporting mechanism of rock bolts has not been fully understood yet. Since most of existing analytical models for rock bolts were developed by drastically simplifying their boundary conditions, they are not suitable for the bolts of in-situ condition. In this study, 3-D elastic FE analysis of fully grouted rock bolts has been conducted to provide insight into the supporting mechanism of the bolt. The distribution of shear and axial stresses along the bolt are investigated with the consideration of different boundary conditions including three different displacement boundary conditions at the bolt head, the presence of intersecting rock joints, and the variation of elastic modulus of adjacent rock. The numerical result reveals that installation of the faceplate at the bolt head plays an important role in mobilizing the supporting action and enhancing the supporting capabilities of the fully grouted rock bolts.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2006.06a
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• pp.311-312
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• 2006

선박의 추진축은 선박의 기관실 최말단부에서 바깥의 프로펠러까지 선체를 관통하여 설치되고 회전하기 때문에 선외로부터의 해수유입을 쳐대한 차단하는 역할을 하는 독특한 메커니즘을 가진 축밀봉장치(Shaft Sealing System)를 필요로 하는데 이것을 스턴튜브 씰(Stem Tube Seal)이라고 한다. 본 연구는 국내 중소형 선사들이 저렴한 가격대비 우수 품질의 씰 및 하우징을 사용할 수 있고 3차원 형상화를 통하여 선박의 운용자가 쉽고 정확하게 스턴튜브 씰을 이해 및 신속 정비가능, 해외업체 생산 규격을 선박 축에 맞게 절단, 접합의 씰 성능저하 관행을 고쳐 선주가 원하는 사양과 규격대로 제작된 우수한 씰 제품을 공급할 수 있고, 선박용 기자재에 대한 기초지식, 씰링 메카니즘, 구조 및 유동 해석 결과를 제공하여 국내 최초의 무접착 원형 메인 씰 개발 및 씰 하우징 제작 및 독자설계 기술을 확립하고자 한다.

• Journal of the Korea Concrete Institute
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• v.14 no.1
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• pp.126-135
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• 2002

Plate bonding technique has been widely used in strengthening of existing concrete structures, although it has often a serious problem of premature falure such as interface separation and rip-off. However, this premature failure problem has not been well explored yet especially in view of local failure mechanism around the interface of plate ends. The purpose of the present study is, therefore, to identify the local failure of strengthened plates and to derive a separation criterion at the interface of plates. To this end, a comprehensive experimental program has been set up. The double lap pull-out tests considering pure shear force and half beam tests considering combined flexure-shear force were performed. The main experimental parameters include plate thickness, adhesive thickness, and plate end arrangement. The strains along the longitudinal direction of steel plates have been measured and the shear stress were calculated from those measures strains. The effects of plate thickness, bonded length, and plate end treatment have been also clarified from the present test results. Nonlinear finite element analysis has been performed and compared with test results. The Interface properties are also modeled to present the separation failure behavior of strengthened members. The cracking patterns as well as maximum failure loads agree well with test data. The relation between maximum shear and normal stresses at the interface has been derived to propose a separation failure criterion of strengthened members. The present study allows more realistic analysis and design of externally strengthened flexural member with steel plates.

• Composites Research
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• v.16 no.4
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• pp.74-79
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• 2003

Comparison of interfacial properties and microfailure mechanisms of oxygen-plasma treated poly(p-phenylene-2,6-benzobisoxazole(PBO. Zylon) and poly(p-phenylene terephthalamide)(PPTA, Kevlar) fibers/ epoxy composites were investigated using micromechanical technique and nondestructive acoustic emission(AE). Interfacial shear strength(IFSS) and work of adhesion, Wa of PBO or Kevlar fibers/epoxy composites increased by oxygen-plasma treatment. Plasma-treated Kevlar fiber shooed the maximum critical surface tension and polar term, whereas the untreated PBO fiber showed the minimum value. Microfibril fracture pattern of plasma-treated Kevlar fiber appeared obviously. Based on the propagation of microfibril failure toward core region. the number of AE events for plasma-treated PBO and Kevlar fibers increased significantly. The results oi nondestructive AE were consistent well with microfailure modes by optical observation in microdroplet and two-fiber composites tests.

• Elastomers and Composites
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• v.35 no.1
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• pp.63-70
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• 2000

Zinc plated steel tire cords were subjected to RF plasma etching of argon, followed by plasma polymerization coating of acetylene or butadiene in order to enhance adhesion to rubber compounds. Plasma polymerization was carried out under optimized conditions of 10 W, 30 sec, 30 mTorr for acetylene and butadiene gas, while plasma etching was performed at 90W, 10min and 30mTorr. The adhesion of tire cords was evaluated via Tire Cords Adhesion Test (TCAT) and the failure surfaces of the tested samples were analyzed by SEM. Polymer coating by plasma polymerization was also characterized by FT-IR, Alpha-Step and dynamic contact angle analyzer in order to elucidate the adhesion mechanism.