• Title/Summary/Keyword: 점착강도

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Synthesis of Water-based Acryl Pressure Sensitive Adhesive for Skin Using Reactive Emulsifier (반응성 유화제를 이용한 피부용 수성 아크릴 점착제의 합성 및 특성)

  • Lee, Sang-Chul;Jeong, Noh-Hee
    • Applied Chemistry for Engineering
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    • v.30 no.3
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    • pp.352-357
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    • 2019
  • In this study, a reactive emulsifier with vinyl groups was synthesized by using 3-butenoic acid and polyoxyethylene(20) stearyl ether. The synthesized reactive emulsifier was confirmed by FT-IR and $^1H-NMR$. In addition, the reactive emulsifier synthesized in the preparation of aqueous acrylic pressure sensitive adhesives was used and the properties of the respective pressure sensitive adhesives were compared to those of using commonly used nonionic emulsifiers. The solid content was measured in the range of 56.8~57.4%. In the case of the initial adhesion, the S20BA made with a reactive emulsifier was measured as $^{\sharp}13$. Peel strengths of the prepared adhesives were measured in the range of $0.66{\sim}1.05kg_f$ and the highest peel strength was observed for S20BA. As a result of the heat resistance test, S20BA showed the highest as $840^{\circ}C$. In order to evaluate the applicability of adhesives for skin, the pH value was measured as 7, neutral and also it was found to be non-irritation from primary skin irritation test results.

Immobilization of Trichoderma harzianum ATCC52445 into Natural Matrix (천연 담체를 이용한 Trichoderma harzianum ATCC52445의 고정화)

  • 이종수;최영준복성해이준식
    • KSBB Journal
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    • v.10 no.2
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    • pp.166-169
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    • 1995
  • Spores of Trichoderma harzianum TCC 52445 for control of Rhlzocronia stem canker on potato were immobilized in various natural matrix, and germination rate and some rheological properties of the spore-matrix complex were Investigated. Germination rate of gelatin gel-spore complex and potato starch gel-spore complex were 2.8% and 2.9%, respectively, but hardness and cohesiveness of the gelstin gel-spoke complex were better than those of potato starch-spore complex. The hardness and cohesiveness were increased when the spores were immobilized in hybrid gelatin gel made by mixing several different types of natural matrix, but decreased their germination rate. Addition of corn steep liquor (1%) as spore nutrient in gelatin gel-spore complex was helpful for increasing the germination rate.

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An Experimental Study of Strength Evaluation in Frozen Soils according to Direct Shear Box Systems (직접전단상자 시스템에 따른 동결토의 강도 평가에 관한 실험적 연구)

  • Kim, Sang Yeob;Kim, YoungSeok;Lee, Jangguen;Lee, Jong-Sub
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.3
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    • pp.5-14
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    • 2017
  • Experimental study on strength characteristics of frozen soils is necessary for the safety evaluation of design and construction in cold region. The objective of this study is to evaluate the direct shear strength of frozen soils obtained from traditional system (Type-1), system with roller on the upper shear box (Type-2), and system with fixed upper shear box separated from bottom shear box (Type-3). Specimens mixed with sand, silt, and water are frozen to $-5^{\circ}C$, and then direct shear tests are conducted under the normal stress of 5, 10, 25, and 50 kPa. Experimental results show that the upper shear box of Type-1 touches the bottom shear box due to the rotation of the upper shear box. The shear strength obtained from Type-2 is overestimated because the preventing rotation force is added to shear force. Type-3 may acquire the only strength of the specimen, and shear strain at peak shear strength is similar to that at the beginning of vertical displacement occurrence. In addition, internal friction angle and cohesion at both peak and residual stresses in Type-3 are smaller than those of Type-2. This study shows that high strength specimens including frozen soils can be effectively evaluated using improved shear box system such as Type-3.

A Study on the Liquefaction Behavior of Soil in Jangbogo Station (남극 장보고기지 현장시료의 액상화거동 특성 연구)

  • Park, Keunbo;Kim, YoungSeok
    • Journal of the Korean Geosynthetics Society
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    • v.13 no.2
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    • pp.49-57
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    • 2014
  • In this study, in order to take advantage of samples collected in the Jangbogo station, and to grasp the liquefaction resistance characteristics of the dynamic load was performed cyclic triaxial test. Also, through the comparison with the existing literature. The test results, for the relationship between number of cycles for the same cyclic shear stress ratio and the cyclic shear stress ratio to produce an axial strain of 5%, in all samples, the cyclic shear stress ratio to liquefaction for the specimen, which has been liquefied, was increased, whereas number of cycles were reduced. The cyclic shear stress ratio of samples first decrease up to the fine content of about 10%. After this strength level, there is a little increase in cyclic shear stress ratio with increasing fine content. In addition, the cyclic shear stress ratio between cohesive strength, mean particle size, and friction angle decrease but some time later, there was a tendency that cyclic shear stress ratio is a little increased.

Characteristic Analysis of Shear Strength of Rock Slope Discontinuity in Yangsan Fault System (양산단층대 암반비탈면에 분포하는 불연속면의 전단강도 특성분석)

  • Lee, Hak-Ju;Kim, Chang-Ho;Hwang, Woong-Ki;Kim, Tae-Hyung
    • Journal of the Korean Geosynthetics Society
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    • v.18 no.3
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    • pp.11-22
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    • 2019
  • This study was conducted to identify the causes of the unusually high number of rock slope failures during an expressway construction in Yangsan fault system. The shear strength (cohesion and internal friction angle) of 128 slopes of discontinuities including bedding, joint, and fault planes were re-evaluated through the examination of face mapping and back analysis. The re-evaluated values were analyzed and then compared with the existing data and values used in the design. As a result, the re-evaluated cohesion and friction angles were very low compared to the existing data and the values applied in the design. This incongruity was pointed as the primary reason for the rock slopes failures during the construction. This may be related to the inherent features of clastic sedimentary rocks in the study area, and the discontinuities in the sedimentary rocks in this region played a significant role. Especially, bedding discontinuity showed a big difference compared to the existing data. The shear strength depended on the type of discontinuity in case of clay filled in discontinuity. However, shear strength was independent on the type of discontinuity in case of shattered materials filled in discontinuity.

Evaluation of Environmental Stability and Durability of Cementitious Mixed Soil (시멘트계 혼합토의 환경안정성 및 내구성 평가)

  • Oh, Sewook;Bae, Wooseok;Kim, Hongseok
    • Journal of the Korean GEO-environmental Society
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    • v.23 no.9
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    • pp.17-23
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    • 2022
  • Using cement as a road subbase is economical, easily modified and supplemented and has excellent road pavement quality control. In addition, cement adheres well to sandy soils without adhesion, and it plays a role of permanently preserving adhesion in viscous soils with adhesion, so it can be widely applied as stable treatment with the advantages of increased strength, reduced compressibility. and improved durability. However, while cement is excellent in terms of strength for a road subbase, the material properties mean that it is difficult to maintain and reinforce when cracks or fractures occur due to dry shrinkage, and the pH increases in the ground due to hexavalent chromium eluting from cement. which can cause environmental problems such as groundwater contamination. Therefore, this study evaluates the usability of alternatives in the road base layer such as environmentally cementitious stabilizer and on-site soil generated from the site. We intend to reduce the environmental damage and evaluate the durability. To evaluate the applicability of the site, Environmental stability test and freeze-thaw test and wetting-drying test was conducted to evaluate the strength characteristics of alternative materials on the road through the limited performance evaluation of environmentally cementitious stabilizer. The test ranges were set at mixing ratios of 10%, 20%, and 30% and ages of three days, and 28 days old to evaluate the early strength and reference strength according to the mixing ratio of the environmentally cementitious stabilizer.

Study of two phase flow and erosion characteristic in SRM nozzle (고체 추진제 로켓 노즐 내부의 2상 유동 및 마모 특성에 관한 연구)

  • 김완식;조형희;배주찬
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1998.10a
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    • pp.32-32
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    • 1998
  • 고체 추진제 로켓의 연소시에 발생되는 산화 알루미늄(A1$_2$O$_3$) 입자는 로켓 추진 노즐에서 팽창과정의 효율을 저하시키는 요소가 되며, 이러한 비효율성은 연소 가스와 입자간의 비평형 상태 효과와 기본적인 속도와 열적 차이에 의해서 발생된다고 보고되었다. 또한 연소시 발생된 산화 알루미늄 입자는 높은 열과 큰 운동량을 가지고 로켓 노즐 내부를 유동하게 되며, 매우 많은 량이 짧은 시간에 고온 고속으로 노즐 벽면이나 기타 구조물에 충돌 및 점착하기 때문에 로켓 노즐내의 표면이 손상을 입게 되고, 로켓의 방향 제어 및 조정 안정성이 저하되며, 구조적인 강도가 약화 될 수 있다. 또한 산화 알루미늄 액적들의 경우 노즐 벽면에 고착되게 되면 로켓의 중량 증가로 인해서 추력의 손실을 초래할 수 있다. 따라서 이러한 연소 부산물들의 운동 경로와 충돌 위치 및 표면에서의 충돌량과 그리고 충돌에 따른 마모량 및 점착 그리고 열전달 특성을 예측하는 것이 필수적이다.

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Peel Stength of the Acrylic Copolymer and Pressure Sensitive Adhesives (아크릴계 점착제의 박리강도와 점착부여제)

  • 김현중
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.1
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    • pp.79-88
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    • 1999
  • The stability and performance (peel strength) of the acrylic copolymer and various modified rosin systems were investigated. The peel strength was measured over a wide range of scaling rates, and the influence of the viscoelasticity of the PSA(pressure sensitive adhesive) was considered. In the case of miscible systems, the peak of peel strength (PSA performance) over wide peel rates was changed and modified systematically with increasing glass transition temperature of the blends. The peak of the peel strength for blended systems shifts toward the lower rate side as glass transition temperature ($T_g$) of the blend increased. The influence of esterification of the rosin on performance and stability against deterioration was greatly modified by blending with rosin of glycerol ester and rosin pentaerythritol ester. The failure mode of the blend varies with the combination with acrylic copolymer and modified rosin, and cohesive failure was found at a lower peel rate while interfacial failure was found at a high peel rate. A few systems where a single Tg could be measured, despite the fact that two phases were observed microscopically, were detected.

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In situ measurement of settling velocity for suspended floc sediment with BW method (BW 방법을 이용한 현장 부유 플록 침강속도 측정)

  • Jung, Eui-Taek;Kim, Dong-Ho;Heo, Je-Woo;Hwang, Kyu-Nam
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.722-726
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    • 2012
  • 각 해역의 부유 플록은 그 해역의 조건에 따라 각기 다르게 형성된 플록이므로, 부유 플록 자체의 특성(결합강도, 밀도 및 크기 등)은 현장특성에 따라 현저하게 다른 "site-specific"한 특성을 가질 뿐만 아니라, 동일 해역이라 하더라도, 조류 등에 의한 유속변화에 따른 흐름전단응력의 증감에 따라 플록의 특성 또한 시간적으로 크게 변화할 수 있다. 이에 현장의 플록 특성이 반영된 부유플록의 침강속도를 산정하기 위해 입도 측정원리중 하나인 BW방법을 응용한 전북대 Owentube를 자체 제작하여 연구가 수행되었으며, 본 연구를 통하여 도출된 현장에서의 점착성 부유 플록의 침강속도 산정 결과는 향후 퇴적물 이송 및 수질 예측을 위한 수치모형 적용시에 필수적으로 요구되는 침강 및 퇴적특성 입력자료로 유용하게 사용될 수 있을 것이다.

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Classification of Shear Strength according to Breccia Content in Fault Core (단층각력 함량에 따른 전단강도의 분류)

  • Yun, Hyun-Seok;Moon, Seong-Woo;Seo, Yong-Seok
    • Economic and Environmental Geology
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    • v.53 no.2
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    • pp.167-181
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    • 2020
  • Analysis of variance (ANOVA) and multiple comparison analysis were performed for shear strengths categorized by breccia content of 5 wt.% (Case-I), 10 wt.%, (Case-II) and 15 wt.% (Case-III) in fault cores. The relationship between breccia contetnt and shear strength was quantitatively classified by calculating the mean and standard deviation of shear strength for each population in each case and then the grouping the breccia contents that had a statistically similar effect on the dispersion of shear strength. As a result, shear strength was clearly classified into group 1 (breccia content of 0-15 wt.%) and group 2 and 3 (breccia coantent of 15-30 wt.% and 30 wt.% or more) in Case-III. Shear strength of the standard line at breccia content of 15 wt.% were determined to be 43.6 kPa, 77.6 kPa, and 118.6 kPa at each normal stress (54 kPa, 108 kPa, and 162 kPa), respectively. In addition, the distribution range of cohesions is 0-43.6 kPa at breccia content of 15 wt.% or less, and 0-70.0 kPa at 15 wt.% or more. Distribution range of friction angles is 0-45.7 ° at breccia content of 15 wt.% or less, and 16.7-57.5 ° at 15 wt.% or more.