• Applied Chemistry for Engineering
• /
• v.2 no.3
• /
• pp.253-261
• /
• 1991

Polyamic acids, precursor polymers of polyimides have been obtained by the solution polycondensation of benzophenone tetracarboxylic dianhydride (BTDA) with 4, 4'-diamino diphenyl methane (MDA) and/or 3, 3'-dimethyl benzidine (OTB). The reaction was carried in two solvent systems such as m-cresol and m-cresol/xylene mixture. The results of TGA analysis showed that the polyimide films had good thermal stability with the initial decomposition temperature ranging from $540^{\circ}$ to $590^{\circ}$. According to DSC analysis of polymers, the glass transition temperature was over $340^{\circ}$. Polyimide film samples, showed good mechanical and electrical properties, had over $16Kg/mm^2$ of tensile strength and about 200 KV/mm of dielectric breakdown voltage. The properties of the copolymer from MAD/OTB were better than those of the homopolymer from MDA. And the polymer synthesized in m-cresol had lower properties than that obtained in m-cresol/xylene.

• Korean Journal of Materials Research
• /
• v.2 no.1
• /
• pp.43-51
• /
• 1992

Thin films of )$Pb(Zr, \;TiO_3$ are fabricated by MOCVD using ultrasonic spraying. The films having perovskite structure are made at low deposition temperature, $300-450^{\circ}C$. The phase and composition of the films vary with the composition of the starting solution and the deposition temperature. Dielectric constant of the films is 187 at 1MHz. Ferroelectric hysterysis loop measurements indicate a remanant polarization of $5.5{\mu}C/cm^2$, and coercive field of 65kV/cm. Resistivity of thin films is about $10^{11}{\Omega}cm$ and the breakdown electric field abort 35kV/cm.

• Korean Journal of Materials Research
• /
• v.3 no.4
• /
• pp.352-360
• /
• 1993

A nitride layer was df'posited on the thermal oxide layer by LPCVD process. ONO(oxidenitricle oxide) capacitors with various thickness of component layer wore fabricated by wet reoxidation of the nitride with and without anrwalmg treatment and their properties were investigated. As a result of observation on the refrative index and etching behavior of the ONO fIlms, the nitride layer OF 40 A thick ness was not so dense that the bottom oxide during the reoxidation process and the capability of securing the capacitance decreased. The conduction current in the ONO multl-Iayer dielctric film was reduced as the bottom(or top) oxide layer became thicker. However, in the case of oxide with thickness more than 50A, it merely plays a factor of reduction in capacitance, and the effect of barrier for hole injection was not so much increased. Annealing of the nitride laypr bpfore reoxidation did not show a grpat effects on the refractive index and capacitance of the film, however, the annealing process increased the breakdown voltage by 2${\cdot}$V.

• Fire Science and Engineering
• /
• v.25 no.1
• /
• pp.50-56
• /
• 2011

In recently years, occurrences of lightning return strokes have been increased by global worming effect and intensity of lightning impulse voltage and current accompanied by lightning discharges has being strengthening. In Korea, 560 thousand lightning discharges happened in 200S. According to the increasing frequencies of lightning, human deaths and damages to the structure have been increased steadily. Electric fire caused by lightning return strokes due to the breakdown between power line and ground line from the ground potential rise on a process of the lightning impulse current through to the ground. The damages of lightning were occurring at same time in the neighboring areas of the lightning point. In order to protect from the lightning stroke, we made a suggestion to use protection devices and equipotential bonding at the dangerous areas. The analysis results of electric fires caused by lightning would be utilized to investigate and to find accurate fire cause in the fire scenes.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.25 no.2
• /
• pp.131-136
• /
• 2011

This paper aims to examine the possibility of using an environmentally friendly $N_2$ as an alternative gas to $SF_6$. For this purpose, we have investigated breakdown characteristics of $N_2$ under impulse voltages in a quasi-uniform electric field gap. The 1.2/50[${\mu}s$] lightning impulse voltage, switching impulse voltages and oscillatory impulse voltages were applied at the test gap. The electric field utilization factor ranges from 0.5 to 0.8. The experimental data of $SF_6$ and $N_2$ acquired in the same experimental condition are presented in parallel for comparison. As a result, the breakdown voltages in $SF_6$ and $N_2$ are linearly increased with the gas pressure, also the breakdown voltages in $N_2$ are increased with increasing the gap distance and electric field utilization factor. The positive breakdown voltages are higher than the negative breakdown voltages. The nagative basic lightning impulse withstand level of 150[kV] in $N_2$ of about 0.5[MPa] is nearly equal to that in $SF_6$ of 0.15[MPa]. It is seen from the results obtained in this work that $N_2$ can be used as an eco-friendly alternative gas to $SF_6$ in distribution power equipment.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.22 no.4
• /
• pp.54-60
• /
• 2008

It is impossible to database(DB) the patterns of power cable events and cause analysis of faulted cable because the product liability(PL) law have been enforced in Korea, since 2002. In additions, simulation and pattern of power cable events are needed for DB system under accelerated deterioration. In this paper, we tested for resistance to cracking of cable below the 22.9[kV] class due to thermal stresses. This method of exam is following IEC 60811-3-1(Common test methods for insulating and sheathing materials of electric cables). From the results, The 22.9[kV] class A power cable was discolored on the surface and significantly reduced in the longitudinal direction. As the thermal weight properties of A power cable was definitely varied, we are able to guess the problem of manufacture. If the cable was defect by the manufacture, the victims would be able to claim for damage in the PL system.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.59 no.8
• /
• pp.1416-1422
• /
• 2010

$SF_6$ is the most commonly used insulating gas in electrical systems. But In these days $SF_6$ mixtures and alternative gas has been studied because of global warming. so although many studies have been carried out about binary gas mixtures with $SF_6$, few studies were presented about breakdown characteristics of $SF_6/N_2$ mixtures. At present study the breakdown characteristics of $SF_6/N_2$ mixtures in Non-uniform field was performed. In this paper, The simulation value are compared with experiment values. Streamer breakdown criterion was used for predicting breakdown voltage. For accurate simulation this simulation apply utilization factor using CST(computer simulation technology) EM $studio^{tm}$ program. AC breakdown experiments in non-uniform field was performed to compare with the breakdown simulation values. The pressure range of gas mixtures was 0.4 MPa to 0.7 MPa. The rod-plane was used and mixture ratio is $SF_6$ 20% : $N_2$ 80%. The gap lengths are 10mm to 70mm. As the pressure increase, this simulation value does not correspond to the experiment value. So this simulation need surface roughness factor. As a result of applying surface roughness factor this simulation decrease a relative error (|experiment value - simulation value| /simulation value).

• Proceedings of the KIEE Conference
• /
• 2009.07a
• /
• pp.1455_1456
• /
• 2009

$SF_6$ is the most commonly used insulating gas in electrical systems. But In these days $SF_6$ mixtures and alternative gas has been studied because of global warming. so although many studies have been carried out about binary gas mixtures with $SF_6$, few studies were presented about breakdown characteristics of $SF_6/CF_4$ mixtures. At present study the breakdown characteristics of $SF_6/CF_4$ mixtures in quasi-uniform field was performed. This experiments were carried out under AC voltages. The rod-rod electrode was used with 5 mm gap distance. The mixture of $SF_6/CF_4$ containing 20%,50%,70% of $SF_6$ were compared with pure $SF_6$ and $CF_4$ gas and gas pressure ranged from 0.1 to 0.5 MPa. The show that the breakdown voltages of gas were linearly increased according to the pressure in quasi-uniform field. For breakdown vlotage values of $(E/P)_{crit}$ are important. Because If values of (E/P) is a little more than $(E/P)_{crit}$, electrons rapidly increase and streamer discharge gernerates. Through this experiments values of $(E/P)_{crit}$ are found to vary with the ratio of $SF_6/CF_4$ mixture according to the following relationship. $V_b=(E/P)_{crit}{\cdot}p{\cdot}d$

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.20 no.1
• /
• pp.85-90
• /
• 2006

This paper presents experimental results relating to the preliminary breakdown characteristics in $SF_6/CO_2$ gas mixtures under a highly non-uniform electric field. The impulse pre-breakdown developments are investigated by the measurements of corona current and light emission images. As a result, the preliminary breakdown development mechanisms for both the positive and negative polarities were fundamentally same. The first streamer corona was initiated at the tip of needle electrode, and the leaders developed with a stepwise propagation and bridged the test gap. The pause time of leader pulses in the positive polarity was significantly shorter than that in the negative polarity. Also, the time interval between the first streamer corona onset and breakdown in the negative polarity was much longer than that in the positive polarity. The discharge channel path in the positive polarity was zigzag, and the leader channel in the negative polarity was thicker and brighter than that in the positive polarity.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.31 no.9
• /
• pp.110-120
• /
• 2003

As the wooden aircraft in the early times has no way to let lightning flow when lighting flash attaches during flight, the aircraft got damage, or caught fire. Though all metal airplane was developed with an advent of aluminum, a lightning accident still occurred including a fire of a fuel tanks. Eventually, NACA declared problems in 1938, and an artificial lightning test began. III succession, FAA established Airworthiness Requirements for certification. The FAA committed test measures study for the protection of an airplane from lightning to SAE. SAE presented the test current and voltage waveforms that simulating natural lightning, and it is utilized on lightning protection certification of an airplane by public. A lightning effects of an airplane through an analysis of lightning mechanism was made in this technical note. Especially, lightning direct effects on aircraft are analyzed and lightning strike zones are described.