• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2009.05a
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• pp.121-121
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• 2009

구리 전해정련 과정에서 전해액 중의 Arsenic과 같은 불순물 성분이 전기동의 전착에 미치는 영향을 확인하고, 전해액 중의 최대 허용 농도를 도출하고자 하였다. 전해정련 과정에서 분순물 성분이 전기동 전착에 미치는 영향을 주사전자현미경(SEM), X-선 회절(X-ray diffraction) 및 전기화학적 분석을 통해 수행하였다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2008.11a
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• pp.129-131
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• 2008

태양전지에서 발생되는 전력을 이용하여 중금속 성분이 함유된 공장 폐수에서 중금속 성분을 전착 회수하는 내용의 연구 및 장치를 개발하였다. 공장 폐수는 316L강을 전해연마한 후 배출되는 용액을 사용하였으며, 양극은 백금도금된 티타늄망을, 음극은 순수 동판을 사용하여 전해에 의해 중금속 성분을 전착시켰다. 전해액 및 전착 금속에 대한 분석도 이루어졌다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2014.11a
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• pp.227-228
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• 2014

마그네슘은 금속 재료중 화학적 활성이 높아 내식성 향상을 위해 표면처리 공정이 반드시 필요하다. 플라즈마 전해 산화를 통한 산화 피막 생성 후 좀더 높은 내식성 향상을 위해 전착 도장법을 사용할 수 있다. 본 논문에서는 전원 인가 방식에 따라 pulse 전원을 on/off 비율에 따른 피막 두께 변화를 측정 하였고 전착 도장을 시행 하여 cross cut test를 통한 부착성 시험을 진행해 on/off 비율 1:4 조건에 250V 전압을 인가 하였을 때 부착성이 가장 우수함을 확인 하였다. 또한 플라즈마 전해 산화 후 탕세 공정을 통해 전착 도장의 내열탕 시험 후 표면 blister의 개선 효과를 얻을 수 있었다.

• Journal of the Korean Electrochemical Society
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• v.20 no.1
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• pp.1-6
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• 2017

This study investigated the effect of surface pretreatment, which removes native Cu oxides on Cu seed layer, on subsequent Cu electro-/electroless deposition in Cu interconnection. The native Cu oxides were removed by using citric acid-based solution frequently used in Cu chemical mechanical polishing process and the selective Cu oxide removal was successfully achieved by controlling the solution composition. The characterization of electro-/electrolessly deposited Cu films after the oxide removal was then performed in terms of film resistivity, surface roughness, etc. It was observed that the lowest film resistivity and surface roughness were obtained from the substrate whose native Cu oxides were selectively removed.

• Korean Journal of Materials Research
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• v.11 no.5
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• pp.413-418
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• 2001

We investigated change of crystal structure, surface morphology and crystal orientation of the electrodeposited film from dispersed $SiO_2$ suspensions (colloidal silica) copper sulfate bath and arse corrosion potentials and physical specific properties. As addition of colloidal silica in copper electrolytic hath, the crystal Particles on filial was fined-down, made uniform and account of particles were increased. Hardness of copper electrodeposited film ascended about 15% and (111), (200) and (311) plane of X-ray diffraction patterns were almost swept away, so preferred orientation chanced from (111) to (110) plane. Also, corrosion potential of electrodeposited copper film was noble with colloidal silica addition.

• Nuclear Engineering and Technology
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• v.29 no.6
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• pp.60-64
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• 1997

핵연료의 가공공정에서 발생하는 스러지를 건식처리공정으로 회수 정제할 수 있는 건식처리 방법에 대하여 논의하고자 하였다. 건식처리방법은 수용액을 전혀 사용하지 알기 때문에 폐기물의 발생량이 습식처리방법에 비해 훨씬 줄어든다. 산화우라늄은 고온의 용융염중에서 염소개스에 의해 염소화반응을 통하여 우라늄염화물을 생성되게 되어 이들은 전기적으로 이동이 가능한 형태로 바뀌므로 전극에 선택적으로 전착될 수 있기 때문에 다른 금속이온과 분리할 수 있다. 본 보고서에서는 산화우라늄의 염소화공정, 전착공정에 대하여 기술하였고 전착된 산화물의 물리적 특성에 대하여 요약하였다.

• Applied Chemistry for Engineering
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• v.4 no.2
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• pp.273-283
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• 1993

Addition of various acids or organic compounds to the electrolyte solution during the electrodeposition of $PbO_2$ on titanium madras substrate strongly affected performance of the deposited $PbO_2$ layer. Results of X-ray diffractometry ascertained that ${\beta}-PbO_2$ was deposited in acidic electrolyte. Among additives used in this experiment, $PbO_2$ with a high oxygen overvoltage was electrodeposited when sodium lauryl sulfate was added, and $PbO_2$ with a lower chlorine overvoltage was electrodeposited when polyethylene glycol was added to the electrolyte solution. The oxygen and chlorine overvoltage of $PbO_2$ was strongly dependent on the stirring provided during the electrodeposition experiment. It was observed by the SEM results that the $PbO_2$ grains deposited when stirring was not provided during the electrodeposition have larger than $PbO_2$ grains deposited by stirring. In the $PbO_2$ deposition under acidic electrolyte, the oxygen overvoltage increased with larger $PbO_2$ grains and the chlorine overvoltage decreased with smaller $PbO_2$ grains. The optimal current efficiency of $PbO_2$ in the presence of perchloric acid was observed at $Pb(NO_3)_2$ 560g/l, $65{\sim}70^{\circ}C$, and pH>1.

• Journal of the Korean Electrochemical Society
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• v.22 no.3
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• pp.128-137
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• 2019

A lithium is the lightest metal on the earth. It has some attractive characteristics as a negative electrode material such as a low reduction potential (-3.04 V vs. SHE) and a high theoretical capacity ($3,860mAh\;g^{-1}$). Therefore, it has been studied as a next generation anode material for high energy lithium batteries. The thin lithium electrode is required to maximize the efficiency and energy density of the battery, but the physical roll-press method has a limitation in manufacturing thin lithium. In this study, thin lithium electrode was fabricated by electrodeposition under various conditions such as compositions of electrolytes and the current density. Deposited lithium showed strong relationship between process condition and its characteristics. The concentration of electrolyte affects to the shape of deposited lithium particle. As the concentration increases, the shape of particle changes from a sharp edged long one to a rounded lump. The former shape is favorable for suppressing dendrite formation and the elec-trode shows good stripping efficiency of 92.68% (3M LiFSI in DME, $0.4mA\;cm^{-2}$). The shape of deposited particle also affected by the applied current density. When the amount of current applied gets larger the shape changes to the sharp edged long one like the case of the low concentration electrolyte. The combination of salts and solvents, 1.5M LiFSI + 1.5M LiTFSI in DME : DOL [1 : 1 vol%] (Du-Co), was applied to the electrolyte for the lithium deposition. The lithium electrode obtained from this electrolyte composition shows the best stripping efficiency (97.26%) and the stable reversibility. This is presumed to be due to the stability of the surface film induced by the Li-F component and the DOL effect of providing film flexibility.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2003.11a
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• pp.368-372
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• 2003

The present study focused on obtaining the optimum conditions for depositing pure uranium onto a solid cathode. As for the results of the experiments, it was conformed that when the concentration of $UCl_3$ in the molten salt(LiCl-KCl) is more than 2wt%, pure uranium could be deposited onto a solid cathode, In addition. the effect of both the current density and the U contents in the molten salt or th ratio of uranium to salt was examined and the uranium morphology was also investigated.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 1999.10a
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• pp.90-91
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• 1999