• Membrane Journal
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• v.26 no.4
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• pp.266-272
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• 2016

The separation and purification of lysozyme enzyme from chicken egg white (CEW) solution was studied using the dead-end filtration. The optimum operation conditions of the dead-end filtration reveal that the maximum value of permselectivity of lysozyme to the other proteins of ovalbumin and conalbumin in the CEW solution was tested with change of molecular weight cut-off (MWCO) of ultrafitration membrane and pH of the CEW solution. The optimum operation conditions for the efficient permeable separation of lysozyme from the CEW solution are that the membrane MWCO is 30 kD and the pH of CEW solution is 11. At this optimum operation conditions, the maximum value of permselectivity of lysozyme to total proteins in CEW solution is about 83.

• Journal of Korean Society of Water and Wastewater
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• v.22 no.4
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• pp.437-444
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• 2008

Many other countries have investigated the new backwash water treatment process to save the existing water resource. There are various methods for reusing backwash water, but the membrane system has received the most interest for its efficiency. The objective of this study was to certify the application of membrane filtration system for the backwash water treatment. The experiment equipment was composed of Lab scale tubular membrane filtration system. Generally, cross-flow operation mode is used in the tubular membrane system but cross-flow operation mode demands high electric cost mainly for the pump energy. So to cut off electric cost, dead-end operation mode was used in this experiment. Filtration and bleed operation cycle was used in this membrane system. Backwash water was concentrated during the filtration process and when backwash water reached our target suspended solid concentration, it was discharged from this system. For efficient operation of filtration and bleed, mathematical matrix was drawn up and with this matrix we could simulate various sets of filtration and bleed time.

• Membrane Journal
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• v.29 no.3
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• pp.147-154
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• 2019

The permeate flux increments of a natural convection instability flow (NCIF) caused by the change of inclined angles ($0{\sim}180^{\circ}$) to gravity of the commercial membrane module were tested in the dead-end membrane filtration of BSA protein solution. The NCIF are more generated as the inclined angle increased from $0^{\circ}$ to $180^{\circ}$, and the occurred NCIF enhances permeate flux. However, the commercial module can only generate NCIF by completely removing the air gap in module. Since the custom design module designed in this study is permeated in a crossward direction ($90^{\circ}$), NCIF is always generated even if there is the air gap in module. The results of membrane filtration of BSA and dextran solutions using a custom design module showed that the flux in the crossward direction is increased to about 3.8 times for BSA solution and 1.8 times for dextran solution after two hours of operation due to the occurrence of NCIF. Also, NCIF generation is continued during 20 hours filtration of BSA solution, increasing the permeate flux to about 7.5 times. Since the custom design module with a permeation in the crossward direction and NCIF is always generated within the module, so it is possible to expect an increase in permeate flux due to the suppression of fouling formation, and thus to be utilized as a superb dead-end membrane module.

• Membrane Journal
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• v.29 no.6
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• pp.314-322
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• 2019

A worsened drought in Chungnam province of Korea due to climate change and increasing water demand at Daesan industrial complex have motivated the 100,000 ㎥/d seawater desalination project. In this study, therefore, the comprehensive analysis of parameters affecting the reverse osmosis (RO) performance was conducted. Under the various conditions of feedwater salinity and temperature in Daesan, energy consumption was calculated as 2.39 ± 0.13 kWh/㎥. The decrease in membrane flux and recovery rate positively impacted annual operation cost. The average total dissolved solids (TDS) of the permeate and energy consumption with highly permeable membrane according to the membrane manufacturer were 3.84 mg/L and 2.22 ± 0.13 kWh/㎥, respectively. In addition, energy saving up to 0.29 kWh/㎥ or cost reduction of membrane module up to 15.6% is expected by changing the RO configuration from full two pass to partial or split partial two pass.

• Korean Journal of Food Science and Technology
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• v.27 no.3
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• pp.313-317
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• 1995

Ion exchange process was optimized to purify ultrafiltrated bean cooking water(BCW) for the production of soy-oligosaccharides. The ultrafiltrated BCW with cutoff MW(COMW) 20,000 membrane was treated with various ion exchange resins. Protein and ash were mostly removed by anion and cation exchange resins, respectively. Based upon removing capabilities for ash and protein, a cation exchange resin(SK1B) and an anion exchange resin(WA30) were selected. Protein and ash were more efficiently removed at low extract/resin ratios(ERR), but part of the oligosaccharides were concomitantly lost. When 2-step-ultrafiltrated BCW first with COMW 20,000 membrane and successively with COMW 5,000 membrane was treated with a mixed resin(SK1B : WA30 =1 : 2) at ERR 5.0, most oligosaccharides were recovered in a clear protein- and ash-free liquid.

• Korean Journal of Food Science and Technology
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• v.27 no.2
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• pp.181-184
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• 1995

Ultrafiltration was applied for the production of soy-oligosaccharides from bean cooking water(BCW), a by-product recovered in soymilk processing. The ultrafiltration of BCW on a membrane of 20,000 cutoff molecular weight recovered most oligosaccharides as permeate with concomitant removal of protein at 40% when volume concentration ratio(VCR) exceeded 5.0. When the VCR exceeded 5.0, membrane rejection value(MRV) for protein started to increase slowly while the MRV for sugar showed a sharp increasing trend showing 6.57% at VCR 5.0 and 19.96% at VCR 10. The optimum VCR based upon the MRV's was 5.0. Maximum recovery of soy-oligosaccharides was, however, obtained at VCR 10.0.

• Membrane Journal
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• v.29 no.1
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• pp.18-29
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• 2019

The dead-end ultrafiltration (UF) of BSA protein solution was performed to investigate the defouling effects of natural convection instability flow (NCIF) induced in membrane module. The permeate fluxes were measured according to the inclined angles ($0{\sim}180^{\circ}$) of membrane module with respect to gravity, and analyzed using the blocking filtration model. NCIF are more induced as the inclined angles increased from $0^{\circ}$ to $180^{\circ}$, and the induced NCIF enhances flux. Comparing the fluxes at $0^{\circ}$ inclined angle (no NCIF induction) and $180^{\circ}$ (maximum NCIF induction), the flux enhancements by NCIF induction are increased about 5 times in the short-term UF operation (2 hours) and about 17 times in the long-term operation (20 hours). As applying the blocking filtration model, it is more suitable to analyze the flux results by using the intermediate blocking model in the early times of UF operation within 15 minutes and then thereafter times by using the cake filtration model. NCIF induced at $180^{\circ}$ inclined angle reduces the intermediate blocking fouling at about 67% in the early times operation and thereafter the cake layer fouling at about 99.9%. The main defouling mechanism of NCIF induced in the membrane module is suppress the formation of protein cake layer.

• Journal of Wetlands Research
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• v.15 no.3
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• pp.407-412
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• 2013

The aim of this study was to develop a tree box filter system, an example of Low Impact Development technology, for treating stormwater runoff from road. Monitoring of storm events was performed between June 2011 and November 2012 to evaluate the system performance during wet day. Based on the results, all runoff volume generated by rainfall less than 2 mm was stored in the system. The minimum volume reduction of 20% was observed in the system for rainfall greater than 20 mm. The greatest removal efficiency was exhibited by the system for total heavy metals ranging from 70 to 73% while satisfactory removal efficiency was exhibited by the system for particulate matters, organic matters and nutrients ranging from 60 to 68%. The system showed greater pollutant removal efficiency of 67 to 83% for rainfall less than 10 mm compared to rainfall greater than 10 mm which has 39 to 75% pollutant removal efficiency. The system exhibited less pollutant reduction for rainfall greater than 10 mm due to the decreased retention capacity of the system for increased rainfall. Overall, the system has proved to be an option for stormwater management that can be recommended for on-site application. Similar system may be designed based on several factors such as rainfall depth, facility size and pollutant removal efficiency.

• Journal of the Korean GEO-environmental Society
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• v.16 no.4
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• pp.13-22
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• 2015

The combined impact of Dissolved Organic Matter (DOM) fouling and inorganic ($CaSO_4,Ca_3(PO_4)_2$) scaling on the retention of TNT (2, 4, 6-Trinitrotoluene), RDX (Hexahydro-1, 3, 5-trinitro-1, 3, 5-triazine) and HMX (1, 3, 5, 7-Tetranitro-1, 3, 5, 7-tetrazocane) explosive contaminants by nano-filtration membrane were studied, since organic fouling and salt scaling are the major limitations for membrane filtration. Results reported here indicate that DOM fouling layer with a humic acid does not necessarily lead to an immediate loss of permeate flux but can result in a severe impact on the flux loss when both humic acid and inorganic scaltants were presented simultaneously. The $Ca_3(PO_4)_2$ mixed with humic acid showd most sever flux loss (42%) compared to that of only humic acid presence (8%). It could be a result that the scaling formation of the NF membrane was dominated by cake layer formation of DOM and it was along with pore blocking by the formation of crystals inside the porous active matrix of the NF membrane. In addition, these results indicated that the membrane selectivity of the explosives retention trended correlated with respect to increasing explosives size (listed by MW) based on greater steric interactions and followed the order (MW, g $mol^{-1}$; removal, %): HMX (296.15; 83%) ${\gg}$ RDX (222.12; 49%) ≋ TNT (227.13; 32%). Because the scaling and fouling layer could lead to a additional cake-enhanced concentration polarisation effect, the retention of explosives with the presence of humic acid in the feed solution and inorganic scaling formation on top of an organic fouling layer do not differ substantially retention from that of pure DI feed and NaCl solution.

• Membrane Journal
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• v.17 no.3
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• pp.219-232
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• 2007

The polyethersulfone(PES)-titanium oxide($TiO_2$) hybrid membranes were prepared by immersion precipitation phase inversion method. The casting solution for the preparation of $PES-TiO_2$ hybrid membrane was provided by adding $TiO_2$ nano particles into the basis polymer solution of 14 wt% and 20 wt% PES/N-methyl-2-pyrrolidone(NMP). The $TiO_2$ loading [wt% ($TiO_2/NMP$)] in eating solution was varied from 0 to 60 wt%. Membrane performance and morphological change of the resulting $PES-TiO_2$ hybrid membranes were discussed in aspect of $TiO_2$ loading, by viscosity, coagulation value and light transmittance of the casting solution, measurement of tensile strength, pore size and contact angle, surface and cross sectional SEM images of the hybrid membrane, and ultrafiltration experiments using the hybrid membrane. According as increase of $TiO_2$ loading in the casting solution, viscosity is increased and coagulation value becomes lower, therefore the thermodynamic instability of the casting solution is increased. It is found that when $TiO_2$ loading is increased, 1) precipitation rate becomes faster while instantaneous demixing is maintained, 2) pure water flux, membrane pore size and compaction stability of the resulting membranes are increased, 3) tensile strength and contact angle are decreased. Dead-end ultrafiltration of bovine serum albumin(BSA) solution using the hybrid membrane shows that membrane performance(flux of BSA solution) enhanced up to 7 times compared with the results obtained using the pure PES membrane(not containing $TiO_2$ particle), due to the increase of hydrophilicity.