• Bulletin of the Korean Chemical Society
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• v.17 no.2
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• pp.173-179
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• 1996

A series of tetradentate Schiff base ligands; [1,2-bis(naphthylideneimino)ethane, 1,3-bis(naphthylideneimino)propane, 1,4-bis(naphthylideneimino)butane, and 1,5-bis(naphthylideneimino)pentane] and their Ni(Ⅱ) complexes have been synthesized. The properties of these ligands and their Ni(Ⅱ) complexes have been characterized by elemental analysis, IR, NMR, UV-vis spectra, molar conductance, and thermogravimetric analysis. The mole ratio of Schiff base to Ni(Ⅱ) metal was found to be 1:1. The electrochemical redox process of the ligands and their Ni(Ⅱ) complexes in DMF and DMSO solution containing 0.1 M tetraethyl ammonium perchlorate (TEAP) as a supporting electrolyte have been investigated by cyclic voltammetry, chronoamperometry, differential pulse voltammetry, and controlled potential coulometry at glassy carbon electrode. The redox process of the ligands was highly irreversible, whereas redox process of Ni(Ⅱ) complexes were observed as one electron transfer process in quasi-reversible and diffusion-controlled reaction. The electrochemical redox potentials of the Ni(Ⅱ) complexes were affected by the chelate ring size of ligands. The diffusion coefficients of Ni(Ⅱ) complexes containing 0.1 M TEAP in DMSO solution were determined to be 5.7-6.9 × 10-6 cm2/sec. Also the exchange rate constants were determined to be 1.8-9.5 × 10-2 cm2/sec. These values were affected by the chelate ring size of ligands.

• Journal of the Microelectronics and Packaging Society
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• v.29 no.1
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• pp.61-66
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• 2022

This study is to increase the surface area and maximize the effect of the catalyst by coating a nanometersized metal catalyst material on the anode layer using atomic layer deposition (ALD) technology. ALD process is known to produce uniform films with well-controlled thickness at the atomic level on substrates. We measured the performance by coating metals (Ni) on Ni/YSZ, which is the most widely known anode material for solid oxide fuel cells. ALD coatings began to show a decrease in cell performance over 3 nm coatings.

• Journal of Marine Life Science
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• v.7 no.2
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• pp.154-162
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• 2022

In this study, data on the types and density of abalone attached organisms were provided in marine net cage of the southern coast. In addition, the effect of the removal of attached organisms was evaluated. In marine net cage, oysters, bryozoa, and barnacles were dominated among the attached organisms, and their average area ratio was about 57.5%. The growth rate and hepatopancreas condition were better in removal group of attached organisms than control group. Therefore, it is judged that the removal of attached organisms from abalone is necessary for the growth of individuals and improvement of value.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.58 no.4
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• pp.334-344
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• 2022

In this study, we used underwater acoustics to analyze the spatial and temporal distribution characteristics of largehead hairtail (Trichiurus leptueus) based on the luminous thronging of metal halide fishing lamps and induction fishing lamps. As a result, the illuminating power was approximately 1.3 times higher using the metal halide fishing lamp whereas the density of hairtals by distance was approximately 1.9 times higher using the induction fishing lamp. Regarding water depth distribution, hairtails were detected depths of 25-30 m during August and at all water depths in November as assessed using fishing lamps.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.6
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• pp.734-740
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• 2023

Hydrogen emphasis on safety management due to its high potential for accidents from wide explosive limits and low ignition energy. To prevent accidents, appropriate explosion-proof electrical equipment with installed to safe management of ignition sources. However, designing all facilities with explosion-proof structures can significantly increase costs and impose limitations. In this study, we optimize the barrier to effectively control the initial momentum in case of hydrogen release and form the control room as a non-hazardous area. We employed response surface method (RSM), the barrier distance, width and height of the barrier were set as variables. The Box-Behnken design method the selection of 15 cases, and FLACS assessed the presence of hazardous area. Analysis of variance (ANOVA) analysis resulting in an optimized barrier area. Through this methodology, the workplace can optimize the barrier according to the actual workplace conditions and classify reasonable hazardous area, which is believed to secure safety in hydrogen facilities and minimize economic burden.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.6
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• pp.712-721
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• 2023

While hydrogen is widely used, it has a low minimum ignition energy, raising safety concerns when using it. This research studied which parameters are the key variables in the hydrogen release and diffusion. These parameters were divided into six process variables in the initial release and two environmental variables in the dispersion. One hundred and twenty cases were selected through design of experiment, and the end-point in each case were analyzed using PHAST. Afterwards, an end-point prediction model was developed using RSM and ANOVA, and the impact of each variable on the endpoint was analyzed. As a result, the influence of eight variables was graded. The nozzle diameter had the greatest influence on the end-point, while the pipe roughness coefficient had no effect on the end-point. It is expected that these results will be used as basic data to improve safety across all fields of hydrogen handling facilities.

• Proceedings of the Korea Information Processing Society Conference
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• 2008.11a
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• pp.895-898
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• 2008

블랙박스 시스템은 평시 및 사고 직전후의 각종 운행 기록 정보, 영상 정보 등 다양한 사고 정보를 저장할 수 있으며 이에 기반하여 교통 사고를 재현해내는 기술에 대한 활발한 연구가 진행 중이다. 본 논문은 USN 환경에서 차량 간 교통사고 발생시 상대 차량 정보를 블랙박스 내에 저장할 수 있는 시스템을 제안한다. 블랙박스에 저장되는 상대 차량에 대한 정보는 각종 사고 발생시 교통 사고 분쟁 해결에 결정적 요인이 될 수 있으므로 그 중요성이 크다. 제안하는 블랙박스 시스템에 저장되는 정보는 차량 고유 번호, 사고 발생 시간 및 위치 등의 정보이고 그 정보는 허가된 사용자에게만 접근 될 수 있다. 본 논문에서는 두 개의 센서 노드를 블랙박스로 가정하고 임의의 충돌 신호를 발생시켜 상대 차량의 정보를 저장하고, 이를 분석하는 시뮬레이션을 통하여 제안하는 블랙박스 시스템이 사고 차량 정보와 위치, 시간 등을 저장함을 보인다. 수집된 정보는 교통 사고에 대한 과학적인 해석과 사건 재현을 위한 객관적인 정보로 사용 될 수 있다.

• Journal of the Korean Institute of Rural Architecture
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• v.26 no.1
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• pp.21-32
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• 2024

This study aimed to suggest the direction of sustainable rural development through the analysis of existing rural revitalization policies and rural status. This study also aimed to explore ways to revitalize the agricultural-oriented rural economy and improve the settlement environment in consideration of the characteristics of rural spaces. Based on the results, we created a regional crop-specific agricultural space, planned concentration, farmland maintenance, and joint agricultural facilities to secure agricultural competitiveness. It also plans a walking-oriented settlement environment to create a safe and pleasant rural village. Finally, by overcoming the limitations of the existing land-use plan, a sub-concept rural spatial plan reflecting the characteristics of rural areas was proposed, and the rural revitalization plan was studied.

• The Korean Journal of Medicine
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• v.94 no.1
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• pp.96-106
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• 2019

Background/Aims: It is well known that gender differences are associated with clinical outcomes in patients with acute myocardial infarction (AMI). However, it is not clear whether gender differences affect the prognosis of elderly patients with AMI. Methods: We analyzed the incidence of in-hospital complications and mortality in the Korea Acute Myocardial Infarction Registry-National Institutes of Health from November 2011 to June 2015. This study included elderly patients (≥ 75 years) diagnosed with AMI. Results: A total of 2,953 patients were eligible for this study. Among them, 1,529 (51.8%) patients were female, and the mean age of the female group was older than that of the male group (80.7 ± 4.4 vs. 79.6 ± 4.0 years, respectively, p < 0.001). Elderly females utilized emergency medical services less frequently compared with elderly males (11.5 vs. 15.4%, respectively, p < 0.001). Elderly female AMI patients had a similar rate of in-hospital mortality compared with elderly males (7.1 vs. 8.4%, respectively, p = 0.196). The rate of major cardiac adverse events (MACEs) was lower in elderly females than males during a 12-month follow-up (hazard ratio [HR] 1.19, 95% confidence interval [CI] 1.00-1.41, p = 0.045). According to multivariate analysis, the male gender is an independent factor for predicting 1-year MACEs (HR 1.37, 95% CI 1.14-1.65, p < 0.001). Conclusions: No significant differences in peri-procedural complications or in-hospital mortality were observed between male and female elderly patients with AMI. However, elderly female patients had a more favorable prognosis than male patients during a 1-year clinical follow-up.

• The Science & Technology
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• v.32 no.2 s.357
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• pp.80-81
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• 1999

20여년동안 수소저장합금분야 연구에만 매달려온 전남대 금속공학과 박충년교수. 수소저장합금은 미래의 청정에너지로 각광을 받고 있는데 박교수는 수소저장합금 분말로 구리도금하여 금속수소화물 전극을 제조하는 방법에 대한 특허를 갖고 있다. 박교수는 전남대 자동차연구소 기능재료실장과 한국수소에너지학회 편집위원장을 맡고 있다.