• Journal of the Korean Chemical Society
• /
• v.35 no.2
• /
• pp.165-171
• /
• 1991

The electrochemical reduction of carbon-6-dibromo groups on 6,6-dibromo penicillanic acid 1,1-oxide(DBPA) was investigated by direct current, differential pulse polarography, cyclic voltammetry and controlled potential coulometry. The irreversible two electrons transfer on the reductive debromination of each bromo group proceeded by EC,EC mechanism at the two electrode reduction steps(-0.48, -1.62 volts). The 6-bromo-PA and 6,6-dihydro-PA was synthesized by controlled potential electrolysis. Upon the basis of results on the products analysis and interpretation of polarograms obtained at various pH, electrochemical reaction mechanism was suggested.

• 한국전기화학회:학술대회논문집
• /
• 1999.10a
• /
• pp.55-55
• /
• 1999

• Proceedings of the Korean Nuclear Society Conference
• /
• 2001.10a
• /
• pp.255.2-255
• /
• 2001

• Journal of the Korean Institute of Gas
• /
• v.9 no.4 s.29
• /
• pp.30-35
• /
• 2005

In order to examine the electrochemical polarization characteristics of hydrogen embrittlement far STS444 with welding conditions, this paper carried out the accelerated hydrogen osmosis test and the electrochemical polarization test. That is, in $0.5M\; H_2SO_4+0.001M\;As_2O_3$ solution, the hydrogen embrittlement behavior of STS444 added to load of $1,400kg/cm^2$ together with hydrogen osmosis by current of $30mA/cm^2$ far 60 min. was considered. In researching the electrochemical polarization characteristics of hydrogen embrittlement for STS444 with welding conditions, the previous study clarified that tensile strength or elongation became low influenced by absorption of oil or water before welding. In this paper, we proposed the advanced mechanism of hydrogen embrittlement that integrated electrochemical corrosion with the existing mechanism of hydrogen embrirtlement.

• Journal of the Korean Chemical Society
• /
• v.39 no.1
• /
• pp.57-65
• /
• 1995

The electrochemical reduction of methylene blue (MB) in 1.0${\times}$10-2 M KNO3 aqueous solution was investigated by direct current (DC), differential pulse (DP) polarography, cyclic voltammetry (CV) and controlled potential coulometry (CPC). The electrode reduction of melthylene blue was processed CE reaction mechanism by two electrons transfer at the first reversible wave (- 0.18 volts vs. Ag/AgCl). MB was strongly adsorbed on the stationary mercury electrode and the reduction product of conptrolled potential electrolysis was rapidly auto-oxidized in air to the original methylene blue. Upon the basis of interpretation of cyclic voltammogram with pH change, possible CE electrode reaction mechanism was suggested.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 1988.10a
• /
• pp.73-75
• /
• 1988

• Journal of the Korean Chemical Society
• /
• v.35 no.6
• /
• pp.673-679
• /
• 1991

The electrochemical reduction of N-tert-butylbenzothiazole-2-sulfenamide (TBBS; vulcanization accelerator) was investigated by direct current, differential pulse polarography, cyclic voltammetry and controlled potential coulometry. The electrode reduction of TBBS proceeded E-C-E-C reaction mechanism by four electrons transfer at irreversible one wave (-2.31 volts vs. Ag/0.1M AgN$O_3$ in AN). As the results of controlled potential electrolysis, mercaptobenzothiazole (MBT), benzothiazole disulfide (MBT dimer) and extricated sulfur were products which followed by cleavage of the sulfenamide (-S-N=) bond. Upon the basis of products analysis and polarogram interpretation with pH variable, electrochemical reaction mechanism was suggested.

• Electrical & Electronic Materials
• /
• v.7 no.6
• /
• pp.543-548
• /
• 1994

전기화학반응은 일반적으로 반응속도가 전류에, 반응의 구동력이 과전압에 대응하기 때문에 전류 또는 전위의 경시적 변화로 부터 적극 반응기구나 반응의 과정을 해석하는 법이 널리 이용되고 있다. cyclic voltammetry과 chrono-potentiometry을 비롯한 시간영역에서의 해석에 대해, 전극계의 동적인 특성을 주파수 영역에서 해석하는 것도 가능하며 교류임피던스법이 가장 잘 알려진 방법이다. 여기서는 교류임피던스법의 고찰법, 기본적인 측정법, 몇개의 계에 있어서 임피던스 특성 및 그 방법의 새로운 전개에 대해서 설명한다.

• Journal of the Korean Chemical Society
• /
• v.35 no.1
• /
• pp.70-77
• /
• 1991

1-Benzyl-4-iodomethyl-2-azetidinone(BIMA) was synthesized and its electrochemical reduction was investigated by direct current, differential pulse polarography, cyclic voltammetry and controlled potential coulometry. The irreversible two electron transfer on reductive dehalogenation of iodo group proceeded to form 1-benzyl-4-methyl-2-azetidinone by EEC electrode reaction mechanism at the first reduction step(-1.35 volts vs. Ag-AgCl). The polarographic reduction waves separated into two reduction steps due to anionic surfactant (sodium lauryl sulfate) effects, while the waves were shifted to the positive potential as the concentration of cationic surfactant (cetyltrimethylammonium bromide) increased. Upon the basis of results on the product analysis and interpretation of polarogram with pH variable, EEC electrochemical reaction mechanism was suggested.

• Journal of the Korea Concrete Institute
• /
• v.25 no.1
• /
• pp.3-9
• /
• 2013

In ultra high strength concrete, when electric arc furnace oxidizing slag is substituted for sea sand as fine aggregate, compressive strength was improved about 15 MPa. To figure out the cause of the improvement in compressive strength, this study considered the dissolution characteristics of Ca component in fine aggregate and examined the microstructure, porosity, microhardness, and Ca/Si mole ratio on the interface of fine aggregate and paste. And to examine the mechanism of strength improvement resulted from the shape of fine aggregate, this study measured the surface roughness of fine aggregate with AFM. According to the result of this experiment, the mechanisms of strength improvement in ultra high strength concrete resulted from the use of electric arc furnace oxidizing slag as fine aggregate can be divided into chemical and physical mechanisms. In the chemical mechanism, the soluble Ca component contained in electric arc furnace oxidizing slag is dissolved and forms a hydrate between fine aggregate and paste to improve the interlocking strength of fine aggregate-paste. Also, it makes the microstructure around the fine aggregate. And in the physical mechanism, electric arc furnace oxidizing slag has a twice greater surface roughness than sea sand, so the interlocking strength between fine aggregate and paste increases, which contributes to the development of compressive strength.