• Journal of the Korean GEO-environmental Society
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• v.25 no.5
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• pp.39-47
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• 2024

In this study, the environmental implications of electric arc furnace steel slag, commonly used in road construction and soil reinforcement, were examined. Experiments were conducted to assess the leaching of heavy metals based on particle size and to investigate ion leaching from specimens with varying mixtures of steel slag and clay. The official waste test revealed no detectable heavy metals in the sample items. However, when subjected to leaching experiments and analyzed using ICP-OES, certain heavy metals were found. The reaction of steel slag with water, facilitated by free CaO within the slag, was identified as the cause of leaching. Results showed that aluminum, exhibiting the highest leaching rate, displayed an inverse relationship with particle size. In mixed soil containing steel slag and clay, higher steel slag content resulted in increased aluminum leaching. Nonetheless, the quantity of leached aluminum was notably lower in mixed soil compared to pure steel slag. Furthermore, leaching of other heavy metals remained within acceptable limits. These findings suggest that recycling mixed soil of steel slag and clay for road construction or soil stabilization presents reduced environmental risks compared to using steel slag alone. Utilizing such mixtures could offer an environmentally sustainable and safe alternative.

• Resources Recycling
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• v.28 no.2
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• pp.40-45
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• 2019

During steelmaking in EAF, recycled scraps is used as a main material, melted by arc, and electricity use as a main energy. Slag foaming is an important technology for reducing electrical energy. CO gas generated by the reaction between injection carbon and (FeO), [C] and injection {$O_2$}. CO gas generated by this reaction is collected in slag, resulted in slag foaming. In general, the carbon materials used in the EAF process is anthracite and coke. This study investigated the effects of the carbon materials used on slag foaming in the steelmaking process. As a result of this study, the slag foaming height is increased by cokes rather than anthracite, and with an increase in the amount of particles samller than $500{\mu}m$. Based on these results, the application to the operation resulted in increase of slag forming height, reduction of injection carbon, and reduction of electrical energy.

• Journal of the Korea Concrete Institute
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• v.14 no.4
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• pp.597-607
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• 2002

Electric arc furnace and converter slag are produced by about 6 millions tons in Korea at 2000 year. But compared with blast furnace slag, those are utilized only in unvalued material like landfill and road construction. There are unstable materials, like free CaO, in electric arc furnace and converter slag at steel-manufacturing process. This might cause volume expansion in concrete, if electric arc furnace and converter slag aggregates were used in concrete. This expansion may reach to crack or collapse of concrete. It is therefore settled by standard specification for concrete that electric arc furnace and converter slag aggregates have not to use in concrete. First of all, volume stability and stabilized process should be solved in electric arc furnace and converter slag aggregate to use in concrete. In this study, 6 types of aging are evaluated for effects of stabilization to reduce the expansion of electric arc furnace and converter slag. h converter slag aggregate, these types of aging are not good for volume stability for concrete aggregate, and even if converter slag aggregate is treated with aging, concrete with it has some problems that strength is reduced with curing days. But in electric arc furnace slag aggregate treated with hotwater and steam aging, the expansion of electric arc furnace slag aggregate is reduced about two times than that of converter slag aggregate, and electric arc furnace slag aggregate concrete has good results in strength compared with control concrete using crushed stone.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.1
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• pp.70-78
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• 2023

Blast furnace slag, a by-product of the steel industry, is mostly recycled as concrete admixture, but electric arc furnace slag has not been recycled to date. In particular, since electric arc furnace slag partially contains free lime (free-CaO) in the discharge, it is necessary to review this in order to recycle f or construction materials. Recently an atomizing process which is a method of rapidly cooling electric arc furnace slag has been developed and applied. Therefore, in order to use the fine aggregate of oxidized slag from electric furnace restored by this method as an aggregate for concrete, physical damage and chemical reviewing are required. In this study, a physical and chemical review was conducted on the fine aggregate of Electric Arc Furnace Oxidizing Slag (EFOS) as a by-product of the steel manufacturing process with atomizing process. In this experimental study, EFOS was experimentally examined about whether it can be used as concrete fine aggregate. Also, we intend to provide basic data for the future use of the EFOS fine aggregate. As a result of the experimental study, it was found that the fine aggregate of the EFOS satisfied the quality standards of the fine aggregate for concrete in most items specified by Korean Standard.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.4
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• pp.112-118
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• 2012

Steel industry produces many by-products and wastes such as blast furnace slag, electric arc furnace slag, and converter slag. As in the case of rock, the main component of steel slag are CaO and $SiO_2$ ; further, steel slag is as alkaline as portland cement or concrete. Electric arc furnace oxidizing slag is possible to use as an aggregate for concrete ; however, it has been reclaimed because of it's expansibility caused by free CaO. Recently, a innovative rapid cooling method for melting steel slag has been developed in Korea, which reduces free lime content to minimum level and increases the stability of iron oxide. Therefore, this study describes the results of a series of research to utilize globular shape of electric arc furnace oxidizing slag fine aggregates made by rapidly cooled method for the construction industry by cooling rapidly melted slag from the steel industry. First of all, an experiment was carried out to investigate the quality characteristics of rapidly cooled electric arc furnace oxidizing slag fine aggregates in order to determine whether they can be applied to the construction industry. Then, by applying them to concrete of various particle sizes, we explored experimentally the desired condition to apply rapidly cooled electric arc furnace oxidizing slag fine aggregates to concrete.

• Journal of the Korean GEO-environmental Society
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• v.25 no.5
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• pp.29-37
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• 2024

This study aimed to investigate the changes in chemical components that occur when weak clay is mixed with steel slag modified with calcium oxide, and to understand the expression characteristics of compressive strength according to hydrophilicity and curing time. XRF testing, SEM imaging, vane shear strength and uniaxial compressive strength testing were conducted. Calcium (Ca) released from the steel slag increases the Ca content in clay by increasing the number of crystal particles and forming a coating layer known as calcium silicate hydrate (CaO-SiO₂-H₂O) through chemical reactions with SiO₂ and Al₂O₃ components. The weak clay stabilized with steel slag is classified into an initial inactive zone where strength relatively does not increase and an activation zone where strength increases over curing time. The vane shear strength of the initial inactive area was found to be 4.4 to 18.4 kN/m² in the state of the weight mixing ratio Rss 30% (steel slag 30% + clay 70%). In the case of the active area, the maximum uniaxial compressive strength increased to 431.8 kN/m² after 480 hours of curing time, which increased due to the apparent adhesion strength of clay through pozzolanic reaction. Therefore, considering the strength expression characteristics of stabilized mixed clay based on the mixing ratio (Rss) during the recycling of steel slag can enhance its practicality in civil engineering sites.

• Journal of the Korean GEO-environmental Society
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• v.13 no.6
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• pp.33-39
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• 2012

With the increase of steel production research interest on the recycling of slag as a by-product also increases steadily. Currently in Korea a lot of researches on blast-furnace slag have been made. However, the researches on the steel slag have been rarely made. Also, a research of steel slag, especially the use of oxidation furnace slag as aggregates for concrete progress, is performing actively, but the research results on the furnace slag are almost nothing. Recently, the research about the furnace slag as backfill material and embankment material confirmed the possibility of the clay soil amendment. Therefore, the object of this study is to review the possibility as civil engineering materials for soil improvement and to find the optimum mixture ratio of furnace slag. This research analyzed the ingredient component of the reduced slag by SEM, XRF, XRD tests and examined the strength increase using unconfined compression tests when the clay and reduced slag are mixed each other. Through this test, the definite strength increase is confirmed according to the mixture of the reduced slag and the possibility of soil improvement is also confirmed based on this result. The object of the study is both utilizing the by-product for civil engineering purpose and effective recycling by the application of the furnace slag for soil improvement.

• Journal of the Korean GEO-environmental Society
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• v.12 no.7
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• pp.31-37
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• 2011

Only a few studies have been conducted using reduced slag as recycled material. The reduced slag in electric furnace is produced as a by-product in making a steel and a few applications of the reduced slag as expensive additives and bonding materials or as the stabilized soils was reported. The purpose of this study is to present the feasibility of the reduced slag as recycled material, especially, in a field of civil engineering. In order to achieve the purpose experiments such as SEM and XRF analysis was conducted for the reduced slag in electric furnace. Based on the results various geotechnical experiments were conducted to know engineering properties of slag-soil mixtures. Weathered soils and clay are mixed with reduced slag for various ratios. As the ratio of reduced slag to weathered soil increases, the maximum dry unit weight of the mixture decreased with increasing optimum moisture content. The results indicates that there is no effect on a reduced slag by compaction efforts. The shear strengths of the weathered soil-slag mixtures are slightly higher or similar to those of weathered soils. The permeability of the weathered soil-slag mixtures is similar to that of silty or sandy soils. Therefore, it is possible to use the mixtures as embankment or backfill materials in the fields. The unconfined strength of the mixtures of reduced slag and clay is higher than that of clay and it tends to increase with the curing time. Therefore it can be used to improve the soft ground.

• Journal of the Korean Recycled Construction Resources Institute
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• v.2 no.1
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• pp.128-135
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• 2006

Steel slag (divided into electric arc furnace slag and convener slag) is being produced by millions of tons per every year in many industrial countries. About 6.5 million tonnes of steel slag is produced yearly as an industrial by-product in Korea. Generally natural aggregate is relatively stable and does not enter into complex chemical reactions with water. Unfortunately, however. steel slag aggregate contains a small amount of free lime. The hydration of free lime makes steel slag aggregate unstable and liable to expand. In this paper, firstly, several aging methods are used in order to decrease the volume expansion of electric arc furnace slag, that is stabilization. The volume expansion of electric arc furnace slag is formulated from the experiment. From the formula, the residual expansibility is predicted with immersion expansion. Compressive strength of concrete with electric arc furnace slag has relation with the residual expansibility in slag aggregate.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.2
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• pp.70-77
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• 2012

The Ladle Furnace Slag, about 20% of the electric arc furnace slag, has high content of free CaO and free MgO, which generates the expansion collapse by hydration reaction. Although many researchers have been endeavoring to recycle the EAF reducing slag in construction fields, there is not found the effective recycling method up to now. However, the LFS(Ladle Furnace Slag) contains mineral composition of the system of calcium aluminate with high-reactivity. Therefore, it is possible to developed the quick setting property and the high strength at the early age by the rapid cooling. This study aimed to check the reactive minerals and predict the reactivity with water on the LFS discharged from different steel product plants. The test results show that many types of LFS has hydration reactivity and can use in construction field as a inorganic binder with the rapid setting property.