• Title/Summary/Keyword: 재활용성평가

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Investigative Analysis of By-products from Lignocellulosic Biomass Combustion and Their Impact on Mortar Properties (목질계 바이오매스 연소부산물 분석과 모르타르 혼입 평가)

  • Jung, Young-Dong;Kim, Min-Soo;Park, Won-Jun
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.6
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    • pp.663-671
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    • 2023
  • This research experimentally evaluated the recyclability of four varieties of lignocellulosic fly ash(FA), a by-product from three power plants employing lignocellulosic biomass(Bio-SRF, wood pellets) as a fuel source. Comprehensive analyses were conducted on FA, encompassing both physical parameters (particle shape, size distribution, fineness, and density) and chemical properties(chemical composition and heavy metal content). Mortar test specimens, with FA mixing ratios ranging from 5 to 20%, were produced in compliance with KS L 5405 standards, and their flow and compressive strength were subsequently measured. The test results indicated that the four types of FA exhibited particle sizes approximately between 20~30㎛, densities around 2.3~2.5g/cm3, and a fineness range of 2,600~4,900cm2/g. The FA comprised approximately 50~90% of components such as SiO2, Al2O3, Fe2O3, and CaO, displaying characteristics akin to type-II and type-III FA of KS L 5405 standards, albeit with differences in chlorine and SiO2 content. From the mortar tests, it was observed that the compressive strength of the mortar ranged between 34~47MPa when the pellet combustion FA was mixed in proportions of 5~20%. FA, produced exclusively from the combustion of 100% lignocellulosic fuel, is assessed to possess high recyclability potential as a substitute for conventional admixtures.

When do we use the Recycling Autograft in Limb Salvage Surgery? (사지구제술에서 언제 재활용 자가골 이식술이 유용한가?)

  • Kim, Jae-Do;Jang, Jae-Ho;Cho, Yool;Kim, Ji-Youn;Chung, So-Hak
    • The Journal of the Korean bone and joint tumor society
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    • v.14 no.2
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    • pp.95-105
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    • 2008
  • Purpose: To identify which is the best procedure in recycling autograft according to the resection & reconstruction type and recycling methods, and so when the recycling autograft is used in limb salvage surgery. Materials and Methods: We have treated fifty-eight patients (34 male, 24 female; age range 5 to 74 years, mean age 36.5 years), who had the malignant musculoskeletal tumors, with recycling autograft (47 patients with extracoporeal irradiation, 11 patients with pasteurization) from December 1995 to February 2006. The resection and reconstruction type was 3 cases with fragmentary, 8 intercalary, 23 rAPC (recycling-Autograft-Prosthesis composite), 18 osteoarticular, 5 total joint and 1 soft tissue (achilles tendon). The result was evaluated by the radiologic union at junctional site, the functional score by musculoskeletal tumor society score and complications according to the resection & reconstruction type and recycling methods. Results: The junctional union was obtained at 15.0 months in extracoporeal irradiation and 12.6 months in pasteurization. Also the mean radiologic union was shown at 6.0 months in fragmentary, 12.8 months in intercalary, 10 months in rAPC, 23.3 months in osteoarticular and 15.6 months in total joint. The functional score was 65.5% in fragmentary, 60.8% in intercalary, 62.8% in APC (except pelvis), 66.0% in osteoarticular and 66.6% in total joint. We have experienced 1 infection, 1 prutrusio acetabuli in pasteurization (18.1%) and other 22 complications (3 deep infections, 8 nonunions, 2 fractures, 2 epiphyseal problems, 5 joint instabilities, 2 local recurrence) in extracoporeal irradiation (46.8%). Also we have experienced 3 complications (3 nonunions) in intercalary (37.5%), 9 complications (4 nonunions, 1 deep infection, 1 periprosthetic fracture, 1 epiphyseal problem, 1 local recurrence, 1 protrusio acetabuli) in rAPC (50.0%), 6 complications (2 deep infections, 2 nonunions, 1 epiphyseal problem, 1 pathologic fracture) in osteoarticular (33.3%), 5 complications (5 joint instabilities) in total joint (100%) and 1 complication(1 local recurrence) in soft tissue (100%). Conclusion: In our experience, according to the resection & reconstruction type fragmentary and intercalary may have several advantages such as good radiologic and functional result and low rate of complication. And it seems that rAPC was available in case which have no sufficient residual bone stock. Also the pasteurization may have more advantages than that of the extracorporeal irradiation.

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Recycling Bone Autotransplantation with Extracorporeal Heat-Treatment for Malignant Bone Tumors of Pelvis (골반골의 악성 골종양의 재건술에서 체외 열처리를 이용한 재활용 자가골 이식술 및 인공 관절 치환술을 시행한 3례 보고)

  • Kim, Sae-Hoon;Lee, Sang-Hoon;Cho, Hwan-Sung;Kim, Han-Soo
    • The Journal of the Korean bone and joint tumor society
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    • v.9 no.1
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    • pp.115-123
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    • 2003
  • Study Design: A retrospective clinical and radiographic review. Objectives: The purpose of this study was to suggest recycling bone autotransplantation with extracorporeal heat-treatment as one of favorable reconstruction method for malignant bone tumors of pelvis through 3 cases. Summary of Literature Review: There are many biologic and nonbiologic reconstruction method in pelvic reconstruction. Cases: Case 1- A 20-year-old women had chief complaint of right hip and thigh pain started 3 months ago and done curettage and bone cementing at right ilium at other hospital. She had impression of malignant bone tumor and undergone postoperative radiation therapy for 6 cycles. After that she was referred to our hospital and undergone wide excision of right ilium and recycling bone autotransplantation with extracorporeal heat-treatment at 132 degree celsius for 2 minutes internal fixation with pelvic reconstruction plate and total hip replacement arthroplasty (ABG$^{(R)}$). There was no evidence of distant metastasis and revealed well-differentiated osteosarcoma on postoperative pathology. Neither adjuvant nor neoadjuvant chemotherapy were done. Case 2- A 56-year-old women who suffered right thigh pain for 3 months was detected radiologic abnormality at right pelvis. After incisional biopsy, osteosarcoma was diagnosed. We had undergone wide excision of right ilium and recycling bone autotransplantation with extracorporeal low heat-treatment at 65 degree celsius for 30minutes internal fixation with pelvic reconstruction plate and total hip replacement arthroplasty (ABG$^{(R)}$). There was no evidence of distant metastasis and revealed high-grade osteosacoma which was fibroblastic type on postoperative pathology. Adjuvant chemotherapy (HDMTX, ADR, CDDP) was done immediate after wound healing was completed. Case 3- A 46-year-old women was incidently found mass at left ilium which was suspected chondrosarcoma. We had undergone wide excision of left ilium and recycling bone autotransplantation with extracorporeal low heat-treatment at 65 degree celsius for 30minutes internal fixation with pelvic reconstruction plate and total hip replacement arthroplasty (Protek$^{(R)}$). There was no evidence of distant metastasis and revealed chondrosarcoma which was graded II/III on postoperative pathology. Results: Oncologic and functional outcome at final follow-up were for case 1, final follow-up time was 7 years, is no evidence of disease and functional score is 53% according to Ennecking et al. During follow-up, evidence of radiologic union was at about 1 and 6 months after operation. The case had breakage of pelvic reconstruction plate and some resorption of autotransplated bone, but no symptom present. For case 2, final follow-up was 3 years and 6 months, is no evidence of disease and functional score is 60%. For case 3, final follow-up was 7 months, no evidence of disease and functional score is 63% which is improving state. Discussion: 3 cases which were undergone recycling bone autotransplantation with extracorporeal heat-treatment and total hip replacement arthroplasty had relatively successful oncologic and functional outcome. Taking account that difficulty in using allograft in Korea this method is thoght to be one of the useful way to reconstruct pelvis after resection of primary malignant bone tumor of the pelvis.

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MCC 입자의 표면화학적 특성에 따른 부유부상 효과

  • 이학래;이진희;허용성;한신호;조중연
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2000.11a
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    • pp.41-41
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    • 2000
  • 부유부상 공정은 현재 신문고지와 사무용 고지의 탈묵을 통한 신문용지 및 화장지 제조 에 널리 사용되고 있는 고지재활용을 위한 핵심공정이다. 하지만 이들 공정은 갈수록 열악 해지는 국내 고지원료의 품질변화에 따라서 잉크 및 토너의 분리효율이 저하되고 있어 생산 되는 탈묵 펄프의 품질저하, 리젝트 발생량의 증대, 폐수 처리공정의 부하 증가 등 다양한 문제점을 발생시키고 있어 이에 대한 대책의 수립이 시급히 요청되고 있다. 현재와 같이 다양한 형태의 잉크 및 인쇄방식으로 인쇄된 많은 종류의 재활용지가 원료 로 투입되고 있는 경우 탈묵공정의 효율 향상을 위해서는 부유부상 공정에 대한 좀 더 체계 적이고 논리적인 접근이 필요하다. 이러한 문제점을 극복하기 위해 먼저 고지 재활용 공정 의 핵심 단위공정인 부유부상 공정에 관련된 복잡한 문제점을 단순화하여 고상 및 액상의 표면화학적 특성을 평가하고, 이에 따른 부유부상 공정의 효율을 분석하였다. 본 연구에서는 부유부상 공정을 기초과학적 측면에서 구명하기 위해 마이크로 크리스탈린 셀룰로오스(Microcrystalline cellulose: MCC)를 모델 물질로 사용하였고, 친수성 의 표면 특 성을 나타내는 MCC의 표면 특성을 바꾸기 위하여 AKD(alkyl ketene dimer)로 처리비율을 달리하여 사이징 처리하였다. 부유부상 실험에 사용된 MCC는 친수성을 띠는 것과 소수성 을 부여한 것을 구별하고 그 비율을 백색도를 통해 측정하기 위하여 자체적으로 친수성을 가지는 MCC는 세척 견뢰도가 높은 검은색 염료로 염색하였다. 준비된 친수성과 소수성 M MCC의 혼합비율 별로 패드를 작성하여 백색도를 측정함으로써 검량선을 작성하였다. 또한 부유부상 시간에 따른 제거효율을 알아보기 위하여 부유부상 시간별로 각각의 리젝트율과 수율올 측정하고, 리젝트 시료로부터 패드를 제조하여 백색도를 측정하였다. 실험 결과 소수성 MCC의 소수화 정도에 따라서 리젝트율이 증가하였으며, 이를 통해 표 면에 소수성을 띠는 입자는 소수성이 강할수록 부유부상공정에서 제거율이 증가한다는 것을 확인하였다. 부유부상 처리한 MCC로 패드를 제조한 뒤 백색도를 비교한 결과에서도 이를 확인하였다. 한편 리젝트로 함께 제거된 MCC 내에 존재하는 친수성 MCC의 양은 극히 미 세하였다. 또한 부유부상를 실시하는 초기에 상당량의 리젝트가 발생함을 확인하였는데, 이 는 전체 부유부상을 통해 제거되는 양의 45-68%였다. 한편 부유부상이 진행됨에 따라서 리젝트 양의 증가폭이 둔화되는 경향을 나타내었다. 이러한 경향은 MCC의 소수성이 강할 수록 더욱 뚜렷하게 나타났다. 이를 통해 계 내로부터 소수성인 물질이 급속하게 제거됨을 알 수 있었으며 필요 이상의 부유부상 처리는 잉크제거 효율을 높일 수는 있으나 소모되는 시간에 비하여 비효과적임을 알 수 있었다.

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Current Status and Characterization of CANDU Spent Fuel for Geological Disposal System Design (심지층 처분시스템 설계를 위한 중수로 사용후핵연료 현황 및 선원항 분석)

  • Cho, Dong-Keun;Lee, Seung-Woo;Cha, Jeong-Hun;Choi, Jong-Won;Lee, Yang;Choi, Heui-Joo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.6 no.2
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    • pp.155-162
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    • 2008
  • Inventories to be disposed of, reference turnup, and source terms for CANDU spent fuel were evaluated for geological disposal system design. The historical and projected inventory by 2040 is expected to be 14,600 MtU under the condition of 30-year lifetime for unit 1 and 40-year lifetime for other units in Wolsong site. As a result of statistical analysis for discharge burnup of the spent fuels generated by 2007, average and stand deviation revealed 6,987 MWD/MtU and 1,167, respectively. From this result, the reference burnup was determined as 8,100 MWD/MtU which covers 84% of spent fuels in total. Source terms such as nuclide concentration for a long-term safety analysis, decay heat, thermo-mechanical analysis, and radiation intenity and spectrum was characterized by using ORIGEN-ARP containing conservativeness in the aspect of decay heat up to several thousand years. The results from this study will be useful for the design of storage and disposal facilities.

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The development of green technology education program for Elementary school creative activities (초등학교 창의적 체험활동을 위한 녹색가술 교육프로그램의 개발)

  • Oh, Dong-Kyu
    • 대한공업교육학회지
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    • v.36 no.1
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    • pp.23-45
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    • 2011
  • The purpose of this study was the development of green technology education program for elementary school creative activities. The result of this study were follow. Basically this program was developed through three steps of preparation, development and improvement. First, in the preparation step, Need analysis were analyzed by investigation the needs of the society. Then the themes of this program were determined by thestages based on the National and social issues. Second, in the development step, the following was included. 1) Begin with Setting up education goals of this program. 2) selecting of learning object and content. 3) structuring educational program. Third, in the improvement step, program was verified of validity by experts

A study on the improvement of 3D animation production productivity (3D 애니메이션 제작 생산성 향상에 관한 연구)

  • Park, Hunjin
    • Journal of Software Assessment and Valuation
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    • v.17 no.2
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    • pp.101-107
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    • 2021
  • Animation production is collaborated by many experts and gives many ideas for new and interesting video production. Interesting video production is a problem directly related to the success of the project, so it can be said that it is better to create an environment that is not burdened with technical aspects in expressing ideas. In the actual keyframe animation production environment, ideas are frequently modified to obtain better results, and techniques that are re-used so that the animation key pose data developed at the early stage of the possible stage can be rewritten without abandoning it, and functions that can temporarily change the center of gravity contribute to the productivity of animation work and greatly help the creator to improve the creative atmosphere. This study analyzes action animations implemented in computer animation software to examine the factors that hinder actual productivity, and derives the technical concepts that can contribute to the improvement of animation production productivity and the necessity of developing related tools.

Characteristics of Concrete Sidewalk Block Manufactured Using Stone Powder Sludge and photocatalytic agent (석분슬러지와 광촉매제를 사용한 콘크리트 보도블록의 특성)

  • Jung, Yong-Wook;Lee, Seung-Han;Choi, Jong-Oh
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.6
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    • pp.4237-4244
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    • 2015
  • This study examined the efflorescence characteristics of a concrete sidewalk block manufactured using recycled stone powder sludge and photocatalytic generated by surface polishing during the sidewalk block manufacturing process. The study evaluated the characteristics of the sidewalk block in terms of its quality, based on the amount of stone powder sludge used, efflorescence, and further based on the mixing ratio and number of applications of the photocatalytic. The experimental results indicated that heavy metals such as lead, hexavalent chrome, cadmium, and mercury were not present in the concrete sidewalk block, thereby confirming the effectiveness of the recycled stone powder sludge. The optimum mixing ratio of used in the concrete sidewalk block (for satisfying KS standard values such as water absorption ratio and flexural strength) was found to be 20%. The concrete sidewalk block incorporating the stone powder sludge and photocatalytic exhibited a water absorption ratio of 5.4% and flexural strength of 5.2 MPa, thereby satisfying the quality standards. Additionally, when the photocatalytic was used, efflorescence did not occur even at the low temperature of $-5^{\circ}C$, and the by the sidewalk block was found to be 70% under normal conditions and 68% when subjected to an accelerated weathering test.

A Study on the Utilization of Coal Fired Fly-ash as Microfine Grouting Materials (초미립자 지반주입재로서 플라이애쉬의 적용성에 관한 연구)

  • 천병식;김진춘
    • Geotechnical Engineering
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    • v.14 no.6
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    • pp.113-125
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    • 1998
  • At the end of 1997 about 3 million tons of coal ash was produced as byproducts from the coal fired electrical power plants in Korea. Only about 27% of that byproducts was utilized as the admixtures of cement and concrete industry. But the large quantity of coal fired fly-ash has been used as the soil improvement materials in other countries. So the aim of this study is the estimation of the applicability of the coal fired fly-ash as microfine grouting materials by admixing the superfine particles which were separated from the coal fired fly-ash for the higher values. The 6 types of specimens were manufactured in the laboratory for the purpose of estimating the chemical and physical properties of cement and grouts. These specimens consisted of 2 specific surfaces of 6, 000 and 8, 000$cm^2$/g in Elaine method. And these specimens are devide into 3 ratios (30%, 50%, 70%) of fly-ash by weight. From the estimated properties of the coal fired fly-ash microflne cements and grouts, 50% fly-ash is the most suitable ratio for grouting materials. However, further study of durability is necessary for using fly-ash grouts practically at the field projects. The higher content of the unburned carbon of fly-ash increases the thinner layer of carbon on the surface of solution of grouts, and requires more quantity of surface active agent. As a results of this study, it is found that the microfine fly-ash is very useful as a good grouting material if 50% of fly-ash is added with the microfine portland cement. So, in the near future, if the coal fired fly-ash is able to be used as grouting material in Korea, the demand of fly-ash will increase rapidly.

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Synthesis of $TiO_2-Fe_2O_3$ Magnetic Photocatalyst Nanocomposite Powder (자성 광촉매용 $TiO_2-Fe_2O_3$나노복합분말의 합성)

  • 이창우;김순길;이재성
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.103-103
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    • 2003
  • 대기나 물에 용해된 여러 가지 유해한 유기물을 분해하기 위한 방안으로서 다양한 광촉매 재료를 이용하려는 시도가 진행되고 있다. 하지만 광촉매 반응은, 현탁액 내에서 submicrometer 크기를 갖는 반도체재료에서 발생하므로 처리된 폐수로부터 촉매를 제거해야 하는 정제공정 (downstream process)이 필요하며, 이는 경제적인 측면에서 큰 경비를 요구하게 된다. 이를 해결 하기 위하여, 가장 우수한 광촉매 재료로 평가받는 TiO$_2$를 glass beads, sands, silica gel등의 물질에 고정시키거나, TiO$_2$를 자성 입자에 코팅시킨 형태인, 자성 광촉매입자를 응용하려는 연구가 최근 활발하게 진행되고 있다. 따라서 본 연구에서는 광촉매의 고정화와 재활용 효율을 향상시키기 위하여 TiO$_2$ 나노입자를 y-Fe$_2$O$_3$ 나노입자의 표면에 코팅하여 나노입자의 큰 비표면적을 활용하고 미세구조를 제어하여 입자간의 고정특성과 자기적 특성의 제어기술을 확립하고자 하였다.

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