• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.7
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• pp.39-45
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• 2017

In this study, permeable repair materials mainly composed of silicate - based inorganic materials(SIM), which are easily available domestically, were prepared as a basic study for the development of permeable repair materials using SIM. SIM were compared and examined for their performance as repair materials by selecting a product group which has many cases of use in foreign countries. The SIM used were mainly composed of sodium, potassium and lithium silicate. Performance evaluation of SIM was performed by absorption and penetration, compression and adhesion, rapid chloride ion penetration, rapid freezing and thawing, and chemical resistance test. According to the test results, SIM showed effective performance in all areas, mainly because SIM permeates into the interior of the capillary and has a dense internal microstructure. Therefore, it can be used variously to improve the durability of concrete based on the results of this experiment.

• Applied Chemistry for Engineering
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• v.28 no.1
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• pp.29-34
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• 2017

This study provides the identification of corrosion cause substances in super heater tube from a commercial scale circulating fluidized bed boiler. Electricity is produced by the combustion of biomass mainly wood waste. The biomass, super heater tube, super heater tube ash, and boiler ash were collected and components associated with corrosion were analyzed. A large amount of oxygen-containing material was found due to oxidation. The chlorine content was analyzed as 6.1% and 4.3% in super heater tube ash and boiler ash respectively which were approximately 20 and 14 times higher than those of designed values. Also, alkaline metal contents (K, Na, Ca) were very high in ash samples collected from super heater tube and boiler. The tendency of slagging and fouling was predicted based on X-Ray Fluorescence (XRF) results. Basicity that can lead to slagging was estimated as 3.62 and 2.72 in super heater tube and boiler ash, respectively. Slagging would occur with ash content when considering the designed value as 0.35.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.7
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• pp.113-119
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• 2019

Concrete structures built on reclaimed land are combined with chemical erosion such as chlorine and sulfate ions from seawater. Chloride attack deteriorates the performance of the structure by corroding reinforcing bars. In addition, the waste water treatment structure has a problem that the concrete is deteriorated by the sulfate generated inside. Therefore, in this study, the characteristics and chemical resistance of low heat cement concrete used in wastewater treatment structures constructed on reclaimed land were evaluated. As a result of the experiment, the target slump and air content were satisfied under all the mixing conditions. The slump of low heat cement (LHC) concrete was higher than that of ordinary portland cement (OPC) concrete, while the air content of LHC concrete was smaller than that of OPC concrete with the same mix proportion. As a result of compressive strength test, OPC concrete showed higher strength at younger age compared to 28 days. In contrast, LHC concrete exhibited higher strength than OPC concrete at the age of 56 days. As a result of chlorine ion penetration tests, LHC-B concrete showed chlorine ion penetration resistance performance of the "very low" level at the age of 56 days. As a result of chemical resistance evaluation, when the LHC concrete is applied without epoxy treatment, chemical resistance is improved by about 18% compared to OPC concrete. In testing chemical resistance, the epoxy coated concrete exhibited less than 5% strength reduction when compared to sound concrete.

• Korean Journal of Food Science and Technology
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• v.43 no.1
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• pp.98-104
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• 2011

The storage quality of fresh buckwheat sprouts, as influenced by pretreatment and packaging within processing steps, was investigated to establish appropriate postharvest handling treatment for the commodity. After harvest, the sprouts were dipped in chlorine water (100 ppm), rinsed twice with clean water, pre-cooled with iced water, de-watered, and packed in plastic trays. Sprout samples taken from each processing step were stored at $5^{\circ}C$ for 6 days to measure quality attributes. Viable cell counts of mesophilic aerobes and coliform bacteria were lower by about 1 log scale in the postharvest treated samples compared to an untreated control, although the initial microbial reduction due to the postharvest treatments was offset by cell growth during storage. All sprout samples showed a decrease of fresh weight by approximately 4% after 6 days of storage. However, moisture and soluble solid contents were maintained at the initial levels of the sprouts. No significant difference in surface color was observed among sample treatments. For sensory properties including discoloration, wilting, decay, and visual quality, there were no significant differences among sample treatments. The present results suggest that proper postharvest processing treatments can exert positive effects on extending the shelf-life of fresh buckwheat sprout.

• Journal of the Korea Concrete Institute
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• v.17 no.5 s.89
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• pp.793-801
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• 2005

This study investigates fundamental properties of recycled aggregate concrete which incorporated 100% recycled coarse aggregate and various amount of recycled fine aggregate. In addition, for the purpose of the improvement of long term strength and durability, a part of cement was replaced with fly ash. Compressive strength and resistance to chloride ion penetration and carbonation were investigated. When the coarse aggregate was completely replaced with the recycled the replacement ratio of the fine aggregate with the recycled was recommended to be limited below 60% in the consideration of strength. The strength of the steam-cured specimen was very comparable to the wet-cured at 28 days. As fly ash content increased the resistance to chloride ion penetration was increased. The chloride ion penetrability based on the charge passed was found to be low at 21 days and very low at 56 days, respectively. Carbonation depth and carbonation velocity coefficient increased as the fly ash content increased and the relationship between the carbonation depth and recycled fine aggregate replacement ratio was not clear. Up to 28days, however, the measured carbonation depth was mostly less than 10mm which could be considered as low.

• Resources Recycling
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• v.30 no.6
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• pp.68-75
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• 2021

This study aims to investigate the manufacturing process of calcium chloride-based special cement, i.e., CCA (calcium chloro aluminate, C₁₁A₇·CaCl₂), which uses limestone, by using one type of random industrial by-product, domestic coal ash, cement kiln dust. The manufacturing process of was examined in detail, and the results suggested that the amount of CCA synthesized increased with an increase in the firing temperature. The manufacturing process of CCA was investigated at 1200℃, which was determined as the optimum firing temperature. The results showed that in general, the amount of CCA synthesized tended to increase with an increase in the firing time; however, the clinker melted when the firing time was more than 30 min, thereby suggesting that a firing time of less than 20 min would be suitable for the clinkering process. The optimal firing conditions for manufacturing CCA were obtained as follows: heating rate of 10 ℃/min, firing temperature of 1200 ℃, and holding time of 20 min. The results also suggest that manufacturing CCA will be easier when high chlorine-containing cement kiln dust is used.

• Journal of the Korea Institute of Building Construction
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• v.19 no.6
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• pp.511-520
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• 2019

The critical chloride content of rebar embedded in concrete was experimentally evaluated according to the admixture replacement ratio and admixture type. Four types of reinforced concrete were mixed OPC 100%, OPC 70% + GGBFS 30%, OPC 40% + GGBFS 60%, and OPC 40% + GGBFS 40% + FA 20%. NaCl solution was supplied to the specimens, and the open circuit potential of the embedded rebar was monitored. The specimens determined to initiate corrosion were cut at intervals of 5mm from the NaCl solution supply surface and conducted to chlorine ion profile. Corrosion initiation time of rebar embedded in concrete was delayed as the admixture replacement ratio increased. Looking at the critical chloride content of the types of reinforced concrete, it was highest in OPC 1.46kg/㎥, followed in order by S30 0.98kg/㎥, TBC 0.74kg/㎥, and S60 0.71kg/㎥.

• Proceedings of the Korea Water Resources Association Conference
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• 2012.05a
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• pp.712-712
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• 2012

하 폐수 처리방류수를 물리적, 화학적 그리고 생물학적 기술을 이용하여 처리한 후 재활용수로 이용하고자 하는 새로운 노력들이 진행되고 있지만 국내의 경우 방류수 재활용 기술과 처리수의 재이용에 대한 평가기술이 선진국에 비해 초기 단계에 있어 이 분야에 대한 적극적인 기술개발이 요구된다. 막 분리 기술을 이용한 처리 수는 소독 등의 추가적인 처리 없이 살수용수나 수경용수로 이용이 가능하며, 잔류염소를 유지시킬 경우 화장실 세정용수로의 이용도 가능하며, 또한 후처리 기술을 조합하면 고급 공업용수 등으로 사용가능하므로 선진기술로서 수요조건에 맞게 전 후 처리를 조합한 수요자 맞춤형 재이용수 공정기술을 개발할 필요가 있다. 이에 효율적인 하 폐수 재이용을 이용하여 농업용수(축산 음용수, 첨단 수출원예용수, 첨단 농업용수, 농산업 클러스터 복합 곡물 용수), 원예용수(원예단지), 공업용수 등의 다양한 용도에 활용 가능한 수요자 맞춤형 모듈 및 공정 개발을 수행하였다. 개발된 공정은 AOP 및 막 세정 시스템을 이용한 새로운 공정으로, AOP 시스템은 전기 이온 모듈을 통해 OH 라디칼을 생성 및 염분 제거 효율을 극대화 하여 오염 물질을 산화시키는 공정이며, FDA 시스템은 탁도가 높은 원수가 과다 유입 될 경우 후단 여과 막의 부하를 줄이는 역할을 하며, 부유 물질을 여과 시킨다. 막 세정 시스템은 미세 입자를 구성된 기포를 이용하여 눈에 보이지 않는 곳 까지 세척하며, 살균 작용을 하며, 분리 막의 성능을 증대 시킨다. 이어 UF 분리 막 시스템은 원수의 미세불순물, 박테리아, 스케일 물질 등을 제거하며, NF 시스템을 통하여 미립자, 박테리아 유기 화합물 및 2가 염 제거를 하여 재이용수를 생산하는 공정을 개발하였다. 개발된 수요자 맞춤형 공정은 하수 재이용 기술의 이용 목적 및 수요자별로 맞춤형으로 운영이 가능하며, 개발된 세척 기술은 분리 막 세정 유지관리비 및 에너지를 저감 할 수 있으며, 현장 적용의 실증화 과정을 거쳐 공정 기술을 신뢰도를 향상하고, 보유 기술을 수요자 맞춤형으로 업그레이드함으로써 기술의 경쟁력 및 고품질의 하수 재이용 기술의 새로운 방향을 제시 할 수 있을 것으로 판단된다.

• The Korean Journal of Pesticide Science
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• v.16 no.1
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• pp.28-34
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• 2012

We analysed 149 samples of Korean traditional herbal tea materials. The 156 pesticides were analyzed by GC/ECD and NPD, detected pesticides were confirmed by GC-TOF/MS. Sample preparation was performed bv multi-residue analysis method of multiclass pesticides of the Korea Food Code. The residual pesticides were detected in 22 samples(14.8%), the highest detection frequency samples are lycium and jujube. Detected pesticides in Korean traditional herbal tea materials were chlorpyrifos (5 samples), chlorothalonil (3 samples), cypermethrin (3 samples), hexaconazol (3 samples) and cyhalothrin(3 samples). The pesticide types detected in Korean traditional herbal tea materials were organophosphorus(29.2%), pyrethroids(16.7%), organochlorines (12.5%) and triazoles(12.5%). The 5 samples(lycium, jujube, chrysanthemum, balloon-flower, milk vetch root) were detected pesticides below MRLs, 2 samples(cornus fruit, cnidium) were detected pesticides unnotificated MRLs.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.8
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• pp.411-419
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• 2016

The objective of this study was to evaluate the application possibility of tube type electrolysis module system using recirculation process through removal organic matters and nitrogen in the pigment wastewater. The tube type electrolysis module consisted of a inner rod anode and an outer tube cathode. Material used for anode was titanium electroplated with $RuO_2$. Stainless steel was used for cathode. It was observed that the pollutant removal efficiency was increased according to the decrease of flowrate and increase of current density. When the retention time in tube type electrolysis module system was 180 min, chlorate concentration was 382.4~519.6 mg/L. The chlorate production was one of the major factors in electrochemical oxidation of tube type electrolysis module system using recirculation process used in this research. The pollutant removal efficiencies from the bench scale tube type electrolysis module system using recirculation operated under the electric charge of $4,500C/dm^2$ showed the $COD_{Mn}$ 89.6%, $COD_{Cr}$ 67.8%, T-N 96.8%, and Color 74.2%, respectively and energy consumption was $5.18kWh/m^3$.