• Proceedings of the Korean Environmental Sciences Society Conference
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• 2006.11a
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• pp.516-518
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• 2006

생분해성 고분자 재료들은 지구환경 보호측면에서 다양한 분야, 즉, 1회용 재료, 농업용 필름 및 생체적합성 재료(약물 방출, 봉합사) 등에서 실용화되거나 활발한 연구가 진행되고 있다. 이들 재료의 상업적응용은 물성, 분해능, 제조가격, 대량생산 등에 의해 좌우 될 수 있다. 이들 중 특히, 분해 속도의 측정 및 조절은 본질적인 응용에서 가장 중요한 위치를 차지 하고 있다. 분해 속도의 규명 및 조절은 제품의 수명을 제어할 수 있고 응용분야를 넓힐 수 있다. 본 연구에서는 단분자 막장치를 이용하여 생분해성 고분자의 분해 속도 및 이성질체간의 complex 형성을 통한 분해속도의 제어를 연구하였다. complex의 형성은 분해성 고분자의 분해속도를 현저히 감소시키는 것으로 나타났다.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.3
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• pp.17-24
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• 2019

Carbon Fiber Reinforced Polymers(CFRP) has widely utilized as a material for rehabilitation because of its light-weight, deformability and workability. Because CFRP is brittle material whereas steel is ductile, it is inappropriate to apply conventional design approach for steel reinforcement. For ductile material, the behavior of combined elements is on average of that of unit element due to the stress redistribution between elements after yielding. Therefore, the mean value of the stress of combined elements is equal to that of unit element and the standard variation is smaller. Therefore, although the design value can increase, it is used as constant value because it is conservative and practical approach. However, for brittle material, the behavior of combined elements is governed by the weaker element because no stress redistribution is expected. Therefore, both the mean value and standard variation of the stress of combined elements decreases. For this reason, the design value would decrease as the number of element increases although it is eventually converged. In this paper, in brittle material, it is verified that the combination of unit element with normal distribution results in combined element with weibull distribution, so the modifying equation of mechanical properties is proposed with respect to the area load applied.

• Polymer(Korea)
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• v.24 no.5
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• pp.599-609
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• 2000

In order to improve the mechanical properties of unsaturated polyester (UPE) resins, the UPE resins with different glycol molar ratios were prepared. The effects of molar ratios of the UPE resins on the curing behaviors and mechanical properties were investigated. The microgel reaction mechanism was employed to characterize the system. It was found that the final conversion increased with increasing NPG molar ratios, and the conversion at the peak of differential scanning calorimetry (DSC) thermogram appeared to decrease with increasing NPG molar ratios. The flexural strength, tensile modulus, water resistance, and infiltration increased with increasing NPG content, but the tensile strength, tensile elongation, and flexural modulus decreased. Among the UPE resins prepared from the glycols with the molar ratios (PG/NPG) of 0.5/0.5, 0.25/0.75, those of laminated composites plates showed better mechanical properties.

• Korean Journal of Materials Research
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• v.9 no.9
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• pp.900-904
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• 1999

The effects of Tio$_2$addition on the microstructural evolution and mechanical properties of alumina ceramics were studied. Bulk density decreased with an increase of the amount of TiO$_2$. Apparent porosity decreased with an increase of the amount of TiO$_2$ up to 7wt%. But beyond 9wt% of TiO$_2$powders, apparent porosity increased. In the compression test, the modulus increased with an increase of the amount of TiO$_2$addition. In the three point bending test, the stress at yield decreased with an increase of the amount of TiO$_2$ addition. The addition. The addition of TiO$_2$ promoted the grain growth of alumina ceramics.

• Polymer(Korea)
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• v.25 no.6
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• pp.774-781
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• 2001

In order to reuse the waste matters, the polyester hybrid composites were fabricated with the waste stone (WSP) and waste tire (WTC). Before mixing, the waste fillers were treated with the silane coupling agent [${\gamma}$-methacryloxy propyl trimethoxy silane(${\gamma}$-MPS)] for enhancing the dispersion of the fillers and interfacial bonding with polymer matrix. Mechanical properties and morphologies of the resulted hybrid composites were investigated with the filler content. The hybrid composites containing surface treated fillers have high initial thermal decomposition temperature and low weight loss compared to the untreated one. The highest mechanical properties of composites were obtained with the ${\gamma}$-MPS (2 wt%) treated fillers. The porosity of composite increased with the content of organic filler which can be reduced by the silane surface treatment of fillers. The pore size distribution of the composites varied with the waste filler content.

• Applied Chemistry for Engineering
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• v.27 no.2
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• pp.179-184
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• 2016

In this work, the influence of milled carbon fiber direction on mechanical properties of milled carbon fibers/carbon blacks/natural rubber compounds was investigated. The compounds were prepared by adding the 6 phr milled carbon fibers (MCFs) and 40 phr carbon blacks (CBs) into the natural rubber. The MCFs were aligned in a parallel and orthogonal direction in the compounds using two-roll-mill machine. Mechanical properties of compounds were studied by tensile characteristics and tearing strength. As a result, the compounds showed higher tensile strength, 100%~300% modulus, and tearing strength than those of using any other compounds due to the aligning MCFs in parallel. Mechanical properties of the compounds reinforced with non-aligned MCFs were inferior to those of others. Consequently, the parallel aligned MCFs in the compounds led to an increase of tensile properties and improvement of tearing strength, resulted from MCFs with the high elastic modulus.

• Applied Chemistry for Engineering
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• v.23 no.3
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• pp.313-319
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• 2012

In this work, the electroplating of copper was introduced on PAN-based carbon fibers for the enhancement of mechanical interfacial strength of carbon fibers-reinforced composites. The surface properties of carbon fibers were determined by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and contact angle measurements. Its mechanical interfacial properties of the composites were studied by interlaminar shear strength (ILSS) and critical stress intensity factor ($K_{IC}$). From the results, it was found that the mechanical interfacial properties of Cu-plated carbon fibers-reinforced composites (Cu-CFRPs) enhanced with increasing the Cu plating time, Cu content and COOH group up to Cu-CFRP-30. However, the mechanical interfacial properties of the Cu-CFRPs decreased dramatically in the excessively Cu-plated CFRPs sample. In conclusion, the presence of Cu particles on carbon fiber surfaces can be a key factor to determine the mechanical interfacial properties of the Cu-CFRPs, but the excessive Cu content can lead the failure due to the interfacial separation between fibers and matrices in this system.

• Composites Research
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• v.33 no.6
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• pp.390-394
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• 2020

The carbon fiber has been damaged via tow spreading process for carbon fiber spread tow. The fiber damage is caused by friction between equipment and fibers or between fibers and fibers in the process of spreading. As a result, mechanical properties are decreased due to differences in process via material and equipment condition. Therefore, minimizing fiber damage have to be considered in the process. In this study, the change in carbon fiber pneumatic spreading process was observed by according to the filament count, sizing content of carbon fiber and process variables in spreading equipment (fiber tension at the beginning, air temperature in spreading zone, vacuum pressure in spreading zone). Tensile strength was evaluated using samples prepared under optimal conditions for each of the carbon fiber varieties, and mechanical properties were reduced due to damage on the carbon fiber.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.31 no.1
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• pp.24-31
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• 2021

We report structural, mechanical, and thermal properties of diecast ADC12 aluminum alloys characterized using synchrotron X-ray diffraction (XRD), scanning electron microscopy, energy dispersive X-ray (EDX) analysis, thermal conductivity (λ), Vickers hardness (Hv), and stress-strain measurements. We also studied the effect of post-annealing performed in a vacuum atmosphere on the mechanical properties of diecast ADC12 alloys. EDX and XRD results revealed that Al2Cu and AlCu3 grains are formed, well dispersed in Al base and highly crystalline. Ultimate tensile strength (UTS) of 307.9 ± 9.1 MPa and elongation of 2.98 ± 0.62 % were estimated. λ was 129.3 ± 0.27 W/m·K and Hv was approximately 130. Both values were significantly higher than the reported values. At annealing temperatures ranging from 25 to 200℃, UTS and Hv values remained constant, while as the annealing temperature increased to 500℃, these values gradually decreased. This is because stabilization of the microstructure improves toughness and ductility.

• Composites Research
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• v.20 no.6
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• pp.1-7
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• 2007

Expanded graphite/carbon fiber hybrid conductive polymer composites were fabricated by the preform molding technique. The conductive fillers were mechanically mixed with a phenol resin to provide an electrical property to composites. The conductive filler loading was fixed at 60wt.% to accomplish a high electrical conductivity. Expanded graphites were excellent in forming a conductive networking by direct contacts between them while it was hard to get the high flexural strength over 40MPa with using only expanded graphite and phenol resin. In this study, carbon fibers were added in composites to compensate the weakened flexural strength. The effect of carbon fibers on the mechanical and electrical properties was examined according to the weight ratio of carbon fiber. As the carbon fiber ratio increased, the flexural strength increased until the carbon fiber ratio of 24wt.%, and then decreased afterward. The electrical conductivity gradually decreased as the increase of the carbon fiber ratio. This was attributed to the non-conducting regions generated among the carbon fibers and the reduction of the direct contact areas between expanded graphites.