• Title/Summary/Keyword: 재료 물성감소

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Properties of Sawdust Board Made from Thinned Logs( I ) - Effect of Pressure and Press Time (간벌재로 제조된 톱밥보드의 물성(I) - 가압압력 및 열압시간의 영향 -)

  • 오승원
    • Journal of Korea Foresty Energy
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    • v.21 no.2
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    • pp.10-16
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    • 2002
  • In this study, sawdust boards with a density 0.6g/$cm^2$, powder phenol resin containing 10% were made from thinned logs of Pinus densiflora, Larix leptolepis and Pinus koraiensis. Four levels of the pressure and press time were designed to investigate the effect on the properties of sawdust boards. Thickness swelling and water absorption were increased as press time was decreased. The condition of 3-stage pressure for lower thickness swelling and water absorption of board was 40$\rightarrow$30$\rightarrow$20kgf/$cm^2$. Bending strength and brinell hardness were decreased as press time was decreased. But there have no change with pressing pressure. These results indicated that properties of sawdust board were affected by press time.

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Dental Properties of Hydroxyapatite Filled Polymer Composite (수산화인회석이 충전된 고분자 복합체의 치과적 물성)

  • Kim Oh-Young;Seo Ki-Taek
    • Polymer(Korea)
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    • v.30 no.2
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    • pp.135-139
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    • 2006
  • To evaluate the dental restorative application of polymer composites filled with hydroxyapatite (HAP) which is an inorganic component of human bone material, dental properties of the polymer composites were investigated. A visible light system was utilized to activate the acrylate resin matrix of the composites. Maximum loading percentage of HAP in composite was 65 wt% and the depth of cure was 6.0 mm which can be applicable for dental restoration. With increasing the HAP content, degree of conversion of polymer composites was slightly decreased, however, polymerization shrinkage value was not varied. Diametral tensile strength value was enhanced with an increase of HAP content, however, there was no strict trend between flexural strength and HAP concentration. Anyhow, polymer composites prepared herein have superior mechanical properties sufficient specifications applicable to dental materials.

A Study on the Effect of Reducing the Saturation Magnetization by Substituting the Non magnetic Ion in Mg Mn Ferrites (Mg-Mn훼라이트의 비자성 이온첨가에 의한 포화자화 감소효과)

  • Yu, Byeong-Du;Kim, Jong-O
    • Korean Journal of Materials Research
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    • v.4 no.1
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    • pp.117-124
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    • 1994
  • The reduction of saturation magnetization in the Mg-Mn microwave ferrites was achieved by substituting the non-magnetic A1 ion for Fe ion. It is necessary for extending the operation frequencies that there is no change in other properties of the microwave ferrites. The electrical and magnetic properties are characterized where the composition of the ferrites studied was given by the general formula $(MgO)_{1.0}(MnO)_{0.1}(Al_xFe_{1.9-x}O_{2.85}$ with x ranging from 0.1 to 0.4. The saturation magnetization and the ferromagnetic resonance linewidth was decreased by the substituting amount of $Al_2O_3$. The value of coercive field was low enough over the composition of x=O.2 and the high squareness ratio was obtained all over the amount of substitution. It is feasible to select the proper application area with the combination of various properties ; that is, low coercive field, high squareness ratio, optimum saturation magnetization and ferromagnetic resonance linewidth.

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Preparation and Properties Enhancement of Epoxy Resin Employing Poly(amic acid) (PAA) (Poly(amic acid) (PAA)를 함유한 에폭시 수지의 제조 및 물성 향상)

  • 이용택;배성호;박병천
    • Polymer(Korea)
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    • v.25 no.2
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    • pp.254-262
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    • 2001
  • Epoxy resin based upon the N,N'-diglycidylaniline which is widely used in optic, electronic and composite material. We modified this epoxy resin with poly(amic acid) (PAA) that is a precursor of polyimide. To improve the mechanical property we controlled PAA content and imidization ratio. PI-modified epoxy blends were prepared for the formation of IPN structure. The possible reaction in the epoxy resin/PAA blends were investigated by FT-IR and inherent viscosity techniques. Thermal properties are measured by TGA, DSC, and TMA. Mechanical properties are measured by UTM and impact test machine. Morphology is investigated by SEM. Thermal stability improved with increasing the content of PAA in blends. As the content of PAA increases in blend, the glass transition temperature and thermal expansion coefficient decreases. Increasing impact strengths in J/m in the range of 920∼2412 were observed in blends. The PAA segment may act as a toughening agent in the epoxy networks, thus contributing the impact strength improvement of the blends.

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Experimental Study on the Damage of Concrete Material by Impact Load (충격 하중에 의한 콘크리트 재료의 손상에 관한 실험적 연구)

  • Song, Jeong-Un;Park, Hoon;Kim, Seung-Kon
    • Explosives and Blasting
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    • v.27 no.2
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    • pp.26-32
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    • 2009
  • Although the number of blasting operations in urban area are growing, lesser attentions have been paid to the effects of impact load on nearby concrete structures. In this study, the properties of concrete were obtained by both the sonic velocity and Schmidt rebound tests, and the degree of damage in concrete material was evaluated by measuring the sonic velocity in sample before and after applying the impact load. The test results shows that the sonic velocity decreases with the increase of intensity of impact load, and the degree of damage in concrete samples is lower when the samples have higher strength and sonic velocity.

Influence of Thickness and Temperature on Delamination Properties of Stitched Carbon Fiber Reinforced Plastics (스티칭 된 탄소섬유 강화 복합소재의 박리 특성에 온도와 두께가 미치는 영향)

  • Yongjun So;Kwak Jin Bae;Han-Gyu Kim;Jaesang Yu
    • Composites Research
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    • v.37 no.5
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    • pp.386-392
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    • 2024
  • Stitching is one of the techniques used to improve the through-thickness properties of CFRPs. In this study, the enhancement of CFRP properties through stitching for aerospace applications was investigated with considering high-temperature conditions and thickness effect. Stitched CFRPs were observed to have 18.2% higher maximum loads and 33.2% higher elastic moduli than non-stitched CFRPs. In addition, as the areas exposed to high temperatures increased, the mechanical properties of the CFRPs decreased regardless of stitching. In thick CFRPs, the load drop rate was complemented by stitching yarn. However, for thin CFRPs, there was no significant change in load drop rate. Additionally, it was observed from testing of the thin CFRPs that multi-layer delamination occurred as the precrack propagation direction changed due to stitching yarns. This study highlights the influence of various factors that need to be considered for the application of CFRPs in the aerospace field, and suggests improving weaknesses by enhancing mechanical properties through stitching. Finally, new perspectives on temperature conditions are presented.

Estimation of Pyrolysis Properties for Fire Propagation Analysis of Furniture Materials (가구소재의 화재전파해석을 위한 열해리 물성 평가)

  • Kim, Sung-Chan
    • Fire Science and Engineering
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    • v.27 no.4
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    • pp.41-46
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    • 2013
  • The present study has been conducted to investigate the reaction kinetics and pyrolysis parameters for flame propagation analysis of furniture material components. TGA measurement for component materials such as MDF (medium density fiberboad) panel including coating material, synthetic leather and foam cushion are performed under maximum temperature of $600^{\circ}C$ and heating rate of $10^{\circ}C/min$. The results of TGA have shown that the peak temperature of MDF panel was $324^{\circ}C$ and the initial peak temperature of coating material decreased by $270{\sim}280^{\circ}C$. In the case of synthetic leather and foam materials, the reference temperature and reference rate depend on the type of polymer consisting the sample, the initial kinetic characteristics was classified into 2 categories of about $270^{\circ}C$ and $420^{\circ}C$ of reference temperature for the tested synthetic materials. The present study showed the pyrolysis parameters of reference temperature and reference rate proposed by Lyon to evaluate the pre-exponential factor and activation energy. The present study can contribute to improve the reliability of computational fire analysis and enhance the understanding of fire propagation phenomena based on the thermal properties study of material.

Development of Oxo-biodegradable Bio Film by Using Biodegradable Catalyst (생분해 촉매제를 이용한 산화생분해 바이오 필름 개발)

  • Rhee, Jin-Kyu;Jung, Dong Seok;You, Young-Sun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.22 no.3
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    • pp.127-134
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    • 2016
  • In this study, Biodegradable masterbatch (M/B) was prepared by different kinds and content of biodegradable catalysts added to oxo biodegradable plastics. The bio film was prepared by adding biodegradable M/B to the polyethylene pellet, and the change of physical properties by UV and heat treatment and the stability as food packaging material were confirmed. As a result of the physical property change, Fe salt and Al salt bio film was superior to Ni salt bio film about a decrease in physical property. However, considering the raw material cost and industrial availability, M/B containing Fe salt was selected and additional experiments were conducted by concentration. The bio films prepared with Fe salt M/B 1.0, 1.5 and 2.0 wt% showed excellent physical properties.

The Influence of E-beam Irradiation on POLY(ETHER-BLOCK-AMIDE) (PEBA, Pebax) (전자 빔 조사후 PEBA (Poly Ether Block Amide)의 구조 및 기계적 특성 변화)

  • Shin, Sukyoung;Cho, SangGyu
    • Progress in Medical Physics
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    • v.25 no.4
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    • pp.205-209
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    • 2014
  • Medical polymers require sterilization and must be able to maintain material properties for a specified shelf life. Sterilization can be achieved by using gamma or e-beam exposure. In this study, accelerated aging tests of poly(ether-block-amide) (PEBA) copolymer samples is presented. PEBA copolymer samples with different polyether content that result in Shore hardness of 35D to 72D, were sterilized using e-beam radiation followed by accelerated aging at $55^{\circ}C$. E-beam sterilization effect on molecular weight and mechanical property has performed and analyzed. The average molecular weight significantly reduced as a result of ageing. The enlarged proportion of low molecular weight chains in the aged samples is consistent with the generation of degradation products produced by oxidative chain scission. Also E-beam materials have shown decreased tensile strength and elongation. Overall, this study demonstrated that the medical grade PEBA was significantly affected by radiation exposure over aging time, particularly at high irradiation doses. For medical use in case of radiation sterilization required, it is recommended to avoid Pebax material. If Pebax material must be in use for medical device, recommend to use alternate sterilization method such as Ethylene Oxide sterilization.

A Study on Processing-Structure-Property Relationships of Extruded Carbon Nanomaterial-Polypropylene Composite Films (탄소나노튜브 및 그래핀 나노플레이트 폴리프로필렌 복합재 필름 압출 및 물성 평가)

  • Kim, Byeong-Joo;Deka, Biplab K.;Kang, Gu-Hyuk;Hwang, Sang-Ha;Park, Young-Bin;Jeong, In-Chan;Choi, Dong-Hyuk;Son, Dong-Il
    • Composites Research
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    • v.26 no.4
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    • pp.254-258
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    • 2013
  • Polypropylene films reinforced with multi-walled carbon nanotubes and exfoliated graphite nanoplatelets were fabricated by extrusion, and the effects of filler type and take-up speed on the mechanical properties and microstructure of composite films were investigated. Differential scanning calorimetry revealed that the addition of carbon nanomaterials resulted in increased degree of crystallinity. However, increasing the take-up speed reduced the degree of crystallinity, which indicates that tension-induced orientations of polymer chains and carbon nanomaterials and the loss of degree of crystallinity due to rapid cooling at high take-up speeds act as competing mechanisms. These observations were in good agreement with tensile properties, which are governed by the degree of crystallinity, where the C-grade exfoliated graphite nanoplatelet with a surface area of $750m^2/g$ showed the greatest reinforcing effect among all types of carbon nanomaterials used. Scanning electron microscopy was employed to observe the carbon nanomaterial dispersion and orientation, respectively.