• Journal of Korean Tunnelling and Underground Space Association
• /
• v.9 no.3
• /
• pp.299-307
• /
• 2007

In this study, a new concept for simulating a physical damage of tunnel shotcrete lining due to a long-term chemical deterioration has been proposed. It is known that the damage takes place mainly by internal cracks, reduction of stiffness and strength, which results mainly from volume expansion of the lining and corrosion of cement materials, respectively. This damage mechanism of shotcrete lining appears similar in most kinds of chemical reactions in tunnels. Therefore, the mechanical deterioration mechanism induced by a series of chemical reactions was generalized in this study and mathematically formulated in the framework of thermodynamics. The numerical model was implemented to a 3D finite element code, which can be used to simulate behaviour of tunnel structures undergoing external loads as well as chemical deterioration in time. A number of illustrative examples were given to show a feasibility of the model in tunnel designs.

• Journal of the Korea Institute of Building Construction
• /
• v.18 no.5
• /
• pp.455-461
• /
• 2018

The purpose of this study is to evaluate the tensile strength performance of the polyurethane coating material used as the waterproofing material in concrete structures. A linear regression equation is proposed to establish a correlation on the tensile strength of polyurethane coating membrane against periodic exposure to chemical degradation. The polyurethane film membrane showed a minimum strength of 23% to a maximum of 38% when subjected to chemical degradation. The elongation rate showed a relation with the tensile strength deterioration rate of at least 15% to 22% at maximum, and the proposed regression equation could be used to predict the degree of performance change of the polyurethane coating membrane under chemical degradation condition.

• Proceedings of the KIEE Conference
• /
• 2008.05a
• /
• pp.141-142
• /
• 2008

국내 배전선로에서는 1999년부터 폴리머피뢰기를 설치하여 운영하고 있으나, 이들의 열화특성에 관한 데이터와 적합한 평가방법이 부족하여 장기적인 운영계획 수립이 어려운 상태이다. 이에 따라 본 논문에서는 폴리머피뢰기의 현장 열화인자를 인가할 수 있는 복합가속열화 시험장치를 제작하고 국내 환경조건을 모의할 수 있는 시험주기를 개발하여 폴리머피뢰기 완제품에 대한 장기신뢰성 평가법을 제안하였다. 그리고 가속열화시험 및 현장설치에 의한 전기적, 화학적 특성변화를 분석하여 폴리머피뢰기의 열화정도를 평가함으로써 본 연구에서 제안한 평가기법의 실효성을 검증하고 국산 폴리머피뢰기의 유지보수에 필요한 특성 데이터를 제시하였다.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.20 no.10
• /
• pp.141-150
• /
• 2006

In this study we developed accelerated aging test cycle and equipment which can simulate domestic weather condition. And we proposed long term reliability assessment method for polymer housed distribution surge arresters. We carried out electrical and chemical analysis of the arresters which are used for accelerated aging test and outdoor exposure test. Through the analysis we verified the capability of the proposed method and we presented characteristic data for maintenance of domestic arresters.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.12 no.5
• /
• pp.55-64
• /
• 2008

Shotcrete have become a deterioration which was exposed to harmful environments. In this study, in order to evaluate the deterioration properties of shotcrete, visual examination, compressive strength, adhesive strength, microstructural analysis were investigated up to the 60th weeks of exposure. The attack solutions for test are sodium sulfate and hydrochloric acid solution with different concentrations, respectively. From the results, although the compressive strength of shotcrete specimens and the adhesive strength between specimens and rocks were high at the early immersion age, they rapidly dropped in the subsequent phases, especially in 5% sodium sulfate and pH1 hydrochloric acid solution. With continued exposure, various harmful ions penetrated into the shotcrete specimen, reacted with the cement hydrate, and generated expansion substances. It was verified that the shotcrete specimens suffered a serious deterioration by chemical attack.

• Journal of the Korean BIBLIA Society for library and Information Science
• /
• v.12 no.2
• /
• pp.71-84
• /
• 2001

The purpose of this study is to provide the methods of preservation for paper, microfilm, digital media. First of all, for acidic papers produced in 19~20 centuries, this study evaluates and analyses deterioration and factors causing deterioration. For book, also, environmental condition for preservation, and a preservation mechanism through acid-free procedure were suggested. Second for microfilm, it emphasized physical and chemical properties, oxidised substance during developing film, materials related to preservation. Third, for digital storages, storage conditions and needs, such as life-cycle and capacity were introduced.

• Proceedings of the Korean Radioactive Waste Society Conference
• /
• 2005.06a
• /
• pp.211-220
• /
• 2005

The concrete structure is being considered for the main engineered barrier of low and intermediate level radwaste disposal facility. Concrete of low permeability can minimize infiltration of water and effectively prevent release of nuclide to ecosystem. But if concrete degrades, structural stability of disposal structure will decrease while permeability increase, resulting in increased possibility of nuclide release due to water infiltration. Therefore disposal concrete structure degradation shall be minimized to maintain capacity of nuclide isolation. The typical causes of concrete structure degradation are sulfide attack, reinforcement corrosion due to chloride attack, leaching of calcium hydroxide, alkali-aggregate reaction and repeated freezing-thawing. The common cause of these degradation processes is infiltration of water or adverse chemicals into concrete. Based on the study of these degradation characteristics and mechanisms of concrete structure, the methodology of design and service life evaluation of concrete structure as an engineered barrier are reviewed to ensure its long-term durability.

• Proceedings of the KIEE Conference
• /
• 2004.07c
• /
• pp.1906-1908
• /
• 2004

본 논문은 옥외용 고분자 절연물로 널리 사용되고 있는 실리콘 고무의 장기 자외선 가속열화에 따른 특성변화를 조사하였다. 이를 위해 전기적인 평가 방법 이외에 각종 화학적 분석기기를 사용하여 보다 정확히 재료의 열화를 판정하고자 하였다. 연구결과, 실리콘 고무는 내후성이 우수하지만, 가속열화가 진행되면서 표면의 전기적 저항률이 높아지고, 전하축적이 용이해지는 표면구조로 변하는 것을 확인하였다. 또한, 재료 내에서 발수성 회복역할을 하는 저분자량 성분이 감소하였고, 열적특성이 변화되는 것을 확인하였다. 이를 통하여, 최근 확산되고 있는 옥외용 고분자 절연물의 성능평가 및 수명예측에 도움이 되고자 하였다.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.7 no.2
• /
• pp.143-152
• /
• 2005

Shotcrete for support of tunnel structures may contact with groundwater. The hazardous components in groundwater may cause corrosion of shotcrete. Also, the hazardous components may deteriorate the engineering properties of shotcrete, such as compressive strength, bond strength, flexural strength and so forth. The more the effect of the hazardous components on the shotcrete may increase, the more the stability of tunnel structure may decrease. The specimens were artificially immersed in various chemical solutions including hazardous components after the specimens were made at the tunnel construction site. It was performed to analyze the effect of the hazardous components in ground water on the engineering properties of shotcrete. The uniaxial compressive strength test, XRD, SEM were conducted to evaluate the durability and corrosion of shotcrete.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2003.05e
• /
• pp.40-43
• /
• 2003

전기방전에 대한 shed 재료의 열화내성과 우수한 발수성의 장기간 유지특성은 폴리머 애자의 장기성능에 있어서 가장 중요한 인자들이다. 애자 제조시 무결점 성형성 또한 중요한데 열화내성을 확보하기 위해 다량의 ATH의 첨가가 수반되기 때문에 적절한 process oil의 사용이 불가피하다. 사용하는 오일의 종류와 량에 따라 옥외절연물의 장기성능에 영향을 주는 표면발수성이나 방전내성은 크게 차이가 나는 것으로 밝혀지고 있다. 본 논문에서는 화학적 구조와 정도가 다른 몇 가지 실리콘 fluid들을 실리콘 고무에 처방하여 기본물성과 초고압 옥외절연물의 shed 재료로서 장기성능에 영향을 주는 방전열화내성과 표면발수성의 회복특성을 평가하였다. 실리콘 고무의 무결점 사출성형에 가소도가 중요한데 동일한 무기물 첨가조건에서 유사한 가소도를 갖게 하는데 필요한 량은 fluid들의 종류에 따라서 상당한 차이가 있었다. 특히 PDMS는 점도는 낮지만 분자량이 커서 많은 량이 첨가되어 기계적 특성저하가 크게 일어났다. 코로나 처리후 발수성 회복특성은 fluid들의 분자크기와 반응기의 종류에 따라 상당히 영향을 받았으며 분자가 클수록 초기회복속도는 다소 느려도 최종의 상시발수성은 다소 높게 유지되었으며 2일 이내에 거의 초기 접촉각으로 회복되었다. 내아크성은 무게손실이 적을수록 오차범위도 작은 안정된 특성을 보였으며 fluid들의 종류에 따른 무게손실의 차이는 크지 않았다. 트래킹 방전에 의한 무게 감소는 fluid의 분자가 크면서 페닐기를 가진 fluid들이 첨가된 고무가 우수한 특성을 보였다.