• Title/Summary/Keyword: 장기 안정성

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High Voltage Performance of the Electrical Double Layer Capacitor with Various Electrolytes (다양한 전해액을 적용한 전기이중층 커패시터의 고전압 특성 연구)

  • Kim, Jung Wook;Choi, Seung-Hyun;Kim, Jeom-Soo
    • Journal of the Korean Electrochemical Society
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    • v.20 no.2
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    • pp.34-40
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    • 2017
  • Electric double layer capacitors (EDLC: electric double layer capacitors) have drew attention as an energy storage device for the next generation because of their outstanding power capability and durability. But their usage is somewhat limited due to low energy density over secondary batteries. One of methods to improve the energy of EDLC is expanding the voltage window of cell operation by increasing the charge cut-off voltage. In this study, $SBP-BF_4$ (spirobipyrrolidinium tetrafluoroborate), $TEA-BF_4$ (tetraethylammonium tetraflouroborate) and $EMI-BF_4$ (1-ethyl-3-methylimidazolium tetrafluoroborate) in AN (acetonitrile) were selected to evaluate the possibility of application at high voltage environment. The LSV (linear sweep voltammetry) measurements showed that the 1.5M SBP-BF4/AN electrolyte was stable over a wide potential window and showed the best electrochemical performance compared to other combinations of electrolytes at high voltage environments (over 3.0 V). Furthermore, TMSP (tris(trimethylsilyl) phosphite) was applied to 1.5M SBP-BF4/AN in order to maintain stable performance at high voltage for the long period of time. The electrolyte with TMSP additive showed the capacity retention of 93% after 10,000 cycles at 3.3 V.

A Study on the Possibility of Malondialdehyde(MDA) as Indicator of Forest Therapy Effectiveness (산림치유 효과 측정 지표로써 과산화지질의 활용가능성 분석)

  • Jeong, Mi-Ae;Park, Sujin;Park, Chan-Woo;Lee, Jeong-Hee;Kwon, Jino
    • Journal of Korean Society of Forest Science
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    • v.102 no.4
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    • pp.530-536
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    • 2013
  • This study aimed to analyze and compare results from psychological relaxations by using profile of mood state (POMS) and Malondialdehyde (MDA) level as a scale of oxidative damage before and after walking in the forest and on the street. 29 participations (15 men and 14 women) walked in the forest and on the street for 30 minutes of each for two days. The participations filled a questionnaire for POMS and conducted an heart rate variability test, oxidative damage test (MDA as biological marker through a urine test) before and after walking. To compare the psychological states after walking in the two difference places, walking in the forest showed statistically more meaningful results in the section of tension, depression, anger, fatigue, confuse and total mood disturbance (p<0.01) than walking on the street. According to the MDA results, a concentration of MDA showed significant increase after walking on the street (p=0.014). On the contrary to this, a concentration of MDA tended to decrease after walking in the forest (p=0.076). The study showed that the psychological states were more stable and oxidative damages were more decreasing after walking in the forest than walking on the street. In the conclusion, MDA would be biological indicator for assessing the effect of alleviation on the oxidative stress after walking in the forest.

Treatment of Ruptured Posterior Cruciate Ligament using Augmentation of the Synthetic Polyester Prosthetic Ligament (Synthetic Polyester Prosthetic Ligament 보강술을 이용한 후방 십자 인대 손상의 치료)

  • Sohn, Sung-Won;Jeon, Si-Hyun;Park, Jin-Uck
    • Journal of the Korean Arthroscopy Society
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    • v.6 no.2
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    • pp.121-125
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    • 2002
  • Purpose : The purpose of this study was to assess the clinical outcomes and radiological changes of arthroscopic augmentation with synthetic polyester ligament for posterior cruciate ligament injury Materials and Methods : The assessment was made among 60 patients who underwent arthroscopic augmentation with synthetic polyester ligament (ABC ligament, Surgicraft, U.K.) into the substance of ruptured PCL proper under the arthroscopic control from January, 1990 to January, 1996 and whose follow-up period was more than 5 years (average 7.8 years). The results were analyzed by using the posterior stress radiographs by Telos stress device, KT-2000 arthrometer and the clinical assessment by using Lysholm knee score. Results : The average difference of posterior displacement on stress radiographs were 13.2 mm preperatively and 3.6 mm at last follow up. Both knee showed minimal difference on KT-2000 arthrometer (0.7 mm on 20 lb) at the last follow-up. The mean Lysholm knee score was 49.2 preoperatively and improved to 84.3 post-operatively. Conclusion : Authors observed that long-term results of arthroscopic augmentation with synthetic polyester ligament for PCL injury were similar with those using human allograft. Taking these results into consideration, the synthetic polyester ligament is assumed to be a method of treatment of the PCL injury.

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Some considerations for the determination of carbonyl compounds in air: Reaction characteristics of formaldehyde with 2.4-DNPH (대기 중 카보닐 계열 성분의 분석기법의 연구: 포름알데하이드와 DNPH의 반응 특성을 중심으로)

  • Hong, Y.J.;Kim, K.H.
    • Analytical Science and Technology
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    • v.18 no.1
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    • pp.43-50
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    • 2005
  • A number of carbonyl compounds including formaldehyde and acetaldehyde are well known for their toxicity and irritancy. Hence, acquisition of both qualitative and quantitative tool for their analysis is essential to resolve issues associated with malodor or indoor pollution. Using HPLC/UV method, we examined various aspects involved in the measurements of formaldehyde in environmental samples. The results of our analysis indicated that its detection was made as low as 0.5 ppb (assuming 5 L of sample volume), while its precision was maintained near 2% in terms of relative standard error (RSE). When the stability of calibration was checked by variability of slope values obtained over long-term period (e.g., one month), its values were found to remain constantly with RSE values of 3%. It was also found that liquid-phase reaction between formaldehyde and DNPH proceed very slowly to attain equilibrium (one and half hour), while requiring adequate amount of DNPH to form their derivatives. The overall results of our study thus suggest that there are a number of factors to consider for the accurate analysis of formaldehyde in ambient air.

A Study on the Optical Internal Recycle Rate and MLSS Concentration of Membrane Coupled $A_2O$ Process for Wastewater Treatment (하수처리를 위한 막결합형 $A_2O$공정에서 최적 내부 순환율 및 MLSS 농도에 관한 연구)

  • Kim Kwan-Yeop;Kim Jin-Mo;Kim Hyung-Soo;Lee Sang-Bek;Park Eugene;Bae Sung-Soo
    • Membrane Journal
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    • v.15 no.2
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    • pp.114-120
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    • 2005
  • The purpose of this study is to obtain practical information about membrane coupled $ A_2O$ system for muncipal wastewater treatment. A flat-plate microfiltration (MF) module with a pore size $0.25\;{\mu}m$ was submerged into the aeration basin and treated water was filtrated through the membrane by continuous suction with low pressure. The system was operated with synthetic wastewater to find operational parameters of internal recycle ratio and maximum MLSS showing best water quality and long-term stability. The internal recycle was defined as type 1 for aerobic to anoxic tank and type 2 for anoxic to anaerobic tank, respectively When the flux was maintained at $0.015\;m^3/m^2/hr$ (15 LMH) with 2Q type 1 internal recycle ratio, the optimal operational setting were 10 internal recycle ratio for type 2 and maximum MLSS of 11,000 mg/L among tested conditions. At this condition, removal efficiencies of BOD, CODcr, T-N and T-P showed $97.3\%,\;94.2\%,\;64.0\%,\;63.0\%$, respectively.

Effects of Hillslope Treatments for Vegetation Development and Soil Conservation in Burned Forests (산불 피해 산림의 식생 발달과 토양 보존을 위한 사면 처리 효과)

  • Kim, Chang-Gi;Choung, Yeon-Sook;Joo, Kwang-Yeong;Lee, Kyu-Song
    • Journal of Ecology and Environment
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    • v.29 no.3
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    • pp.295-303
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    • 2006
  • Clear-cut followed by tree planting has been a conventional management practice in burned forests in Korea. Because this can considerably increase soil loss, hillslope treatments may be needed in order to improve soil stability at poorly regenerating areas. This paper reviews the effects of hillslope treatments, such as seeding, mulching and log erosion barriers, which have been applied to restore vegetation and conserve soil in burned forests in North America and Europe. Seeding has been the most common method for postfire restoration. However, the effects of seeding on vegetation cover and soil erosion are not clear and seeding with non-native species has been reported to inhibit regeneration of native vegetation. Mulching has been found to be effective at reducing soil erosion. However, this also can introduce non-native plant species and inhibit native plant regeration. Although studies on the effect of log erosion barriers are very few, it appears that log erosion barriers are effective in the period of little rainfall. Hillslope treatments for postfire restoration is not necessary for naturally regenerating areas and therefore, they should be restricted to the areas where regeneration potential is low and runoff and soil loss is considerable. Long-term monitoring is needed to assess the effectiveness of hillslope treatments on soil erosion, the introduction of non-native plant species and the inhibition of natural plant regeneration.

Accuracy and Stability of Temperature and Salinity from Autonomous Profiling CTD Floats (ARGO Float) (자동 수직물성관측 뜰개(ARGO Float)로 얻은 수온과 염분의 정확도와 안정도)

  • 오경희;박영규;석문식
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.9 no.4
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    • pp.204-211
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    • 2004
  • Autonomous profiling CTD floats are a useful tool for observing the oceans. We, however, cannot perform post-deployment calibration of the CTD's attached to the floats, and the assessment of the accuracy and stability of the profile data from the floats is one of the important issues in the delayed mode quality control of the profiles. Variations in salinity in the intermediate level of East Sea is comparable to the accuracy of salinity data required by the international Argo Program, which is 0.01. Therefore, we can assess the credibility of salinity data from the floats deployed in the East Sea using three independent methods while considering the East Sea as a salinity calibration bath. The methods utilized here are 1) comparison of high quality CTD data and float data obtained at similar locations at similar time, 2) comparison of float data obtained at similar locations at similar time, and 3) investigation of long term stability and accuracy of salinity data from parking depths. All three methods show that without any calibration, the salinity data satisfy the accuracy criterion by the Argo Program. While assuming that the intermediate level temperature in the East Sea is as homogeneous as the salinity, we have applied the three methods to temperature data. We found that the accuracy of temperature reading is 0.01$^{\circ}C$, which is about twice larger than the requirement by the Argo Program, 0.005$^{\circ}C$. This does not mean that the temperature readings are inaccurate, because the intermediate level temperature does vary spacially and temporally more than the accuracy interval required by the Argo Program. If we take into account the variation in the intermediate level temperature, the accuracy of temperature data from the floats is not significantly different from that proposed by the Argo Program. Therefore, one could use both temperature and salinity profiles from the floats assessed in this study without calibration.

Revegetaton and human(III) - Perspective on the revegetation of the face of slopes - (녹화(綠化)와(と) 인간(人間)(III) - 비탈면 녹화(綠化)의 전망(展望) -)

  • Chun, Kun-Woo;Seomun, Won;Seo, Jung-Il;Ahn, Young-Sang;Kim, In-Ae;Inoue, Shoji;Iwamoto, Tohru;Ezaki, Tsugio
    • Journal of Forest and Environmental Science
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    • v.18 no.1
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    • pp.15-30
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    • 2001
  • The twenty-first century was entered and began to show the extent where revegetation of the face of slopes using the native woody plant was nationwide at last. Then, future revegetation of the face of slopes was considered on the basis of them in order to attempt the development of this direction, while the recognition for fundamental matter of the revegetation and revegetation of the regional inhabitant was arranged this time. The regional inhabitant sufficiently understood the necessity of the revegetation, and the method using the native woody plant had sufficiently been recognized, and the high evaluation was given in the method. In the other, the major inhabitant questioned it for introducing the exotic species. It was proposed that the utilization of native weeds should be advanced by the pursuit of many facets of the revegetation of the face of the slopes based on these in future in the place where the introduction of the native woody plant is difficult. And, the method for stretching the wire netting for the face of slopes indicated the necessity of the urgent review, because the artificial disaster might be caused. As a conclusion, the goal of the revegetation of the face of slopes confirmed that it was ecologically stable short-terminable face of slopes physically and connects it with the medium and long term for improvement and improvement of global environment, and it indicated the importance of the revegetation of the face of slopes.

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Optimum Monitoring Parameters for the Safety of Mechanical Seals (미캐니컬 씰의 안전운용 감시를 위한 최적 계측인자)

  • Soon-Jae Lim;Man-Yong Choi
    • Journal of the Korean Society of Safety
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    • v.12 no.4
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    • pp.214-219
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    • 1997
  • The mechanical seals, which are installed in rotating machines like pump and compressor, are generally used as sealing devices in the many fields of industries. The failure of mechanical seals such as leakage, crack, breakage, fast and severe wear, excessive torque, and squeaking results in big problems. To identify abnormal phenomena on mechanical seals and to propose the proper monitoring parameter for the failure of mechanical seals, sliding wear experiments were conducted. Acoustic emission, torque, and temperature were measured during experiments. Optical microstructure was observed for the wear processing after every 10 minute sliding at rotation speed of 1750 rpm and scanning electron microscopy was also observed. Except for the initial part of every experiment, the variation of acoustic emission was well coincided with torque variation during the experiments. This study concludes that acoustic emission and torque are proper monitoring parameters for the failure of mechanical seals. The intensity of acoustic emission signals is measured in root mean square voltage. Temperature of sealing face will be used as a parallel parameter for increasing the reliability of monitoring system.

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Synthesis of C9-Alcohol through C9-Aldehyde Hydrogenation over Copper Catalysts (구리 촉매 상에서 C9-알데히드의 수소화 반응에 의한 C9-알코올 합성)

  • Park, Young-Kwon;Noh, Sang Gyun;Cho, Kyu Sang;Jeon, Jong-Ki
    • Korean Chemical Engineering Research
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    • v.44 no.4
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    • pp.363-368
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    • 2006
  • This study selected the optimal catalyst for the process of producing $C_9$-alcohol by hydrogenating $C_9$-aldehyde, and carried out an experiment in order to establish the operating condition for maximizing the yield of $C_9$-alcohol. The BET surface area and the specific area of copper were most excellent in $CuO/ZnO/Al_2O_3$ (60:30:10 wt%) catalyst produced using acetate as a precursor of copper and $Na_2CO_3$ as a precipitant, and the catalyst also showed the highest performance in $C_9$-aldehyde hydrogenation. Using a trickle bed reactor loaded with optimized catalyst, we attained 94.1 wt% yield of $C_9$-alcohol under the condition of $175^{\circ}C$, 800 psi and $WHSV=3hr^{-1}$. According to the result of comparing with other catalysts used in the hydrogenation of aldehyde, the catalyst showed similar performance to that of Ni/kieselghur and higher than that of $Cu-Ni-Cr-Na/Al_2O_3$ and $Ni-Mo/Al_2O_3$. According to the result of examining the stability of the catalyst through a long-term catalysis test, the yield of $C_9$-alcohol decreased slowly after around 72 hours due to the increasing production of high boiling-point byproducts.