• Title/Summary/Keyword: 잔류 구조

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Investigation on Reaction Products From Oxidative Coupling Reactions of 1-Naphthol By Manganese Oxide (망간산화물에 의한 1-Naphthol의 산화-결합 반응에 따른 반응산물 연구)

  • Lim, Dong-Min;Lee, Doo-Hee;Kang, Ki-Hoon;Shin, Hyun-Snag
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.9
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    • pp.989-996
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    • 2007
  • In this study, abiotic transformation of 1-naphthol(1-NP) via oxidative-coupling reaction and its reaction products were investigated in the presence of Mn oxides. The reaction products were characterized for their relative polarity using solvent extraction experiment and reverse-phase HPLC, and for structure using CCMS and LC/MS, and for absorption characteristics using UV-Vis spectrometry. The reaction products present in aqueous phase were more polar than parent naphthol and comprised of 1,4-naphthoquinon(1,4-NPQ) and oligomers such as dimers and trimers. Hydrophilic component present in water phase after solvent$(CH_2Cl_2)$ extractions was identified as naphthol polymerized products having molecular weight(m/z) ranging from 400 to 2,000, and showed similar UV-Vis. absorption characteristics to that of foil fulvic acid. Transformation of 1,4-NPQ, which is non-reactive to Mn oxide, to the polymerized products via cross-coupling reaction in the presence of 1-NP was also verified. In this experimental conditions(20.5 mg/L, 1-NP, 2.5 g/L $MnO_2$, pH 5), the transformation of 1-NP into the oligomers and polymerized products were about 83% of initial 1-NP concentrations, and more than 30% of the reaction products was estimated to be water insoluble fractions, not extracted by $H_2O$ methanol. Results from this study suggest that Mn oxide-mediated treatment of naphthol contaminated soils can achieve risk reduction through the formation of oligomers md polymer precipitation.

Evaluation of Buckling Load and Specified Compression Strength of Welded Built-up H-section Compression Members with Residual Stresses (잔류응력의 영향을 고려한 조립 H-형강 부재의 좌굴하중 및 설계압축강도 평가)

  • Lee, Soo-Keuon;Yang, Jae-Guen;Kang, Ji-Seok
    • Journal of Korean Society of Steel Construction
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    • v.29 no.1
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    • pp.81-88
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    • 2017
  • Residual stress is defined as stress that already exists on a structural member from the effects of welding and plastic deformation before the application of loading. Due to such residual stress, welded H-section compression members under centroidal compression load can undergo buckling and failure for strength values smaller than the predicted buckling load and specified compressive strength. Therefore, this study was carried out to evaluate the effect of residual stress from welding on the determination of the buckling load and specified compressive strength of the H-section compression member according to the column length variation. A three-dimensional nonlinear finite element analysis was performed for the H-section compression member where the welded joint was fillet welded by applying heat inputs of 3.1kJ/mm and 3.6kJ/mm using the SAW welding method.

Transition of the Korean Rural Society: On the Basis of Population and Family Changes (한국 농촌사회의 변천: 농촌 인구와 가족의 변화를 중심으로)

  • 김태헌
    • Korea journal of population studies
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    • v.24 no.1
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    • pp.5-40
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    • 2001
  • We have approached this study on the basis of population and family changes. We have selected two suburban and two general rural areas for this research. The suburban rural areas are located next to Chungju City, which is the biggest city in Chungbuk Province, and the residents are able to commute to Chungju. The general rural areas are located in Boeun Gun, which is a typical agricultural county in Chungbuk Province. We have conducted two round surveys at the research areas: 1995-1996 for the first round and 1999-2000 for the second round surveys. Since the surveys were completed ones interviewed by enumerators, we have used the survey data directly for the analysis by year and region. The population structure by age and sex in general rural areas is shaped as a reverse triangle, which is becoming more serious because of the continuing emigration of young generation. Most of the young generation moves to the urban areas and their old parents only are left in their hometown, rural areas. When the parents become old and die, the number of households in the areas decreases rapidly. If there are no more new family formations, therefore, the rural society itself would cease to exist in near future. However, the situation of suburban rural areas was a different case. Although the rural young generation has moved to urban areas, other young age groups have moved into the areas with their small enterprises and for the low living costs. The original residents become older and the young age groups are replaced with the new immigrants continuously. Therefore, the traditional agricultural society will be replaced with a non-agricultural society, which will have more characteristics of urban areas.

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Analysis of Cyclic Loading Transferred Mechanism on Geosynthetic-Reinforced and Pile-Supported Embankment (토목섬유로 보강된 성토지지말뚝 시스템의 반복하중 전이 메커니즘 분석)

  • Lee, Sung-Jee;Yoo, Min-Taek;Lee, Su-Hyung;Baek, Min-Cheol;Lee, Il-Wha
    • Journal of the Korean Geotechnical Society
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    • v.32 no.12
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    • pp.79-91
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    • 2016
  • Geosynthetic-reinforced and Pile-supported (GRPS) embankment method is widely used to construct structures on soft ground due to restraining residual settlement and their rapid construction. However, effect of cyclic loading has not been established although some countries suggest design methods through many studies. In this paper, cyclic loading tests were conducted to analyze dynamic load transfer characteristics of pile-supported embankment reinforced with geosynthetics. A series of 3 case full scale model tests which were non-reinforced, one-layer-reinforced, two-layer reinforced with geosynthetics were performed on piled embankments. In these series of tests, the height of embankment and pile spacing were selected according to EBGEO (2010) standard in Germany. As a result of the vertical load parts on the pile and on the geosynthetic reinforcement measured separately, cyclic loads transferred by only arching effect decreased with strength geosynthetic-reinforced case. However, final loads on the pile showed no differences among the cases. These results conflict with previous studies that reinforcement with geosynthetics increases transfer load concentrated on piles. In addition, it is observed that the load transferred to pile decreases at the beginning of cycle number due to reduction of arching effected by cyclic loading. Based on these results, transferred mechanism for cyclic load on GRPS system has been presented.

A Study on the Pile Material Suited for Pile Supported Embankment Reinforced by Geosynthetics (토목섬유로 보강된 성토지지말뚝 구조에 적합한 말뚝재료의 개발)

  • Choi, Choong-Lak;Lee, Kwang-Wu;Kim, Eun-Ho;Jung, Ji-Won
    • Journal of the Korean Geosynthetics Society
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    • v.15 no.1
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    • pp.21-35
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    • 2016
  • It is a current trend that the concrete track is applied for high speed railway. In the case of the railway embankment constructed on soft ground, the damage to concrete track which is sensitive to settlement such as distortion and deflection could be caused by very small amount of long term settlement. Pile Supported Embankment method can be considered as the effective method to control the residual settlement of the railway embankment on soft ground. The Geosynthetics is used inside of the embankment to maximize the arching effect transmitting the load of the embankment to the top of the piles. But, PHC piles that are generally used for bridge structures are also applied as the pile supporting the load of embankment concentrated by the effect of the Geosynthetics. That is very low efficiency in respect of pile material. So, in this study, the cast in place concrete pile was selected as the most suitable pile type for supporting the embankment by a case study and the optimum mixing condition of concrete using a by-product of industry was induced by performing the mixing designs and the compressive strength designs. And it is shown that the cast in place pile with the optimum mixing condition using the by-product of industry is 2.8 times more efficient than the PHC pile for the purpose of Pile Supported Embankment by the finite element analysis method.

Characterization of Ferroelectric $SrBi_2Ta_2O_9$ Thin Films Deposited by RF Magnetron Sputtering With Various Annealing Temperatures (RF magnetron sputtering으로 제조된 강 유전체 $SrBi_2Ta_2O_9$ 박막의 열처리 온도에 따른 특성 연구)

  • 박상식;양철훈;윤순길;안준형;김호기
    • Journal of the Korean Ceramic Society
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    • v.34 no.2
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    • pp.202-208
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    • 1997
  • Bi-layered SrBi2Ta2O9(SBT) films were deposited on Pt/Ti/SiO2/Si sibstrates by rf magnetron sputt-ering at room temperature and then were annealed at 75$0^{\circ}C$, 80$0^{\circ}C$ and 85$0^{\circ}C$ for 1 hour in oxygen at-mosphere. The film composition of SrBi2Ta2O9 was obtained after depositing at room temperature and annealing at 80$0^{\circ}C$. Excess 20mole% Bi2O3 and 30 mole% SrCO3 were added to the target to compensate for the lack of Bi and Sr in SBT film. 200 nm thick SBT film exhibited and dense microstructure, adielectric constant of 210, and a dissipation factor of 0.05 at 1 MHz frequency. The films exhibited Curie temperature of 32$0^{\circ}C$ and a dielectric constant of 314 at that temperature under 100 kHz frequency. The remanent polarization(2Pr) and the coercive field(2Ec) of the SBT films were 9.1 $\mu$C/$\textrm{cm}^2$ and 85 kV/cm at an applied voltage of 3V, resspectively and the SBT film showed a fatigue-free characteristics up to 1010 cy-cles under 5V bipolar pulse. The leakage current density of the SBT film was about 7$\times$10-7A/$\textrm{cm}^2$ at 150 kV/cm. Fatigue-free SBT films prepared by rf magnetron sputtering can be suitable for application to non-volatile memory device.

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A Study on the Electric and Ferroelectric Properties of PZT(30/70) Thick Film Prepared by Using 1,3-Propanediol (1, 3-Propanediol 을 이용해 제작된 PZT(30/70) 후막의 전기적 및 강유전 특성에 관한 연구)

  • 송금석;장동훈;강성준;윤영섭
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.40 no.9
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    • pp.631-637
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    • 2003
  • We have evaluated structural and electric, ferroelectric properties of PZT(30/70) thick film prepared by using 1,3-propanediol based sol-gel method on Pt/Ti/SiO$_2$/Si substrates. Rapid thermal annealing (RTA) is used to reduce the thermal stress and final furnace annealing is processed at $650^{\circ}C$. As the results of SEM analysis, we find that we get 350 nm in thickness for one coating and 1 $\mu$m for three times of coating. In the results of C-D analysis at 1 kHz, dielectric constant ($\varepsilon$$_{r}$) and dissipation factor were 886 and 0.03, respectively. C-V curve is shaped as a symmetrical butterfly. Leakage current density at 200 kV/cm is 1.23${\times}$10$^{-5}$ A/cm$^2$ and in the results of hysteresis loops measured at 150 kV/cm, the remnant polarization (P$_{r}$) and the coercive field (E$_{c}$) are 33.8 $\mu$C/cm$^2$ and 56.9 kV/cm, respectively. PZT(30/70) thick film exhibits relatively good ferroelectric, electric properties.s..

The Relationship between Organizational Commitment and Intention to Leave and the Moderating Effect of Gender and Occupation in Dae-deok Venture Enterprises (조직몰입과 이직의도의 관계 및 성별과 직종의 조절효과: 대덕 벤처기업을 중심으로)

  • Kim, Jung Seok;Ahn, Kwan Young
    • Asia-Pacific Journal of Business Venturing and Entrepreneurship
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    • v.7 no.4
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    • pp.77-86
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    • 2012
  • The purpose of this paper is to review the relationship between organizational commitment, and voluntary turnover(intention to leave), and the moderating effects of personal factors(gender and occupation) on the relationship between organizational commitment and intention to leave. In order to verify and achieve the purposes mentioned above, questionnaire data are gathered and analysed from 458 employees in Daedeok Innopolis Venture Enterprises, Dae-jeon Metropolis, South Korea. Multiple regression and multiple hierarchical regression analysis are applied to test the proposed hypotheses: 1) the relationship between organizational commitment(affective commitment, continuance commitment and normative commitment) and intention to leave, 2) the moderating effects of personal factors(gender and occupation) on the relationship between organizational commitment and intention to leave. Empirical survey's findings are as follows; First, affective commitment(AC) and continuance commitment(CC) are related negatively with intention to leave(IL), but normative commitment(NC) is not related significantly with IL. Second, gender positively moderates the relationship between affective commitment and intention to leave, and occupation negatively moderates the relationship between continuance commitment and intention to leave.

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Origin and Characteristics of Sand Ridges in the western Continental Shelf of Korean Peninsula (한반도 서부대륙붕에 발달한 사퇴의 발생기원과 특성)

  • 방효기;이차원
    • 한국해양학회지
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    • v.29 no.3
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    • pp.217-227
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    • 1994
  • From northeast to southwest, discontinuous sand ridges distribute on the western continental shelf of Korean Peninsular. The dimension of sand ridges is 3 to 21 m high, 3.1 to 6.8 km wavelength and 9-64 km long with 0.5 steep slope. they are probably originated and reformed by the intensity of tidal current according to the sea level rise. The characteristics of sand ridges revealed in study area are summarized as follows: (1) The sand ridges line up with the long axes of the tidal current ellipses, indicating a tidal control. (2) these are composed of two sedimentary sequences on the 3.5 kHz seismic profiles and core sediments. The upper sequence characterized by prolonged type is covered with thin veneer of massive fine sand(Mz, 2-3$\phi$) with Olive Gray(5Y 5/2). The lower sequence is characterized by internal reflector type with parallel and discontinuous. It consists of sandy mud or muddy sand(Mz, 5-7$\phi$) with laminar structures. the parallel internal reflectors are truncated on the slope of sand ridges. (3) Asymmetrical sand waves are superimposed on the sand ridges, and facing to the crest. However, symmetrical sand waves lie on the crest. Sand ridges having characteristics above is originated by scouring of tidal current, covered with coarase relict sediments, and modified by sadware.

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Interfacial Adhesion and Reliability between Epoxy Resin and Polyimide for Flexible Printed Circuit Board (연성인쇄회로기판의 에폭시수지와 폴리이미드 사이의 계면접착력 및 신뢰성 평가)

  • Kim, Jeong-Kyu;Son, Kirak;Park, Young-Bae
    • Journal of the Microelectronics and Packaging Society
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    • v.24 no.1
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    • pp.75-81
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    • 2017
  • The effects of KOH pretreatment and annealing conditions on the interfacial adhesion and the reliability between epoxy resin and polyimide substrate in the flexible printed circuit board were quantitatively evaluated using $180^{\circ}$ peel test. The initial peel strength of the polyimide without the KOH treatment was 29.4 g/mm and decreased to 10.5 g/mm after 100hrs at $85^{\circ}C/85%$ R.H. temperature/humidity treatment. In case of the polyimide with annealing after KOH treatment, initial peel strength was 29.6 g/mm and then maintained around 27.5 g/mm after $85^{\circ}C/85%$ R.H. temperature/humidity treatment. Systematic X-ray photoelectron spectroscopy analysis results showed that the peel strength after optimum annealing after KOH treatment was maintained high not only due to effective recovery of the polyimide damage by the polyimide surface treatment process, but also effective removal of metallic ions and impurities during various wet process.