• Journal of the Korea institute for structural maintenance and inspection
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• v.17 no.6
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• pp.11-20
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• 2013

In this paper, the quantitative damage index for reinforced concrete (RC) columns with non-seismic details were presented. They are necessary to carry out the postearthquake safety evaluation of RC buildings under 5 stories without seismic details. The static cyclic test of the RC frame sub-assemblage that was an one span and actual-sized was first conducted. The specimen collapsed by the shear failure after flexural yielding of a column, lots of cracks on the surfaces of columns and beam-column joints and the cover concrete splitting at the bottom of columns occurred. The damage levels of these kinds of columns with non-seismic details were classified to five based on the load-displacement relationship by the test result. The residual story drift ratios and crack widths were then adapted as the quantitative index to evaluate the damage limit states because those values were comparatively easy to measure right after earthquakes. The highest one among the residual story drift ratios under the similar maximum story drift ratio decided on the residual story drift ratio of each damage limit state. On the other hand, the lowest and average ones among the respective residual shear and flexural widths under the similar maximum story drift ratio decided on the residual shear and flexural widths of each damage limit state, respectively. These values for each damage limit state resulted in being smaller than those by the international damage evaluation guidelines that are for seismically designed members under the same deformations.

• Proceedings of the KWS Conference
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• 2009.11a
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• pp.98-98
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• 2009

용접에 의해 발생하는 용접잔류응력은 강구조물의 피로성능, 파괴양상 등에 영향을 주고 있으나 이러한 용접잔류응력을 예측하는 것은 쉽지 않다. 이러한 용접잔류응력을 예측하는 방법으로는 열탄소성해석과 같은 수치적 방법과 실험적 방법이 있다. 열탄소성해석의 경우 실제문제를 이상화하는 과정에서 매우 복잡한 모델링 기술이 필요하다. 또한, 측정방법에서는 표면의 잔류응력을 측정할 수 있는 홀드링법과 X-선법 등이 있고, 내부 잔류응력의 측정방법으로는 중성자회절법이 있다. 그러나 홀드링법의 경우, 사용범위의 한계와, 중성자회절법에서의 내부 잔류응력을 측정할 수 있는 두께의 제약이 있어 후판의 잔류응력을 측정하는 것은 한계가 있다. 따라서 본 연구에서는 용접잔류응력의 생성근원인 고유변형도를 측정하고 이것으로부터 맞대기용접에서 발생하는 두께방향의 용접잔류응력을 계측하였다.

• Journal of the korean veterinary medical association
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• v.29 no.3
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• pp.165-167
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• 1993

1. FDA와 FSIS는 제약회사에서 설정한 잔류 검사 방법의 유효성과 실용성에 대하여 합의한다. 2. FSIS는 식용동물에서 약물이나 살충제, 환경오염물질의 잔류를 조사한다. 3. FSIS에서 불법적인 약물잔류를 발견하면 FDA와 가축생산자 그리고 적절한 주정부기관에 통보한다. 4. FDA나 적절한 주 정부기관은 의심되는 생산자의 현장조사를 할 수도 있다. 만약 중대한 법률의 위반이 발견되거나 불법적인 잔류가 반복된 경우 생산자에게 벌금형이 부과될 수도 있다. 5. 유죄로 판결된 동물약품남용자는 죄과에 따라 벌금형이나 징역형을 받을 수 있다. 6. 출고 보류된 가축에서 불법적인 잔류가 발견되면 FSIS에 의해 폐기되며 이러한 가축의 생산자는 그들이 생산하는 가축이 잔류허용한계에 적합하다는 것이 증명될 때까지 출하를 금지 당할 수 있다.

• Proceedings of the Korean Geotechical Society Conference
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• 1999.10a
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• pp.169-176
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• 1999

본 논문은 지하수 흐름하에서의 풍화 잔류토의 세립자 유동특성을 파악하기 위한 수치모델을 개발하고, 실내에서 실시한 수리 모형실험을 통하여 수치모델의 적합성을 규명하였다. 한국의 풍화 잔류토는 점토와 모래의 중간 상태의 특성을 보이는 관계로 기존의 토립자 유동모델중 점토 또는 모래에 적합한 모델에 의해서는 정확한 유동특성의 파악에 한계가 있었다. 따라서, 본 연구에서는 한국의 풍화 잔류토에 적합한 세립자 유동모델을 제시함으로써 풍화 잔류토를 대상으로 시공되는 굴토공사, 댐 축조공사, 그리고 터널공사시 지하수 유입에 따른 세립토사의 유실특성을 이론적으로 규명하였고, 현장에서 배수재로 광범위하게 쓰이고 있는 토목섬유인 부직포의 투수 및 배수특성을 검토하였다

• Journal of Food Hygiene and Safety
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• v.34 no.1
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• pp.30-39
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• 2019

An analytical method was developed for the determination of sedaxane in agricultural products using liquid chromatograph-tandem mass spectrometry (LC-MS/MS). The samples were extracted with acetonitrile and partitioned with dichloromethane to remove the interference, and then purified by using silica SPE cartridges to clean up. The analytes were quantified and confirmed by using LC-MS/MS in positive ion mode using multiple reaction monitoring (MRM). The matrix-matched calibration curves were linear over the calibration ranges ($0.001-0.25{\mu}g/mL$) into a blank extract with $r^2$>0.99. For validation, recovery tests were carried out at three different concentration levels (LOQ, 10LOQ, and 50LOQ, n=5) with five replicates performed at each level. The recoveries were ranged between 74.5 to 100.8% with relative standard deviations (RSDs) of less than 12.1% for all analytes. All values were consistent with the criteria ranges requested in the Codex guidelines (CAC/GL 40, 2003) and Food Safety Evaluation Department guidelines (2016). The proposed analytical method was accurate, effective and sensitive for sedaxane determination in agricultural commodities.

• Korean Journal of Food Science and Technology
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• v.42 no.5
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• pp.515-520
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• 2010

This research investigated benzimidazole residues (albendazole, fenbendazole, flubendazole, thiabendazole, oxibendazole) in livestock products. A total of 270 samples of livestock products (beef, pork and chicken) were purchased from local markets in Korea. Ethyl acetate was used to extract analytes from the sample, after which ethyl acetate extracts were purified using a MCX cartridge. Analytes were detected using liquid chromatography-tandem mass spectrometry. The limit of detection was 0.01-0.04 ppb, the limit of quantification was 0.03-0.13 ppb, the linearity ($r^2$) was 0.9992-1.0000, and the recovery was 70-85%. Residues of benzimidazoles, except for fenbendazole in pork, were not found in any of the 270 livestock samples. Fenbendazole was detected in the range of 1.2 to 3.1 ppb in 12 samples of pork.

• Proceedings of the Korean Geotechical Society Conference
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• 1999.11c
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• pp.169-178
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• 1999

본 논문에서는 실내에서 실시한 Filtration실험을 통하여 지하수 흐름하에서 이탈한 풍화 잔류토의 세립자가 흙-토목섬유 복합체를 통과하면서 발생하는 이동 (Transportation), 퇴적 (Deposition), 그리고 폐색 (Clogging)되는 과정을 분석하였다. 본 연구에서는 한국의 풍화 잔류토에 적합한 토목섬유 배수재의 새로운 설계기준을 제시함으로써 풍화 잔류토상에 축조되는 터널 구조물 시공시 광범위하게 사용되고 있는 토목섬유재인 부직포의 투수 및 배수특성과 세립토사에 의한 폐색 (Clogging)영향을 분석할 수 있게 되었다.

• The Korean Journal of Pesticide Science
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• v.17 no.2
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• pp.107-116
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• 2013

Polar pesticides like pymetrozine (log $P_{ow}$: -0.18) are known to be difficult to analyze. The analytical method of pymetrozine using hydromatrix included in the official method of KFDA was uncommon and provided ambiguous evidence to confirm both the identity and the quantity. Therefore, precise single residue analytical method was developed in representative crops for using liquid-liquid extraction (LLE). The pymetrozine residue was extracted with methanol from 11 representative crops which comprised apple, blueberry, broccoli, cabbage, cherry, crown daisy, hulled rice, Korean cabbage, potato, rice and watermelon. The extract was purified serially by liquid-liquid extraction (LLE) and silica solid phase extraction (SPE). For rice and hulled rice samples, n-hexane partition was additionally adopted to remove nonpolar interferences, mainly lipids. The residue levels were analyzed by HPLC with DAD, using $C_8$ column. LOQ (limit of quantitation) of pymetroizinie was 1 ng (S/N > 10) and MQL (method quantitation limit) was 0.01 mg/kg. Mean recoveries from 11 crop samples fortified at three levels (MQL, 10 ${\times}$ MQL and 50 ${\times}$ MQL) in triplicate were in the range of 83.1~98.5% with coefficients of variation (CV) of less than 10%, regardless of sample type, which satisfies the criteria of KFDA. The method established in this study could be applied to most of crops as an official and general method for analysis of pymetrozine residue.

• Journal of Food Hygiene and Safety
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• v.38 no.3
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• pp.79-88
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• 2023

Trifludimoxazin is a triazinone herbicide that inhibits the synthesis of protoporphyrinogen oxidase (PPO). The lack of PPO damages the cell membranes, leading to plant cell death. An official analytical method for the safety management of trifludimoxazin is necessary because it is a newly registered herbicide in Korea. Therefore, this study aimed to develop a residual analysis method to detect trifludimoxazin in five representative agricultural products. The EN method was established as the final extraction method by comparing the recovery test and matrix effect with those of the QuEChERS method. Various sorbent agents were used to establish the clean-up method, and no differences were observed among them. MgSO₄ and PSA were selected as the final clean-up conditions. We used LC-MS/MS considering the selectivity and sensitivity of the target pesticide and analyzed the samples in the MRM mode. The recovery test results using the established analysis method and inter-laboratory validation showed a valid range of 73.5-100.7%, with a relative standard deviation and coefficient of variation less than 12.6% and 14.5%, respectively. Therefore, the presence of trifludimoxazin can be analyzed using a modified QuEChERS method, which is widely available in Korea to ensure the safety of residual insecticides.

• Horticultural Science & Technology
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• v.34 no.4
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• pp.644-654
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• 2016

Supervised residue trials for mandipropamid in Korean cabbage(Brassica campestris L.) were conducted to establish its pre-harvest residue limit (PHRL), a criterion to ensure the safety of the terminal pesticide residue during cabbage production. Tissues of Korean cabbage were collected at 0, 1, 3, 5, 7, and 10 days after mandipropamid application and subjected to residue analysis. The analytical method was validated by recoveries ranging from 88.2-92.2% at two levels (0.4 and $2.0mg{\cdot}kg^{-1}$), and a limit of quantitation (LOQ) of $0.04mg{\cdot}kg^{-1}$. Mandipropamid residues in Korean cabbage gradually decreased over time. The dissipation rate of the residue would be affected by intrinsic degradation of the compound along with dilution resulting from the fast growth of Korean cabbage. The decay pattern was well fitted by simple first-order kinetics. Biological half-lives of mandipropamid in Korean cabbage ranged from 3.9-4.0 days in two field conditions. Calculated by the regression curve of mandipropamid dissipation, the PHRLs of mandipropamid in Korean cabbage were recommended as 11.07-12.19 and $5.76-6.05mg{\cdot}kg^{-1}$ for 10 and 5 days prior to harvest, respectively.