• Title/Summary/Keyword: 잔류특성

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Residual Toxicity of Bifenthrin and Imidacloprid to Honeybee by Foliage Treatment (Bifenthrin과 Imidacloprid의 작물잎에서의 잔류량과 꿀벌에 대한 독성)

  • Cho, Kyung-Won;Park, Hyun-Ju;Bae, Chul-Han;Kim, Yeon-Sik;Shin, Dong-Chan;Lee, Seung-Yeol;Lee, Suk-Hee;Jung, Chang-Kook;Park, Yeon-Ki;Kim, Byung-Seok;Lee, Kyu-Seung
    • The Korean Journal of Pesticide Science
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    • v.14 no.3
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    • pp.226-234
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    • 2010
  • Foliage residue toxicity experiment was performed against honeybee (Apis mellifera) with bifenthrin, a synthetic pyrethroid insecticide with strong acute contact toxicity and imidacloprid, a neo-nicotinoid insecticide with strong acute oral toxicity to know the honeybee toxicity at the residue level on the leaves of alfalfa and apple. Also, the formulation differences to honeybee toxicity were investigated with WP (2%) and EC (1%) of bifenthrin and WP (10%) and SL (4%) of imidacloprid. Generally, foliage residual toxicity of honeybee and residual amounts of tested insecticides was higher in alfalfa leaves with large leaf area per unit weight than in apple leaves. While on the other hand, the only bifenthrin WP treatment showed higher honeybee toxicity on apple leaves than alfalfa. Although imidacloprid showed higher residue amounts ranged $4.9{\sim}25.4\;mg{\cdot}kg^{-1}$ than bifenthrin ranged $0.6{\sim}12.7\;mg{\cdot}kg^{-1}$ on the leaves, the residual toxicity to honeybee was lower than bifenthrin because of its strong penetration character. In conclusion, the residual toxicity of insecticide to honeybee could be affected by the contact and vaporized toxicity of chemical, the residual amounts on the surface of leaves, and the leaf area per unit weight and formulation differences.

A Study on the Characteristics of the Residual Stress Distribution of Steel Structural Members (용접(鎔接) 강구조(鋼構造) 부재(部材)의 잔류응력(殘留應力) 특성(特性)에 관한 연구(研究))

  • Chang, Dong Il;Kim, Doo Hwan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.1
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    • pp.93-101
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    • 1987
  • Residual stresses have remained around welding areas of a steel structure member after welding operation. The major causes to occur these residual stresses are the local heat due to a welding, the heat stresses due to a irregular and rapid cooling condition, the material and rigidity of a steel structure. Ultimatly, these residual stresses have been known to decrease a brittle fracture strength, a fatigue strength, a buckling strength, dynamic properties, and the corrosion resistance of the material. This paper deals with the residual stresses on a steel structure member through experimental studies. SWS 58 plates were welded by the method of X-groove type. These plates were layed on the heat treatment at four different temperatures; $350^{\circ}C$, $500^{\circ}C$, $650^{\circ}C$ and $800^{\circ}C$. The resulting residual Stresses were measured by hole drilling method, and the followings were obtained. The residual stresses on the vicinity of a welding point were relieved most effectively at the temperature of $650^{\circ}C$, and these stresses relieved completly when the ratio of a hole diamerter to a hole depth became unity. Hardness test shows that the higher value of hardness at the heat affected zone dropped to belower as the temperature went up from $350^{\circ}C$ to $800^{\circ}C$. The Welding input heats have not influenced the magnitude of residual stresses at the input heat range between above and below one forth than standard.

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Instrumented Indentation Technique: New Nondestructive Measurement Technique for Flow Stress-Strain and Residual Stress of Metallic Materials (계장화 압입시험: 금속재료의 유동 응력-변형률과 잔류응력 평가를 위한 신 비파괴 측정 기술)

  • Lee, Kyung-Woo;Choi, Min-Jae;Kim, Ju-Young;Kim, Kwang-Ho;Kwon, Dong-Il
    • Journal of the Korean Society for Nondestructive Testing
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    • v.26 no.5
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    • pp.306-314
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    • 2006
  • Instrumented indentation technique is a new way to evaluate nondestructive such mechanical properties as flow properties, residual stress and fracture toughness by analyzing indentation load-depth curves. This study evaluated quantitatively the flow properties of steels and residual stress of weldments. First, flow properties can be evaluated by defining a representative stress and strain from analysis of deformation behavior beneath the rigid spherical indenter and the parameters obtained from instrumented indentation tests. For estimating residual stress, the deviatoric-stress part of the residual stress affects the indentation load-depth curve, so that by analyzing the difference between the residual-stress-induced indentation curve and residual-stress-free curve, the quantitative residual stress of the target region can be evaluated. The algorithm for flow property evaluation was verified by comparison with uniaxial tensile test and the residual stress evaluation model was compared to mechanical cutting and ED-XRD results.

Residual Characteristics of a Systemic Insecticide Flonicamid and Its Metabolites in Sweet Pepper (착색단고추 중 침투성농약 플로니카미드 및 대사물질의 생성 및 잔류양상)

  • Seo, Eun-Kyung;Kim, Taek-Kyum;Hong, Su-Myeong;Kwon, Hye-Young;Gwon, Ji-Hyeong;Cho, Nam-Jun
    • The Korean Journal of Pesticide Science
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    • v.18 no.4
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    • pp.228-235
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    • 2014
  • The residue levels of flonicamid and its metabolites, 4-(trifluoromethyl)nicotinic acid (TFNA) and N-4-(trifluoromethyl)nicotinoyl glycine (TFNG) in sweer pepper were investigated to examine the residual characteristics of analytes for 87 days after pesticide application. The pesticide was applied once at recommended dosage and double dosage by foliar sprays and the samples of fruits and leaves of sweet pepper were collected for each treatment. The residues of flonicamid in all of fruits and leaves decreased gradually over time, while the residue levels of TFNG metabolite exhibited tendency that increased for long periods and thereafter decreased. Total flonicamid residual concentrations containing metabolites residues in fruit samples increased consistently until 30 days post-application and higher residue levels than residues at 1 day post-application were detected from 30 day to 87 day after treatment. The residue pattern observed in fruit could be explained by the movement of TFNG from leaves to fruits of plant. Such residual characteristic was similarly found in samples treated both recommended dosage and double dosage.

Critical-speed Increase of Optical Disk by Applying Residual Stresses (잔류응력 부과에 의한 광디스크의 임계속도 증가)

  • Kim, Nam Woong;Na, Sang Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.5
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    • pp.2092-2099
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    • 2013
  • Through the data transfer race in industry since 1990s, the operational speed of optical disk drive(ODD) becomes commonly over 10,000 rpm. Such high speed operation inevitably causes the vibration, which is also the disturbances in the read-write process of pick-up servo-controller. Generally the vibration disturbance problem can be solved by the vibration isolation using the rubber mount and the increase of robustness of the pick-up servo-controller. Optical disk itself has not been targeted for the vibration reduction, because it is manufactured under the standardized format. In this paper we focused on the increase of critical speed of optical disk, that is, the improvement of dynamic characteristics, with the control of residual stresses which are come from the injection molding process. To do this, first, the residual stresses induced from the injection molding process are calculated using finite element method. The major design parameters of the process conditions are flow rate and melt temperature, which control the residual stresses in optical disk. Second, the critical speed of optical disk is calculated with modal analysis considering residual stress distributions. It was found out that the critical speed can be improved by the control of operational parameters in the injection molding process.

Residual Characteristics of Bistrifluron and Fluopicolide in Korean Cabbage for Establishing Pre-Harvest Residue Limit (생산단계 잔류허용기준 설정을 위한 엇갈이배추 중 bistrifluron과 fluopicolide의 잔류 특성 연구)

  • Lee, Dong Yeol;Jeong, Dong Kyu;Choi, Geun-Hyoung;Lee, Deuk-Yeong;Kang, Kyu Young;Kim, Jin Hyo
    • The Korean Journal of Pesticide Science
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    • v.19 no.4
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    • pp.361-369
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    • 2015
  • This study investigated residual characteristics of bistrifluron and fluopicolide in Korean cabbage, and suggested the pre-harvest residue limits (PHRLs) based on their dissipation patterns and biological half-lives. The pesticides were sprayed on Korean cabbage in two different region under greenhouse conditions at the recommended dose, respectively. The samples for residue analysis were harvested at 0 (2 hr), 1, 2, 4, 6, 8 and 10 days after treatment, and analyzed by HPLC after clean-up with Florisil SPE. The limit of quantification (LOQ) was $0.03mg\;kg^{-1}$ for bistrifluron and fluopicolide, and the recoveries ranged from 87.2-110.6% with below 5% of RSD. The biological half-lives of field I and field II were 3.9 and 4.2 days for bistrifluron and 4.9 and 4.2 days for fluopicolide, respectively. The PHRL of bistrifluron and fluopicolide were recommended as 3.83 and $3.23mg\;kg^{-1}$ for 10 days before harvest, respectively.

Environment-friendly Processing Technologies of Mine Tailings: Research on the Characteristics of Mine Tailings when Developing of Deep Sea Mineral Resources (선광잔류물의 친환경적 처리 기술: 심해저광물자원개발시 발생하는 선광잔류물 특성 연구)

  • Moon, Inkyeong;Yoo, Chanmin;Kim, Jonguk
    • Economic and Environmental Geology
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    • v.53 no.6
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    • pp.781-792
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    • 2020
  • Mine tailings, which are inevitably formed by the development of manganese nodules, manganese crusts, and hydrothermal seafloor deposits, have attracted attention because of their quantity and potential toxicity. However, there is a lack of data on the quantity of mine tailings being generated, their physicochemical properties, and their effects as environmental hazards and on marine ecosystems in general. The importance of treating mine tailings in an environmentally friendly manner has been recognized recently and related reduction/treatment methods are being considered. In the case of deep-sea mineral resource development, if mine tailings cannot be treated aboard a ship, the issue becomes one of the cost of transporting them to land and solving the problem of environmental pollution there. Therefore, the Korea Institute of Ocean Science and Technology conducted research on the harmfulness of mine tailings, their effect on marine ecosystem, the diffusion model of contaminated particles, and candidate purification treatment technologies based on five representative controlling factors: 1) effects of pollution /on the environment, 2) effects of environmental/ biological hazards, 3) diffusion of particles, 4) mineral dressings, and 5) reducing/processing mine tailings. The results of this study can provide a basis for minimizing environmental problems by providing scientific evidences of the environmental effects of mine tailings. In addition, it is also expected that these results could be applied to the treatment of pollutants of different origins and at land-based mining waste sites.

Effect of Waxing and Heat Setting of Two-ply Wool Yarn on Torsional Properties (왁싱과 열고정이 2합연 모사의 비틀림 특성에 미치는 영향)

  • 남윤수;강복춘;박신웅
    • Proceedings of the Korean Fiber Society Conference
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    • 2001.10a
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    • pp.127-130
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    • 2001
  • 실의 잔류토크는 싱글저지 편성물에서 스파이럴러티를 일으키는 중요한 요소 중의 하나이다 실의 잔류토크를 감소시키거나 제거하기 위해서는 물리적으로 안정된 토크밸런스를 유지하도록 하는 방법과 퍼머넌트 세팅(permanent setting)방법 등을 택하고 있다. (중략)

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The Behaviour of Residues of Flonicamid and Metabolites in Sweet peppers (착색단고추 중 플로니카미드 및 그 대사산물의 잔류특성)

  • Son, Kyeong-Ae;Kwon, Hyeyoung;Jin, Yong-Duk;Park, Byeong Jun;Kim, Jinba;Park, Jung-Hwon;Kim, Taek-Kyum;Im, Geon-Jae;Lee, Key-Woon
    • The Korean Journal of Pesticide Science
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    • v.17 no.3
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    • pp.145-154
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    • 2013
  • Flonicamid was a water-soluble and systemic insecticide. It was applied to control neonicotinod pesticide-resistant cotton aphid in sweet peppers. However, the residue levels of total flonicamid in sweet pepper exported to Japan in 2009 were exceeded the maximum residue limit (MRL). This study was conducted to elucidate residual properties of flonicamid parent compound and its metabolites in sweet peppers. It was carried out to compare the variation of residues in sweet pepper in three different greenhouses for 21 days after 3 times application with 7 days interval. The mean residues were 0.176, 0.152 and 0.108 mg $kg^{-1}$ and the residue levels in sweet pepper among three greenhouses show significant difference. The maximum residue levels were detected 10 days later after last treatments. The overall residue levels were lower than MRL 2.0 mg $kg^{-1}$ (by Korea) and 0.4 mg $kg^{-1}$ (by Japan in 2009 but now revised MRL is 2.0 mg $kg^{-1}$). But the residue level of total flonicamid at the 21th day after 3 times treatment with 7 days interval was 0.429 mg $kg^{-1}$ restricted by the application of double rate than recommended rate. The amounts of metabolites, TFNA, 4-Trifluoro methyl nicotinic acid and TFNG, N-(4-trifluoro methyl nicotinoyl) glycine were increased while flonicamid parent compound was decreased over time. Therefore the longer trial period should be needed for flonicamid in sweet peppers.