• The Korean Journal of Pesticide Science
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• v.13 no.1
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• pp.13-20
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• 2009

Two insecticides, commonly used for Chinese cabbage, etofenprox and methoxyfenozide, were subjected to a field residue trial to evaluate safeties of the residues at harvest. The pesticides were sprayed onto the crop at recommended and double doses 10 days before the prearranged harvest and then sampling was done at 0, 1, 2, 3, 5, 7, 10, and 12 days after spraying. The amounts of pesticides residues in the crop were analyzed by chromatographic methods. Limits of detection (LODs) of both etofenprox and methoxyfenozide were $0.01mg\;kg^{-1}$ and mean recoveries were $96.76{\pm}2.67$ (CV=2.76%) and $95.84{\pm}2.57%$(CV=2.69%) in case of etofenprox and $103.26{\pm}3.21$ (CV=3.11%) and $94.50{\pm}1.35%$(CV=1.43%) in case of methoxyfenozide, respectively. Biological half-lives of etofenprox and methoxyfenozide were 3.2 and 3.5 days at the recommended dose and 2.7 and 3.5 days at the double dose, respectively. Initial residue levels of the pesticides at the recommended and double doses exceeded their MRLs, but final residue levels of the pesticides in the crop samples at harvest were less than their MRLs. The ratios of the EDI to ADI by intake the crop harvested 10 days after spraying were less than 4% of their ADIs, representing that residue levels of two pesticides at harvest were evaluated as safe.

• Proceedings of the Korean Geotechical Society Conference
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• 1991.10a
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• pp.332-347
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• 1991

Accurate prediction of future settlement is essential for the settlement control of soft soil by pre-loading method. To predict future settlement in clayey soft soils, several methods like Asaoka method, Hyperbolic Method and Hoshino method are currently being used. These methods predict the future sett1ement by mathmatical treatment of the measured settlement data on the basis of consolidtion theory and empiricism. But the correlation coefficient between the measured and the predicted settlement was relatively low (0.8~0.9). Also, the prediction of future settlemet for the design load is very difficult. In this article, the measured field settlement data was treated as the the field consolidation test. Hence, condolidation coefficient(Cv) and compression index(Cc) was evaluated from the field settlement data. Cv and Cc values from field data was used to calculate the degree of consolidation and settlement at desired time. By this method, the correlation coefficent between the measured and the predicted settlement was significantly increased(0.97~0.99). Also the settlement by the design load after the improvement of soft soil could be predicted reasonably. This method is quite rational and sound but it requires thousands of calculation steps. Today, by the aid of low priced personal computers above mentioned technique could be used much acre economically and effectively than conventional methods. This article presented the mechanisms and capacities of this method and demonstrated the enhanced correlation coefficient when applied to actual field settlement data.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.7
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• pp.806-813
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• 2014

The EGR system being reburned the part of the exhaust gas through intake system indicates more favorable emission characteristics to reduce NOx in a gasoline engine, but the case of inappropriate exhaust gas quantity induced from engine is fallen engine power caused by unstable combustion. In this study, we examined a method to predict EGR ratio according to various engine operation condition based by intake manifold pressure and confirmed such a prediction data through an experimental method. And after having constituted feedback EGR control algorithm in a base with such a prediction data, we acquired qualitatively similar results by having compared data provided through an EGR feedback control experiment with the data which calculated quantity of residual gas for the engine operation condition. Therefore, the applied algorithm and the system for feedback EGR control showed feasibility applied to real electronic control EGR technology.

• Korean Journal of Environmental Agriculture
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• v.32 no.1
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• pp.78-83
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• 2013

BACKGROUND: This study was performed to investigate the change of deltamethrin residue after spraying for control of hygienic insects in bush of levee at Bansuk-dong stream (A) and Juk-dong ditch (B) in Yuseong, Daejeon. The drop concentrations and disappearance of deltamethrin residue in stream water were determined to evaluate the toxic effects of stream ecosystem. METHODS AND RESULTS: Water samples were collected at 7 points including 0, 5, 10, 20, 40, 70 and 100 m downstream from the deltamethrin spraying point. Water sample was partitioned into dichloromethane, and was determined with GC/${\mu}$-ECD. Limit of Quantitation of deltamethrin was 0.04 ${\mu}g/L$. Recoveries of deltamethrin at two fortification levels of 0.4 and 2.0 ${\mu}g/L$ were $91.57{\pm}3.13%$(n=3) and $94.40{\pm}4.59%$(n=3) in A stream, and $88.24{\pm}3.33%$(n=3) and $85.20{\pm}3.73%$(n=3) in B stream, respectively. Residue of A stream were from <0.04 ${\mu}g/L$ to 0.48 ${\mu}g/L$ and B stream were from 0.08 ${\mu}g/L$ to 14.95 ${\mu}g/L$ under practice application condition. And residues were from <0.04 ${\mu}g/L$ to 0.2 ${\mu}g/L$ in A stream treated deltamethrin with 1.0 mg level at the upper region. CONCLUSION(S): Practice application of deltamethrin for the pest control of waterside was not much shown toxic effect to ecosystem of stream.

• The Korean Journal of Pesticide Science
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• v.18 no.4
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• pp.236-246
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• 2014

Pesticide is used to protect the crops, but also become a cause of polluting the environment. Perform a risk assessment using physical and chemical properties, environmental fate and toxicity data in order to determine the pesticide registration. The aquatic model estimates pesticide concentrations in water bodies that result from pesticide applications to rice paddies and apple orchard. The used models are the PRZM, EXAMS and AGRO shell (PA5), Rice Water Quality Model (RICEWQ) and Screening Concentration In GROund Water (SCI-GROW). The residual concentration of water body was estimated using meteorological data, crop calendar and soil series of Korea. The chosen pesticides were butachlor, carbofuran, iprobenfos and tebuconazole. It has shown the potential that the RICEWQ is possible to predict residue level in water of butachlor and iprobenfos, because the maximum value in water monitoring data is lower than the peak concentration of the model, and the minimum value is lower than the average annual concentration of the model. But RICEWQ was insufficient to predict exposure concentrations in ground water. The estimated exposure concentrations of carbofuran in ground water is very higher than in surface water because of its low soil adsorption coefficient. Although tebuconazole were not detected in the water monitoring that means very low concentration, it is possible that the PA5 can be used to predict residue level in water.

• Transactions of the Korean Society of Mechanical Engineers
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• v.18 no.3
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• pp.600-611
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• 1994

The purpose of this research is to propose a model for the prediction of residual strength. For this purpose, two-paremeter model based on Caprino's is developed and formulated by the ratio of indentation due to impact and normalized residual strength. The damage zone is considered only as an indentation. Impact tests are carried out on laminated composites by steel balls. Test material is carbon/epoxy laminate. The specimens are composed of $[{\pm}45^{\circ}/0^{\circ}/90^{\circ}]_2$ and $[\pm}45^{\circ}]_4$ stacking sequence and have $0.75^T{\times}0.26^W{\times}100^L(mm) dimension. A proposed model shows a good correlation with the experimental results And failure mechanism due to high impact velocity is discussed on CFRP laminates to examine the initiation and development of damage by fractography and ultrasonic image ststem. The effect of the unidirectional ply position on the residual strength is considered here.

• Journal of the Korean Society of Food Science and Nutrition
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• v.35 no.10
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• pp.1405-1411
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• 2006

The presence and content of residual hexane in the olive oils were studied. Total 41 olive oils of imported and domestic brands, which were labeled as extra virgin and refined (mixed), were collected from the market. For analysis, electronic nose and headspace SPME-GC/MS were used. Electronic nose equipped with 12 metal oxide sensors was used for the discrimination of odor pattern of olive oils against the different concentrations of hexane. From the results, it is assumed that the contents of residual hexane in the collected olive oils were below 5 ppm. For Qualitative and quantitative analysis of hexane, polydimethylsiloxane (PDMS) fiber was employed for SPME-GC/MS. In the results, the peak of residual hexane was detected in 8 samples from 41 olive oils. But the detected level was no more than 1 ppm that is under the regulation limit (5 ppm) by Korea Food Additive Code.

• Proceedings of the Korea Water Resources Association Conference
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• 2015.05a
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• pp.46-46
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• 2015

강우가 지역별 계절별로 편중되어 있는 우리나라는 수자원의 안정적인 확보와 이용을 위해 다양한 형태의 댐을 건설하여 운영하고 있다. 그러나 대부분의 댐건설을 통해 형성된 저수지들은 탁수 장기화 및 녹조 발생 등의 환경, 생태적인 문제를 겪고 있으며, 그에 따른 사회적 우려로 인해 신규댐 건설을 통한 수자원확보는 더 이상 어려운 실정이다. 이러한 문제에 대응하기 위한 대안으로 기존 댐 저수지들(안동호-임하호)의 구조적 연계운영방안이 진행되고 있다. 본 연구의 목적은 2차원 CE-QUAL-W2모형을 활용하여 안동호와 임하호의 구조적 연결에 따른 탁수의 이동과 각 저수지 내에서의 유동 변화를 해석하는데 있다. 저수지 연계 시나리오는 EL. 138 m 위치에 길이 2 km, 직경 5.5 m 의 콘크리트관(마찰계수 0.05)이 안동호 좌안인 임동면 마리와 임하호 우안 망천리를 연결하는 것으로 가정하였다. 모델의 보정은 실측자료가 풍부한 2006년도 수문사상을 대상으로, 개별 저수지에 대해 수행하였고, 탁수 유동 시나리오 해석은 임하호에 심각한 탁수장기화 문제가 발생했던 2002년을 대상으로 댐 연계 탁수모의를 수행하였다. 안동호와 임하호의 댐 앞에서 모의값과 실측값을 오차를 분석한 결과 탁수예측오차는 AME 0.5~24 mg/L, RMSE 0.7~30.2mg/L의 범위로 비교적 실측값을 잘 반영한 것으로 나타났다. 임하댐의 경우 탁수층의 위치와 두께, 그리고 최고 탁도값을 적절히 재현 하였지만, 안동댐은 최고 탁도값 예측에서 다소 오차가 발생하는 것으로 나타났다. 안동호와 임하호 단독 운영시와 연계 운영시의 탁수변화 파악을 위해 초기 홍수사상이 발생한 8월 이후부터 저수지내의 TSS농도 분포를 비교하였다. 안동호의 경우 댐앞지점의 탁수분포는 수온성층구조에 영향을 받아, 단독 운영시(EL. 130 m)보다 연계운영시(EL. 140 m)에 탁수의 중심이 높은 위치에 형성되었다. 단독 운영시 10월 이후에 전도현상으로 인해 침강되지 않은 잔류 탁수층이 저수지 하부로 확산되었지만, 연계 운영시에는 재부상 되어 상층으로 확산되는 것으로 모의되었다. 또한 연계운영시 유량이동으로 인해 안동호의 탁수 댐앞 도달시간이 짧아지는 것으로 나타났다. 반면 임하호는 연계 운영시 안동댐으로 유출이 생기면서 중층에서 탁수량이 저감되는 것으로 모의되었다. 저수지 내 탁수량 분석을 위해 SS 15 mg/L 이상의 잔류 탁수량을 분석한 결과, 연계운영시 안동호의 평균 잔류탁수량 비율은 11.8% 증가, 임하호의 경우 11.7% 감소하였다. 또한, 탁수의 댐하류 방류일수도 SS 15 mg/L 기준 임하호 9일 저감, 안동호는 70일 증가하여 임하호의 탁수가 안동호의 탁수 장기화에 영향을 주는 것으로 나타났다.

• The Korean Journal of Pesticide Science
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• v.18 no.1
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• pp.1-7
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• 2014

The present study was performed to investigate the pre-harvest residue limit (PHRL) of pesticides namely, metalaxyl-M and flusilazole in oriental melon, and to identify the biological half-life and characteristics of their residues. In this study, pesticides were sprayed once as single spray and double spray on oriental melon. The oriental melon samples were collected at 0, 1, 2, 3, 5, 7, 9 and 11 days before harvest and samples were extracted with QuEChERS method. The residues of both the pesticides were quantified using GC/NPD and LC/MS/MS. The limit of detection was found to be 0.02 mg/kg and 0.01 mg/kg and their recoveries were greater than 95% (95.7% ~ 103.2% for metalaxyl-M and 100.2% ~ 106.8% for flusilazole) for both pesticides. The biological half-lives of both metalaxyl-M and flusilazole were 12 days at single and double spray, respectively. The PHRL of metalaxyl-M and flusilazole was found 1.0 mg/kg and 0.3 mg/kg, respectively for 10 days before harvest. The results of the present study shows the residual level of both the pesticides metalaxyl-M and flusilazole in oriental melon were less than their maximum residual limits.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2001.04a
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• pp.76-76
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• 2001

종이가 가지는 공극 특성은 종이의 광학적 특성에 지대한 영향을 미칠 뿐만 아니라 인쇄용 지로서 사용될 때 잉크의 다공성 기질로서 잉크의 잔류 특성에도 큰 영향을 미친다. 특히 다공성 기지의 표변에 유동성이 뛰어난 물질이 가해 질 때, 이들의 유동 특성은 기질이 지 니고 있는 공극율과 공극의 분포에 따라 큰 차이를 나타내는 것으로 알려져 있다. 이러한 공극성은 백상지의 경우 사용된 펄프의 혼합 비율과 충전제의 사용량 그리고 펄프의 고해 정도에 따라 종이의 공극울이 달라진다. 종이의 공극성이 광학적 특성과 밀접한 연관성을 지니는 것은 종이의 광산란 계수를 결정하기 때문이다. 잘 알려진 바와 같이 종이의 광산란 계수는 빛의 산란과 관계되어 백색도와 백감도에 영향을 미친다. 그러나 도공지가 인쇄 용 지로 사용 될 경우, 도공지 표면에 도피되는 영크층은 도공지가 가지고 있는 구조적 특성을 변화시킬 수 있는 제3의 요인으로 간주 될 수 있다. 결국, 인쇄가 완료된 종이의 경우 원지층, 도공층 그리고 잉크층으로 구성된다. 따라서 다양 한 공극 구조를 가지는 기질위에 잉크가 도피될 경우 기질의 공극 특성에 따라 잉크 조성분 의 침투 거동에도 많은 차이가 있을 것으로 예측된다. 잉크의 구성 요소를 살펴보면 잉크의 색상을 결정하는 안료, 단일의 각 안료 입자를 도포하여 인쇄판으로부터 종이까지 운송시키 는 기능과 인쇄기에서 잉크의 유동성을 유지하고 종이 또는 기타 피인쇄체에 전이된 후에는 건조막을 형성하는 비히클 그리고 각종 기능성 첨가제로 구성되어 있다. 동일한 성분으로 구성된 잉크를 사용하여 각각 공극성이 다른 피인쇄체 위에 인쇄 될 경우 이들 조성분의 이 동과 표면 잔류 특성에 변화가 있을 것으로 생각된다. 즉 공극성이 풍부한 기질에 도피된 잉크는 반대의 경우와 비교하여 보다 많은 조성분이 종이의 공극 속으로 침투하게 될 것이 다. 이 과정에서 특히 미세한 안료 입자의 경우 피인쇄체의 표면 공극을 채우고, 비히클의 경우 미세한 공극속으로 침투되어 경화됨으로써 피인쇄체가 지니고 있는 공극량을 감소시커 게 될 것이다. 그리고 피인쇄체의 각종 형태의 공극으로 침투된 잉크의 양에 반비례적으로 피인쇄체의 표변에 잉크가 잔류하게 될 것이다. 따라서 본 연구에서는 여러가지 안료를 사용하여 각각 다른 공극 특성을 지니는 도공지를 제조한 후 이들이 가지는 공극 특성과 잉크의 잔류 거동에 대해 고찰해 보고자 하였다.