• Title/Summary/Keyword: 자외선 조사

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Multi-functional Finish of Polypropylene Nonwoven by Photo-induced Graft Polymerization (II) - Grafting of Styrene and Its Ammonia Adsorption Behavior - (광그라프팅에 의한 폴리프로필렌 부직포의 복합기능화 가공(II) -스티렌의 그라프트 반응 및 암모니아 흡착거동 -)

  • 김상률;최창남
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.642-648
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    • 2001
  • An attempt was made to synthesize an ammonia adsorbent by the photo-induced grafting of styrene (St) onto polypropylene (PP) nonwoven using benzoin ethyl ether (BEE) as a photosensitizer with urea and trimethylol propane triacrylate in methanol medium. As styrene concentration was increased, the graft yield was increased. It was also found that the graft yield increased with reaction time. The polypropylene grafted with styrene (PP-g-St) was sulfonated by chlorosulfonic acid in dichloroethane and complexed with several metal ion, such as $cO^{+2}$, $nI^{+2}$, $cU^{+2}$, $Zn^{+2}$. The amount of ammonia gas adsorbed by these sample was dependent on the degree of sulfonation, adsorption time, and ammonia gas pressure. The adsorption capacity of ammonia gas by the sulfonated PP-g-St(SPP-g-St) nonwoven with 4. 25 mmol $H^+$/g was 6.61 mmol/g. Metal ion complexed SPP-g-St nonwovens had higher adsorption capacity than SPP-g-St nonwoven and the $Co^{+2}$ complexed SPP-g-St showed 9.90 mmol $NH_3$/g, which was much higher than that of active carbon or silica gel.

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Development Trend of Environment Monitoring Payloads (환경감시탑재체 개발 동향)

  • Yeon, Jeoung-Heum;Kim, Seong-Hui;Ko, Dai-Ho;Lee, Seung-Hoon;Yong, Sang-Soon
    • Current Industrial and Technological Trends in Aerospace
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    • v.7 no.1
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    • pp.79-88
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    • 2009
  • Environment and climate changes affect all aspects of our society, and its researches are rapidly growing recently. The enhanced remote sensing technology made the satellite to be widely used in the environment monitoring applications with the increased worldwide interests. In this paper, recent development trends of environment monitoring payloads are researched. The major specifications, observational methods and objects of each payloads are surveyed and described. The environment monitoring payloads have been developed for the low-earth-orbit satellite to cover the entire earth area with single satellite. However, as the importance of time-scale resolution increases, payloads for geostationary orbit are under developing recently. Also, ultraviolet, visible, and infrared observation payloads are being developed depending on the monitoring objects. According to these trends, domestic environment monitoring payloads have to be developed with clear and careful mission analysis.

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Molecular Cloning of Chitinase Genes Family from Serratia marcescens

  • Song, Young-Hwan;Kweon, Oh-Gun
    • Journal of fish pathology
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    • v.6 no.2
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    • pp.103-110
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    • 1993
  • Total genomic DNA library of Serratia marcescens was prepared by inserting Sau3AI partial digesting fragments(above 5 kb) into the dephosphorylated BamHl site of pUC19. In primary screening, two colonies were selected by observing the halo around E. coli transformants grown on the swollen colloidal chitin media. Secondary screening was performed by soaking two colonies with a few drops of 4-methylumbelleliferryl N-acetyl-$\beta$-D-glucocosaminide(4-MuNGlcNAc). As 4-MuNGlcNAc is a specific, fluorogenic substrate for chitinase, the positive clones produce light fluorescence by the exposure under the long wave U.V. light(360 nm). From genomic DNA library derived from pUC19, we have isolated two different chitinase clones, pCH1(11.0Kb) and pCH2(7.5Kb), which show completely different restriction map to each other. The cross-hybridization of pCH1EA and pCH2 have not revealed any hybridization signals to each other.

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Performance Improvement of Scrubber by Introducing $TiO_2$ Photocatalytic Nanoparticles ($TiO_2$ 광촉매를 이용한 스크러버 집진장치의 성능 향상에 대한 연구)

  • 천세경;곽승엽
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.31-31
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    • 2003
  • 최근 각종 산업 기술의 발달과 함께 다량의 악취, 오염 물질이 심각한 사회문제로 대두되고 있다. 특히 산업 현장의 경우, 악취로 인해 작업 환경이 매우 열악하여 환경 설비의 개발이 절실히 요구되고 있다. 본 연구에서는 기존의 스크러버 집진 장치의 친수성 가스를 제거할 수 있는 장점을 유지하면서, 소수성 기체의 제거율이 낮은 단점을 보완할 수 있는 TiO$_2$나노 입자의 광분해 특성을 이용한 스크러버 집진 장치를 제작하였다. TiO$_2$ 광촉매 나노 입자는 실험실에서 합성한 QT를 비롯하여, 국내외에서 생산된 P-25, NT-20, ST-01로 특성 분석을 실시하였다. 광촉매 나노 입자의 특성 분석에는 X선 회절 분석법, 적외선 분광기, 제타 전위 분석기, 동적 광산란 분광기를 사용하였으며, 그 결과 ST-01이 본 실험에 가장 적합한 광촉매로 선정되었다. 악취 및 대기 오염 물질 선정은 염색 가공 공장에서 정련제, 산화 환원제등으로 많이 사용하고 있는 암모니아, 아세트산, 옥탄올, 휘발성 유기물질인 톨루엔, 벤젠으로 하여, 실험실 자체 제작한 batch type과 산업 현장에서 사용할 수 있는 continuous type의 스크러버 이용하여 실험하였다. 이들 물질의 제거율은 가스 크로마토그래피, 자외선/가시광선 분광기를 이용하여 조사하였으며, 친수성 기체인 암모니아와 아세트산의 경우는 기존의 스크러버 효율의 약 70%인 반면에, 광촉매를 이용한 스크러버의 경우 90%이상의 우수한 제거 효과를 보였다. 또한, 기존의 스크러버가 거의 분해를 할 수 없었던 소수성 기체 옥탄올, 톨루엔, 벤젠의 경우는 기존의 스크러버가 약 10%내외를 제거하는 것에 비해, 광촉매를 이용한 스크러버의 경우 약 80% 이상의 제거 효율을 나타내었다. 결과적으로 광촉매를 이용한 스크러버의 제거효율이 기존의 스크러버에 비해, 친수성 가스의 경우 20% 이상, 소수성 가스의 경우70% 이상 향상되었음을 알 수 있었으며, 본 연구를 통해 광분해를 이용한 스크러버가 기존설비의 장.단점을 충분히 보완 가능한 환경 설비임을 확인할 수 있었다.

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Construction of Starch-Fermenting Yeast Using Protoplast Fusion Technique (원형질체 융합 방법을 이용한 전분 발효성 효모의 개발)

  • Chun, Soon-Bai;Bai, Suk;Lee, Kee-Young;Kim, Soo-Hyun;Lee, Jin-Jong;Kim, Sang-Moon
    • Korean Journal of Microbiology
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    • v.28 no.2
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    • pp.120-127
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    • 1990
  • Intraspecific fusion frequency between Filobasidium capsuligenum CBS6122-2 ade and met trp or met strains was $2.9\times 10^{-3}$ and $8.5\times 10^{-3}$, respectively. And intergeneric fusion frequency between Folobadidium capsuligenum CBS 4318 (cys his) and Saccharomyces cerevisiae 262-12-1 (hom3 thr1) or X2180-1A (ade thr) was $8.8\times 10^{-6}$ and $9.5\times 10^{-4}$, respectively. Nuclear fusion appears to occru in fusants between intraspecies and intergenera as strongly suggested by DNA content, nuclear staining, comparison of survival rate to UV light and mitotic segregation analysis. It was also found that $\alpha$-amylase and glucoamylase activity from intraspecific hybrids was 1.6-2.1 fold increased when compared with that from thier parents.

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Anti-wrinkle Activities Verification of Buplerum falcatum Extracts on CCD-986sk (CCD-986sk세포내 시호 추출물의 항주름 활성 검증)

  • Kim, Dong-Hee;Park, Tae-Soon;Son, Jun-Ho
    • Journal of Applied Biological Chemistry
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    • v.58 no.2
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    • pp.183-187
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    • 2015
  • The electron donating ability, elastase inhibitory, procollagen synthesis and Matrix metalloprotease-1 (MMP-1) activities were measured in order to verify the anti-wrinkle properties of extracts from Buplerum falcatum as a functional ingredient for cosmetic products. Electron donating ability and elastase inhibition activities were 80 and 52% at a dose of $1,000{\mu}g/mL$ of B. falcatum 70% ethanol extract. Pro-collagen synthesis was increased with the increase concentration of B. falcatum extract on CCD-986sk in addition to decrease the amount of protein of MMP-1. The results suggested that B. falcatum extract can be used to reduced electron donating ability, elastase, pro-collagen synthesis and MMP-1 activity and is a potential candidate for cosmedical materials.

Determination of Sesame oil Adulterated with other Vegetable oils by Spectrophotometric Method (자외선 흡수특성을 이용한 참기름의 이종기름 혼입판별에 관하여)

  • 이영근
    • Journal of Food Hygiene and Safety
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    • v.8 no.3
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    • pp.151-155
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    • 1993
  • Since there have been no method which can applicable to the screening of commercial sesame oil adulterated with other vegetable oils, the present investigation was carried out particularily focusing on the the pattern of IN absorption of sesame oil and other vegetable oils. For this, a variety of oil samples prepared by the conventional method from sesame seeds, perilla seeds, com, soybean, and rice bran were analyzed by IN spectrophotometer. IN spectra of sesame oil and oil of unheated sesame seeds showed absorption peaks at 215, 230 and 290 nm. While UV spectra of com oil, perilla oil and soybean oil all showed absorption peaks at 215, 230 and 280 nm, that of rice bran oill showed peaks at 215, 290 320 nm. When sesame oil was mixed with com oil, perilla oil or soybean oil, respectively, from which the absorbance of peaks at 290 nm were lower than pure sesame oil. The peak at 320 nm which was typical absorption peak of rice bran oil was still observed in the spectnun of mixture of sesame oil with rice bran oil.

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A Study of Corona Discharge in Polymer Insulators by Artificial UV Radiation (인위적인 자외선 조사량에 따른 폴리머애자에서의 코로나 방전 특성)

  • Kim, Y.S.;Choi, M.I.;Kim, C.M.;Bang, S.B.;Shong, K.M.;Kwag, D.S.
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.62 no.5
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    • pp.643-648
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    • 2013
  • In this study, degradation was observed by irradiating UV rays to the polymer insulators which have been widely used in outdoor electric power facilities. For an indoor accelerated UV test, 0.55 w/m2 of UV rays were applied using a xenon-arc method. A UV detection system with 65 ${\phi}mm$ in diameter, 100 mm in length and 1.0 of brightness (F/#) has been designed. Even though efflorescence on the surface of polymer insulators wasn't observed according to the accelerated UV test. UV rays were detected at around 50% and 40% of insulation breakdown in EPDM and silicone-type insulators respectively. As degradation continued because of an indoor accelerated UV test, breakdown voltage with which UV rays can be detected in an early stage decreased as well. A silicone polymer insulator would be severer than EPDM polymer insulator in terms of surface degradation because of UV strength against $V_m/V_{BD}$ was high in silicone polymer insulators. UV strength in silicone-type insulators increased at 1,000 $kJ/m^2$ because contact angle at the intial stage sharply decreased to from $113^{\circ}$ to $92.1^{\circ}$.

The Image-forming Property of Optical System having Gaussian Amplitude for Polychromatic Source (다색 광원에 대한 가우시안 진폭을 갖는 광학계의 결상 특성)

  • Park, Seong Jong;Park, Hae Jong
    • Journal of Korean Ophthalmic Optics Society
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    • v.4 no.2
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    • pp.33-38
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    • 1999
  • To investigate the image-forming property of optical system having Gaussian amplitude for polychromatic source, we calculated the chromaticity variation and the illuminance distribution. Considered polychromatic sources in this paper are A light which is on incandescent-tungsten lamp, C light which is a daylight, and $D_{65}$ light which is a extend daylight to the near ultraviolet. The polychromatic sources represent the different chromaticity values at a geometrical image point. The chromaticity variation of optical system having a Gaussian amplitude is smaller than that having an uniform amplitude. The illuminance distributions for polychromatic sources present nearly the same values, and the depth of focus for optical system having a Gaussian amplitude is wider than that having an uniform amplitude. From these results, we know that the depth of focus increases and the chromaticity variation decreases, when the incident light amplitude is modulated from an uniform amplitude to a Gaussian amplitude.

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Spectroscopic and Surface Characteristics of Tintable Hard Coating by Sol-Gel Method (졸-겔법에 의한 착색이 가능한 하드코팅의 분광 및 표면 특성)

  • Yu, Dong-Sik;Kim, In-Su;Ha, Jin-Wook
    • Journal of Korean Ophthalmic Optics Society
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    • v.13 no.1
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    • pp.37-42
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    • 2008
  • Purpose: This study is to prepare tintable hard coatings for plastic lenses and to evaluate spectroscopic and surface characteristic for these coatings. Methods: These coatings had been prepared by the sol-gel method using TEOS, MTMS and GPTS. Scanning electron microscopy (SEM), Raman spectroscopy, infrared (IR) spectroscopy and UV/VIS spectroscopy have been used to investigate the optical and structural characteristics of the coatings. Results: Tint ability of this coating was about 2 times higher than general hard coatings. The lenses applied by tintable hard coatings showed excellent adhesion, abrasion resistance, hot water resistance, and chemical resistance. Pencil hardness was 5H and the surface of coatings was smooth and free of cracks. Conclusions: This hard coating system for plastic lenses offered a hard and stable surface that could be tinted.

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