• Journal of the Korean Chemical Society
• /
• v.38 no.7
• /
• pp.480-484
• /
• 1994

The durability of UV radiation cured coatings near the film-substrate interface has been studied. Particularly, the influence of the reactive diluent and oligomer in the UV-cured urethane acrylate formulation on the wrinkle formation of coating films was investigated. Results showed that wrinkle resistance increases when DMTA loss peaks of coating network are broad and has shoulder. When modified aromatic urethane acrylate oligomer is used to replace the aliphatic one, resulting cured network provides coating film of high hardness and flexibility. Therefore, the high values of loss modulus as low temperature are considered to be the main reason for wrinkle resistance improvements. The SEM and instron data support above conclusion.

• Proceedings of the Korean Ceranic Society Conference
• /
• 2003.10a
• /
• pp.82.1-82
• /
• 2003

• Proceedings of the Korean Society of Dyers and Finishers Conference
• /
• 2007.11a
• /
• pp.21-22
• /
• 2007

• Korean Chemical Engineering Research
• /
• v.50 no.4
• /
• pp.621-626
• /
• 2012

In this study, the composite coating materials with improved thermal insulation property were prepared by incorporating the hollow micro-spheres with high heat transfer resistance. The UV curable resin system consisting of hexa aliphatic urethane acrylate (UP118), trimethylolpropane triacrylate (TMPTA), 1,6-hexanediol diacrylate (HDDA), and photoinitiator (Irgacure184) was employed as an organic binder. The glass substrates were coated by the prepared composites via bar coating method and cured under UV radiation. The optical transparency, thermal insulation property, adhesion, and surface hardness of the glass coated with composites containing different type of micro-spheres were investigated. The incorporation of micro-spheres with only 20 vol% of content resulted in remarkable improvement in the thermal insulation property of the coated glass. In addition, the transparent coated glass with light transmittance of about 80% could be obtained when silica micro-sphere (SP) was used as a thermal barrier.

• Journal of the Korean Applied Science and Technology
• /
• v.29 no.1
• /
• pp.141-148
• /
• 2012

In this study, the composite coating materials with improved thermal insulation property were prepared by incorporating the hydrophobic silica aerogel. The surface modification of silica aerogel was performed to obtain UV curable urethane acrylate hybrid coating sols with good compatibility by using surfactant(Brij 56). The polycarbonate substrates were coated by the prepared composites and cured under UV radiation. The incorporation of aerogel with only 10 vol% of content resulted in remarkable improvement by about 28% in the thermal insulation property of the coated film, as compared with substrate. In addition, increasing aerogel content was found to give minor effect on the variation of optical transparency, adhesion, and surface hardness of the coated film.

• Polymer(Korea)
• /
• v.38 no.5
• /
• pp.573-579
• /
• 2014

The effect of synthesis conditions such as carbon nanotube (CNT), 2,2,2-trifluoroethylmethacrylate (3FMA), and composition of organic-inorganic material in ozone resistance and surface characteristics of ultraviolet cured organic-inorganic hybrid coating film has been investigated. Coating solution was prepared using tetraethoxysilane (TEOS), silane coupling agent methacryloyloxypropyltrimethoxysilane (MPTMS), 3FMA, various organic materials with acrylate group, and CNT, then bar-coated on substrates using applicator, and densified by UV-curing. It was found that ozone resistance and adhesion of the coating film were strongly dependent upon contents of TEOS, 3FMA, and CNT. Especially, ozone resistance, adhesion, and surface hardness of coating film with CNT were improved, relatively. Ozone resistance of coating film with a high TEOS content was increased, but adhesion was decreased. In addition, it was also found that ozone resistance of coating film was increased with contents of 3FMA. On the other hand, surface hardness was decreased with increase of 3FMA.

• Journal of Adhesion and Interface
• /
• v.16 no.2
• /
• pp.55-62
• /
• 2015

It was investigated that the effect of surface modification and concentration of fumed silica on the adhesion properties and thermal stability of 2-EHA/AA pressure sensitive adhesive (PSAs) prepared by UV irradiation. The influence of repeating units of crosslinking agent on PSAs were also studied. From SEM analysis, PSAs synthesized with surface modified silica had finer dispersion of silica particles in polymer matrix due to the interfacial interaction. Results of the study showed that increase in tack and peel strength when under 0.3 wt% of silane treated silica were added in the reaction mixture. The addition of PEGDMA for crosslinking agent offers positive effect on adhesion properties in comparison with PSAs using EGDMA for crosslinker, which may be attributed to high mobility of ethylene oxide repeating units in PEGDMA. From the thermal degradation residue of PSAs, it was revealed that thermal stability was improved with silica addition due to the strong interfacial bonding between silane modified silica and polymer matrix, which may act as a thermal barriers into 2-EHA/AA PSAs.

• Journal of Adhesion and Interface
• /
• v.10 no.4
• /
• pp.191-198
• /
• 2009

UV-curable aliphatic epoxy acrylates were prepared by the reaction of glycerol diglycidyl ether (GDE) with 2-carboxyethyl acrylate (2-CEA) or 2-hydroxyethyl acrylate (2-HEA). The structures of the epoxy acrylates were characterized by FT-IR, $^1H$-NMR, and $^{13}C$-NMR and the yield was obtained by prep-LC. The UV- and the thermal-curing behaviors of the product were investigated using photo-DSC and DSC, respectively. The reactivity of 2-CEA was higher than 2-HEA and the yield of the product (GEA-C) which was prepared using 2-CEA was about 83%. The maximum UV-curing time ($T_{max}$) of the GEA-C contained non-reactive components and by-product was about 10 seconds. The GEA-C showed low color difference (${\Delta}E^*$), low viscosity, and good thermal stability - its value was 2.51, 192 cps, and $299^{\circ}C$ (at 5% weight loss), respectively. The activation energies ($E_a$) of thermal-curing reaction calculated from Kissinger and Ozawa-Flynn-Wall method were 91~92 kJ/mol.

• Elastomers and Composites
• /
• v.49 no.3
• /
• pp.210-219
• /
• 2014

In this study, the acrylic pressure sensitive adhesive (PSA) for the optical functionality sheet was prepared by blending liquid isoprene rubber. The acrylic PSA was synthesized with butyl acrylate, acrylic acid, 2-ethylhexyl acrylate and 2-hydroxyethyl methacrylate. Toluene was used to a solvent for polymerization. Liquid isoprene rubber (LIR-50) was blended with the acrylic PSA and blend ratio was 0 ~ 50 wt%. According to the results, the adhesive transfer, which was the big problem of acrylic adhesive, was reduced with the addition of LIR-50. The secondary bonding of LIR-50 with substrate did not occurred due to absence of polar group in LIR-50. The peel strength and adhesive transfer were decreased by UV curing and the degreed of decrease depended on the amounts of photoinitiator and UV irradiation time. On the other hand holding power increased drastically by increasing amounts of photoinitiator and UV irradiation time.

• Polymer Science and Technology
• /
• v.10 no.5
• /
• pp.629-639
• /
• 1999