• Title/Summary/Keyword: 자외선 경화형

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Development of Surface Improvement Technique of Japanese Larch flooring Board(I) (낙엽송 마루판재의 표면강화처리기술개발(I))

  • Park, Sang-Bum
    • Journal of the Korean Wood Science and Technology
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    • v.27 no.3
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    • pp.31-38
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    • 1999
  • This paper deals with a coating technique of hardening surface layer of softwood{Larix leptolepis) flooring board to improve its surface properties such as hardness and abrasion resisitance without spoiling its exellent qualities such as beautiful color tones and great strength. For surface hardening of the wood, polyurethane wood sealer was used as under coat, polyurethane sanding sealer as intermediate coat, and UV-curing epoxy acrylate and urethane acrylate varnishes as top coat. The hardness of the wood was improved by the coating treatment and it was similar to that of high density hardwood such as oak, keruing. The abrasion resistance of the coated wood was greatly improved by UV curing epoxy acrylate or urethane acrylate varnishes. Adhesion properties and impact resisitance of the coated wood surface were also good. It was suggested that the well-coated larch wood could be used as interior flooring board as substitute for hardwood such as keruing.

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Synthesis of Adhesion Promoters with Improved Compatibility and Properties of UV-Curable Adhesives Containing Adhesion Promoters (상용성이 개선된 접착 증진제의 합성 및 이를 함유한 자외선 경화형 접착제의 특성분석)

  • Park, Jung-Hyun;Won, Jonh-Woo;Kim, Ju-Yeol;Yoon, Yoo-Jung;Kwon, Oh-Hyeong;Hwang, Jin-Sang
    • Journal of Adhesion and Interface
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    • v.19 no.4
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    • pp.145-153
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    • 2018
  • In this study, adhesion promoters with acrylate and carboxylic acid moiety were synthesized from malenized polybutadiene and 2-hydroxyethyl acrylate for producing adhesive film with low water absorption and high adhesion. The surface properties, adhesion strength, mechanical properties and water absorption of adhesive films were characterized according to the amount of acrylate and carboxylic acid in the synthesized adhesion promoters. As the carboxylic acid in the adhesion promoters increased, the adhesion strength showed a tendency to increase and the mechanical properties also improved compared to the commercial adhesion promoter. The compatibility of adhesion promoters improved remarkably due to the presence of polybutadiene (hydrophobic nature), maleic anhydride (hydrophilic nature) and carboxylic acid (hydrophilic nature).

Preparation and application of silica-based coatings for corrosion protection of marine structures (해양구조물용 silica 기반 내해수성 코팅제의 제조 및 응용)

  • Lee, Byeong Woo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.3
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    • pp.137-142
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    • 2021
  • In this study, the development of the room temperature curable silica-based coating compositions for anticorrosive and antifouling performance in marine environments was carried out. The marine (plant) structures with many exposed parts are operated in harsh marine environments such as strong ultraviolet rays, extreme temperature differences and salt water corrosion. Organic paints that are easily degraded under these environments and easily eroded by physical stimuli such as waves can not play a role properly. Dense ceramic coatings on marine structures provide careful protections even in saltwater environments due to their high hardness and rust resistance. Therefore, in the case of ceramic coatings, their use and application range in marine structures can be greatly improved due to their functional advantages. In the present study, silica-based coating compositions based on colloidal silica with silane coupling agents, curing salts, and ceramic fillers were developed, and their applications as protective coatings for corrosion protection and fouling prevention in seawater were also studied.

Synthesis of UV Curable Polyurethane Adhesives Based on Various Compositions of Mixed Polyol with Improved Adhesion and Flexural Properties (다양한 조성의 혼용 폴리올에 기초한 접착력 및 굴곡성이 향상된 자외선 경화형 폴리우레탄 접착제의 합성)

  • Won-Young Lee;Soo-Yong Park;Guni Kim;Ildoo Chung
    • Journal of Adhesion and Interface
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    • v.23 no.4
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    • pp.137-143
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    • 2022
  • In this study, the polyurethane acrylates (PUA) resin with good adhesive and flexibility for adhesive for shoes and clothing were synthesized using that poly(tetramethylene adiphate glycol) (PTAd), poly(tetramethylene ether glycol) (PTMG) as polyester polyol and polyether polyol respectively, including 4,4'-methylene diphenyl diisocyanate (MDI), isophorone diisocyanate (IPDI), 1,4-butandiol (1,4-BD), 2-hydroxyethyl methacrylate (2-HEMA) and dibutyl amine (DBA). The effect of polyol blend in the polyurethane acrylate on thermal and mechanical properties, adhesion strength and flexural strength were studied. The glass transition temperature (Tg) of PUA was confirmed in range of -70~-40 ℃. In addition, the glass transition temperature (Tg), decomposition temperature (Td), tensile strength adhesion strength and heat resistance were increased as increasing of PTAd amount while the elongation, water resistance and flexural properties were decreased. The synthesized polyurethane acrylate with 5:5 ratio of PTAd and PTMG indicated the highest adhesion strength and flexural properties.

A CLINICAL STUDY ON THE MAINTENANCE OF LIGHT INTENSITY OF VISIBLE-LIGHT CURING MACHINES FOR THE POLYMERIZATION OF COMPOSITE RESINS (복합레진 중합용 가시광선 광중합기의 적정 광강도 유지를 위한 임상적 고찰)

  • Lee, Dong-Soo;Jeong, Tae-Sung;Kim, Shin
    • Journal of the korean academy of Pediatric Dentistry
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    • v.28 no.3
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    • pp.363-368
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    • 2001
  • It is well known that numerous factors influence the light output of curing units, but many dentists are un aware that the output of their curing lights are inadequate. This study was conducted to evaluate the light in tensity of visible-light curing units in some private dental clinics and hospital dental clinics. In order to determine the maximum light intensity of the curing units, lamps, filters and fiber optic bundles, they were replaced with new ones and light intensity was remeasured. Light intensity was measured by employing a digital radiometer (EFOS model #8000, USA). Light intensity ranged in $29\sim866mW/cm^2$ (below $150mW/cm^2$ ; 17.8%, $150\sim300mW/cm^2$ : 46.6%, above $300mW/cm^2$ ; 35.6%). The replacement of the components increased the light intensity, with maximum increases of 94.8% for lamps, 82.3% for filters, 200.8% for fiber optics and 361.5% for all three parts. According to the manufacturer of radiometer, curing light is considered as unsuitable for use with a reading of above $300mW/cm^2$ by the radiometer. Applying these criteria to the present study, 64.4% of the curing units required repair or replacement. The results of this study indicated that the light intensities of the curing units used in dental practice were lower than optimum level.

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Electro-optical Characteristics of the Dual-frequency Bistable Nematic Liquid Crystal Cell with Pixel-isolating Polymer Wall (폴리머 격벽에 의해 화소고립된 구조의 이중주파수 쌍안정 네마틱 액정셀의 전기광학 특성)

  • Lee, Seong-Ryong;Lee, Joong-Ha;Shin, Jae-Hoon;Song, Dong-Han;Yoon, Tae-Hoon;Kim, Jae-Chang
    • Korean Journal of Optics and Photonics
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    • v.19 no.3
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    • pp.161-168
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    • 2008
  • We propose a novel bistable nematic liquid crystal cell, which has a dual-frequency liquid crystal material and pixel-isolating polymer wall formed by an anisotropic phase separation of a mixture of liquid crystals and UV-curable pre-polymers. The proposed cell has two stable states of left- and right-handed ${\pi}$-twist. The switching between the two states is achieved by using a sequential waveform of low and high frequencies. A transmissive bistable liquid crystal display is designed, which achieves high contrast ratio by using the proposed cell and optical films.

Effect of Combined Environmental Factors on Degradation Behavior of Carbon Fiber/Epoxy Composites (복합적인 환경인자의 영향에 따른 탄소섬유/에폭시 복합재의 열화 특성)

  • Hwang, Young-Eun;Lee, Gil-Hyung;Yoon, Sung-Ho
    • Composites Research
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    • v.22 no.5
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    • pp.37-42
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    • 2009
  • Thermal analysis properties and chemical structure of carbon fiber/epoxy composites under environmental exposure were examined using an accelerated aging tester which can simulate real weather conditions such as temperature, moisture and ultraviolet. The composite specimens were exposed to combined environmental factors up to 3000 hours. Thermal analysis properties and chemical structure of the composites were evaluated with various exposure times through Modulated DSC and FTIR. According to the results of Modulated DSC, the glass transition temperature increased as exposure time increased due to the formation of network structures in the composites. Also endotherm peaks of enthalpy relaxation related to physical aging that can affect the properties of the composites were observed as exposure time increased. From the results of FTIR, it was found that the location of the peaks was little affected by exposure time, but the intensity of the peaks slightly decreased as exposure time increased due to the curing reaction in the epoxy group.

Isolation and Characterization of Pyrimidine Auxotrophs from the Hyperthermophilic Archaeon Sulfolobus acidocaldarius DSM 639 (Sulfolobus acidocaldarius 균주로부터 피리미딘 영양요구주의 분리 및 특성 연구)

  • Choi, Kyoung-Hwa;Cha, Jae-Ho
    • Journal of Life Science
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    • v.21 no.10
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    • pp.1370-1376
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    • 2011
  • To study the functional genomic analysis of a crenachaeon Sulfolobus acidocaldarius, we have constructed an auxotrophic mutant based on pyrEF, which encodes the pyrimidine biosynthetic enzymes orotate phosphoribosyltransferase and orotidine-5'-monophosphate decarboxylase. S. acidocaldarius was shown to be sensitive to 5-fluoroorotic acid (5-FOA), which can be selected for mutations in pyrEF genes within a pyrimidine biosynthesis cluster. Spontaneous 5-FOA-resistant mutants by ultraviolet, KH1U and KH2U, were found to contain two point mutations and a frame shift mutation in pyrE, respectively. Mutations at these sites from KH1U and KH2U decreased the activity of orotate phosphoribosyltransferase encoded by the pyrE gene and blocked the degradation of 5-FOA into toxic 5-FOMP and 5-FUMP that kill the cells. Therefore, KH1U and KH2U were uracil auxotrophs. Transformation of Sulfolobus-Escherichia coli shuttle vector pC bearing pyrEF genes from S. solfataricus P2 into S. acidocaldarius mutant KH2U restored 5-FOA sensitivity and overcame the uracil auxotrophy. This study establishes an efficient genetic strategy towards the systematic knockout of genes in S. acidocaldarius.

The properties of AlGaN epi layer grown by HVPE (HVPE에 의해 성장된 AlGaN epi layer의 특성)

  • Jung, Se-Gyo;Jeon, Hun-Soo;Lee, Gang-Seok;Bae, Seon-Min;Yun, Wi-Il;Kim, Kyoung-Hwa;Yi, Sam-Nyung;Yang, Min;Ahn, Hyung-Soo;Kim, Suck-Whan;Yu, Young-Moon;Cheon, Seong-Hak;Ha, Hong-Ju
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.1
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    • pp.11-14
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    • 2012
  • The AlGaN layer has direct wide bandgaps ranging from 3.4 to 6.2 eV. Nowadays, it is becoming more important to fabricate optical devices in an UV region for the many applications. The high quality AlGaN layer is necessary to establish the UV optical devices. However, the growth of AlGaN layer on GaN layer is difficult due to the lattice mismatch and difference thermal expansion coefficient between GaN layer and AlGaN layer. In this paper, we attempted to grow the LED structure on GaN template by mixed-source HVPE method with multi-sliding boat system. We tried to find the optical and lattice transition of active layer by control the Al content in mixed-source. For the growth of epi layer, the HCl and $NH_3$ gas were flowed over the mixed-source and the carrier gas was $N_2$. The temperature of source zone and growth zone was stabled at 900 and $1090^{\circ}C$, respectively. After the growth, we performed the x-ray diffraction (XRD) and electro luminescence (EL) measurement.