• Title/Summary/Keyword: 자동차연료

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Hydrogen Production by Autothermal Reforming Reaction of Gasoline over Ni-based Catalysts and it Applications (Ni계 촉매상에서 가솔린의 자열 개질반응에 (Autothermal Reforming)의한 수소제조 및 응용)

  • Moon, Dong Ju;Ryu, Jong-Woo;Yoo, Kye Sang;Lee, Byung Gwon
    • Transactions of the Korean hydrogen and new energy society
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    • v.15 no.4
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    • pp.274-282
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    • 2004
  • This study focused on the development of high performance catalyst for autothermal reforming (ATR) of gasoline to produce hydrogen. The ATR was carried out over MgO/Al2O3 supported metal catalysts prepared under various experimental conditions. The catalysts before and after reaction were characterized by N2-physisorption, CO-chemisorption, SEM and XRD. The performance of supported multi-metal catalysts were better than that of supported mono-metal catalysts. Especially, it was observed that the conversion of iso-octane over prepared Ni/Fe/MgO/Al2O3 catalyst was 99.9 % comparable with commercial catalyst (ICI) and the selectivity of hydrogen over the prepared catalyst was 65% higher than ICI catalyst. Furthermore, it was identified that the sulfur tolerance of prepared catalyst was much better than ICI catalyst based on the ATR reaction of iso-octane containing sulfur of 100 ppm. Therefore, Ni/Fe/MgO/Al2O3 catalyst can be applied for a fuel reformer, hydrogen station and on-board reformer in furl cell powered vehicles.

The Process of Development and the Change of Freight Flows in the Influence Areas of pyeongtaek and Dangjin Port, Korea (평택.당진항의 항만발달과 화물유동에 의한 항세권 변화)

  • Han, Ju-Seong
    • Journal of the Korean Geographical Society
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    • v.45 no.6
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    • pp.766-787
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    • 2010
  • This study seeks to clarify the process of development and the change of freight flows in the influence areas of Pyeongtaek and Dangjin Port, which opened lately. The results of analysis are as follows: from development period to growth period, the relation between the development of the port and the change of the hinterland and foreland shows no great change and the freight concentration rates of the first hinterland and foreland decreased, but those of periphery region increased. While the composition rate of import and export freight of vehicle, fuel and energy decreased, the rate of imported freights (iron or steel, other textile articles, rag and organic compounds) and exported freight (manufacture of basic metals) increased. The reasons for such changes in influence areas of port were the increase of export to China and the U.S.A. in the development period, the increase of import from China in the growth period and the diversification of nations from which fuel and energy were imported.

Two-Phase Flow Analysis of The Hydrogen Recirculation System for Automotive Pem Fuel Cell (자동차용 고분자 연료전지 수소 재순환 시스템의 이상 유동해석)

  • Kwag, Hyun-Ju;Chung, Jin-Taek;Kim, Jae-Choon;Kim, Yong-Chan;Oh, Hyung-Seuk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.6
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    • pp.446-454
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    • 2008
  • The purpose of this paper is to analyze two-phase flows of the hydrogen recirculation system. Two-phase flow modeling is one of the great challenges in the classical sciences. As with most problems in engineering, the interest in two-phase flow is due to its extreme importance in various industrial applications. In hydrogen recirculation systems of fuel cell, the changes in pressure and temperature affect the phase change of mixture. Therefore, two-phase flow analysis of the hydrogen recirculation system is very important. Two-phase computation fluid dynamics (CFD) calculations, using a commercial CFD package FLUENT 6.2, were employed to calculate the gas-liquid flow. A two-phase flow calculation was conducted to solve continuity, momentum, energy equation for each phase. Then, the mass transfer between water vapor and liquid water was calculated. Through an experiment to measure production of liquid water with change of pressure, the analysis model was verified. The predictions of rate of condensed liquid water with change of pressure were within an average error of about 5%. A comparison of experimental and computed data was found to be in good agreement. The variations of performance, properties, mass fraction and two-phase flow characteristic of mixture with resepct to the fuel cell power were investigated.

Estimation for output correction of internal combustion engine (내연기관의 출력수정에 관한 평가)

  • 김문헌
    • Journal of the korean Society of Automotive Engineers
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    • v.8 no.1
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    • pp.22-28
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    • 1986
  • 기관의 성능에 영향을 주는 인자로서는 외적인자(outside factor), 작동인자(operating factor) 및 설계인자(design factor)의 3가지로 나눌 수 있다. 작동인자로서는 기관회전수, 공기연료비, 점화 시기 또는 분사시기 등이면 설계인자로서는 행정체적, 압축비, 흡배기계통의 구조 및 치수, 냉각 방식 등으로 기관에 따라 고유한 값을 가지는 인자이다. 그러나 외적인자인 대기조건 즉 대기 압력, 대기온도 및 대기습도는 계절, 지역 및 기상조건에 따라 달라지므로 이것에 따라 기관이 흡입하는 공기의 압력, 온도 및 습도는 변화하게 된다. 그러므로 대기조건의 변화에 따라서는 기관작동인자인 공기연료비에도 영향을 미치게 할 것이고 또한 연소상태의 변화로 유효압축비 에도 영향을 미치게 할 것이므로 대기상태의 변화는 곧 바로 기관 출력의 변화를 초래하게 될 것이다. 그러므로 같은 운전조건에서의 기관출력도 대기상태의 변화에 따라 변화하게 되므로 임의의 대기 상태에서 측정한 기관출력을 표준대기상태의 기관출력으로 환산해서 평가할 필요가 생긴다. 이것을 일반으로 출력수정(output correction)이라 하고 있으며 각 나라마다 공업규격 또는 기타규격으로 출력정식을 제정하고 있다. 예를 들면 K.S.B 9102, SAE J816B, B.S. 765, DIN 70020, JIS B 8013등이다. 이들 출력수정식들은 많은 문제점을 가지고 있으므로 종래의 출 력수정식으로 출력수정을 하여도 정확하게 맞지 않은 경우가 많다. 출력수정에 관한 문제는 수 10년전부터 많은 연구자에 의하여 연구되고 거론되어 왔으나 과거의 연구자들이 제안하고 거론 되어 왔으나 과거의 연구자들이 제안하고 있는 출력수정식, 또는 규격으로 정하고 있는 출력수 정방법은 어느 것이나 실용상 만족스러운 것이 아직 없다. 그러므로 본 자료는 스파아크 점화 기관의 흡기습도에 관한 출력수정의 문제를 실험적으로 수행한 실험적 출력수정방법에 의한 것과 종래의 출력수정방법에 의한 것과를 비교 검토하였다.

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Physicochemical Characteristics of CDPF according to Ash a Cleaning agent (Ash 세정제에 따른 CDPF의 물리화학적 특성)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.4
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    • pp.641-647
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    • 2017
  • In order to meet the stricter emission regulations, the proportion of after-treatments for vehicles and vessels has been increasing gradually. The objective of this study is to investigate the physicochemical properties according to ash cleaning agents of CDPF for Diesel Engines. Penetrating agents with strong penetration into ash and a surfactant component to mix water and oil were prepared properly. The cleaning characteristics of S1 sample were good. Washcoat loss rate of S1 sample was lower by about 2.2% because of less KOH component and lower Na2SiO3 content. Washcoat loss rate of S4 sample with an added KOH and Na2SiO3 components by penetration agents was increased by about 13%. In terms of less than about 13% of CDPF's washcoat loss rate, it was able to reduce the harmful gas components.

Combustion Characteristics and the Modeling of Ionized Methane for Battery Fires (배터리화재를 모사한 이온화 메탄의 연소특성 및 모델링)

  • Ko, Hyuk-Ju;Lee, Eui-Ju
    • Fire Science and Engineering
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    • v.33 no.1
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    • pp.23-29
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    • 2019
  • Rechargeable battery such as lithium-ion battery has been noticed as a kinds of the energy storage system in the recent energy utilization and widely used actually in various small electronic equipment and electric vehicles. However, many thermal runaway caused battery accidents occurred recently, which still is obstacle for advanced application of lithium ion battery. One of the main differences to general fires is the existence of ionized electrolyte with electron during combustion. Therefore, we simply simulated the ion addition effects of battery fires by introducing an ionized fuel in jet diffusion flames. When the ionized methane through a corona discharge was used as fuel, the overall flame stability and shape such as flame length showed no significant difference from normal methane flame, but NOx and CO emissions measured at the post flame region decreased. The ion addition effect of methane oxidation was also numerically simulated with the modeling of hydrogen addition in the mixture. It was confirmed that the hydrogen addition at a fixed temperature had a similar effects on ionization of methane and hence could be modeled successfully.

Experimental Investigations of the Characteristics of the Length Variation of Kerosene-Oxygen Laminar Diffusion Flames (등유-산소 층류 확산화염의 길이 변화 특성에 관한 실험적 연구)

  • Lee, Soo-Han;Lee, Jong won;Park, Seul Hyun
    • Fire Science and Engineering
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    • v.32 no.6
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    • pp.22-27
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    • 2018
  • The flame length in coaxial diffusion flame configurations was investigated when the kerosene fuel flow rate, temperature of the oxidizer stream, and inert gas concentrations in the oxidizer stream were varied. The diffusion flame was photographed using a Schlieren camera under each of the experimental conditions and the obtained images were then digitized to measure the flame length. The measured flame lengths were proportional to the kerosene fuel flow rate and increased with increasing temperature of the oxidizer stream. In addition, increases in the inert gas concentration in the oxidizer stream resulted in stretching of the flame. In particular, the flame was further elongated in the oxidizer steam diluted with helium gas. Inert substitutions in the oxidizer stream that can adjust the viscous drag are believed to be one of the important mechanisms that affect the length of the coaxial diffusion flames.

A Simulation Study of Renewable Power based Green Hydrogen Mobility Energy Supply Chain Systems (재생에너지 기반 청정 수소 운송 에너지 시스템 모사 연구)

  • Lee, Joon Heon;Ryu, Jun-Hyung
    • Korean Chemical Engineering Research
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    • v.60 no.1
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    • pp.34-50
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    • 2022
  • Since the Paris climate agreement, reducing greenhouse gases has been the most important global issue. In particular, it is necessary to reduce fossil fuels in the mobility sector, which accounts for a significant portion of total greenhouse gas emissions. In this paper, we investigated the economic feasibility of green mobility energy supply chains, which supply hydrogen as fuel to hydrogen vehicles based on electricity from renewable energy sources. The design and operation costs were analyzed by evaluating nine scenarios representing various combinatorial possibilities such as renewable energy generation, hydrogen production through water electrolytes, hydrogen storage and hydrogen refueling stations. Simulation calculations were made using Homer Pro, widely used commercial software in the field. The experience gained in this study could be further utilized to construct actual hydrogen energy systems.

Rotordynamic Performance Measurements of a Two-Pad Beam-Type Gas Foil Journal Bearing for High Speed Motors (고속 전동기용 2 패드 빔 타입 가스 포일 저널 베어링의 회전체동역학 성능 측정)

  • Jeong, Kwon Jong;Hwang, Sung Ho;Baek, Doo San;Kim, Tae Young;Kim, Tae Ho
    • Tribology and Lubricants
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    • v.38 no.5
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    • pp.205-212
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    • 2022
  • This paper presents experimental measurements of the structural characteristics of a two-pad beam-type gas foil journal bearing and its rotordynamic performance for a high-speed motor-driven turbocompressor. The test bearing had two top foils and two beam foils, each with an arc length of ~180°. Each beam foil was etched to obtain 40 beams with six geometries of different lengths and widths. The insertion of beam foils into the bearing housing produces equivalent beam heights. The structural tests of the bearing with a non-rotating journal revealed a smaller bearing clearance and larger structural stiffness for the load-on-pad configuration than for the load-between-pads configuration. Rotordynamic performance measurements during driving tests up to 100 krpm demonstrated synchronous vibrations and subsynchronous vibrations with large amplitudes. The test was repeated after inserting the shim between the top foil and beam foil to reduce the bearing radial clearance. The reduced bearing clearance resulted in a reduction in the peak amplitude of the synchronous vibrations and an increase in the speed at which the peak amplitude occurred. In addition, the onset speed and amplitude of the subsynchronous vibrations were dramatically increased and diminished, respectively. The rotor coast-down tests at 100 krpm show that the reduction in the bearing clearance extends the time to rotor stop, thus implying an improvement in hydrodynamic pressure generation and a reduction in bearing frictional torque.

A Study on Precuring Condition of the 2-step Manufacturing Method for PEMFC Composite Bipolar Plates (PEMFC용 복합소재 분리판을 위한 2단계 제조공법의 예비성형 조건에 대한 연구)

  • Heo, Seong-Il;Oh, Kyung-Seok;Jang, Jun-Ho;Yang, Yoo-Chang;Han, Kyung-Seop
    • Composites Research
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    • v.20 no.2
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    • pp.10-16
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    • 2007
  • The 2-step manufacturing method consisting of preforming and stamping processes was developed to manufacture composite bipolar plates for PEMFCS. The preform was composed of expanded graphite, graphite flake and phenol resin. Procuring conditions were optimized by checking the electrical conductivity, flexural strength and microstructure. Procuring temperature $(100^{\circ}C)$ slightly above the melting point of phenol powders $(90^{\circ}C)$ induced moderate curing, but also prevented excessive curing. Preforms utilizing the tangled structure of expanded graphite were easily fabricated at low pressure of 0.07-0.28MPa. The proper procuring time, 5min, was determined to fabricate the preform stably because insufficient and excessive procuring deteriorated the flexural strength of composite bipolar plates.