• Title/Summary/Keyword: 입자경 분포

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Study on the Flame Retardation and Thermal Resistance for CPE Rubber Material Added Etching By-product of Aluminum (알루미늄 엣칭부산물을 첨가한 CPE 고무재료의 난연성 및 내열성 연구)

  • Kim, Kyung Hwan;Lee, Chang Seop
    • Journal of the Korean Chemical Society
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    • v.45 no.4
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    • pp.341-350
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    • 2001
  • Aluminum Hydroxide was employed as a thermal retardent and flame retardent for Chloropolyethylene (CPE) rubbery materials which is the construction material of automotive oil cooler hose. and then cure characteristics, physical properties, thermal resistance and flame retardation of compounded rubber were investigated, and optimum mixing conditions of rubber and flame retarding agent were deduced from the experimental results. CPE rubber material which has excellent properties of chemical corrosion resistance and cold resistance and inexpensive in price was used to prepare rubber specimen. The by-product of ething, produced from the process of surface treatment of aluminum was processed to aluminum hydroxide via crushing and purification, which is characterized by XRD, PSA, SEM and ICP-AES techniques in terms of phase, size, distribution, morphology and components of particles and then mixed to CPE rubber materials in the range of 0~80 phr. Hardness, tensile strength, elongation and thermal properties of compounded rubber specimens were tested. The optimum mixing ratio of rubber to additives to give maximum effect on thermal resistance and flame retardation, within the range of tolerable specification for rubber materials, was determined to be 40 phr. The flame retardation of CPE rubber materials was found to be increased by 5 times at this mixing ratio.

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Analysis of Soil Characteristics and its Relationship According to the Geological Condition in Natural Slopes of the Landslide Area (산사태지역 자연사면의 지질별 토질특성 및 상관관계 분석)

  • Kim, Kyeong-Su
    • The Journal of Engineering Geology
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    • v.17 no.2 s.52
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    • pp.205-215
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    • 2007
  • In this study, the soil characteristics are analyzed using the result of various soil tests as an object of the soil layer of natural slopes in landslides areas. Also, the relationship with landslides and interrelation with each soil properties are analyzed. The landslides in three areas with different geological condition are occurred due to heavy rainfall in same time. The geology of Jangheung area, Sangju area and Pohang area is gneiss, granite, and the tertiary sedimentary rock, respectively. However soil characteristics have a little differentiation to geological condition, the soils sampled from landslide area have higher proportion of fine particle and porosity, and lower density than those from non landslide area. In case of same geological condition, landslides are occurred in the terrain slope with high permeability. The permeability is mainly influenced by the soil characteristics such as particle size distribution, porosity, particle structure, and the geological origins such as weathering, sedimentary environment. The soil layer with high internal friction angle is more stable than that with low internal friction angle in all geological condition. The permeability is mainly influenced by effective particle size, coefficient of uniformity, coefficient of gradation, porosity, density and so on. Also, those have interrelation with each factor. These interrelations are similar in all study area. Meanwhile, in proportion as the void ratio and the porosity rises the permeability increases.

Geoacoustic Model of Surface Sediments in the East of Geoje Island, the South Sea of Korea (거제도 동쪽 해역 표층 퇴적물의 지음향모델)

  • KIM, GIL YOUNG;KIM, DAE CHOUL;SHIN, BO KYOUNG;SEO, YOYUNG KYO;LEE, GWANG HOON
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.10 no.2
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    • pp.129-138
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    • 2005
  • Sediment texture, physical (porosity, water content, bulk density, grain density, and shear strength), and geoacoustic properties (compressional wave velocity and attenuation) were measured on eighteen core samples collected from the shelf off eastern Geoje Island, the South Sea of Korea. Based on these properties, the study area is divided into three different sub-areas: (1) Area I affected directly by the Nakdong River discharge; (2) Area II covered by the southern branch of the Nakdong River discharge; and (3) Area III dominated by relict sediment. Mean grain size, velocity, and bulk density decrease from Area $I(7.4\Phi,\;1528m/s,\;1.6g/cm^3,\;respectively)$ to Area $II(8.1\Phi,\;1485m/s,\;and\;1.5g/cm^3)$, and then increase rather rapidly in Area $III(1.4\Phi,\;1664m/s,\;and\;2.2g/cm^3)$. Porosity, on the other hand, exhibits an opposite trend, increasing from Area $I(64.5\%)$ to Area$II(73.9\%)$ and then decreasing significantly in Area $III(32.9\%)$ From the results measured and calculated, we suggest a specified geoacoustic model in the study area.

Physico-Chemical Properties among Three Products of Granular Fused Magnesium Phosphate (세가지 입상(粒狀) 용성인비(熔成燐肥) 제품간(製品間)의 이화학적(理化學的) 특성(特性))

  • Lim, Dong-Kyu;Kim, Seok-Cheol;Lee, Sang-Kyu;Choi, Du-Hoi;Kang, Ui-Gum;Park, Kyeong-Bae
    • Korean Journal of Soil Science and Fertilizer
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    • v.29 no.2
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    • pp.113-123
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    • 1996
  • This experiment was carried out to compare with the physico-chemical properties of granular fused magnesium phosphates which were two domestic products(Pungnong Biryo Industrial Co., LTD and Kyunggi Chemical Industrial Co., LTD) and a imported Chinese product. The changes of pH, distribution of particle size, disintegration in water and in soil, hardness in soil, chemical composition, and dissolution rates in water, in soil and in 2% citric acid solution were investigated. The changes in pH were bigger in Jungmun series(black volcanic soil), in the imported chinese product, and in Jungmun series with the larger quantities applied. The domestic products were lower in pH, calcium, alkalinity and 1/2N-HCl soluble silicate than the Chinese product but total(Aqua regia) soluble phosphate, 2% citric acid soluble phosphate, 1/2N-HCl soluble and 2% citric acid soluble magnesium, and 2% citric acid soluble manganese concentration were similar among the domestic products and the imported product. In particle sizes, Chinese product was the biggest, Kyunggi product was the next, and Pungnong product was the smallest. The changes of disintegration rate in water and in soil were smaller in Pungnong and Kyunggi products at the early days of dissolution, and there were decreased with the order of Kyunggi product> Chinese product> Pungnong product at the latter days. The hardness of the products in soil was the strongest in Kyunggi product, the next was Pungnong product and Chinese product was the weakest so as to hardly measurable. The changing dissolution rates of 2% citric acid soluble phosphate concentration of granular fused magnesium phosphate products were the highest in Kyunggi product and the lowest in Pungnong product at the early days, the three products were dissolved over 90% within 50 days, and there were no clear difference among the products after 70 days of dissolution. The dissolution rates of 2% citric acid soluble phosphate concentration of granular fused magnesium phosphate products in soil were the highest in Pungnong product and Chinese product was the lowest, but they were less than 60% in 100 days of dissolution.

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A Study on the Improvement of Skin-affinity and Spreadability in the Pressed Powder using Air Jet Mill Process and Mono-dispersed PMMA (Air Jet Mill 공법과 PMMA의 단분산성이 프레스드 파우더의 밀착성 및 발림성 향상에 대한 연구)

  • Song, Sang Hoon;Hong, Kyong Woo;Han, Jong Seob;Kim, Kyong Seob;Park, Sun Gyoo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.43 no.1
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    • pp.61-68
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    • 2017
  • The key quality attributes of the pressed powder, one of base makeup products, are skin-affinity and spreadability. In general, there was a limit to meet skin-affinity and spreadability simultaneously, which are opposite attributes each other. In this study, air jet mill process was tried to satisfy two main properties. Skin-affinity was improved by a wet coating of sericite with a mixture of lauroyl lysine (LL) and sodium cocoyl glutamate (SCG). The application of mono-dispersed polymethyl methacrylate (PMMA) and diphenyl dimethicone/vinyl diphenyl dimethicone/silsesquioxane crosspolymer (DDVDDSC) improved both qualities. Air jet mill process has been mainly applied in the pharmaceutical and food industries, and is a method used for processing powder materials in cosmetic field. In this study, we were able to complete makeup cosmetics with an optimum particle size $6.8{\mu}m$ by combining the air jet mill process at the manufacturing stage. It was confirmed that the Ti element was uniformly distributed throughout the cosmetics by EDS mapping, and that the corners of the tabular grains were rounded by SEM analysis. It is considered that this can provide an effect of improving the spreadability when the cosmetic is applied to the skin by using a makeup tool. LL with excellent skin compatibility and SCG derived from coconut with little skin irritation were wet coated to further enhance the adhesion of sericite. SEM images were analyzed to evaluate effect of the dispersion and uniformity of PMMA on spreadability. With the spherical shapes of similar size, it was found that the spreading effect was further increased when the distribution was homogeneously mono-dispersed. The dispersion and spreadability of PMMA were confirmed by measuring the kinetic friction and optimal content was determined. The silicone rubber powder, DDVDDSC, was confirmed by evaluating the hardness, spreading value, and drop test. Finally, it was found that the dispersion of PMMA and silicone rubber powder affected spreadability. Such makeup cosmetics have excellent stability in drop test while having appropriate hardness, and good stability over time. Taken together, it is concluded that air jet mill process can be utilized as a method to improve skin-affinity and spreadability of the pressed powder.

Clay Mineralogical Characteristics and Origin of Sediments Deposited during the Pleistocene in the Ross Sea, Antarctica (남극 로스해 대륙대 플라이스토세 코어 퇴적물의 점토광물학적 특성 및 기원지 연구)

  • Jung, Jaewoo;Park, Youngkyu;Lee, Kee-Hwan;Hong, Jongyong;Lee, Jaeil;Yoo, Kyu-Cheul;Lee, Minkyung;Kim, Jinwook
    • Journal of the Mineralogical Society of Korea
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    • v.32 no.3
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    • pp.163-172
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    • 2019
  • A long core (RS15-LC48) was collected at a site in the continental rise between the Southern Ocean and the Ross Sea (Antarctica) during the 2015 Ross Sea Expedition. The mineralogical characteristics and the origin of clay minerals in marine sediments deposited during the Quaternary in the Ross Sea were determined by analyzing sedimentary facies, variations in grain size, sand fraction, mineralogy, clay mineral composition, illite crystallinity, and illite chemical index. Core sediments consisted mostly of sandy clay, silty clay, or ice rafted debris (IRD) and were divided into four sedimentary facies (units 1-4). The variations in grain size distribution and sand content with depth were very similar to the variations in magnetic susceptibility. Various minerals such as smectite, chlorite, illite, kaolinite, quartz, and plagioclase were detected throughout the core. The average clay mineral composition was dominated by illite (52.7 %) and smectite (27.7 %), with less abundant clay minerals of chlorite (11.0 %) and kaolinite (8.6 %). The IC and illite chemical index showed strong correlation trends with depth. The increase in illite and chlorite content during the glacial period, together with the IC and chemical index values, suggest that sediments were transported from the bedrocks of the Transantarctic Mountains. During the interglacial period, smectite may have been supplied by the surface current from Victoria Land, in the western Ross Sea. High values for IC and the illite chemical index also indicate relatively warm climate conditions during that period.

Cooking Properties of Fresh Pasta Using Korean Wheat and Durum Rimachinata (우리밀과 Durum Rimachinata를 이용한 생면 파스타의 조리특성)

  • Kim, Yeon-Ju;Ju, Jong-Chan;Kim, Rae-Young;Kim, Won-Tae;Park, Jae-Hee;Chun, Soon-Sil
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.40 no.10
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    • pp.1474-1481
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    • 2011
  • This study investigated the physicochemical characteristics of Korean wheat flour substituted for 0%, 15%, 30%, 45%, and 60% durum rimachinata wheat in order to develop a Korean wheat pasta suitable for consumer-preferred soft textures. The particles of Korean wheat that were less than 250 ${\mu}M$ were 87.03% of all particles, while 68.7% of durum rimachinata had particles more than 250 ${\mu}M$ in size. Durum rimachinata had more protein (13.84${\pm}$0.03) and ash (0.70${\pm}$0.02) than Korean wheat. In farinograph characteristics, water absorption, development time, stability, and weakness increased as the amounts of substituted Korean wheat flour increased. Also, the gelatinization characteristics of the amylograph exhibited an increase of gelatinization temperature and decrease in maximum viscosity. However, maximum viscosity was shown to be more than 550 B.U. until 30% of the substitution level of Korean wheat flour to durum rimachinata wheat. Also, it did not affect the texture of the noodle product. We could make pasta with softness and springiness with less than a 15% substitution level of Korean wheat flour due to similar characteristics in cooking properties such as weight, volume, water absorption, turbidity, and cooking loss when compared to the control. L and a values increased, and the b value decreased in color as substitution amounts of Korean wheat flour increased. The hardness and adhesiveness of cooking noodles was shown to be a low value at more than a 30% substitution level of Korean wheat flour, and springiness, gumminess, and chewiness all exhibited high values. In a sensory evaluation, overall acceptability was shown to have the highest score in control. More than 30% of substitution of Korean wheat flour showed high preferences. Therefore, 15% of the substitution level of Korean wheat flour could be adapted in dough and cooking properties for making pasta-substituted Korean wheat. However, a texture analyzer and sensory evaluation of cooked pasta was shown to have a good quality at more than 30% substitution level of Korean wheat flour.