• Title/Summary/Keyword: 일산화질소 생성

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A Study on Technology Status and Project of Hydrogen Production from Coal Gasificiation (석탄가스화를 이용한 수소생산 기술현황 및 프로젝트 분석)

  • Seungmo Ko;Hochang Jang
    • Journal of the Korean Institute of Gas
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    • v.27 no.1
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    • pp.1-12
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    • 2023
  • Coal gasification is a process of incomplete coal combustion to produce a syngas composed of hydrogen and carbon monoxide. It is one of methods to utilize coal cleanly because the process does not emits nitrogen oxides or sulfur oxides and particulate matters. In addition, chemicals can be produced using syngas. Coal gasification is classified as IGCC (Integrated Gasification Combined Cycle), Plasma coal gasification and UCG (Underground Coal Gasification). Recently, WGS (Water Gas Shift) reactor and carbon capture system have been combined to gasifier to produce hydrogen from coal. In this study, the coal gasification and method of hydrogen production from syngas was summarized, and the hydrogen production from coal gasification project was investigated.

Application of Passive Sampler for Ozone Measurement in Ambient Air (대기 중 오존 측정을 위한 Passive Sampler의 적용)

  • 정의석;김선규;김학민;김선태
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.04a
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    • pp.123-124
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    • 2000
  • 오존($O_3$)은 이산화질소, 일산화탄소, 휘발성유기화합물 둥을 포함하는 다양한 물질과 광화학반응에 의하여 생성되는 2차적인 오염물질로 사람과 식물에 영향을 미치고 있는 중요한 오염물질로 알려지고 있으며, 국내에서는 이와 관련하여 오존예보제, 경보제 둥을 운영하여 오존에 의한 피해 영향을 줄이고자 노력하고 있다. 현재 오존을 측정할 수 있는 방법은 환경오염공정시험방법과 정부에서 운영하고 있는 대기오염 자동측정망의 오존 측정방법인 자외선광도법(Ultra Violate Photometric Method)으로 구분되어 지고 있으나, 자동측정장비는 매우 고가의 장비이며, 관리를 위하여 전문적인 지식이 요구되고 있고, 측정소의 개수가 매우 부족한 실정이기 때문에 대기중 오존농도의 지역적인 자료와, 실내공기 측정, 그리고 공간적인 분포 해석을 위해서는 다른 측정방법이 요구된다고 하겠다. (중략)

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Effects of Dietary Supplementation of a New Probiotic CS61 Culture on Performance in Broiler Chickens (새로운 생균제 CS61 배양액의 사료 내 급여가 육계의 생산성에 미치는 영향)

  • Kim, Sung-Hwan;Lee, In-Chul;Baek, Hyung-Seon;Kang, Seong-Soo;Kim, Hyoung-Chin;Yoo, Jin-Cheol;Kim, Jong-Choon
    • Journal of Life Science
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    • v.22 no.3
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    • pp.340-346
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    • 2012
  • Bacterial resistance to antibiotics and residues of antibiotics in poultry products have encouraged the use of probiotics, prebiotic substrates, and synbiotic combinations of prebiotics and probiotics as alternative approaches to the use of antibiotics in poultry. The present study was carried out to evaluate the effect of a new probiotic CS61 culture on growth performance, feed conversion efficiency, and safety in broiler chickens, and to evaluate its value as an alternative for antibiotics used as a feed additive. Two dosages of CS61 culture (0.1% and 1%) were fed to chickens for 28 days. The results showed that terminal body weight and daily weight gain in the treatment groups increased in a dose-dependent manner when compared with the control group. Dietary supplementation with CS61 culture also improved feed conversion rate compared to the control group. There were no treatment-related toxic effects in terms of clinical findings, mortality, necropsy findings, hematology, or serum biochemistry parameters in any group tested. The nitric oxide assay showed that CS61 peptide has a dose-dependent inhibitory effect on lipopolysaccharide-induced nitric oxide production in RAW 264.7 cells. The results of this experiment indicated that dietary supplementation of CS61 culture may improve growth performance and feed conversion efficiency in chickens through its anti-inflammatory effect.

A Ginseng Saponin Induces Production of Nitric Oxide in Macrophages (인삼사포닌에 의한 대식세포 일산화질소 생성 유도)

  • Kim Ji Yeon;Lee Hwa Jin;Kim Ji Sun;Ahn Hanna;Ryu Jae-Ha
    • YAKHAK HOEJI
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    • v.49 no.1
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    • pp.80-85
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    • 2005
  • Ginseng root is an important remedy in oriental countries, which has been used for thousands of years. Saponins of ginseng root has been known to be the major component which mediate diverse pharmacological actions of the ginseng. Heat processing of ginseng root potentiates its biological activity such as anti-tumor and anti-oxidative activities. The butanol fraction of heat-processed ginseng (HGB) induced the production of nitric oxide in macrophages in a dose-dependent manner with IFN-${\gamma}$(30 U/ml) priming. The active component was identified as ginsenoside-$Rg_5$ from the activity-guided purification. Ginsenoside $Rg_5$ is one of major components of heat-processed ginseng and red ginseng that is responsible for the potentiated biological activities of processed ginseng. The induction of NO production by heat-processed ginseng might contribute to the potentiated biological activity of heat-processed ginseng.

Combustion Gas-emission of Medium Density Fibreboard (MDF) Treated with Alkylenediaminialkyl-bis-phosphonic Acids and Bis-(dimethylaminomethyl) Phosphinic Acid (알킬렌디아미노알킬-비스-포스폰산과 비스-디메틸아미노메틸 포스핀산으로 처리된 중질섬유판의 연소가스 발생)

  • Park, Myung-Ho;Chung, Yeong-Jin
    • Applied Chemistry for Engineering
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    • v.28 no.1
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    • pp.112-117
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    • 2017
  • This study demonstrated the emission of combustion gases of medium density fibreboard (MDF)s coated with piperazinomethyl-bis-phosphonic acid (PIPEABP), methylpiperazinomethyl-bis-phosphonic acid (MPIPEABP), N,N-dimethylethylenediaminomethyl-bis-phosphonic acid (MDEDAP), or bis-(dimethylaminomethyl) phosphinic acid (DMDAP). Each MDFs were coated in three times with a brush with 15 wt% aqueous solution of the phosphorus-nitrogen acid additives. After the specimens were dried at room temperature, the emission of combustion gases was tested using a cone calorimeter (ISO 5660-1, 2). The peak smoke production rate ($SPR_{peak}$) of the specimens coated with phosphorus-nitrogen acids was 18.5 to 41.5%, which is lower than that of using the virgin plate. However, the production of peak carbon monoxide ($CO_{peak}$) was 6.7 to 24.2% higher than that of using the virgin plate. Also, the peak carbon dioxide ($CO_{2peak}$) was 4.2 to 24.4% lower than that of using virgin plate. While the peak oxygen depletion rate was much higher than the level of 15%, which can be fatal to humans and the resulting risk could thus be eliminated. Overall, the combustibility of coated specimens was partially suppressed, but showed a negative effect on the reduction of carbon monoxide.

Emission of Carbon Monoxide and Carbon Dioxide Gases during Fire Tests of Specimens Treated with Phosphorus-Nitrogen Additives (인-질소 첨가제로 처리된 시험편의 연소 시에 발생하는 일산화탄소와 이산화탄소 생성)

  • Chung, Yeong-Jin
    • Applied Chemistry for Engineering
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    • v.26 no.5
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    • pp.609-614
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    • 2015
  • This study was to investigate the production of combustion toxic gases of pinus rigida specimens treated with pyrophosphoric acid (PP)/4ammonuium ion ($4NH_4{^+}$), methylenepiperazinomethyl-bis-phosphonic acid (PIPEABP) and PIPEABP/$4NH_4{^+}$. Each pinus rigida plates was painted in three times with 15 wt% in the aqueous solution followed by drying the species at room temperature. Emission of combustion toxic gases was examined by the cone calorimeter (ISO 5660-1). First-time to peak mass loss rate (1st-$TMLR_{peak}$) treated with chemicals was delayed upto 66.7~250.0% compared to those of untreated specimens. For test pieces treated with the chemicals, the emission of peak carbon monoxide ($CO_{peak}$) values of 0.0136~0.0178% and peak carbon dioxide ($CO_{2\;peak}$) value of 0.04432~0.3648% were obtained, which were higher than those for the virgin plate. In particular, oxygen emission is much higher than the level of 15% which can be fatal to humans. Therefore, the resulting risk could be eliminated. However it is supposed that the combustion-toxicities were partially increased compared to those of virgin plate.

Preparation and Reactions of Bis(trimethylsilylmethyl)-1,2-bis(disphenylphosphino)ethanenickel(II) (비스(트리메틸실릴메틸) 1,2-비스(디페닐포스피노)에탄니켈(II)의 합성 및 반응)

  • Chong Shik Chin;M. D. Curtis
    • Journal of the Korean Chemical Society
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    • v.25 no.5
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    • pp.311-317
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    • 1981
  • A new nickel(II) compound, $Ni(CH_2SiMe_3)_2((C_6H_5)_2PCH_2CH_2P(C_6H_5)_2)$, 1, has been prepared by the reaction of $NiCl_2((C_6H_5)_2PCH_2CH_2P(C_6H_5)_2)$ with $Me_3SiCH_2Li$. The compound, 1, is stable under nitrogen at room temperature both in solution and in the solid state. Thermal decomposition of 1 in solution or in the solid produces the reductive coupling product, $Me_3SiCH_2CH_2SiMe_3$ which is also afforded by the reactions of 1 with CO and $O_2$ at room temperature, and with $(C_6H_5)_2PCH_2CH_2P(C_6H_5)_2$ at 80${\circ}$C.

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A stepwised catalytic combustion of ammonia with $H_2$ and CO on supported Pt, Pd and Rh catalysts (Pt, Pd와 Rh가 담지된 촉매상에서 암모니아와 수소/일산화탄소의 단계별 촉매연소에 관한 연구)

  • Hwang, J.Y.;Ryu, I.S.;Lee, K.C.;Lee, S.J.;Noh, D.S.;Rhee, K.S.;Kang, S.K.
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.20-26
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    • 2006
  • This study investigated on the conversion of nitrogen component in ammonia gas to control fuel-NOx. Control conditions were found to suppress the production of NOx in the catalytic combustion of the gasified fuels. Also, the results would provide the basis of the theoretical study on fuel-NOx generation mechanism.

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Experimental Study on the Flame Stability and the NOx Emission Characteristics of Low-Btu Coal Gas Fuel (저 발열량 석탄가스 연료의 화염 안정성 및 NOx 발생 특성에 관한 실험적 연구)

  • Lee, Chan;Kim, Yong-Chul
    • Journal of Energy Engineering
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    • v.9 no.2
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    • pp.109-116
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    • 2000
  • 저발열량 석탄가스의 thermal/fuel NOx 생성특성과 화염 안정성을 규명하기 위한 실험적 연구를 수행하였다. 저발열량 합성 연료 가스는 일산화탄소, 수소, 질소 및 암모니아를 천연가스 연료와 동일한 입열량을 가지도록 혼합하여 만들었고 , 합성가스는 평면 화염 버너를 공급하여 태웠다. 특정한 합성가스에 대해 당량비를 변화시켜 가며, 비화 또는 역화에 의한 화염안정성을 규명하였고 안정된 화염 영역을 정의하였다. 저발열향 합성가스의 연소시 발생하는 thermal 및 fuel NOx를 측정하여 천연가스 연소시의 경우와 비교하였다.

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Modulatory Effects of 21 kinds of Medicinal Herbs Including Herba Pogostemi (Agastache rugosa) on Nitric Oxide Production in Macrophage Cell line RAW 264.7 cells (곽향(Agastache rugosa)을 포함한 21종의 한약재가 대식세포주 RAW 264.7 세포의 nitric oxide(NO) 생산 조절에 미치는 효과)

  • Kim, Seung-Hyun;Kang, Mi-Young;Nam, Seok-Hyun
    • Applied Biological Chemistry
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    • v.48 no.4
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    • pp.411-417
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    • 2005
  • Aqueous extracts were prepared from 21 medicinal herbs including Herba Pogostemi (Agastache rugosa) to examine their modulatory effects on NO production in mouse macrophage cell line RAW264.7 cells. While almost all medicinal herb extracts failed to show marked scavenging activities to NO produced by LPS stimulation, only Herba Pogostemi showed a rather strong induction of NO production in RAW264.7 cells without stimulation with LPS. When we treated the cell with $200{\mu}M\;of\;N^G-monomethyl-L-arginine\;(N^GMMA)$, a NOS2 inhibitor, a significant reduction in NO production could be observed. Moreover, a treatment of $100{\mu}M$ pyrrolidine dithiocarbamate (PDTC) led to about a 79% reduction of NO production. These results demonstrated that the aqueous extract of Herba Pogostemi might provide a second signal for the expression of NOS2 in RAW264.7 cells, and suggested that Herba Pogostemi induces NO production through L-argininedependent pathway.