• Title/Summary/Keyword: 인화성물질

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Evaluation of Peak Overpressure and Impulse Induced by Explosion (폭발에 따른 최대과압 및 충격량 평가)

  • Yoon, Yong-Kyun
    • Explosives and Blasting
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    • v.34 no.4
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    • pp.28-34
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    • 2016
  • Empirical model, phenomenological model, and CFD model have been used to evaluate the blast effects produced by explosion of explosives, flammable gas and liquid or dust. TNT equivalence method which is one of empirical models has been widely used as it is simple. In this study, new peak overpressure-scaled distance and scaled impulse-scaled distance equations are induced through fitting data from the curves given by TNT equivalence method. If the TNT equivalent mass is calculated, it is possible to estimate the peak overpressure and impulse using the regression equations. Differences of peak overpressure with yield factor which is a component of TNT equivalence method are found to be great in near-by distances from explosion source where the increase in overpressure is very steep, but the differences are getting smaller as the distances increase.

안전관리 - 용접공사의 화재.폭발 등 안전사고 예방대책(2)

  • 대한설비건설협회
    • 월간 기계설비
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    • s.267
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    • pp.65-71
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    • 2012
  • 지난 8월 13일 서울 종로구 소격동 국립현대미술관 서울관 공사현장에서 화재 발생으로 4명이 숨지고 18명이 중경상을 입는 등 많은 인명피해를 냈다. 이처럼 인명피해가 컸던 것은 우레탄 공사를 하던 밀폐공간에서 불이 나면서 발생한 유독가스 때문에 사람들이 제대로 대피하지 못했기 때문이다. 사고발생 원인으로 '용접공사' 여부를 놓고 공방을 벌였으나 경찰은 '전기합선'이라는 잠정 결론을 내렸다. 지난 2008년 1월에 발생한 경기도 이천 냉동창고 화재는 40명의 목숨을 앗아갔다. 화재 원인은 냉동배관을 설치하면서 전기 용접을 하기 위해 불을 붙였다가 공기 중에 차 있던 유증기(기름증기)와 만나면서 폭발이 일어난 것이었다. 인화성 액체(유기용제)를 취급하는 건설현장에서는 다량의 유증기가 발생할 수 있을 뿐만 아니라 건조한 조건일 경우 정전기에 의한 화재 폭발 누출사고의 발생 위험이 높다. 기계설비공사에서 화재, 폭발 위험성이 가장 큰 공사는 용접공사이기에 용접공사를 할 때 화재, 감전의 위험성을 배제한 후 공사에 들어간다. 용접으로 인한 사망사고의 유형으로는 용접 중 추락사고와 더불어 용접 불꽃이 가연성 물질에 옮겨 붙어 화재 발생으로 인한 질식사, 용접작업 중 절연체가 파손된 용접기 홀더 충전부의 접촉으로 인한 감전사 등이 있다. 본지는 용접으로 인한 화재 감전 등의 사고발생을 미연에 방지하기 위해 안전작업 수칙 및 안전수칙 체크리스트, 재해사례를 지난호부터 시리즈로 연재하고 있다.

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The Relationship Between Fire Service Demand and Project Budget (소방수요와 사업비예산과의 관계)

  • Kim, Jin-Dong;Kim, Hyung-Doo
    • Fire Science and Engineering
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    • v.21 no.3
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    • pp.24-32
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    • 2007
  • The environment of fire service is more uncertain as cities become complicated and new combustibles are used. If fire service's budget is not allocated sufficiently for fire facilities and equipment, fire service's quality and firefighter's safety are affected seriously. Therefore project budget must be increased to prevent fire and disaster effectively. This study investigate the change of fire service demands, the change and priority of fire service budget and project budget. And this study examined the relationship between fire service demand and project budget using correlation and regression analysis. Analysis showed that a number of rescue and emergency medical service were significant variable for project budget.

Prediction of the Net Heats of Combustion of Organic Halogenated Compounds based on the Atomic Contribution Method (원자기여법에 근거한 유기 할로겐 화합물의 순연소열 예측)

  • Ha, Dong-Myeong;Lee, Sung-Jin
    • Fire Science and Engineering
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    • v.17 no.4
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    • pp.7-12
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    • 2003
  • The heat of combustion is one of the major physical properties used to determine the fire and explosion hazards of the flammable substances. Empirical equations have been developed to pre-dict the net heats of combustion of organic halogenated compounds based on the atomic contribution method. The method developed in this study was compared with Cardozo's method and Hanley's method. As can be seen from the average absolute deviation(A.A.D.), the proposed equation was found to be best. The proposed equation may serve as an estimation scheme for the heats of combustion of the other organic halogenated compounds.

안전관리 - 용접공사 중 화재.폭발 등 안전사고 예방대책(1)

  • 대한설비건설협회
    • 월간 기계설비
    • /
    • s.266
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    • pp.49-57
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    • 2012
  • 지난 8월 13일 서울 종로구 소격동 국립현대미술관 서울관 공사현장에서 화재 발생으로 4명이 숨지고 18명이 중경상을 입는 등 많은 인명피해를 냈다. 이처럼 인명피해가 컸던 것은 우레탄 공사를 하던 밀폐공간에서 불이 나면서 발생한 유독가스 때문에 사람들이 제대로 대피하지 못했기 때문이다. 사고발생 원인으로 '용접공사' 여부를 놓고 공방을 벌였으나 경찰은 '전기합선'이라는 잠정 결론을 내렸다. 지난 2008년 1월에 발생한 경기도 이천 냉동창고 화재는 40명의 목숨을 앗아갔다. 화재 원인은 냉동배관을 설치하면서 전기 용접을 하기 위해 불을 붙였다가 이것이 공기 중에 차 있던 유증기(기름증기)와 만나면서 폭발이 일어난 것이었다. 올 여름처럼 기온이 높고 건조한 날이 지속되면서 인화성 액체(유기용제)를 취급하는 건설현장에서는 다량의 유증기가 발생할 수 있을 뿐만 아니라 건조한 조건에서 정전기에 의한 화재 폭발 누출사고의 발생 위험이 높아지고 있다. 기계설비공사에서 화재, 폭발 위험성이 가장 큰 공사는 용접공사이기에 용접공사를 할 때 화재, 감전의 위험성을 배제한 후 공사에 들어간다. 용접으로 인한 사망사고의 유형으로는 용접 중 추락사고와 더불어 용접 불꽃이 가연성 물질에 옮겨 붙어 화재 발생으로 인한 질식사, 용접작업 중 절연체가 파손된 용접기 홀더 충전부의 접촉으로 인한 감전사 등이 있다. 본지는 용접으로 인한 화재 감전 등의 사고발생을 미연에 방지하기 위해 안전작업 수칙 및 안전수칙 체크리스트, 재해사례를 시리즈로 연재한다.

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Design of Rule-based Inference Engine for the Monitoring of Harmful Environments in Workplace

  • Ahn, Yoon-Ae
    • Journal of Korea Society of Industrial Information Systems
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    • v.14 no.4
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    • pp.65-74
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    • 2009
  • The risk of health impairment due to poor ventilation, fire and explosion by inflammable materials, and other unintended occurrences is always present in dangerous workplaces such as manholes, underground septic tanks, storage tanks and confined areas. Therefore, it a system which can monitor harmful working environment through sensors in workplace on a realtime basis and keep workers safe from the risk is needed. This paper has attempted to design an inference engine to monitor harmful environments in the workplace. The proposed inference engine has a rule-based system structure using JESS. This system is not confined to a particular computing platform and is easily interlocked with OSGi-based middleware.

A Study for Key Points of PSM to Guarantee the Safety of Liqufied Hydrogen Storage Tank (액화수소 저장탱크 안전성 확보를 위한 PSM 중점사항에 관한 연구)

  • Myoung Sun Wu;Chang Jun Lee
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.74-79
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    • 2023
  • As the demand for hydrogen increases, the facilities for storing hydrogen has been important, and a few laws for hydrogen facilities should be complied. According to the Occupational Safety and Health Act in Korea, in case liquid hydrogen with a storage capacity of 5 tons or more is handled, a Process Safety Management (PSM) system should be complied. However, there are some standards which are not proper for flammable low-temperature liquefied substances on the current Occupational Safety and Health Act. In this study, 7 key points in process safey information and safety operation procedures among PSM components are suggested and how these key points should be improved is derived based on scientific analysis.

A Study on the Flammability and Combustion Risk of Biodiesel Mixture (바이오디젤 혼합물의 인화 및 연소 위험성에 관한 연구)

  • Kim, Ju Suk;Ko, Jae Sun
    • Journal of the Society of Disaster Information
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    • v.17 no.1
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    • pp.10-24
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    • 2021
  • Purpose: The purpose of this study is to determine the dangers of biodiesel and general diesel mixtures currently used as alternative fuels by equipment (tag method and penski Marten method) and to determine the difference between flash point and combustion point (closed, open) according to test methods. It is intended to be used as a reference material for identification and evaluation of firecausing substances by confirming the risk of mixtures by comparative analysis and measurement, and establishing a risk assessment method for chemical substances. Method: Flash point test method and result treatment were tested based on ASTM and KS M mode, which are tag sealing and pen schematense test methods used as flash point and combustion point test methods for crude oil and petroleum products. The manufacturer of the equipment used in this experiment was a test equipment that satisfies the test standards of KS M 2010 with equipment produced by TANAKA of Japan. The flash point and combustion point were measured, and the flash point according to the test method of biodiesel and general diesel mixture ( Closed, open), and the ignition point of a mixture of biodiesel and general diesel was compared and analyzed for ignition risk compared with conventional diesel. Results: Looking at the experimental results, first, as an analysis of the risk of flammability of the mixture, the flash point of a substance containing 70% biodiesel was found to be about 92℃ based on general diesel with a flash point of 64.5℃, and gasoline and biodiesel or When the biodiesel mixture was synthesized, it was confirmed that the flash point tends to decrease. In addition, the difference between the flash point and the combustion point was analyzed as about 20 ~ 30℃, and when a small amount of gasoline or methanol was mixed, the flash point was lowered, but it was confirmed that the combustion point was similar to that of the existing mixture. Conclusion: In this study, in order to secure the effectiveness of the details of the criteria for judging dangerous materials in the existing Dangerous Materials Safety Management Act, and to secure the reliability and reproducibility of the judgment of dangerous materials, we confirm the criteria for judging the risk of the mixture through an experimental study on flammable mixtures. It will be able to provide reference data for experimental criteria for flammable liquids that are regulated in the field. In addition, if this study accumulates know-how on experiment by test method, it is expected that it can be used as a basis for research on risk assessment and research on dangerous goods.

Experimental Study on Ignition and Explosion Hazard by Measuring the Amount of Non-volatile (NVR) and Explosion Limit of Biodiesel Mixture (바이오디젤 혼합물의 가열잔분측정과 폭발한계 측정을 통한 발화 및 폭발위험성에 대한 실험적인 연구)

  • Kim, Ju Suk;Koh, Jae-Sun
    • Journal of the Society of Disaster Information
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    • v.18 no.1
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    • pp.182-193
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    • 2022
  • Purpose: By measuring and evaluating the risk of biodiesel through non-volatile residue (NVR) and flash point and explosion limit measurement at a specific temperature according to ASTM test standards, the risk of chemical fire causative substances is identified and a universal evaluation method By derivation and securing the risk-related data of the material, it can be used for the identification and analysis of the cause of the fire, and it can be applied to the risk assessment of other chemical substances Method: In order to measure the risk of biodiesel, it was measured using the non-volatile residue(NVR) measurement method, which measures how much flammable liquid is generated at a specific temperature. Heating was tested by applying KS M 5000: 2009 Test Method 4111. In addition, the flash point was measured using the method specified in ASTM E659-782005, and the energy supply method was measured using the constant temperature method. In addition, the explosion limit measurement was conducted in accordance with ASTM E 681-04 「Standard test method for concentration limits of flammability of chemicals(Vapors and gases)」 test standard. Result: As a result of checking the amount of combustible liquid by the non-volatile residue (NVR)measurement method, the non-volatile residue(NVR) of general diesel when left at 105±2℃ for 3 hours was about 30% (70% of volatile matter) and about 4% of biodiesel. In addition, similar results were obtained for the non-volatile residue(NVR)heating temperature of 150±2℃, 3 hours and 200±2℃ for 1 hour, and white smoke was generated at 200℃ or higher. In addition, similar values were obtained as a result of experimentally checking the explosion (combustion) limits of general diesel, general diesel containing 20% biodiesel, and 100% biodiesel. Therefore, it was confirmed that the flammability risk did not significantly affect the explosion risk. Conclusion: The results of this study suggested the risk judgment criteria for mixtures through experimental research on flammable mixtures for the purpose of securing the effectiveness, reliability, and reproducibility of the details of the criteria for determining dangerous substances in the existing Dangerous Materials Safety Management Act. It will be possible to provide reference data for the judgment criteria for flammable liquids that are regulated in the field. In addition, if the know-how for each test method is accumulated through this study, it is expected that it will be used as basic data in the research on risk assessment of dangerous substances and as a basis for research on the determination of dangerous substances.

Numerical Study on Atmospheric Dispersion and Fire Possibility in Toluene Leakage (톨루엔 누출 시 대기확산 및 화재가능성에 관한 수치해석 연구)

  • Ko, Jae Sun;Kim, Joo-Seok
    • Fire Science and Engineering
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    • v.31 no.3
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    • pp.1-10
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    • 2017
  • This study examined the risk of accidents when handling hazardous materials in hazardous materials storage facilities without safety facilities. In the case of illegal dangerous cargo containers, the burning rate is very fast in the case of fire, which leads to explosions, that are damaging and difficult to control. In addition, accidents that occur in flammable liquid hazardous materials are caused mostly by accidents that occur in the space due to leakage. Therefore, the variables that affect these accidents were derived and the influence of these variables was investigated. Numerical and computational fluid dynamics programs were used to obtain the following final results. First, when a flammable liquid leaks into a specific space, it is influenced by temperature and relative humidity until a certain concentration (lower limit of combustion) is reached. In the case of temperature, it was found that the reaching time was shorter than the flash point In addition, the effect of variables on pool fire accidents of leakage tanks is somewhat different, but the variables that have the largest influence are the wind speed. Therefore, it is expected that the results of this study will be used as basic data for similar numerical analysis and it will provide useful numerical information about the accidental leakage of hazardous materials under various research conditions.