• Title/Summary/Keyword: 인산 나트륨

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Study on the Facile Preparation of S-2-(${\omega}$-aminoalkylamino) ethyl Dihydrogen Phosphorothioates (티오인산이수소 S-2-(${\omega}$-아미노알킬아미노) 에틸들의 간편합성법 연구)

  • You Sun Kim;Suc Won Kim
    • Journal of the Korean Chemical Society
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    • v.27 no.6
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    • pp.449-456
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    • 1983
  • The facile route of preparing S-2-(${\omega}$-aminoalkylamino) ethyl dihydrogen phosphorothioates, potential chemical radioprotectants, have been studied. Intermediate 3-(2-phthalimidoethyl)-2-oxazolidinone was prepared by a reaction of potassium phthalimide and 3-(2-bromoethyl)-2-oxazolidinone, which was obtained through the alkaline ring closure of a mixture of carbonate and 2,2'-dibromo diethylamine prepared from diethanolamine. This was converted to N-[2-(2-bromoethylamino)ethyl] phthalimide hydrobromide by 30% HBr(gas) in acetic acid and N-(2-bromoethyl)-1,2-ethanediamine dihydrobromide was obtained by reacting the hydrobromide with a solution of HBr-HOAc. N-(2-bromoethyl)-1,3-propanediamine dihydrobromide could be prepared through the Cortese treatment of 2-(3-aminopropylamino) ethanol, which was prepared by a reaction of 1,3-diaminopropane and 2-chloroethanol. These dihydrobromides were treated by sodium thiophosphate in DMF to result S-2-(${\omega}$-aminoalkylamino) ethyl dihydrogen phosphorothioates. The characteristics of each reaction path were discussed in regards to reaction conditions and overall yields and a facile route of preparing each derivative was proposed.

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Application of L-Arginine as a Substitute for Inorganic Polyphosphate in Pork Sausage Production (소시지 제조시 인산염 대체 소재로 L-Arginine의 활용)

  • Kim, Yong-Duk;Lee, Jun-Soo;Park, Joon-Hyun;Park, Dong-Cheol;Jeon, Young-Seung;In, Man-Jin;Oh, Nam-Soon
    • Journal of Applied Biological Chemistry
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    • v.57 no.2
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    • pp.171-174
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    • 2014
  • $\small{L}$-Arginine was applied to processed pork sausages and evaluated as a substitute for commonly used inorganic polyphosphate. Processed pork sausage was prepared with an addition of 0.25, 0.5, and 1.0% (w/w) $\small{L}$-arginine. Quality characteristics of the processed pork sausages were than evaluated in terms of pH, moisture content, emulsion stability and textural properties. The pH of sausage increased with increasing $\small{L}$-arginine concentration. Moisture content of 0.25% $\small{L}$-arginine sausage, emulsion stability of 0.5% $\small{L}$-arginine sausage, and textural properties of 1.0% $\small{L}$-arginine sausage were similar to those of 0.5% polyphosphate sausage, respectively. In terms of sensory evaluation, taste and overall acceptability of 0.5% $\small{L}$-arginine sausage were slightly higher than those of 0.5% polyphosphate sausage and textural properties were reversed. According to sensory score and quality characteristics, $\small{L}$-arginine had a potential as a substitute for inorganic polyphosphate and the optimum concentration of $\small{L}$-arginine was around 0.5%.

Salt tolerance in phosphorus efficient tomato (Lycopersicon esculentum Mill.) (고린(高燐) 활용성 토마토 항 염분 특성)

  • Lee, Dong-Hee
    • Korean Journal of Environmental Agriculture
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    • v.17 no.1
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    • pp.34-38
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    • 1998
  • To test a potential salt tolerance in phosphorus (P) efficient plants (T9 and T8), tomato seedlings were hydroponically grown in saline media. The tolerance was evaluated by comparing growth and metabolism against T5, non-P-efficient variety, at different salt concentrations: 0, 1, 5, 10 g/L. Fresh weights (FW) were measured weekly. Dry weight (DW), mineral contents, and stomatal resistance (Rs) were measured at the termination of experiment. At the lower two salt concentrations (0, 1 g/L), no significant difference was observed in terms of FW, DW, and Rs. At 5, 10 g/L of salt concentration, however, significant variation is evident: T9 and T8 outperformed T5. On the other hand, no difference was also in N, P, K, and Na contents at the corresponding salt concentration. These observations together indicate that P-efficient strain can better tolerate to salinity.

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Nutrient Contents of Bracken (Pteridium aquilinum L.) and Soil Chemical Properties of Its Habitat in the Coastal Area (남서해안 고사리 생육지의 토양화학적 특성과 고사리식물체의 무기성분 함량)

  • Lee, Soo-Young;Park, Kang-Yong;Park, Yang-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.5
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    • pp.631-636
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    • 2010
  • One experiment was carried out to investigate the soil chemical properties of bracken growth and the inorganic element contents of plant. To the results of soil analysis in native bracken (Pteridium aquilinum L.) growth, soil pH was 5.2, organic matter was 19 g $kg^{-1}$ and available phosphate was 20 mg $kg^{-1}$, and exchangeable potassium, calcium, magnesium were 0.32, 2.0 and 1.3 $cmol_c\;kg^{-1}$, respectively. In the bracken cultivation soil, pH was 5.7, organic matter was 13 g $kg^{-1}$ and available phosphate 367 mg $kg^{-1}$, and exchangeable potassium, calcium and magnesium were 0.81, 4.0 and 1.4 $cmol_c\;kg^{-1}$, respectively. The soil pH, available phosphate and exchangeable calcium were much lower in bracken native soil than those of cultivation soil, while organic matter was a little higher in native soil than that of cultivation soil. In native bracken plants, three major elements of nitrogen, phosphorus and potassium, were 4.40, 0.55 and 3.40%, calcium and magnesium were 0.22 and 0.32%, and microelements of iron (Fe), manganese (Mn), copper (Cu), zinc (Zn) and boron were 126, 210, 23, 75 and 11 mg $kg^{-1}$, respectively. In cultivation bracken, three major elements of nitrogen, phosphorus and potassium, were 5.50, 0.73 and 3.55%, calcium and magnesium were 0.17 and 0.28%, and microelement contents of iron (Fe), manganese (Mn), copper (Cu), zinc (Zn) and boron (B) were 120, 252, 19, 72 and 20 mg $kg^{-1}$, respectively.

Study on Skin pH Improvement Effect through Regulation of Na+/H+ Exchanger 1 (NHE1) Expression of Prunella vulgaris Extract and Its Active Compound, Caffeic Acid (꿀풀 추출물과 그 활성 화합물인 카페인산의 Na+/H+ exchanger 1 (NHE1) 발현 조절을 통한 피부 pH 개선 효과에 대한 연구)

  • No-June Park;Sim-Kyu Bong;Sang-A Park;Gi Hyun Park;Young Chul Ko;Hae Won Kim;Su-Nam Kim
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.49 no.1
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    • pp.87-96
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    • 2023
  • This study was conducted to discover substances that regulate skin surface acidification using human epidermal keratinocyte cell lines, and to investigate their effects on the moisturizing ability and skin barrier function of the stratum corneum. Prunella vulgaris (P. vulgaris) is an herb widely distributed in Northwest Africa and North America that has been studied for its anti-apoptotic, antioxidant, and anti-inflammatory effects. However, research on the regulation of NHE1 expression and the restoration of skin barrier function has not been conducted. Analysis of P. vulgaris revealed the presence of rosmarinic acid and caffeic acid as active ingredients, which were tested for toxicity in human epidermal keratinocyte cell lines (HaCaT), and showed no toxic effects were observed at high concentarion (100 ㎍/mL or 100 µM). It is known that sodium-hydrogen ion exchange pumps (NHE1) decrease in expression in aging skin to maintain the acidic pH of the stratum corneum, and it is hypothesized that this decrease plays an important role in the impaired restoration of skin barrier function in aging skin. P. vulgaris extract and caffeic acid increased the expression of NHE1 in keratinocytes, increased the expression of natural moisturizing factor (NMF) precursor filaggrin and ceramide synthesis enzyme serine palmitoyl transferase (SPT). In addition, P. vulgaris and caffeic acid decreased the extracellular pH of keratinocytes, indicating a direct effect on skin pH regulation. Taken together, these results suggest that P. vulgaris and caffeic acid can regulate skin pH through NHE1 modulation, and may help to restore skin barrier function by increasing NMF and ceramide synthesis. These results show the possibility that honeysuckle and caffeic acid can have a positive effect on skin health, and can be the basis for the development of new skin protection products using them.

무전해 도금방식을 이용한 PET 필름 위 선택적 Ni-Cu 박막의 특성분석

  • Kim, Na-Yeong;Baek, Seung-Deok;Lee, Yeon-Seung;Kim, Hyeong-Cheol;Na, Sa-Gyun;Choe, Seong-Chang
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.387.2-387.2
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    • 2014
  • 최근 이동통신 LED 에너지 자동차 산업분야에서 제품의 고기능화 고성능화를 위한 신소재 개발 및 친환경적인 신공정 개발에 있어, PI 또는 PET와 같은 유연성 소재 위에 선택적 패턴 도금 기술, 고기능성 나노/복합 도금 등이 주목 받고 있다. 또한 전 세계적으로 유해물질의 수 출입 규제 움직임이 강력하게 제기되고 있다. 본 연구에서는 유연성 소재인 PET 위에 친환경적 방법으로 구리를 선택적으로 도금하기 위한 실험을 진행하였다. 준비된 PET 필름 위에 Ag paste를 Screen Printing법을 이용하여 Ag 전극을 패턴하고, 그 위에 무전해 도금방식을 이용하여 Ni과 Cu가 도금 되도록 하였다. Ni 무전해 도금은 pH6.5, 65도에서 시행되었으며, Cu 무전해 도금은 환경규제물질인 포름알데히드 대신에 차아인산나트륨을 사용하여 70도에서, 중성근처의 pH 농도(pH7과 pH8)에서 시행되었다. 이들 다층 박막에 대해 X-ray diffraction (XRD), SEM (Scanning Electron Microscope), XPS (X-ray Photoelectron Spectroscopy) 등을 이용하여 물리-화학적/전기적 특성들을 이용하여 조사 분석하였다.

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수종 점막 추출액중 메치오닌엔케팔린 및 유사체의 분해 억제

  • 전인구;이치호;신영희
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1993.04a
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    • pp.178-178
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    • 1993
  • 생리활성 펩타이드류의 경점막 수송을 검토하기 위하여 토끼의 비강, 직장, 질 또는 눈 점막 구출액에서의 메치오닌엔케팔린 (Met-Enk) 및 그 합성 유사체인 [D-알라$^2$]-메치오닌엔케팔린아미드 (YAGFM)의 효소적 분해를 억제하고자 수종 효소억제제를 검토하였다. 방법: 토끼의 질, 직장 및 비강 점막을 차례로 적출하여 신속히 Valia-Chien투과셀에 마운팅하고, 눈의 각막은 절취하여 따로 각막 투과셀에 마운팅한 다음 등장 인산염 완충액 3.5ml씩으로 8시간씩 3회 추출하여 점막측 및 장막측 추출액을 제조하였다. 추출 완료 직후 이들 추출액에 Met-Enk 또는 YAGFM 50$\mu\textrm{g}$/ml의 농도로 첨가하고 여러 효소억제제를 단독 또는 혼합하여 첨가한 조건에서 37$^{\circ}C$에서 60 rpm으로 24시간 동안 흔들면서 경시적으로 시료를 취하여 잔존 펩타이드의 양을 HPLC법으로 정량하여 속도론적으로 비교 검토하였다. 이 연구에 사용한 효소억제제로는 아미노펩티다제의 억제제인 amastatin (AM), bestatin (BS). 엔케팔리나제 A의 억제제로 알려진 thiophan (TP), 엔케팔리나제 B의 억제작용이 있는 것으로 밝혀진 thimerosal (TM), metalloenzyme의 억제제인 에데트산나트륨 (EDTA) 등을 검토하였고 또 $\beta$-시클로덱스트린 유도체인 디메칠-$\beta$-시클로덱스트린과 2-히드록시프로필-$\beta$-시클로덱스트린이 펩타이드의 분해억제효과도 함께 검토하였다.

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A Study on the Optical and Electrical Characteristics of Multi-Silicon Using Wet Texture (습식텍스쳐를 이용한 다결정 실리콘 광학적.전기적 특성 연구)

  • Han, Kyu-Min;Yoo, Jin-Su;Yoo, Kwon-Jong;Lee, Hi-Deok;Choi, Sung-Jin;Kwon, Jun-Young;Kim, Ki-Ho;YI, Jun-Sin
    • 한국태양에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.383-387
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    • 2009
  • Multi-crystalline silicon surface etching without grain-boundary delineation is a challenging task for the fabrication of high efficiency solar cell. The use of sodium hydroxide - sodium hypochlorite (NaOH40% + NaOCl 12%) solution for texturing multi-crystalline silicon wafer surface in solar cell fabrication line is reported in this article. in light current-voltage results, the cells etched in NaOH 40% + NaOCl 12% = 1:2 exhibited higher short circuit current and open circuit voltage than those of the cells etched in NaOH 40% + NaOCl 12% = 1:1 solution. we have obtained 15.19% conversion efficiency in large area(156cm2) multi-Si solar cells etched in NaOH 40% + NaOCl 12% = 1:1 solution.

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Effect of sodium hexa-meta phosphate as pore-sealing agent on the corrosion performance of Al-Zn coating deposited by twin-wire arc thermal spray process in 3.5 wt.% NaCl solution (3.5 중량% NaCl 용액에서 쌍선 아크 용사 공정으로 증착된 Al-Zn 코팅의 부식 성능에 대한 기공 밀봉제로서의 헥사메타인산나트륨의 영향)

  • Singh, Jitendra Kumar;Adnin, Raihana Jannat;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.81-82
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    • 2022
  • Al and Zn are used to protect the steel structures from corrosion. In the present studies, 15Al-85Zn alloy wires has been used for the deposition of coating by arc thermal spray process. Moreover, this process of coating exhibited severe defects formation, therefore, this coating was post-treated with different concentrations i.e. 0.05, 0.1 and 0.5M sodium hexa meta phosphate (Na6[(PO3)6]: SHMP) to fill to defects of deposited coatings and assessed their corrosion resistance in 3.5 wt.% NaCl solution with exposure periods. After the treatment, the porosity of the coating reduced significantly by formation of composite oxide films onto the coating surface. Initially, 0.5 M SHMP treated coating exhibited highest in total impedance due to significant reduction of porosity but once the exposure periods are extended, the composite oxides are dissolved, thus, total impedance is decreased.

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A Study on the Basic Properties of Wood Impregnated with Inorganic Compounds (무기물처리 목재의 기초물성에 관한 연구)

  • Kim, Geon Hyoung;Oh, Tae Kyung;Lee, Weon Hee
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.4
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    • pp.15-21
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    • 2006
  • Composite materials were prepared by impregnating water glass into the wood, followed by soaking in solutions of boric acid or phosphoric acid. The effects of these treatments on the physical and mechanical properties of the specimens and especially on its heat resistance were investigated. 1) Weight Percent Gain (WPG)s increased with increase of concentrations of water glass. However, there was little relationship between treatment temperatures and WPG. Generally, WPGs of double treated specimens were higher than single treated ones. 2) Percent shrinkages in each directions of the specimens treated with water glass had higher value than other specimens. Percent shrinkages of the specimens treated with boric acid or phosphoric acid were decreased as compared with untreated specimen. However, the specimens treated with water glass or phosphoric acid showed very high hygroscopicity. 3) The bending strengths of all specimens treated inorganic substances were slightly decreased. However, the values of compressive strength and hardness of most specimens treated with inorganic substances increased or similar to that of untreated specimen except for a phosphoric acid treated specimens. 4) The specimens had good heat resistance. Weight losses of all specimens treated inorganic substances were about 50~70%. In particular, the specimens treated at $300^{\circ}C$ and $400^{\circ}C$ almost kept their shapes.