• Title/Summary/Keyword: 인광

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Multi Quantum Well 구조를 이용한 Red에서 Green으로의 energy transfer mechanism의 이해

  • Kim, Gang-Hun;Park, Won-Hyeok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.145-145
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    • 2015
  • 처음 유기물의 인광 발견 이후 Host-dopant 시스템을 이용하여 Emission layer(EML)을 Co-deopsition 하는 방법으로 주로 인광 유기 발광 다이오드를 제작 하였다. [1] co-deposition을 이용해 만든 유기 발광 다이오드에 많은 장점이 있지만, 반대로 소자를 제작하는데 있어서는 많은 문제점을 가지고 있다. [2-4] 이러한 문제점을 개선하기 위하여 co-deposition 대신 non-doped Multi Quantum Well(MQW) 구조를 사용하여 doping 하지 않는 방법을 이용하는 논문들이 보고 되고 있다. Hole, electron, exciton이 MQW 구조를 지나면서, dopant well 안에 갇히게 되고, 그 안에서 다른 layer 간에 energy transfer와, hole-electron leakage가 줄어 들어, 더 효율적인 유기 발광 다이오드를 만들 수 있게 된다. [5-7] 이 연구에서는 CBP를 Potential Barrier로 사용하고, Ir(ppy)3 (Green dopant), Ir(btp)2 (Red dopant) 를 각각 Potential Well로 사용하였고, 두께는 CBP 9nm, dopant 1nm로 하였다. 이러한 소자를 만들고 dopant를 3개의 well에 적당히 배치하여, 각 well에서의 실험적인 발광 량 과, EML 안에서의 발광 mechanism 그리고 각 potential barrier를 줄여가며 dexter, forster에 의한 energy transfer에 대하여 알 수 있었다.

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Efficient red organic light-emitting devices based on electrophosphorescence (전기인광을 이용한 고효율 적색 유기 전기발광소자)

  • Song, Won-Jun;Kang, Gi-Wook;Park, Su-Yeon;Seoul, Chang;Lee, Chang-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04a
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    • pp.121-124
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    • 2000
  • Achieving red light-emitting diodes with high quantum and luminous efficiency is required to fabricate the full-color organic electroluminescence display. In this work, we report that devices with 2.3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine palladium (II) (PdOEP), doped into tris(8-Hydroxyquinolinato)-aluminum (III) (Alq3) show a narrow deep red emission (670nm). In addition, PdOEP has been used as host material in which red dyes such as 4-(Dicyanomethylene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran (DCM) doped in order to fabricate efficient red-emitting diodes.

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Study on Temperature Field Measurement of Fluid using Phophor Particle (Sr,Mg)2SiO4:Eu2+ (인광입자(Sr,Mg)2SiO4:Eu2+를 이용한 액체의 온도장 측정에 관한 연구)

  • Song, Dong Jin;Lee, Hyunchang
    • Journal of the Korean Society of Visualization
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    • v.17 no.3
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    • pp.59-65
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    • 2019
  • Phosphor particles ((Sr,Mg)2 SiO4:Eu2+ were suspended in deionized water in quartz cuvette and used for measuring liquid temperature field by using two-color-ratio method. In the temperature range of 23~77℃, it showed the relative error from 2.4% to 4% and the temperature sensitivity of 0.65 %/℃ at 30℃ and 0.95 %/℃ at 77 ℃. This performance is comparable to measurement techniques using thermographic liquid crystal or laser induced fluorescence or other thermographic phosphor particle. Among investigated potential error sources, the particle number density affected the intensity ratio and the temperature, but the effect of laser fluence was not evident.

Development of a multi-sensing technique for temperature and strain field of high-temperature using thermographic phosphors (온도감응형 인광물질을 이용한 온도장 및 열변형 동시 계측 기법 개발)

  • Im, Yujin;Yeom, Eunseop
    • Journal of the Korean Society of Visualization
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    • v.19 no.3
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    • pp.77-83
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    • 2021
  • Solid oxide fuel cell (SOFC) operates at high temperatures in range of 600-800℃. Since layers of SOFC are composed of different substances, different thermal expansion in SOFC can result in defects under high temperature conditions. For understanding relation between temperature field and the thermal deformation in SOFC, temperature and strain field were simultaneously estimated using thermographic phosphors by optical measurement. Temperature fields were obtained by the life-time method, and the temperature differences of one specimen was checked with thermocouple. The thermal deformation was estimated by digital image correlation (DIC) method with extracted phosphorescence images. To investigate the deformation accuracy of DIC measurement, thermographic phosphors were coated with and without grid pattern on aluminum surface. Simultaneous measurement of temperature fields and thermal deformation were carried out for YSZ. This study will be helpful to multi-sensing of temperature field and thermal deformation on SOFC cells.

Effect of Stepwise Doping on Performance of Green Phosphorescent Organic Light-Emitting Diodes (단계적 도핑구조에 따른 녹색 인광 유기발광 다이오드의 성능에 미치는 효과에 관한 연구)

  • Hwang, Kyo-Min;Lee, Song-Eun;Lee, Seul-Bee;Yoon, Seung-Soo;Kim, Young-Kwan
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.1-6
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    • 2015
  • We investigated green phosphorescent organic light-emitting diodes with stepwise doping to improve efficiency roll-off and operational lifetime by efficient distribution of triplet excitons. The host material which was 4,4,N,N'-dicarbazolebiphenyl (CBP) of bipolar characteristic that can control the carrier in emitting layer (EML). When the EML devided into four parts with different doping concentration, each devices shows various efficiency roll-off and lifetime enhancement. The distribution of the carrier and excitons in the EML can be confirmed by using stepwise doping structure. The properties of device C exhibited luminous efficiency of 51.10 cd/A, external quantum efficiency of 14.88%, respectively. Lifetime has increased 73.70% compared to the reference device.

Effect of Changing the Thickness of Charge Control Layer on Performance of Green Phosphorescent Organic Light-Emitting Diodes (녹색 인광 유기발광다이오드에서 전하 조절층의 두께 변화가 성능에 미치는 효과에 대한 연구)

  • Lee, Dong-Hyung;Lee, Seok-Jae;Koo, Ja-Ryong;Lee, Ho-Won;Lee, Song-Eun;Yang, Hyung-Jin;Park, Jae-Hoon;Kim, Young-Kwan
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.2
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    • pp.244-250
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    • 2013
  • We investigated green phosphorescent organic light-emitting diodes (PHOLEDs) with charge control layer (CCL) to produce high efficiency. The CCL and host material which was 4,4,N,N'-dicarbazolebiphenyl (CBP) of bipolar property can control the carrier movement in emitting layer (EML). The performance improvement by the insertion of CCL was realized to the well confined exciton and the reduced triplet exciton quenching effect in EML. Five types of devices (Device A, B, C, D, and E) were fabricated following the thickness of CCL within EML. The properties of device D using optimized thickness of CCL showed external quantum efficiency of 16.22% and luminous efficiency of 55.76 cd/A, respectively.