• Applied Chemistry for Engineering
• /
• v.10 no.1
• /
• pp.166-172
• /
• 1999

Fixed-bed adsorption of metal ions on chitosan bead was studied to remove heavy metal ions in waste water. Chitin was extracted from carb shell and chitosan was prepared by deacetylation of the chitin. The chitosan in bead was used as an adsorbent for heavy metal ions. Freundlich and Langmuir isotherm was determined from the experimental results of equilibrium adsorption for individual metal ion ($Cu^{2+}$, $Co^{2+}$, $Ni^{2+}$) on chitosan bead. Adsorption strength of metal ions decreased in the order of $Cu^{2+}$>$Co^{2+}$>$Ni^{2+}$ ion. Breakthrough curves of single and multicomponent adsorption for metal ions were obtained from the experimental results of fixed-bed adsorption. The breakthrough curves were analyzed by simulation with fixed-bed adsorption equation based on LDFA (linear driving force approximation) adopted LAS (ideal adsorbed solution) theory which can predict multi-component adsorption isotherm from individual adsorption isotherm. The behavior of fixed bed adsorption for single and multi-component system could be nicely simulated by the equation.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.1 no.1
• /
• pp.81-92
• /
• 2003

In order to predict the dynamic behaviors of uranium and cobalt in a fixed bed at various influent pH values of liquid waste, the adsorption system is regarded as a multi-component adsorption between each ionic species in the solution. Langmuir isotherm parameters of each species were extracted by incorporating equilibrium data with the solution chemistry of the uranium and cobalt using IAST. Prediction results were in good agreement with the experimental data, except for a high concentration and pH. Although there was some limitations in predicting the cobalt adsorption, this method may be useful in analyzing a complex adsorption system where various kinds of ionic species exist in a solution.

• Applied Chemistry for Engineering
• /
• v.28 no.5
• /
• pp.521-528
• /
• 2017

To find a recycling method for waste liquid crystal display (LCD) panel glasses, we investigated the synthesis process of zeolite with an ion exchange ability by hydrothermal reaction using waste LCD panel glass as a raw material. It was shown that the waste LCD panel glass can be used as a raw material for the production of zeolites having the ion exchange ability. Following conditions for the synthesis of the zeolite with an ion exchange ability were required : the molar ratio of Si to Al components of the waste LCD glass needs to be 2.0 to 2.8, and the temperature of $100^{\circ}C$ and reaction time of 12 hours are needed for the hydrothermal reaction. Based on the required conditions previously mentioned, the A type zeolite was synthesized when the molar ratio of the Si to Al component was 2.0, and the P type zeolite was produced when the molar ratio was 2.8. The type A zeolite synthesized by using the waste LCD panel glass showed a good ion exchange ability and heavy metal adsorption ability. Also, an excellent ion exchange capacity was observed as the crystal phase grows stably in a cubic phase.

• Korean Journal of Soil Science and Fertilizer
• /
• v.34 no.3
• /
• pp.213-236
• /
• 2001

The ionic composition of soil solution is related to a nutrient uptake by plant. Many models for estimating ionic composition of solution have been developed, and most of them have been used for calculating a content of mineral and ionic species in a geochemical point of view. An approximation model considering both cation and anion in soil solution was developed. Variables such as pH, Eh, EC, cations(K, Ca, Mg. Na, Fe, Mn, Al, $NH_4{^+}$), anions(Si, S, P, CY, $NO_3{^-}$, $HCO_3{^-}$ and chemical equilibria of ionic species in soil solution were input into Excel sheet. The activities of soluble ion, ionpairs and complexes of input element were estimated by Newton-Raphson method using conditional equilibrium constant calculated by Davies equation and special models. Equilibrium contents of insoluble minerals and complexes were also calculated.

• 건강소식
• /
• v.36 no.7
• /
• pp.38-39
• /
• 2012

마라톤과 같은 격렬한 운동 후, 또는 열대지방에서 골프를 친 후에 의식을 잃거나, 신부전에 빠지거나 심한 경우 사망하는 경우를 이따금 매스컴을 통해서 접하게 된다. 본 원고에서는 이에 대한 궁금증, 원인, 예방 및 치료 그리고 흔히 마시는 이온음료(스포츠 드링크)의 조성성분과 문제점 등에 대해서 문답식으로 알아보고자 한다.

• Proceedings of the Membrane Society of Korea Conference
• /
• 1993.10a
• /
• pp.75-76
• /
• 1993

자연수에는 무기이온, 용해유기물, 미립자, 미생물과 같은 성분들이 혼재되어 있다. 일반실험실에서 사용하는 증류수, RO수 또는 이온교환수는 실험용 기구 세척수, 일반 정성화학 실험 등에는 적당하지만, 최근 급속히 발전하는 생명공학의 조직배양용이나 PHLC, AAS, 이온크로마토그래피 등 정밀분석기기 용수로는 부적당하다.

• KSBB Journal
• /
• v.16 no.1
• /
• pp.54-60
• /
• 2001

The activity of microorganisms is an important factor that determines the efficiency of the bacterial recovery of precious metals from low-grade ore. Metal-leaching microorganisms must have a tolerance, within the concentration levels encountered to leached metals. In this study, the tolerance levels of Thiobacillus ferroxidans to the single and mixed metal ions systems, composed of $Zn^{2+}$, $Cu^{2+}$, $Ni^{2+}$, and $Cd^{2+}$ were investigated. When single metal ions of $Zn^{2+}$ (10~60 g/L), $Cu^{2+}$ (1~6 g/L), $Ni^{2+}$ (1~6 g/L), or $Cd^{2+}$ (1~6 g/L) were added to the growth medium of T. ferrooxidans, the iron oxidation rate of this bacterium was not significantly inhibited. The maximum inhibition percentage observed on the iron oxidation rate of T. ferrooxidans was approximately 50% in the medium supplemented with two or three mixed metal ions of $Cu^{2+}$, $Ni^{2+}$, and $Cd^{2+}$. However, when $Zn^{2+}$ was also added to the medium with the other metal ions, the inhibitory effect on the iron oxidation activity of T. ferroxidans was remarkably increased.

• Proceedings of the Korean Nuclear Society Conference
• /
• 1998.05b
• /
• pp.808-813
• /
• 1998

EDTA 의 농도 및 온도가 일정한 조건에서 수용액의 pH 를 변화시켜 가며, 토양으로부터 Co$^2$$^{+}$ 이온의 탈착특성을 살펴보았다. 실험범위에서, pH 4 일 때 $CO_2$$^{+}$ 이온의 탈착율이 가장 양호하였으며, pH 가 상승함에 따라 탈착율이 감소되는 것으로 나타났다. 또한, 반응중 철 성분이 용해되어 나오는데 이는 반응 초기 수소이온에 의한 용해와 반응중 탈착된 Co$^2$$^{+}$ 이온에 의한 용해로 설명하였다.

• Korean Journal of Organic Agriculture
• /
• v.20 no.2
• /
• pp.231-241
• /
• 2012

Farming using natural salts for supply of nutrients to crops is increasing recently. It is necessary to evaluate the salt accumulation in soil and the effects on crop growth by treatment of natural salt. This study was conducted at the organic cultivation fields which garlics were planted. The treatments were no natural salts (control) and plots applied 100~600 $kg\;ha^{-1}$ with natural salts. Soil samples were taken from the 0 to 25 cm depth at 12 and 107 day (harvest time) after natural salts application. The results showed that electrical conductivity (EC), exchangeable Na (Exch.$-Na^+$) and Cl- were increased by application of natural salts. But, pH and exchangeable cations ($K^+$, $Ca^{2+}$ and $Mg^{2+}$) had not significantly differences among treatments. In 300 $kg\;ha^{-1}$ plots of natural salt, the level of EC, Exch.$-Na^+$ and $Cl^-$ in top soil (0-5 cm) was were increased more 0.3, 3.7, and 12.7 times than control plot, respectively. EC, Exch.$-Na^+$, and $Cl^-$ were highest in the top 5 cm of soil and decreased with depth at 12 days after natural salts application, but were decreased in the plower layer (0-15cm) at the harvest time because they were leached with natural rain. An increasing the application level of natural salt resulted in increasing of sodium adsorption ratio, exchangeable sodium percentage, and percentage of soil dispersion. The concentration of nutrient uptake such as total nitrogen (T-N), chloride (Cl) in garlic had significant difference between control and plots applied with natural salts The content of T-N of garlic in plots with natural salt application was lower than control plot, but Cl is higher than control plot.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2004.04a
• /
• pp.477-481
• /
• 2004

지하수 수질자료의 분포가 광역적이고 자료의 수가 많은 지역과 자료의 분포가 국부적이고 갯수가 적은 지역을 선정하여, 모수적 통계기법인 정규크리깅과 비모수적 통계기법인 지시크리깅을 동시에 적용하였다. 베리오그램 분석은 각 수질자료의 원시 자료와 제한값을 적용하여 제한값 보다 낮거나 동일하면 '1' 의 값으로, 제한값 보다 높으면 '0' 의 값으로 변환된 자료에 대해 실시하였는데, 원시 염소이온 성분은 선형 모델이 선정되었으며, 비소 성분은 지수형 모델이 가장 적합한 것으로 선정되었다. 변환된 염소이온 성분과 비소 성분은 모두 구상형 모델이 가장 적합한 것으로 선정되었다. 정규크리깅과 지시크리깅 기법을 이용하여 지하수 오염 분포도를 작성하여 비교해 본 결과, 정규크리깅 기법은 연구지역의 자료 분포, 갯수와 범위의 영향을 크게 받는 것으로 나타났고, 지시크리깅 기법은 연구지역의 자료 분포와 특히 제한값에 따라 변환된 자료의 갯수의 영향을 크게 받는 것으로 나타났다. 정량적으로 나타낼 수 정규크리깅 기법과 정성적으로 나타낼 수 있는 지시크리깅 기법을 같이 적용한다면 지하수 오염 현황을 효과적으로 파악할 수 있을 것으로 판단된다.