• Journal of the Korean Geotechnical Society
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• v.15 no.1
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• pp.185-196
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• 1999

A laboratory experiment was performed to examine the relationship between resistivity and ionic components in the pore water of a sand by using soil resistivity test box and STING-Rl. The resistivity measurement was performed with the concentration changes of ionic components. Also, the resistivity change was evaluated for multiple components. The results showed that the resistivity of Arsenic was less than other heavy metals. In the case of complex components, resistivity ranges depended on the resistivity of components existed in the pore water.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2001.11a
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• pp.115-115
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• 2001

강수중에 존재하는 이온성분은 강수의 화학적 조성을 변화시키는 주요 요인이 되는 물질로서 자연적 또는 인위적으로 배출된 대기오염물질을 비롯하여 토양입자를 구성하고 여러가지 성분들이 수용액 중에 용해되어 존재하게 된다. 강수의 pH는 이와 같은 용해성분들의 화학적 구성상태에 따라서 결정되게 된다. 따라서 강수의 pH별 이온성분들의 분포특성을 파악하는 것은 산성강하물의 산도증가에 직접적인 원인이 되는 산도유발물질의 종류나 산성강하물의 생성과정의 추정에 있어서 매우 중요한 역할을 하게 된다. (중략)

• Applied Chemistry for Engineering
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• v.4 no.1
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• pp.171-177
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• 1993

In decontamination process to remove radioactive materials of reactor cooling system, the metal ions dissolved by organic acids in decontamination solution are separated by use of ion exchange resin in the column. However, organic acids in decontamination solution decrease the apparent affinity of the resin to metal ions. In light of this, some experiments were carried out on the Amberlite IRN-77 cation resin with cobalt and iron to gain a better understanding of the complexation effects on the ion exchange process. Experimental results showed that EDTA among organic acids used as chemical decontaminants predominantly caused reduction of ion exchange capacity of cobaltous ion to resin since this reagent formed the complex with the cobaltous ion stronger than that with the ferrous ion. In contrast, the effects of oxalic acid and citric acid were found to be negligible. And, single and two-component nonlinear equilibrium relationships of the metal ions were established using experimental data.

• Proceedings of the KAIS Fall Conference
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• 2006.05a
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• pp.599-601
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• 2006

본 논문에서는 용액의 농도가 이온교환 특성에 미치는 영향을 조사하기 위하여 농도는 $Na^+\;50$, 125, 250ppm, $Cl^-\;165$, 315, 610ppm, 입자성 물질의 유입 농도 0ppm, 유속 500ml/min, 이온교환 수지는 ROHM&HAAS IR 120 양이온 수지와 ROHM&HAAS IRA 402 음이온 수지를 사용하였다. 수지탑 배열은 혼상-혼상-음이온 수지탑 순으로, 이온교환 수지탑의 양 음이온교환 수지의 조성 비율은 1:2 로 실험한 결과 이온교환 수지탑 성능은 유입 용액 성분 및 농도에 영향을 받는 것으로 나타났다. 이온교환 수지탑 배열 순서에 따라 파과시점이 연장되며, 파과순서는 음이온의 경우 $Cl^-\;<\;NO_3\;^-\;<\;F^-$, 양이온의 경우 $Na^+\;<\;K^+\;<\;Ca^{2+}$ 순 이였으며, 용액의 농도가 증가할수록 파과시간이 단축되었다.

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 2002.02a
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• pp.186-191
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• 2002

실시간 온라인 계측에 의한 순환식 양액조제 알고리즘을 위해서 이온센서를 사용하였다. 이온센서의 내구성이 약하고 배양액 내에는 이온센서의 정확한 계측의 방해요인인 이온성분들이 포함되어 있기 때문에 매번 정확한 측도 설정을 수행 해줌으로써 계측값의 신뢰도를 높일 수 있었고 이온센서를 이용한 온라인계측의 가능성을 확인할 수 있었다. 그러나 배양액 속에 장시간 넣어둔 상태로 사용하였을 경우 4시간 이상 경과하면 센서에서 나오는 신호가 지속적으로 상승하는 경향을 보였다. 장시간 동안 배양액에 노출되었던 센서는 측도설정이 불가능한 수준으로 일정농도의 용액 내에서 일정한 값을 나타내지 못하고 계측값이 지속적으로 상승하던가 하강하여 한계값 까지 이르렀다. 이러한 이유로 연구용이 아닌 실제 장치에 적용하여 실용화하기 위해서는 내구성이 강하고 계측하고자 하는 이온에 대해 영향을 주는 방해이온 속에서도 정확도를 유지 할 수 있는 센서의 개발이 선행되어야 한다. 또한 정확한 퇴액 성분의 측정을 위해서는 측도 설정이 선행되어야 하는데 계측이 필요할 때마다 측도 설정을 자동으로 해줄 수 있는 자동 측도 설정 모듈의 개발도 수행되어야 할 것으로 사료된다.

• Journal of the Korea institute for structural maintenance and inspection
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• v.14 no.3
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• pp.138-143
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• 2010

Recently, as many big marine concrete structures increase, it is necessary that chloride ion diffusion coefficient of concrete shall be evaluated but it will take a long time to evaluate chloride ion diffusion coefficient of concrete. Accordingly, many test methods are suggested to evaluate chloride ion diffusion coefficient in a short period time by the promotion in electro chemical ways but the systematic study for this is insufficient. Therefore, this study evaluates chloride ion penetration and diffusion features by three representative electric promotion tests targeting for three different cements whose ingredients are different and analyzes the correlationship between them. As a result, diffusion features of chloride ion varied according to the cement ingredients and three ingredients cement in which blast furnace slag powder and fly ash are mixed in constant ratio, which shows the most excellent cement diffusion properties. For diffusion properties of chloride ion, the correlationship between test methods are good.

• Journal of the Korean Society for Marine Environment & Energy
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• v.16 no.4
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• pp.227-238
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• 2013

The purpose of this study is to develop a process technology to produce high hardness drinking water which meet drinking water standard, remaining useful minerals like magnesium and calcium in the seawater desalination process while removing the sulfate ions and chloride ions. Seawater have been separated the concentrated seawater and desalted seawater by passing on Reverse Osmosis membrane (RO). Using Nano-filtration membrane (NF), We were prepared primary mineral concentrated water that sodium chloride were not removed. By the operation of electro-dialysis (ED) having ion exchange membrane, we were prepared concentrated mineral water (Mineral enriched desalted water) which the sodium chloride is removed. We have produced the high hardness water to meet the drinking water quality standards by diluting the mineral enriched desalted water with deionized water by RO. Reverse osmosis membranes (RO) can separate dissolved material and freshwater from seawater (deep seawater). The desalination water throughout the second reverse osmosis membrane was completely removed dissolved substances, which dissolved components was removed more than 99.9%, its the hardness concentration was 1 mg/L or less and its chloride concentration was 2.3 mg/L. Since the nano-filtration membrane pore size is $10^{-9}$ m, 50% of magnesium ions and calcium ions can not pass through the nano-filtration membrane, while more than 95% of sodium ions and chloride ions can pass through NF membrane. Nano-filtration membrane could be separated salt components like sodium ion and chloride ions and hardness ingredients like magnesium ions and calcium ions, but their separation was not perfect. Electric dialysis membrane system can be separated single charged ions (like sodium and chloride ions) and double charged ions (like magnesium and calcium ions) depending on its electrical conductivity. Above electrical conductivity 20mS/cm, hardness components (like magnesium and calcium ions) did not removed, on the other hand salt ingredients like sodium and chloride ions was removed continuously. Thus, we were able to concentrate hardness components (like magnesium and calcium ions) using nano-filtration membrane, also could be separated salts ingredients from the hardness concentration water using electrical dialysis membrane system. Finally, we were able to produce a highly concentrated mineral water removed chloride ions, which hardness concentration was 12,600 mg/L and chloride concentration was 2,446 mg/L. By diluting 10 times these high mineral water with secondary RO (Reverse Osmosis) desalination water, we could produce high mineral water suitable for drinking water standards, which chloride concentration was 244 mg/L at the same time hardness concentration 1,260 mg/L. Using the linked process with reverse osmosis (RO)/nano filteration (NF)/electric dialysis (ED), it could be concentrated hardness components like magnesium ions and calcium ions while at the same time removing salt ingredients like chloride ions and sodium ion without heating seawater. Thus, using only membrane as RO, NF and ED without heating seawater, it was possible to produce drinking water containing high hardness suitable for drinking water standard while reducing the energy required to evaporation.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.29 no.4A
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• pp.347-353
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• 2009

The qualitative factors influencing the ingress of chloride ion into concrete are water-binder (W/B) ratio, cement type, age, chloride ion concentration of given environment, wet and dry conditions, etc. Thus, an objective of this experimental research is to investigate the effects of cement types and environmental conditions on the chloride ion diffusion characteristics in concrete through the chloride ion diffusion test. For this purpose, the diffusion coefficients for chloride ion in concrete with three types of cement such as ordinary portland cement (OPC), binary blended cement (BBC), and ternary blended cement (TBC), were measured for the concrete specimens with W/B ratios of 32%, 38%, and 43%, respectively. The diffusion coefficients for chloride ion were also measured for the concrete specimens with W/B ratio of 43%, which were subjected to standard curing and field exposure conditions. It was observed from the test results that the resistance against chloride ion penetration increased with decreasing W/B ratio and those of BBC and TBC concretes were greater than that of OPC concrete. Therefore, it was revealed that the use of these cements containing mineral admixtures is required to extend the service life of RC structures exposed to chloride environment. On the other hand, it was noted that the resistance against chloride ion penetration of field exposure test specimens was slightly lower than that of standard curing test specimens due to the penetration of chloride ion under the irregular ambient temperature, splash of wave, and cycle of wet and dry.

• Proceedings of the KAIS Fall Conference
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• 2002.05a
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• pp.140-143
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• 2002

연속 이온교환 평형 모델을 개발하여 원자력발전소 탈염기의 성능을 평가한 결과 특정이온의 누출 현상과 유입수 및 유출수중 이온농도 비율이 운전조건에 따라서 달라짐을 확인하였다. 본 모델은 국부 불완전 평형을 고려할 수 없으나 다성분 존재하의 경쟁적 이온교환을 묘사할 수 있는 장점을 가지고 있다.

• Proceedings of the Korean Nuclear Society Conference
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• 1997.10a
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• pp.387-391
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• 1997

냉각재중의 방사능을 띤 성분 중에는 이온교환기에서 제거가 가능한 이온성분과 함께 필터에 의해서 주로 제거되는 입자성 물질로 존재한다. 운전중의 냉각재내 방사성 부식생성물의 물리적 조성 분포 측정 결과에 따르면 90%이상이 0.45$mu extrm{m}$필터에 의해 제거되는 입자성 물질로 구성되어 있다. 이로 인해 새수지 충전후 얼마 사용하지 않은 탈염기의 제염계수가 탈염기에서 완벽한 제거가 어려운 입자성 부식생성물로 인해 10이하를 나타낼 수 있다. 1차계통에 쓰이는 수지의 성능검사를 위해 사용하고 있는 현재의 제염계수 측정법은 다음과 같은 두가지 이유로 완벽하지 않음을 알 수 있다. 첫째, 냉각재중의 방사능을 띤 성분중에는 이온교환기에서 제거가 가능한 이온성분과 함께 필터에 의해 제거되는 입자성 물질도 함께 존재하므로 탈염기의 제염계수 측정 절차는 입자성 물질을 배제한 후 측정해야 하며, 특히 수치 교체를 결정하기 위한 제염계수 측정시에는 여과된 여액으로 방사능 농도를 측정하는 것이 바람직하다. 둘째 운전중인 냉각재의 시료중에는 핵분열 수율이 높고 핵연료봉 손상부위로 유출이 용이한 불활성 기체핵종들이 많이 존재하며, 탈염기 후단에서 채취한 시료중에도 많이 존재하고, 시료 이송과 방사능 측정동안의 짧은 시간동안에도 계속 붕괴반응함으로서 새로 생긴 핵종으로 인해 마치 탈염기의 제거능이 낮은 것으로 오판될 수 있다. 이러한 측정 오차인자를 고려하여야 1차계통 탈염기의 교환능력을 정확히 판정할 수 있다.