• Journal of Advanced Marine Engineering and Technology
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• v.18 no.2
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• pp.33-40
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• 1994

알루미늄 코팅막은 부식환경으로부터 강판을 보호하는 데에 자주 사용된다. 그러나 이 코팅막은 때때로 사용조건에 따라 제한을 받는다. 아무리 강판상에 치밀한 양질막을 코팅시켰다 할지라도, 사용중 이 피막이 손상을 받아서 강판이 노출되는 경우는 강판과의 갈바닉(Galvanic)작용으로 급격한 부식을 일으킨다. 본 연구는 내식성 개선을 목적으로 해서, 고밀착성의 코팅막을 제공하는 비평형프라즈마 프로세스인 이온프레이팅법에 의해 냉간압연강판상에 Al-Mg합금 코팅막을 제작했다. 제작된 막들은 우선, EMPA측정에 의해 원소조성분석을 한 후, 상구조분석 및 표.단면의 몰포로지(Molphology)를 X선 회절 및 주사형 전자현미경(SEM)에 의해 관찰했다. 또한, 이들막은 탈기시킨 3%NaCl용액중 양극분극 측정을 통해서 내식특성에 대한 평가를 행했다. 이들의 결과에 의하면, 알루미늄과 마그네슘의 조성비에 따라 주상, 미결정 및 아몰포스(Amorphous)조직을 보이는 금속간화합물이나 고용체의 Al-Mg박막이 나타났다. 이들 Al-Mg합금 코팅막은 강판과의 갈바닉 부식작용에 대한 방지 및 부동태 피막의 형성을 촉진하는 등의 좋은 내식성을 나타냈다.

• Journal of Advanced Marine Engineering and Technology
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• v.20 no.5
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• pp.103-113
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• 1996

The properties of the deposited film depend on the deposition condition and these, in turn depend critically on the morphology and crystal orientation of the films. Therefore, it is important to clarify the nucleation occurrence and growth stage of the morphology and orientation of the film affected by deposition parameters, e.g. the gas pressure and bias voltage etc. In this work, magnesium thin flims were prepared on cold-rolled steel substrates by a thermo-eletron activation ion plating technique. The influence of nitrogen gas pressure and substrate bias voltage on their crystal orientation and morphology of the coated films were investigated by scanning electron microscopy (SEM) and X-ray diffraction, respectively. The diffraction peaks of magnesium film became less sharp and broadened with the increase of nitrogen gas pressure. With an increase in nitrogen gas pressure, flim morphology changed from colum nar to granular structure, and surface crystal grain-size decreased. The morphology of films depended not only on gas pressure but also on bias voltage, i.e., the effect of increasing bias voltage was similar to that of decreasing gas pressure. The effect of crystal orientation and morphology of magnesium films on corrosion behaviors was estimated by measuring anodic polarization curves in deaerated 3%NaCl solution. Magnesium, in general, has not a good corrosion resistance in all environments. However, these magnesium films prepared by changing nitrogen gas pressure showed good corrosion resistance. Among the films, magnesium films which exhibited granular structure had the highest corrosion resistance. The above phenomena can be explained by applying the effects of adsorption, occlusion and ion sputter of nitrogen gas.