• Title/Summary/Keyword: 이온용출

Search Result 343, Processing Time 0.032 seconds

Manufacture of the far infrared ray emission materials and analysis of the characterization of materials (원적외선 방사물질 제조 및 물질의 특성 분석)

  • Cho, Bong-Heuy
    • Analytical Science and Technology
    • /
    • v.21 no.4
    • /
    • pp.279-283
    • /
    • 2008
  • Blood soil and the mixture of blood soil, elvan soil and, silica soil materials were molded, then they were sintered in $1100^{\circ}C$ and were used for the emission of the far infrared ray boll. The emission from the manufactured bolls was relatively high in the range of $8{\sim}12{\mu}m$ wavelength each. The elution of minerals from mixture bolls was very low, but the elimination of heavy metal cadmium ion in activated water and energy water treated with mixture bolls was very high. Activated water and energy water had a high to the UV protected ability in comparison to drinking water.

Effect of Ponded Water on Variation of Redox Potential and Phosphorus Concentration in a Paddy Field (논에서 담수가 토양 산화.환원전위 변화와 인의 용출에 미치는 영향)

  • Kim, Young-Hyeon;Kim, Jin-Soo;Jang, Hoon
    • Proceedings of the Korea Water Resources Association Conference
    • /
    • 2010.05a
    • /
    • pp.1661-1666
    • /
    • 2010
  • 본 연구의 목적은 충북대학교 부속농장에서 2009년 영농기간을 중심으로 담수된 논에서의 산화환원전위(Eh)의 변화와 시비에 따라 영양물질인 인(P)의 농도변화 특성을 파악함으로써, 논으로 부터의 인의 유출제어에 관한 기초 자료를 제공하는데 있다. 이 연구는 2009년 5월부터 11월까지 논에서 담수의 총인(T-P)과 인산염 인($PO_4$-P)의 농도변화와 토양의 산화환원전위(Eh)와의 관계 특성을 파악하였다. 관개기의 논에서 인은 분얼비 시기에 인성분이 시비되지 않았는데도 불구하고 T-P농도가 0.68 mg/L로 높게 나타났다. 이는 담수의 영향으로 논이 환원상태로 되어, 논바닥에 침전된 철이온에 흡착되어 있던 인이 철이온의 환원으로 함께 용출하기 때문이라고 생각된다. 높은 Eh는 산화경향을, 낮은 Eh는 환원경향을 나타낸다. 본 연구기간 동안의 Eh 값은 연속적으로 담수되었던 7월 중순까지는 74~112 mV 가량 나타냈고, 그 이후에는 담수상태가 아닌 경우가 많아 179~636 mV로 높게 나타났다. 논 담수의 T-P와 $PO_4$-P 농도는 분얼비 직후 1주일후까지 같이 상승하다가 T-P농도는 약 2주일까지 더 상승한 반면 $PO_4$-P 농도는 하강하였는데 이는 논 토양이 환원상태로 되면서 바닥에 있던 입자성 인이 논 표면으로 떠올랐기 때문으로 사료된다. 그 후에는 담수가 끝나는 시점까지인 농도는 낮아졌다. 관개초기에 인의 농도는 비교적 높게 나타났지만, 7월 이후로는 작물의 생장에 필요한 영양물질 섭취 등으로 인 농도가 낮게 나타났는데 이는 7월 이후의 논은 인의 유출을 억제하고 있는 것으로 추정된다. 또한 논 담수위의 증감에 따른 $PO_4$-P 농도와 Eh 값을 회귀분석 한 결과 각각 정의 상관관계와 부의 상관관계가 있는 것으로 나타났다. 이와 같이 논 담수 및 시비에 따른 인의 유출부하 특성과 산화환원전위(Eh)의 변화 특성이 규명된다면, 향후 환경부하가 작은 물관리가 가능해 질 것으로 판단된다.

  • PDF

Stabilization of Heavy Metal Contaminated Paddy Soils near Abandoned Mine with Steel Slag and CaO (제강슬래그와 CaO를 이용한 폐광산 주변 중금속 오염 농경지 토양의 안정화 처리 연구)

  • Son, Jung-Ho;Roh, Hoon;Lee, Sun-Young;Kim, Sung-Kyu;Kim, Gil-Hong;Park, Joong-Kyu;Yang, Jae-Kyu;Chang, Yoon-Young
    • Journal of Soil and Groundwater Environment
    • /
    • v.14 no.6
    • /
    • pp.78-86
    • /
    • 2009
  • Applicability of CaO and steel slag as stabilizers in the treatment of field and paddy soils near Pungjeong mine contaminated with arsenic and cationic heavy metals was investigated from batch and column experiments. Immobilization of heavy metals was evaluated by TCLP dissolution test. Immobility of heavy metal ions was less than 15% when steel slag alone was used. This result suggests that $Fe_2O_3$ and $SiO_2$, known as the major component of steel slag, have little effect for the immobilization of heavy metal ions due to acidity of TCLP solution. Immobilization of cationic heavy metals was little affected by the ratio of CaO and steel slag while arsenic removal was increased as the ratio of steel slag to CaO increased. In the column test, concentrations of both arsenic and cationic heavy metals in effluents were below the water discharge guideline over the entire reaction period. This result can be explained by the immobilization of cationic heavy metals from the increased pH in soil solution as well as by the formation of insoluble $Ca_3(AsO_4)_2$. From this work, it is possible to suggest that arsenic and cationic heavy metals can be concurrently stabilized by application of both CaO and steel slag.

Effect of Alumina on the Ion-Exchange Capacity of Porous Glasses (다공질유리의 이온교환성에 미치는 알루미나의 영향)

  • 김병호;이덕열;김성길
    • Journal of the Korean Ceramic Society
    • /
    • v.25 no.3
    • /
    • pp.251-260
    • /
    • 1988
  • Ion-exchange porous glasses were prepared by heat treatment and subsequently hydro thermalor acid leaching treatment $10Li_2O$.$(90-x)B_2O_3$.$xSiO_2$ base glasses containing various amount of $Al_2O_3$ or $MoO_3$. It was investigated how the phase separation and the cation exchange capacity(CEC) were affected by the addition of $Al_2O_3$ or $MoO_3$. The optimum condition of phase separation in these glasses was about 48$0^{\circ}C$ for 10 hrs. The degree of phase separation was rapidly suppressed by the addition of $Al_2O_3$ up to 10 mol% and thereafter suppression effect was decreased. The maximum value of CEC, about 252meq/100g, was observed with the $1OLi_2O$.$45B_2O_3$.$45SiO_2+7.5Al_2O_3$ porous glass prepared by hydrothermal treatment and its mean pore radius was about 16.3A. The addition of $MoO_3$ accelerated phase separation and leaching rate. Looking at the remakable increment of pore diameter and pore volume of these porous glasses by the addition of $MoO_3$, the effect of $MoO_3$ may be ascribed to the lowering of silica concentration in the borate phase and to the forming of water-soluble complex with silica during the leaching treatment.

  • PDF

Experimental Study of Desalting Methods Using Ethyl Alcohol for Archaeological Cast Iron Objects (에틸알코올 용매를 이용한 주조철제유물의 탈염 실험 연구)

  • Lee, Hye Youn;Cho, Ju Hye
    • Journal of Conservation Science
    • /
    • v.31 no.2
    • /
    • pp.95-104
    • /
    • 2015
  • Excavated archaeological cast iron objects in improper storage are quickly corroded and disintegrated into block and powder finally. Hence desalination treatment which is a way of removing internal corrosive factors, especially chloride ion, is an important process. But desalination is often omitted or objects are dehydrated by alcohol because the destruction of objects could occur during desalting. Although current desalting methods mostly use an aqueous alkali solution, $OH^-$ ions of water could accelerate corrosion and broaden internal cracks cause of high surface tension. Therefore this study experimented desalting using ethyl alcohol, which is low surface tension, to investigate an effect of desalination. As a result, desalting using ethyl alcohol showed the similar or more effective results of desalting using water. In addition, as aspects of desalting safety, ethyl alcohol desalting method was smaller destruction of objects and extraction of Fe from the objects than the aqueous alkali solution. However, this study explored the possibility of desalting methods using organic solvent in fieldwork, so the results would provide basic date for making the safe and effective desalting method for archaeological cast iron objects through further experiments.

Movement for the Various Coated and Uncoated Potassium(K) Fertilizers in the Turfgrass Soils of Golf Course (골프장의 잔디 토양에서 다양한 코팅 및 비코팅 칼륨(K) 비료의 이동성 평가)

  • Kim, Hong-Ki;Han, Seok-Soon;Kwon, Sang-Moon;Kim, Hee-Jung;Woo, Sun-Hee;Lee, Moon-Soon;Baek, Ki-Tae;Lee, Bong-Gyu;Lee, Sang-Sung;Kim, In-Su;Chung, Keun-Yook
    • Asian Journal of Turfgrass Science
    • /
    • v.23 no.1
    • /
    • pp.133-142
    • /
    • 2009
  • This study was initiated to evaluate the K leaching potential in the green soils and K uptake by the turfgrass in the golf course using the K fertilizers. The turfgrass, Floradwarf bermudagrass(Cynodon dactylon L. $P_{ERS}$.) was planted and grown in the mixture of sand and peat moss in this lysimeter study. Eight representative K fertilizers, such as, monopotassium phosphate (MKP), KCL, $K_2SO_4$, $KNO_3$, CKCl, $CK_2SO_4$, $CKNO_3$, and 0-20-20(liquid) were used in this study. Based on the total K quantity of leachate collected during the whole 12 weeks, 0-20-20 is the K fertilizers the most contributing to the leaching of K, then MKP, the second, KCL, the third, and finally $KNO_3$ are K fertilizers contributing to the K leaching. However, most amount of K applied and collected in the lysimeter were leached during the first period of two and four weeks, compared to that of K leached during the second period of six, eight, ten, and twelve weeks. Application of CKCL and $CK_2SO_4$ producted the largest amount of total dry matter, then MKP and KCL, $KNO_3$ and $CKNO_3$, 0-20-20 in second group. However, except $K_2SO_4$, most K fertilizer sources such as MKP, KCL, $KNO_3$, CKCL, $CK_2SO_4$, $CKNO_3$, 0-20-20 showed the largest amount of K uptake, except $K_2SO_4$. Therefore, based on the K leaching, dry matter production, and plant K uptake, it appears that the coated fertilizers, CKCL, $CKNO_3$, and $CK_2SO_4$ are the environmentally sound fertilizers recommended in the turfgrass green soil of golf course.

Studies on Ion-exchange Chromatography of Elements in Special Nonferrous Alloys (비철특수합금에서 금속원소의 이온교환 크로마토그라프에 관한 연구)

  • Kyung Woong Lee;Young Jin Yoo
    • Journal of the Korean Chemical Society
    • /
    • v.29 no.2
    • /
    • pp.178-182
    • /
    • 1985
  • The purpose of this study was to develop a separation method of Zn(II), Cu(II) and Mg(II), by ion exchange chromatography using cation exchange resion (Dowex 50w${\times}$8, 80-100 mesh) and anion exchange (Amberlite IRA-400). Ion exchange resions were packed into 25 ${\times}$ 2cm ID column and flow rate was controlled to 0.30 ml/min. Good eluents for separation of nonferrous metal ions such as Zn(II), Cu(II), Mg(II) were as follow: 0.5M $NaNO_3$ (pH 3.1), 0.2~0.5M HCl + 50~60% Acetone, and 1M HAc + 0.1M NaAcf(pH 3.7) aqueous solution. The mixed solution of 0.1M NaAc(pH 3.7), 0.5M HCl + 50% Acetone were found to be the best eluent for step elution. Analysis of metals were determined by atomic absorption spectrophotometer. In addition, separated Zn(II) fraction was obtained by eluted with 0.12N HCl and 1.5N $NH_4OH$ aqueous solution. This solution was titrated by the E. D. T. A.

  • PDF

Contents of Minerals and Vitamines in Soybean Sprouts (콩나물의 무기이온 및 비타민 함량)

  • Youn, Jung-Eun;Kim, Hee-Seon;Lee, Kyong-Ae;Kim, Yong-Ho
    • KOREAN JOURNAL OF CROP SCIENCE
    • /
    • v.56 no.3
    • /
    • pp.226-232
    • /
    • 2011
  • Soy sprouts cultured in a lab with five soybean cultivars and three commercial soy sprouts purchased in a market were investigated to compare the mineral and vitamine contents. In case of minerals, K, Ca, Mg, and Na were found as major minerals and a small quantity of Fe, Zn, Mn, and Cu was also analyzed in soy sprout. The all minerals were distributed in the cotyledon and the hypocotyl but their concentration orders were different between in cotyledon and in hypocotyl. After boiling, much of minerals eluted in water, the pattern of release of the minerals from the soy sprout to water was similar in all soy sprouts. The vitamin C was concentrated a great amount in hypocotyl than in cotyledon whereas vitamin B was found in the cotyledon generally. And their contents were reduced after boiling owing to heat-mediated degrading. The vitamin C and B contents were different according to cultivars, which shows chemical composition of soybean seed was important to soy sprout characters. The present results provide a basis for attempt to improve seed quality in soybean breeding program for soy sprout.

The Properties of STS 630 Alloy by Plasma nitriding Treatment (플라즈마질화 처리에 따른 STS630합금의 특성)

  • Jeong, Yong-Ho;Song, Ho-Cheol;Jeong, Yeon-Ok
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2016.11a
    • /
    • pp.138-138
    • /
    • 2016
  • 의료용 공구로 사용되는 합금은 마르텐사이트계 스테인리스강의 대표 강종인 420스테인리스강이 사용되며, 이 합금은 고온의 오스테나이트 상태에서 ?칭하면 마르텐사이트 조직으로 변태하여 현저하게 경화하는 특징을 가지고 있으며, 오스테나이트화 후 템퍼링시 우수한 기계적 성질이 얻어진다. 그러나 템퍼링 온도의 영향으로 석출탄화물이 형성되어 기계적 성질이나 내식성이 저하되는 단점이 있다. 본 연구에서는 STS 420스테인리스강의 템퍼링 온도에 의한 내식성 문제점을 개선시키기 위해 STS630 합금을 사용하여 다양한 석출 열처리 조건 및 플라즈마 질화공정을 연구하였다. 구입한 소재의 균일한 성분 조정을 통한 미세 편석 및 물성부여를 위한 균질화 조건 도출 열처리를 실시하였으며, STS630의 고용화열처리는 오스테나이트 균일조직이 되는 온도영역으로 가열하여 급냉하는 것으로 마르텐사이트 변태시키는 열처리를 진행하였으며, 열처리온도는 $1020{\sim}1060^{\circ}C$로 설정하였다. 석출경화 열처리는 $460{\sim}480^{\circ}C$$500{\sim}520^{\circ}C$의 온도에서 실시, 제품에 따른 인성을 부여하였으며, 질화공정은 플라즈마 장비를 이용하여 플라즈마 가열 ${\rightarrow}$플라즈마 이온질화를 통하여 가장 최적의 공정을 도출하였다.- 질화가 마무리 된 시료는 내식성 및 물성 평가를 통해 제품으로서의 특성을 평가하였다. 석출경화 열처리에 의해 STS420합금에 버금가는 인장강도 및 경도값이 나타났으며, 플라즈마 질화에 따라 물성 값의 향상이 나타났다. 용출실험결과 STS420합금의 경우 Fe, Cr원소의 용출이 나타나며 변색이 형성되었으나 STS630합금의 경우 그 현상이 미미하였다.

  • PDF

A Simplified Procedure for the Large-Scale Purification of Urokinase from Human Urine (인뇨로부터 유로키나제 대량정제공정의 단순화)

  • 정광회;선우명
    • KSBB Journal
    • /
    • v.5 no.2
    • /
    • pp.183-189
    • /
    • 1990
  • An efficient method has been developed for the purification of urokinase from 1, 000 liter batches of human urine. The procedure involved precipitation of urokinase with 2mM zinc chloride, resuspension of the precipitate with 0.1M EDTA/0.5M Glycine solution, and CM-Toyopearl and benzamidine-Sepharose column chromatography. The purified urokinase was fully active and possessed a specific activity of 1.07$\times$105IU/mg. The recoveries ranged from 42 to 65% in several preparations(mean value was 51%). And the urokinase purified by this process consisted of about 13% of single chain urokinase (pro-urokinase) as evaluated by SDS-polyacrylamide gel electrophoresis in reducing condition and by S-2444 amldolytic activity under plasmin treatment.

  • PDF