• Title/Summary/Keyword: 이산화황 농도

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The Analysis of Time Series of SO2 Concentration and the Control Factor in An Urban Area of Yongsan-gu, Seoul (서울시 용산구 지역에 이산화황 농도의 시계열 변동과 영향인자 분석)

  • Kim, Bo-Won;Kim, Ki-Hyun
    • Journal of the Korean earth science society
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    • v.35 no.7
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    • pp.543-553
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    • 2014
  • The environmental behavior of $SO_2$ was investigated in terms of the factors affecting the temporal variabilities by analyzing the data sets obtained from the Yongsan district in Seoul from 2004 till 2013. To this end, the relationship between $SO_2$ and relevant parameters including particulate matters (such as $PM_{2.5}$, $PM_{10}$, and TSP (total suspended particulates)) and gaseous components ($CH_4$, CO, THC (total hydrocarbon), NMHC (non-methane hydrocarbon), NO, $NO_2$, NOx, and $O_3$) was investigated in several aspects. Over a decade, the annual mean concentrations of $SO_2$ varied in the range of $4.36-5.86nmole\;mole^{-1}$ (min-max) which was about five times lower than the regulation guideline set for the air quality management in Korea. In fact, this pattern greatly contrasts with some other air pollutants of which concentrations exceeded their guideline values significantly. According to our analysis, $SO_2$ was strongly correlated to the temperature and other relevant parameters. The overall results of this study confirm that the administrative regulation of $SO_2$ levels has been made effectively relative to other airborne pollutants.

Concentration of $NO_2$ and $SO_2$ of Underground Shopping Center in Chonan City (천안시내 지하상가의 이산화질소 및 이산화황 농도)

  • 손부순;장봉기
    • Journal of environmental and Sanitary engineering
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    • v.15 no.1
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    • pp.102-108
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    • 2000
  • Seasonal variation of $NO_2$ and $SO_2$ concentration was investigated at the underground shopping center in Chonan from October 1997 to August 1998. $NO_2$ and $SO_2$ was collected by personal air sampler at $0.4{\ell}/min$ and $0.5{\ell}/min$ respectively and analyzed using UV spectrophotometer at 550nm and 548nm individually. The results were as follows. 1. The concentration of $NO_2$ was 0.070 ppm in spring, 0.068 ppm in summer, 0.074 ppm in autumn and 0.085 ppm in winter. There was no significant difference. 2. The concentration of $SO_2$ was 0.0233 ppm in spring, 0.0216 ppm in summer, 0.0188 ppm in autumn and 0.0621 ppm in winter. There was significant difference (p<0.01). 3. The higher concentration of $NO_2$ and $SO_2$ gases were shown near the cafeteria (p<0.001, p<0.05). 4. The higher concentration of $NO_2$ was observed at indoor than the underground passage. There was significant difference between two values (p<0.01).

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Characteristics of Atmospheric Dry Deposition of Nitrogen-containing Compounds (대기 중 질소산화물의 건식침적 특성)

  • Yi, Seung-Muk;Han, Young-Ji;Cheong, Jang-Pyo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.775-784
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    • 2000
  • Nitrate dry deposition fluxes were directly measured using knife-leading-edge surrogate surface (KSS) covered with greased strips and a water surface sampler (WSS). The average gaseous flux ($8.3mg/m^2/day$) was much higher than the average particulate one ($3.0mg/m^2/day$). The best fit gas phase mass transfer coefficient (MTC) of $HNO_3$ was obtained by linear regression analysis between measured gaseous flux containing nitrogen compounds and measured ambient $HNO_3$ concentration. The result showed that the MTCs of $HNO_3$ were approximately two times higher than those of $SO_2$. Especially, during the ozone action day, measured gaseous fluxes containing nitrogen compounds were much higher than those ones calculated as the product of measured ambient $HNO_3$ concentration and gas phase MTC of $HNO_3$, which is calculated from MTC of $SO_2$ using Graham's diffusion law. This result indicated that other nitrogen compounds except $HNO_3$ contributed to gaseous flux containing nitrogen compounds into the water surface sampler. The theoretical calculations suggest the contributions of nitrous acid ($HNO_2$) and PAN to the gaseous dry deposition flux of nitrogen containing compounds to the WSS.

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SO2 Concentrations and Health Damages under Alternative US-EPA Policies (US-EPA 정책하에서의 SO2 농도와 건강피해)

  • Hlasny, Vladimir
    • Environmental and Resource Economics Review
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    • v.18 no.3
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    • pp.393-430
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    • 2009
  • This study uses a computable partial-equilibrium model of the U.S. energy industry to evaluate sulfur dioxide concentrations under two environmental policies. The policies, generator-level emission caps and tradable allowances, are selected to yield identical aggregate emissions. Regional concentrations are found to vary across the two policies significantly. These variations translate into different losses for individual states, and, nationwide, to differences of hundreds of millions of dollars in aggregate health damages. Emission caps outperform allowances by $452 million. Caps favor the southwestern, south-central and southeastern states, where they deliver $840 million lower damages than the other policies, while they deliver $390 million higher damages In northern and northeastern states.

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A Study on the Prediction of SO2 Concentration in local Circulation of Mesoscale (중규모 국지순환에서 이산화황의 농도예측에 관한 연구)

  • Lee, Hwa-Woon;Kim, Yoo-Keun;Jang, Eun-Suk
    • Journal of Environmental Science International
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    • v.5 no.3
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    • pp.277-284
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    • 1996
  • The Characteristics of atmospheric flow and dispersion of air pollutants in the mountainous coastal area were studied using two-dimensional model by the combination of land-sea breezes and transport. The pollutants emitted into the simulated wind field in considering with the mesoscale local circulations. The typical effects of land-sea breezes and tophography of coastal area on the dispersion are discussed in detail, and the model is proved as an useful tool to pridict real time pollutant transport by the results of application studies in Pusan, Korea where the urbanized coastal area with mountainous topography. It was found that sulfur dioxide ($SO_2$) are differently transported and concentrated as going inland by the influence of the sea breeze with topographic changes. Key words : land-sea breezes, sulfur dioxide, dispersion, coastal area.

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Perspectives on the 210-m super tower for the monitoring air pollution and meteorological changes at high elevation (대기환경 및 기상관측용 다목적 초고층 (210 미터) 타워의 건설과 전망)

  • Kim, Min-Young;Kim, Gi-Hyun;Kim, Jun;Lee, Gang-Woong
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.04a
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    • pp.79-80
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    • 2002
  • 지난 수 십여년에 걸쳐 대기질 관리를 위해 시도된 범국가적 또는 범국제적 차원의 노력에 힘입어, 일반적으로 대기질을 평가하는 보편적인 지표로 간주되는 기준성 오염물질들의 계량적인 수치자료들은 괄목할 만한 개선효과를 확인시켜 주고 있다. 특히 기기적으로 검출한계 이하의 관측자료가 양산되는 이산화황 (SO$_2$) 또는 규제기준에 접근하기 어려울 정도로 낮은 농도에서 관측되는 납 (Pb) 성분 등의 시간적 저감양상은 이러한 노력의 큰 결실로 지목할 수 있다. 이와 같은 대기질 개선의 노력에도 불구하고, 아직까지 많은 사람들이 체감하는 대기질에 대한 평가는 상당 수준 부정적으로 남아 있다. (중략)

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Analysis of statistical models for ozone concentrations at the Paju city in Korea (경기도 파주시 오존농도의 통계모형 연구)

  • Lee, Hoon-Ja
    • Journal of the Korean Data and Information Science Society
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    • v.20 no.6
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    • pp.1085-1092
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    • 2009
  • The ozone data is one of the important environmental data for measurement of the atmospheric condition of the country. In this article, the Autoregressive Error (ARE) model and Neural Networks (NN) model have been considered for analyzing the ozone data at the northern part of the Gyeonggi-Do, Paju monitoring site in Korea. In the both ARE model and NN model, seven meteorological variables and four pollution variables are used as the explanatory variables for the ozone data set. The seven meteorological variables are daily maximum temperature, wind speed, relative humidity, rainfall, dew point temperature, steam pressure, and amount of cloud. The four air pollution explanatory variables are Sulfur dioxide ($SO_2$), Nitrogen dioxide ($NO_2$), Cobalt (CO), and Promethium 10 (PM10). The result showed that the NN model is generally better suited for describing the ozone concentration than the ARE model. However, the ARE model will be expected also good when we add the explanatory variables in the model.

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Toxicity Evaluation of the Combustion Products from Synthetic Wood as Internal Finish (건축물 내부 마감재인 합성목재별 연소가스 독성평가)

  • Kim, Jong-Buk;Lee, Si-Young
    • Fire Science and Engineering
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    • v.30 no.2
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    • pp.7-18
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    • 2016
  • This study evaluated the toxicity of the burning gas from the synthetic wood products used in housings or warehouses. The combustion products of five materials, viz. impregnated laminated board, MDF, Douglas fir plywood, core plywood, and Lauan retardant, were analyzed using SEM, FTIR and a Cone Calorimeter. For the Lauan retardant, 256,965 ppm of carbon dioxide ($CO_2$) and 1,475 ppm of sulfur dioxide ($SO_2$) were measured, which are 2.5 times and 3.6 times as high as their lethal concentrations of 100,000 ppm and 400 ppm, respectively. For the impregnated laminated board, 1,569 ppm of nitrogen dioxide ($NO_2$) was measured, which is 6 times as high as its lethal concentration of 250 ppm. For MDF, 795 ppm of ammonia ($NH_3$) was measured, which is higher than its lethal concentration of 750 ppm. As a result, most internal-finishes generated toxic combustion products at levels higher than their lethal concentrations, which underlines the importance of the selection and manufacturing of internal-finish materials.

Atmospheric Acidic Deposition: State of Acid Rain in Korea and the World (대기산성강하물: 한국과 세계의 산성비 실태)

  • Kim, Joon-Ho
    • The Korean Journal of Ecology
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    • v.28 no.3
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    • pp.169-180
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    • 2005
  • Nitrogen dioxide concentration was being grown ca. 8% per year although sulphur dioxide concentration was being reduced ca. 10% per year in Seoul from 1996 to 2003. The rainwater was heavily acidic with pH 4.19 to 4.68 in Seoul during 1980 to 1991. Acidity score on the basis of the total anion concentration of rainwater follows the higher in sequence with Seoul(Kwanaksan)(341.5 ${\mu}equiv{\cdot}L^{-1}$), Gwangneung(199.2 ${\mu}equiv{\cdot}L^{-1}$) and whole Korea mean(10.3 ${\mu}equiv{\cdot}L^{-1}$). Rainwaters from 38 sampling sites of 16 countries in the world, on the basis of the acidity score, are classified and designated as five acid rain grades(ARG): the least score is founded in Tana Rata(16.2 ${\mu}equiv{\cdot}L^{-1}$), Malaysia where has the best rain but the greatest founded in Chongquing(541.1 ${\mu}equiv{\cdot}L^{-1}$), China where has the worst rain in the world. Even though acidic deposition decrease with time in the world generally, it is expected to increase in Asia, Africa and Mid-South America.

Effect of Aeration Rates on Emissions of Oxygen and Sulfur compound gases during Composting of Dairy Manure (우분(牛糞) 퇴비화시(堆肥花時) 공기주입률(空氣注入率)이 산소 및 황화합물 가스 배출(排出)에 미치는 영향(影響))

  • Kang, Hang-Won;Zhang, Ruihong;Rhee, In-Koo
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.6
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    • pp.472-481
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    • 2000
  • This experiment used the enclosed bench-scale reactors was conducted to find out optimal aeration rate for reducing the emission of odors and producing the good-quality compost with the mixture of dairy manure and rice straw. The reactors with gas sampler were aerated at four different rates of 0.09, 0.18, 0.90 and $1.79l\;min^{-1}kg^{-1}$dry solids for 574 hours. The oxygen content within composting pile instantly decreased after aeration. Oxygen limitation(below 15%) in the treatments of $0.90l\;min^{-1}kg^{-1}$ and less was exponentially negative relationship with aeration rates and in the range of 35 to 300 hours after aeration. However, the treatment of $1.79l\;min^{-1}kg^{-1}$ didn't show the oxygen limitation. The oxygen consumption rate and the cumulative amount of oxygen consumed by different aeration rates was ranged in $0.80{\sim}1.57O_2g\;h^{-1}\;kg^{-1}VS^{-1}$, $460{\sim}900O_2g\;kg^{-1}VS^{-1}$, respectively, and they were high in the order of 0.90, 1.79, 0.18, $0.09l\;min^{-1}kg^{-1}$. The maximum oxygen consumption rate was estimated in the range of $1.2{\sim}1.3lmin^{-1}kg^{-1}$. The emission concentrations of sulfur compounds such as hydrogen sulfide, sulfur dioxide and methylmercaptan were remarkably high in the initial composting time. Then they were rapidly decreased with the passing of composting time and clearly with increasing aeration rates. Their average concentrations were in the range of 0.03~2.18, 0~0.50, $0.07{\sim}3.38mg\;kg^{-1}$, respectively and high in the order of methylmercaptan, hydrogen sulfide, and sulfur dioxide. Concentrations of sulfur compounds emitted from composting showed exponentially negative relationship at 1% statistically with the oxygen concentration. It was estimated that hydrogen sulfide and methylmercaptan suddenly increased in the level of 5% oxygen concentration and below, that they were little emitted in 15% and over but sulfur dioxide was emitted in the level of 20% oxygen.

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