• Economic and Environmental Geology
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• v.47 no.6
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• pp.625-633
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• 2014

The Aquistore project is the world's first commercial capture, transportation, utilization and storage project of post-combustion $CO_2$ from a coal-fired thermo electric power plant, and the proposed storage is a saline aquifer at a depth of about 3,500 m. Deep saline aquifer, compared to hydrocarbon reservoir, provides the great volumetric potential for storage of $CO_2$ anywhere in the world, therefore the research results from the project may be exported globally to other sites. Geological $CO_2$ storage characterization for saline aquifer instead of hydrocarbon reservoir needs to estimate the geophysical properties of subsurface geology. This study calculated the geophysical property of water-saturated formation by applying amplitude variation analysis developed from oil and gas exploration. We correlated horizon tops at the well logs to seismic traveltime of 1,815 and 1,857 ms as Winnipeg and Deadwood formations. Gradient analysis from seismic traces showed correlation coefficient of 45 - 81 % on amplitude variation with respect to incident angle. Crossplot of intercept and gradient shows the inverse proportional trend which represents typical water saturated sediments. Product attribute of intercept and gradient described the base of wet sediment. Poisson's ratio change attribute increased at the top of target area satisfying with wet sediment and decreased at the top of basement in a dry rock bed.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2018.05a
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• pp.234-236
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• 2018

기후변화는 더 이상 피할 수 없는 매우 중요한 문제다. 온실가스 중 큰 비중을 차지하는 이산화탄소 배출을 억제하거나 제거하기 위한 많은 연구들이 진행되고 있다. 최근에는 CCS 중 하나인 지중저장(underground storage)의 대안으로 해양에 이산화탄소를 저장하는 기술인 AWL(Accelerated Weathering of Limestone)을 이용한 해양저장(ocean storage)에 대한 연구가 진행되고 있다. AWL은 이산화탄소를 중탄산이온 형태의 농축수로 만들어 해양에 방류하여 희석 저장시키는 방법으로, 대기 중 재방출이 거의 발생하지 않고 배출된 농축수는 해양의 알칼리도를 높여 해양산성화를 방지할 수 있는 장점이 있다. 금회 연구는 AWL에 의한 방법 중 중탄산이온 농축수의 해양방류 시 이산화탄소 등을 포함하는 용존 무기탄소(DIC, Dissolved Inorganic Carbon)의 거동특성을 파악하기 위한 목적으로 수행하였다. 연구대상 해역은 충분한 수심과 작업효율성이 확보되는 울릉도 부근으로 설정하였으며, 거동특성을 파악하기 위하여 표층방류(surface discharge)와 수중방류(submerged discharge)에 의한 물질확산을 계산할 수 있는 CORMIX모형을 채택하였다. 실험결과, 방류 시점으로부터의 희석률을 고려했을 때, 표층방류 시나리오가 농축수 방류에 가장 적합한 방식이라고 사료된다.

• Food Science and Preservation
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• v.6 no.2
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• pp.153-160
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• 1999

This study was carried out to investigate the production of C$_2$H$_4$ and CO$_2$, and the change of flesh firmness and peel color in 'Fuji' apples during CA storage. ACC oxidase activity was more inhibited by the low O$_2$ concentration, and the low level of internal C$_2$H$_4$ in apples was maintained under the low O$_2$ conditions during 8 months storage. Especially, the level of internal C$_2$H$_4$ in apples was maintained below 1 ppm during storage under 1% O$_2$+1% CO$_2$ at 0$^{\circ}C$, and not much changed for 7 days in air at 20$^{\circ}C$ after storage. The influence of CO$_2$ on the C$_2$H$_4$ production was dependent on the O$_2$ concentration. Increasing of CO$_2$ concentration with 3% O$_2$ decreased the C$_2$H$_4$ Production during storage, but that with 1% O$_2$increased. Internal C$_2$H$_4$ concentration and the rate of CO$_2$ evolution in apples showed the close correlation. Internal CO$_2$ concentration of apples was positively related to the rate of CO$_2$ evolution and maintained the lower level in 1% O$_2$+1% CO$_2$ than the other conditions during storage but nu different in the increment after storage. The relationship between C$_2$H$_4$ and CO$_2$ production was exhibited in CA and the short-term air stored apples, but not in the long-term air stored apples. Loss of flesh firmness and green color in apples was more less in storage condition retarded effectively the production of C$_2$H$_4$ and CO$_2$.

• Plant Journal
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• v.9 no.2
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• pp.42-45
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• 2013

The worldwide issue of greenhouse gas reduction has recently drawn great attention to carbon capture and storage(CCS). In this study, we developed a 10,000 ton/year pilot injection plant for geological storage of carbon dioxide. Major components of the pilot plant include a pressure pump, a booster pump, and an inline heater to bring liquid carbon dioxide into its supercritical state. The test results show that the pilot plant readily achieves the injection pressure and temperature, showing satisfactory control performance. The overall power consumption is 2,000 ~ 2,500 W, more than 75% of which consumed by the pressure pump. This study will facilitate varied research on greenhouse gas reduction as the only domestically developed system for geological injection.

• Korean Journal of Food Science and Technology
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• v.31 no.5
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• pp.1295-1299
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• 1999

This study was conducted to develop a index for the judgment of suitability of storage conditions by internal gas concentration of 'Fuji' apples under CA storage, and was examined the relationship between the levels of quality characteristics(flesh firmness, titratable acidity and surface green color) and the infernal ethylene and carbon dioxide concentrations of apples. The levels of quality characteristics were not decreased for terms of storage when the infernal ethylene concentration of apples was below 10 ppm, but the levels of quality characteristics were sharply decreased when it was above 10 ppm of Internal ethylene. The high levels of quality characteristics were maintained by the lower internal carbon dioxide concentration of apples, especially at below 2% of internal carbon dioxide. These result showed that the suitable condition for CA storage of 'Fuji' apples was a condition for having below 10 ppm of internal ethylene and below 2% of internal carbon dioxide in apples. The internal ethylene and carbon dioxide concentrations of apples during CA storage can be used as a crucial index for the suitability judgment of storage conditions.

• Tunnel and Underground Space
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• v.26 no.4
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• pp.293-303
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• 2016

Underground $CO_2$ storage technology is one of the most effective methods to reduce atmospheric $CO_2$. In this study, $CO_2$ storage condition was simulated in the laboratory. Sandstone and shale specimens were saturated in 1M NaCl and were reacted at $45^{\circ}C$, 10 atm for 4 weeks. The physical and microstructural properties of rock specimens were measured. Variations on physical properties of shale specimens were bigger than those of sandstone specimens, such as volume, density, elastic wave velocity, Poisson's ratio and Young's modulus. Microstructure were analyzed using X-ray computed tomography. Total number of pores were decreased, and average volume, average area and average equivalent diameter of each pore were changed after $CO_2$ reaction. Swelling and leakage of clay mineral caused by $CO_2$-mineral reaction were the reason of changes. The results of this study can be applied to predict the physical and microstructural changes in underground $CO_2$ storage condition.

• Tunnel and Underground Space
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• v.26 no.3
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• pp.181-191
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• 2016

In geological storage of $CO_2$, the behavior of $CO_2$ is influenced by pore network of rock. In this study, the drilling cores from Pohang Basin were analyzed quantitatively using three-dimensional images acquired by X-ray micro computed tomography. The porosities of sandstone specimens around 740 m-depth (T1), 780 m-depth (T2) and 810 m-depth (T3) which were target strata were 25.22%, 23.97%, 6.28%, respectively. Equivalent diameter, volume, area, local thickness of pores inside the sandstone specimens were analyzed. As a result, the microstructural properties of T1 and T2 specimens were more suitable for geological storage of $CO_2$ than those of T3 specimens. The result of the study can be used as input data of the site for decision of injection condition, flow simulation and so on.

• Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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• 2003.10a
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• pp.189.1-189
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• 2003

‘부유’단감은 국내에서는 일반화되어 있는 PE필름 밀봉 저장방식으로 과실의 호흡에 의해 산소농도의 감소와 이산화탄소의 증가로 호흡이 억제되고 이에 따라 노화가 지연됨으로 과실의 저장수명을 증가시키는 방식이며, 최적저장온도는 -0.5~$0^{\circ}C$라고 보고되고 있다. 이에 본 실험에서는 상온유통을 고려하여 2$0^{\circ}C$에서 0.03mm, 0.05mm LDPE필름으로 포장한 경우와 무포장한 경우를 비교하여, 중량, 수소이온농도, 가용성고형분, 경도를 측정하고 이를 외관품질검사 결과와 종합적으로 검토하였으며, 또한 환경기체조성의 범위를 설정하기 위하여 산소농도(1~5%), 이산화탄소농도(5~15%)를 독립변수로 중심합성계획법(central composite design)에 의해 3단계로 부호화하였고 산소소비농도, 이산화탄소 발생속도, pH 당도, 경도를 종속(반응)변수로 결과를 이용하여 독립변수와 종속변수간의 함수관계를 규명하며, 독립변수들의 값의 변화에 따라서 반응량(종속변수)이 어떻게 달라지는 가를 예측하며, 독립변수가 종속변수인 반응량을 최적화(Optimize) 하는가와 어떤 실험계획법을 쓰면 가장 좋은 정도를 얻을 수 있는지를 규명하고자 한다.

• Economic and Environmental Geology
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• v.45 no.1
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• pp.41-48
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• 2012

A theoretical $CO_2$ storage capacity is estimated on the southwestern continental shelf margin of Ulleung Basin, offshore Korea using 2D/3D multi-channel seismic and wellbore data acquired in the area over the two decades since the late 1980s. For the first time in Korea, the present study applies an efficiency factor to the capacity calculation, together with the other required parameters. For possible $CO_2$ storage volume estimation of the study area, we interpreted the seismic data in the Gorae area from 800 m to 3,000 m below the seafloor integrated with the well data, and identified five different seismic units; the limited depth interval is considered because of fluid state of $CO_2$ and tightness of the formation. The total volumes of each seismic unit were converted with a time-depth relation inferred from the checkshot surveys before the other required parameters including porosity and density were applied to compute the potential storage capacity. The accumulated possible storage volume from the five depositional units in the study area is estimated to be approximately 5,100 Mton ($P_{50}$). The approaches made in this study will be applied to the rest area of the basin and other continental shelves (i.e., Yellow Sea and northern part of East China Sea) in the next phase.

• 한국지구물리탐사학회:학술대회논문집
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• 2008.10a
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• pp.141-144
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• 2008

Geological storage of carbon dioxide has been studying in advanced countries to reduce greenhouse gases and a pilot site for geological storage is also in operation in the deep saline aquifer. Seismic wave and electrical resistivity tomography methods are applicable to monitoring techniques and they are used to evaluate the distribution range and behavior of the carbon dioxide injected in the porous sandstone formations. This paper describes the construction of an experimental apparatus which consists of a high pressure vessel and a measurement system for geological storage of carbon dioxide. The experiment apparatus will be used to measure seismic velocities and resistivities during the injection of carbon dioxide at the supercritical phase in the porous sandstones.