• Title/Summary/Keyword: 이산화탄소($CO_2$) 배출량

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Water Gas Shift reaction research of the synthesis gas for a hydrogen yield increase (수소 수율 증가를 위한 합성가스의 수성가스전환 반응 연구)

  • Kim, Min-Kyung;Kim, Jae-Ho;Kim, Woo-Hyun;Lee, See-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.840-843
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    • 2009
  • 폐자동차의 최종처분 과정에서 발생하는 자동차 파쇄 폐기물(Automobile Shredder Dust)은 대부분이 고분자 화합물로 높은 발열량을 가지고 있다. 또한 할로겐족 원소가 포함된 난연성 고분자류가 많아 다이옥신의 생성 우려가 높은 고분자류와 다이옥신 생성의 촉매 역할을 할 수 있는 금속성분이 많이 함유되어 있어 가스화용융시스템에 적용하여 처리하기에 매우 적합한 폐기물이다. 본 연구에서는 ASR의 가스화 용융 시설에서 고농도 CO를 함유한 합성가스를 수성가스전환반응(Water Gas Shift reaction, WGS)을 이용하여 수소의 수율을 높이는 기술을 제시하였다. 가스화 용융 설비에서 배출되는 합성가스 조성을 기준으로 적합한 고정층 WGS 반응기를 설계하고, 고온 촉매(KATALCO 71-5M)와 저온 촉매(KATALCO 83-3X)를 사용하여 실험하였다. 수성가스 반응 후의 가스 조성은 온도가 상승할수록 일산화탄소가 줄어들고 이에 따라 수소와 이산화탄소 발생량이 증가 되어 고온 촉매를 사용했을 경우 일산화탄소 전환율 ($1-CO_{out}/CO_{in}$)은 55.6에서 95.8%까지 상승하였다. 동일한 온도조건에서는 촉매에 관계없이 $CO/H_2$가 감소할수록 전환율도 감소하는 경향을 보였지만 동일한 합성가스 조성에서 일산화탄소 전환율을 비교하면 저온 촉매가 고온 촉매보다 매우 우수함을 알 수 있었다.

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Recent Development of Carbon Dioxide Conversion Technology (이산화탄소 전환 기술의 현황)

  • Choi, Ji-Na;Chang, Tae-Sun;Kim, Beom-Sik
    • Clean Technology
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    • v.18 no.3
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    • pp.229-249
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    • 2012
  • At present, global warming and depletion of fossil fuels have been one of the big issues which should be solved for sustainable development in the future. CCS (carbon capture and sequestration) technology as the post $CO_2$ reduction technology has been considered as a promising solution for global warming due to increased carbon emission. However, the environmental and ecological effects of CCS have drawn concerns. There are needs for noble post reduction technology. More recently, CCU (carbon capture and utilization) Technology, which emphasizes transforming carbon dioxide into value-added chemicals rather than storing it, has been attracted attentions in terms of preventing global warming and recycling the renewable carbon source. In this paper, various technologies developed for carbon dioxide conversion both in gas and liquid phase have been reviewed. For the thermochemical catalysis in gas phase, the development of the catalytic system which can be performed at mild condition and the separation and purification technology with low energy supply is required. For the photochemical conversion in liquid phase, efficient photosensitizers and photocatalysts should be developed, and the photoelectrochemical systems which can utilize solar and electric energy simultaneously are also in development for more efficient carbon dioxide conversion. The energy needed in CCU must be renewable or unutilized one. CCU will be a key connection technology between renewable energy and bio industry development.

Study on the Reduction of NPS Pollution and GHG Emission from Paddies with SRI Methods (SRI 방법을 적용한 논에서의 비점오염원 및 온실가스 저감효과)

  • Park, Woon-Ji;Lee, Su-In;Yun, Dong-Koun;Kim, Gun-Yeob;Choi, Joong-Dae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.440-440
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    • 2012
  • 본 연구에서는 수질관리 및 기후변화(온실가스 저감) 등에 부응할 수 있는 SRI 벼재배 방법을 국내 논에 적용하여 농업비점오염원과 온실가스 저감효과를 측정하고 비교하여 SRI의 환경개선효과를 평가하고자 하였다. 시험포는 대조구인 상시담수처리구(관행, 재식거리 $30{\times}15cm$)와 SRI 물관리 처리구로 조성하였다. 각 시험포에는 관개배수시설 및 관개량을 측정할 수 있는 수도계량기, 유출량 측정을 위한 플륨 및 수위계 그리고 온실가스(메탄 및 이산화질소)를 측정하기 위한 아크릴재질의 Chamber를 설치하였다. 관행 및 SRI 시험포에 이앙할 모의 재배품종으로 오대벼를 공시하고 모든 시험포의 경우 1주당 3-5본씩 기계이앙을 실시하였으며, 물관리를 제외한 시비와 제초 등의 영농관리는 동일하게 수행하였다. 메탄($CH_4$)과 아산화질소($N_2O$)는 주 2회, 오전 9시 12시에 60 mL 주사기로 주기적으로 시료를 채취하여 GC로 분석하였다. 그리고 관개기간동안 관개량, 강우량 그리고 강우 유출량을 측정하고 수질시료를 채취하여 오염부하를 산정하였다. SRI 시험포의 SS, $COD_{Cr}$, $COD_{Mn}$, BOD, TN, TP의 총 오염부하량은 각각 583 kg/ha, 210.8 kg/ha, 70.1 kg/ha, 30.7 kg/ha, 56.1 kg/ha, 3.55 kg/ha로서 관행 시험포의 오염부하량에 비해 27.1~46.0%의 오염물질 저감 효과를 보였다. 그리고 각 시험포별 온실가스 메탄과 아산화질소의 총 배출량을 지구온난화잠재력(GWP)으로 환산하여 이산화탄소($CO_2$) 기준으로 산정한 결과, 관행은 14.2 톤/ha 그리고 SRI 물관리 처리구 4.0 톤/ha로 관행 대비 SRI 처리구에서 71.8%의 온실가스 감축효과를 나타내었다. 따라서 SRI 벼재배기술은 논 비점오염부하 및 온실가스 저감을 위한 효과적인 최적영농관리방법인 것으로 판단된다.

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A Prototype of Demand Response System for Reducing Electric Power Load (전력수요관리를 위한 Demand Response시스템 구현)

  • Heo, Byeong-Mun;Ko, Jong-Min;Kim, Young-Il;Song, Jae-Ju;Ryu, Keun-Ho
    • Proceedings of the Korean Information Science Society Conference
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    • 2010.06c
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    • pp.132-137
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    • 2010
  • 이 논문에서는 전력기기의 사용량증가에 따른 전력량 부족으로 전력공급확보에 필요한 인원, 자재, 비용 등의 부족과 발전연료비용의 상승, 전력발전에 따른 $CO_2$배출량증가 등의 문제점을 최소화하기 위한 전력관리시스템(Demand Response System)을 제안한다. 전력관리 시스템은 전력사용자와 전력사업자와의 협력을 통해 전력확보와 수요를 관리하기 위한 전력절감 이벤트, 전력사용량 모니터링, 분석 등의 기능을 통하여 전력수요 관리가 가능한 시스템이다. 더 나아가 전력소비 관리가 이루어짐으로써 전력생산량 감소에 따른 이산화탄소의 절감효과를 기대할 수 있을 것이다.

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Effects on CO2 and NOx Emissions at Real Driving Condition in the Passenger Car using Gasoline Fuel with Various Engine Displacements (휘발유 승용자동차의 엔진 배기량이 실도로 주행시 이산화탄소 및 질소산화물 배출에 미치는 영향)

  • Lee, Jongtae;Kim, Hyung Jun;Lim, Yun Sung;Yun, Chang Wan;Keel, Ji Hoon;Hong, You Deug
    • Journal of ILASS-Korea
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    • v.23 no.3
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    • pp.122-127
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    • 2018
  • Recently, registrated passenger cars have increased and were close about seventy million at the end 2017 year in Korea. Among the passenger car using gasoline fuel make up forty six percentage of total registrated vehicles. In this study, investigation on real driving emission characteristics in the passenger car using gasoline fuel with various engine displacements were carried out. The real driving emission characteristics were measured and analyzed by using PEMS (Portable Emission Measurement System). PEMS was composed of gas analyzer, emission flow meter and sample conditioning system et al. Also, test six vehicles were selected to the gasoline passenger car with engine displacement from 1.6L to 3.7L. Two test routes with engine start of cold and hot conditions were applied to analyze the emission characteristics of RDE, respectively. The results show that the $CO_2$ emission have a increasing trend as the engine displacement and vehicle weight. Also, it is guessed that the $CO_2$ emission and vehicle weight were more correlated than the engine displacements. On the other hand, NOx emissions of RDE have not increasing or decreasing tendency according engine displacements or vehicle weight because the activation of three-way catalyst in the gasoline vehicles.

Analysis of Performance and Energy Saving of a SOFC-Based Hybrid Desiccant Cooling System (건물용 연료전지 기반 하이브리드 제습냉방시스템 성능 및 에너지 절감 분석)

  • IN, JUNGHYUN;LEE, YULHO;KANG, SANGGYU;PARK, SUNGJIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.2
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    • pp.136-146
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    • 2019
  • A solid oxide fuel cell (SOFC) based hybrid desiccant cooling system model is developed to study the effect of fuel utilization rate of the SOFC on the reduction of energy consumption and $CO_2$ emission. The SOFC-based hybrid desiccant cooling system consists of an SOFC system and a Hybrid desiccant cooling system (HDCS). The SOFC system includes a stack and balance of plant (BOP), and HDCS. The HDCS consists of desiccant rotor, indirect evaporative cooler, electric heat pump (EHP), and heat exchangers. In this study, using energy load data of a commercial office building and SOFC-based HDCS model, the amount of ton of oil equivalent (TOE) and ton of $CO_2$ ($tCO_2$) are calculated and compared with the TOE and $tCO_2$ generation of the EHP using grid electricity.

Study of the $SO_2$ combustion gases occurring from a livestock waste biogas power system (축산바이오가스발전시스템 가동 시 발생되는 연소 배기가스 중 $SO_2$에 관한 연구)

  • Choi, Jaejoon;Jung, Daehun;Park, Byungsik;Park, Jinsung;Huh, Changsu
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.173.2-173.2
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    • 2011
  • 대체 에너지 자원 중 폐기물의 소화 가스를 이용한 바이오가스 발전은 이산화탄소에 비해 온실효과 영향력에 21배에 해당하는 메탄가스를 연료로 사용하여 환경부하를 저감시키고 에너지를 생산한다. 바이오가스에 포함된 $H_2S$는 연소 후 $SO_2$형태로 발생되는데 $SO_2$는 수분과 반응을 하게 되면 $H_2SO_4$등의 강한 산성을 띄는 물질로 생성되어 배관 및 발전기에 손상을 주고 저온부식현상을 유발하게 하며, 동물이나 인체에 노출되면 기관지 수축현상이 일어나 호흡기에 영향을 주는 질식성을 띄는 가스이다. 축산바이오가스에 포함된 $H_2S$의 함유량과 가스엔진의 연소 시 배출되는 $SO_2$ 배기가스 성분의 관련성을 검증하기 위해 60-65%의 $CH_4$와 30-35%의 $CO_2$ 성분의 바이오가스를 50kW급 발전기에서 사용하였고 연소 후 배출되는 가스 성분을 분석하였다.

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A suggestion on the incentive and penalty based on carbon tax scheme through EEOI results (EEOI 결과에 따른 탄소세 기반 격려금과 벌과금 부과 방안 제시)

  • Park, Go-Ryong;Cho, Kwon-Hae
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.4
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    • pp.323-329
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    • 2017
  • Nowadays, considering global warming and enhanced prohibition to discharge pollutants at sea, all of existing operation-ships must lead to the reduction of fuel consumption. International standards of International Maritime Organization and EU rules governing harbor pollutants are being strengthened. Therefore, ship-owners and operators are seeking ways to reduce $CO_2$, SOx, and NOx emissions. Although world trade continues to expand, total fuel usage for sea transport tends to diminish. However, ICS(International Chamber of Shipping) has set a goal of reducing $CO_2$ emissions from shipping by 50% until 2050. In addition, with respect to the Paris Climate Change Accord in 2015, IMO proposes to set up a reduction target of GHG emission from existing operation-ships. For setting up a reduction target of GHG from international maritime transport, "A data collection system for fuel consumption" will be introduced in the near future. In order to effectively reduce the use of fuel in a ship in accordance with the trend of compulsory fuel saving from operation ships, this paper suggested adoption of an Incentive-Penalty scheme based on Emission-Trading-Scheme, Carbon Tax, and basic calculation formula after verifying the EEOI level for a year.

The Greenhouse-Gas Mitigation Potential analysis by Distribution of Solar Thermal System in Housing Sector (태양열난방시스템 도입에 따른 주거부문에서의 온실가스 감축 잠재량 분석)

  • Jeong, Young-Sun;Mun, Sun-Hye;Yu, Ki-Hyung
    • Journal of the Korean Solar Energy Society
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    • v.32 no.1
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    • pp.32-39
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    • 2012
  • New and renewable energy systems(solar thermal system, photovoltaic system, geothermal system, wind power system) are environmentally friendly technologies and these in South Korea are very important measures to reduce greenhouse-gas(GHG) and to push ahead with Green Growth. The purpose of this paper is to analyze GHG mitigation potential by distribution of solar thermal system in housing sector with bottom-up model called 'Long-range Energy Alternative Planning system'. Business as usual(BAU) was based on energy consumption characteristic with the trend of social-economic prospects and the volume of housing. The total amount of GHG emission of BAU was expected to continuous increase from 66.0 million-ton $CO_{2e}$ in 2007 to 73.1 million-ton $CO_{2e}$ in 2030 because of the increase of energy consumption in housing. The alternative scenario, distribution of solar thermal system in housing sector had GHG mitigation potential 1.54 million-ton $CO_{2e}$ in 2030. The results of this study showed that new and renewable energy systems made a contribution of reducing the use of fossil fuel and the emission of greenhouse-gas in building.

Global Trend of CO2 Capture Technology Development (이산화탄소 포집기술 국외 기술개발 동향)

  • Baek, Jeom-In
    • KEPCO Journal on Electric Power and Energy
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    • v.2 no.2
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    • pp.143-165
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    • 2016
  • The amount of greenhouse gas emission reduction based on INDCs (Intended Nationally Determined Contributions) submitted to UN by each party is not sufficient to achieve the Paris Agreement's aim to "hold the increase in the global average temperature to well below $2^{\circ}C$ above pre-industrial levels and to pursue efforts to limit the temperature increase to $1.5^{\circ}C$" which was determined in the $21^{st}$ Conference of the Parties to the UNFCCC (COP 21). Accordingly, the emission reduction target of each party will be revised for the $2^{\circ}C$ goal. Among the several options to reduce the carbon emission, CCS (Carbon Capture and Storage) is a key option to curb $CO_2$ emissions from large emission sources such as fossil-based power plants, cement plants, and steel production plants. A large scale CCS demonstration projects utilizing $1^{st}$ generation $CO_2$ capture technologies are under way around the world. It is anticipated, however, that the deployment of those $1^{st}$ generation $CO_2$ capture technologies in great numbers without government support will be difficult due to the high capture cost and considerable increase of cost of electricity. To reduce the carbon capture cost, $2^{nd}$ and $3^{rd}$ generation technologies are under development in a pilot or a bench scale. In this paper, current status of large scale CCS demonstration projects and the $2^{nd}$ and $3^{rd}$ generation capture technologies are summarized. Novel capture technologies on wet scrubbing, dry sorbent, and oxygen combustion are explained in detail for all capture areas: post-combustion capture, pre-combustion capture, and new combustion technologies.