• Title/Summary/Keyword: 이동경화

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Preparation and Properties of Flame Retardant Epoxy Resins Containing Phosphorous/Silicone Components (인/실리콘 함유 난연성 에폭시 수지의 제조 및 물성)

  • Kim, Chang-Heon;Ha, Do-Young;Lee, Young Hee;Lee, Dong-Jin;Kim, Han-Do
    • Clean Technology
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    • v.23 no.4
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    • pp.378-387
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    • 2017
  • To obtain epoxy resin with permanently attached flame-retardant groups, phosphorus compound containing di-hydroxyl group [10-(2,5-dihydroxyphenyl)-9,10-dihydro-9-oxa-10-phospha phenanthrene-10-oxide, DOPO-HQ] and silicone compound containing di-hydroxyl group (polydimethylsiloxane, hydroxyl terminated, PDMS) were reacted with uncured epoxy prepolymer (diglycidyl ether of bisphenol A, DGEBA) and then cured using 4,4-diaminodiphenylmethane (DDM) as a crosslinking agent. The properties of the resulting epoxy materials were characterized using Fourier transform infrared (FTIR) spectrometer, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), limiting oxygen index (LOI) test/vertical burning test (UL 94-V test), tensile properties test and impact test. This study examined the effect of phosphorus/silicone compound contents on the thermal/mechanical properties and flame retardancy of cured epoxy resins containing phosphorus and silicone compounds. It was found that the thermal/mechanical properties of epoxy resins containing phosphorus and silicone components were higher than those of simple epoxy resin. The flame-retardancy (LOI: 29.9 ~ 31.8% and UL 94-V: V-0) of all samples containing phosphorus compound and phosphrous compound/silicone compound was found to be passed the flame-retardant requirements (LOI: > 30%, UL 94-V: V-0) of LOI and vertical burning tests. However, the flame-retardancy (LOI: 21.4% and UL 94-V: no rating) of simple epoxy resin was found to be failed the flame-retardant requirements.

Surface Modification of Matrix and filler for Ultra High Density Elastomeric Material (초 고비중 탄성체 개발을 위한 매트릭스 탄성체 표면개질 및 충전제 제어기술 기초연구)

  • Chung, K.;Lee, D.;Yang, K.;Lee, W.;Hong, C.
    • Elastomers and Composites
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    • v.40 no.2
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    • pp.93-103
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    • 2005
  • In this study, surface treatment of the elastomeric matrix was investigated to develop a substituting material for steel dynamic damper of automobile. The key technology is to get ultra high density elastomeric compound in order to substitute steel dynamic damper. The optimum matrix material(chloroprene rubber) and filler(metal powder) were selected for this. The several properties of elastomeric compound were examined. According to the results, the $t_{s2}$ of filled elastomeric compound was decreased with increasing the filler loading whereas the $t_{90}$ was increased. Also, tensile strength and rebound resilience were decreased with filler loading. To solve the problem of high filler loading, the photo grafting technique was employed on elastomeric matrix. The degree of grafting was determined by FTIR-ATR. Also, the filler surface was modified by chemical etching and the surface morphology was examine by SEM. After chemical treatment of filler, the particle size analyzer was used to examined the particle size, size distribution, and morphology of the modified filler.

The Effect of Au Addition on the Hardening Mechanism in Ag-20wt% Pd-20wt% Cu (Ag-20wt% Pd-20wt% Cu 3원합금(元合金) 및 Au첨가합금(添加合金)의 시효경화특성(時效硬化特性))

  • Park, M.H.;Bae, B.J.;Lee, H.S.;Lee, K.D.
    • Journal of Technologic Dentistry
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    • v.19 no.1
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    • pp.21-35
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    • 1997
  • The Ag-Pd-Cu alloys containing a small amount of Au is commonly used for dental purposes, because this alloy is cheaper than Au-base alloys for clinical use. However, the most important characteristic of this alloy is age-hardenability, which is not exhibited by other Ag-base dental alloys. The specimens used were Ag-20Pd-20Cu ternary alloy and Au addition alloy. These alloys were melted and casted by induction electic furace and centrifugal casting machine in Ar atmoshpere. These specimens were solution treated for 2hr at $800^{\circ}C$ and were then quenched into iced water, and aged at $350{\sim}550^{\circ}C$ Age-hardening characteristics of the small Au-containing Ag-pPd-Cu dental alloys were investigated by means of hardness testing, X-ray diffraction and electron microscope observations, electrical resistance, differential scanning calorimetric, emergy dispersed spectra and electron probe microanalysis. Principal results are as follows : Hardening occured in two stages, I. e., stage I in low temperature and stage II in high temperature regions, during continuous aging. The case of hardening in stage I was due to the formation of the Llo type face centered tetragonal PdCu-ordered phase in the grain interior and hardening in stage I was affedted by the Cu concentration. In stage II, decomposition of the $\alpha$ solid solution to a PdCu ordered phase(L1o type) and an Agrich ${\alpha}2$ phase occurred and a discontiunous precipitation occurred at the grain boundary. Form the electron microscope study, it was concluded that the cause of age-hardening in this alloy is the precipitation of the PdCu ordered phase, which has AuCu I type face-centered tetragonal structure. Precipitation procedure was ${\alpha}\to{\alpha}+{\alpha}2+PdCu\to{\alpha}1+{\alpha}2+PdCu$ at Pd/Cu = 1 Ag-Pd-Cu alloy is more effective dental alloy as ageing treatment and is suitable to isothermal ageing at $450^{\circ}C$.

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Effect of Trametes cubensis Extract on Vascular Function of Bovine Aortic Endothelial Cells (Trametes cubensis 버섯 추출물이 소의 대동맥 내피세포의 혈관 기능에 미치는 효능)

  • Jang, Sujeong;Lee, Dong Hyeung;Kim, Seong Hwan;Park, Heonyong
    • The Korean Journal of Mycology
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    • v.48 no.1
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    • pp.1-13
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    • 2020
  • Mushrooms have been extensively used as traditional medicines to treat cancer and inflammatory diseases. In this study, we examined whether Trametes cubensis extract (TCE) exerted beneficial effects on cardiovascular function. First, we demonstrated that TCE was non-cytotoxic and enhanced cell proliferation of bovine aortic endothelial cells (BAEC). Moreover, TCE induced cell migration and blocked lipopolysaccharide-induced adhesion of monocytes to BAEC. We performed a variety of cell signaling studies, showing that TCE activates p38 MAPK and generates reactive oxygen species (ROS). Our results showed that TCE-induced vascular functions were mediated by p38 MAPK, but not by ROS. These results provide insights into bio-medical applications of TCE as a preventive or therapeutic agent for treating cardiovascular diseases including atherosclerosis.

Soil Moisture Flow Assessment in Variably Saturated and Different Layered Soil using Richards Equation (Richards 공식을 이용한 불포화 이(異)층 토양에서의 토양수분 거동 특성 분석)

  • Choi, Soon-Kun;Nam, Won-Ho;Choi, Jin-Yong;Hur, Seung-Oh;Kim, Hak-Jin;Chung, Sun-Ok;Han, Kyung-Hwa
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.107-107
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    • 2012
  • 우리나라의 시설재배는 연중 고품질의 농산물을 요구하는 소비자의 기대와 생산자의 경제적 목적이 부합되어 재배면적이 증가하고 있으며 전체 시설재배면적의 31.3%는 수리시설이 완비된 관개논에 위치한다. 시설재배지에서의 수분관리는 작물의 안정적인 생산과 수자원의 효율적인 사용을 위하여 토양 특성을 고려하여 운영되어야 한다. 따라서 시설재배지 토양 특성을 반영한 작물근군역에서의 물수지와 수분거동 특성에 관한 연구가 선행되어야한다. 불포화토양에서의 수분이동은 토양-작물-대기의 연속계에서 수분의 공급과 증발산, 배수 및 유거에 의한 토양수분 장력의 변화로 이루어지며 토양수분과 토양수분 장력, 수리전도도와의 관계는 토양의 수리적 특성에 따라 상이하다. 실험을 통한 토양수분 거동 분석은 시간적, 비용적 측면에서 비효율적이므로 모형에 의한 분석이 요구된다. 본 연구에서는 불포화토양에서의 수분이동을 모의하기 위하여 Richards 공식을 유한차분법으로 해석하였으며 국내 논 시설재배지 이(異)층토양에 대하여 다양한 관개조건을 적용하여 토양수분 거동 특성을 분석하였다. 관개와 작물의 수분흡수가 지속됨에 따라 근군역을 이탈한 토양수분이 유하되어 밭 토양과 논 토양의 경계에 축적됨을 확인 하였으며 과다관개가 이루어질수록 이러한 현상이 심화되는 것으로 나타났다. 본 연구의 결과는 관개시스템의 설계와 운영에 기초자료로 활용될 수 있다.

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A Study on the Automatic Measurement of Salt Contamination (염분 오손 자동측정에 관한 연구)

  • Kwak, Hee-Ro;Kim, Han-Sang;Kweon, Dong-Jin;Lee, Dong-Zoon;Kim, Kyoung-Wha;Cho, Kug-Hee
    • Proceedings of the KIEE Conference
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    • 1995.07c
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    • pp.1362-1364
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    • 1995
  • In this paper, the automatic device for measuring the salt contamination on insulators was developed. The device consists of electronic insulators, measuring system, monitoring system, and printer. It was shown that the level of salt contamination measured by the developed device is similar to that measured by the brush cleaning method. Therefore, the developed automatic measuring device can be used in field, in order to predict the cleaning time of insulators and prevent the failure due to the salt contamination.

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Electrophysiological Studies in the Diagnosis of Amyotrophic Lateral Sclerosis (근위축성 측삭경화증의 진단에 있어서 전기진단학적 검사)

  • Lee, Dong Kuck
    • Annals of Clinical Neurophysiology
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    • v.6 no.1
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    • pp.1-13
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    • 2004
  • Amyotrophic lateral sclerosis (ALS) is a progressive neurodegenerative disorder that primarily affects motor neurons. The characteristic features of this devastating disorder are the simultaneous presence of upper and lower motor neuron (LMN) signs with progression from one region of the neuraxis to the next and eventual death, typically from respiratory compromise. Electrophysiological studies are an indispensible part of the ALS evaluation, especially serving as an extension of the clinical examination, and most useful in identifying LMN dysfunction. Not only may electrodiagnostic studies reveal characteristic changes in those regions clinically manifesting signs, but it also serves to disclose asymptomatic areas of involvement.

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Residual Stress Distribution of Laser Hardened SCM440 for Diesel Engine Piston (디젤엔진 피스톤용 SCM440의 레이저 표면경화부의 잔류응력)

  • Lee, D.S.;Yoo, W.J.;Kim, J.D.
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.3
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    • pp.182-186
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    • 1995
  • SCM440, which is widely used as the diesel engine piston of vessel, has been hardened by a $CO_2$ laser with the wavelength of $10.6{\mu}m$. Laser hardening experiment has been carried out for the condition of a laser power 1kW, the travel speed between 0.4 and 1.5m/min, and a rectangular-Gaussian beam. Residual stress has been measured by using middle point technique of half value width of X-ray diffraction method. It was found that the compressive residual stress with the range between 400 and 600MHz has distributed in the laser hardening zones and the tensile residual stress between 100 and 200MHz has distributed in the boundary of hardening zones.

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Synthesis and Properties of Photocurable Dimethylol Propionic Acid modified Hyperbranched Acrylates (광경화형 Dimethylol Propionic Acid 변성 하이퍼브랜치 아크릴레이트의 합성과 물성)

  • Kim, Dong Kook;Lim, Jin Kyu;Kim, Woo Geun
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.342-347
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    • 2005
  • Photocurable hyperbranched acrylates were prepared from acrylic acid and hyperbranched polyol (HBP-16, 32, 64). Physical properties of three kinds of photocurable hyperbranched acrylated were investigated. Thermal stability of UV cured film measured by TGA shifted to higher temperature with increasing of functionality. Hardness, abrasion resistance, and tensile strength of UV cured film also increased with increasing functionality of acrylate. Weathering test for UV cured film showed the value of yellow index increased with increasing functionality of acrylate.

A New Algorithm for the Integration of Thermal-Elasto-Plastic Constitutive Equation (열탄소성 구성방정식 적분을 위한 새로운 알고리즘)

  • 이동욱;신효철
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.6
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    • pp.1455-1464
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    • 1994
  • A new and efficient algorithm for the integration of the thermal-elasto-plastic constitutive equation is proposed. While it falls into the category of the return mapping method, the algorithm adopts the three point approximation of plastic corrector within one time increment step. The results of its application to a von Mises-type thermal-elasto-plastic model with combined hardening and temperature-dependent material properties show that the accurate iso-error maps are obtained for both angular and radial errors. The accuracy achieved is because the predicted stress increment in a single step calculation follows the exact value closely not only at the end of the step but also through the whole path. Also, the comparison of the computational time for the new and other algorithms shows that the new one is very efficient.