• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.215-215
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• 2022

현재 국내 정수시설은 정수공정별 감시제어-데이터수집시스템(SCADA: Supervisory Control And Data Acquisition)에 기반하여 감시제어 및 모니터링 위주로 운영·관리를 실시하고 있다. 또한, 주요 핵심 공정인 응집제 약품투입, 소독 및 여과 설비 공정의 운영방식에 있어서 선험적 운영지식에 의한 방식으로 운영되고 있기 때문에 지속적인 안정적 운영을 위해서는 표준적이고 체계적인 운영관리 수단이 필요하다. 국외에서는 다양한 운영 조건에 기반한 정수처리 효율을 예측할 수 있는 모의(simulation) 도구의 개발을 통해 기존 운영되고 있는 정수장의 효율을 예측하는 데 활용하고 있는 실정이다. 본 논문은 실시간 운영관리가 가능한 기반을 구축하여 정수처리의 효율을 예측할 수 있는 시뮬레이터 개발을 통해 정수처리 공정별 기본 및 조합의 공정 시뮬레이션 모의 모듈 기술을 개발하기 위한 연구를 수행하였다. 또한 개발된 기술의 실증 운영을 통해 검증된 모듈을 반영한 정수장 시뮬레이터 시스템을 개발을 위한 연구를 수행하였다. 정수장 시뮬레이터는 수질정보, 물질수지, 수두손실등의 운영현황 데이터를 수집하는 기능, 착수-혼화-응집-침전-여과-소독 등 개별 공정별 주요 운전변수의 모니터링 및 제어를 통한 운영관리 기능, 원수 수질변화에 신속한 대응을 위한 정수처리 공정제어 의사결정지원 기능, 그리고 온라인 관망해석을 포함한 정수처리 전(단위)공정 시뮬레이터 기능 및 공정별 운영인자 최적화 기능 등으로 구성되어 있다. 현재 운영 중인 정수장의 공정별 운전 상태를 평가·관리하여 정수공정 운영 안정화 체계를 확보하고, 정수장의 유량과 수질의 갑작스런 변화에 따른 모의를 통한 수질예측으로 실시간 정수장 최적운영관리가 가능하다. 또한 원수 성상에 따른 적정 공정운영 자동화로 운영비 절감 및 효율적 인력 활용으로 정수장 운영 효율성을 제고함으로써 지속적이고 안정적인 정수장 운영 체계를 확보할 수 있다.

• Membrane Journal
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• v.17 no.3
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• pp.191-196
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• 2007

In the study, excess of lime-soda ash(L-S) was added to groundwater for chemical precipitation of hardness ions. After formation of the coagulated flocs, sedimentation step was replaced with crossflow ultrafiltration(UF) process using tubular ceramic membrane. As results, our treated water was below total hardness(TH) 10 mg/L as $CaCO_3$ from groundwater using washing water in a soymilk factory. Then, we investigated the change of permeat flux(J) and dimensionless permeate flux($J/J_0$) during experiments for variations of TMP(Trans-membrane pressure) or flow rate, to see effect of TMP or flow rate on membrane fouling by the coagulated Inorganic flocs. In the result, membrane fouling and rejection rate of total hardness were not affected by TMP and flow rate variations in the range of our experiments.

• Journal of the Korean Ceramic Society
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• v.40 no.6
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• pp.577-582
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• 2003

BaTiO$_3$ fine powders were synthesized by hydrothermal process from peroxo-coprecipitate precursors. The peroxo-coprecipitates were obtained by addition of the BaCl$_2$, TiCl$_4$, and $H_2O$$_2$ aqueous solution to an ammonium solution. Hydrothermal reaction was conducted at various reaction temperatures, times and pH ranges. Unlike the conventional hydrothermal synthesis which needs highly alkaline condition over pH 13 with KOH or NaOH, the present method offered well-developed crystalline (perovskite) BaTiO$_3$ powders synthesized below pH 12 with use of ammonium solution. It was found that the phase-pure fine powders were formed at temperatures as low as 11$0^{\circ}C$ and the properties of the powders synthesized over 13$0^{\circ}C$ were almost same regardless of the reaction time. BET surface area of the prepared powder was as high as 76 $m^2$/g and the calculated particle (particulate) size was below 20 nm. The ultrafine particulates formed weak agglomerates. The microstructure and dielectric properties of BaTiO$_3$ ceramics sintered at the temperature range of 1150~125$0^{\circ}C$ were evaluated.

• Journal of Environmental Science International
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• v.7 no.1
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• pp.104-111
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• 1998

The Dongbok lake water before and after alum coagulation and activated carbon adsorption were analyzed in terms of organic contents, molecular weight distributuin (MWD), and UV-absorbance. Dissolved organic compounds in the Dongbok lake were fractionated into three molecular size classes by gel permeation chromatography. The fractionation was reasonably successful in isolating compounds with The bulk of the dissolved carbon was present in compounds of molecular weight in the range of 3,000~10,000. Alum coagulation preferentially treated molecules of high molecular weight, which has molecules larger than 10,000. The dissolved organic carbon (DOC) removal after activated carbon adsorption was high in the Fraction B , IR . The $A_{260}$/DOC ratio after alum and activated carbon treatment the Fraction II, III. This results suggest that the organics remaining after each treatment has a trihalomethane formation potential

• Proceedings of the Membrane Society of Korea Conference
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• 1997.10a
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• pp.133-134
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• 1997

1. 서론 : 제지산업은 용수 다소비용 산업으로, 생산하는 제품 톤당 약 40톤으로 폐수가 배출되고 있으며 공정내로 재활용하는 폐수량을 고려한다면 그 사용량은 더욱 클 것이다. 이와 같은 다량의 용수 사용으로 인하여 제지 공장의 폐수를 제조공정에서 재활용하는 방법이나 배출량을 감소시키는 방안들이 법률적이나 경제적인 측면에서 연구되고 있는 실정이다. 본 연구에서는 기존의 응집, 침전공정을 대신하고 여재를 이용힌 물리적 여과와 활성높은 미생물이 여재 표면에 부착되어 수중 유기물질을 생물학적으로 분해 제거하는 이중의 효과를 거둘 수 있는 호기성 생물막 공정을 도입하고 그 처리수의 유기물 및 용존 무기물을 Membrane 공정으로 제거함으로써 제지공업폐수를 재활용하여 용수기준까지 처리하 System의 개발을 그 목적으로 하였다.

• Proceedings of the Membrane Society of Korea Conference
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• 1998.10a
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• pp.146-149
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• 1998

우리 나라는 1994년 말 현재 654개소에 28,434개소의 수도사업체가 있으며, 이중 간이상수도는 26,363개소로 총 93%를 차지하고 있다. 간이상수도와 같은 소규모 수도사업체에서는 재정적인 기반이 취약하며, 기술자 등이 인재확보가 어려운 형편이다. 이에 따라 대부분의 경우 수도시설의 일상적인 유지관리에 많은 불편이 따르고 있을 뿐만 아니라 적정 수질을 확보하기가 곤란한 실정이다. 간이상수도에서 수질이 좋은 물을 효율적으로 공급하기 위해서는 기존의 정수처리 시스템으로는 어려운 형편이다. 즉, 우리 나라 간이상수도의 정수처리과정은 소독을 기본으로 하여 응집침전, 급속모래여과, 등의 고액분리조작을 주체로 하고 있어 각 과정에 대한 유지관리에 많은 노력이 필요하다. 이에 따라 간이상수도에서는 보다 효율적으로 수질관리가 이루어질 수 있는 장치 및 시스템의 개발이 절실하다.

• Korean Journal of Veterinary Research
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• v.36 no.4
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• pp.895-902
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• 1996

산란계에 불활화 개 파보바이러스 백신을 근육내로 1주 간격으로 4회 접종하여 면역화시키고 최종 접종 2주후에 채란하여 $4^{\circ}C$에 보관하며 사용하였다. 난황항체는 5% HPMCP를 이용하여 분리하였고 0.5% HPMCP 용액은 lipid 침전에 매우 효과적이었으며 희석배수 10배에서 투명한 상층액을 나타내었다. 1차분리한 상층액의 단백질 농도는 2.5mg/ml이었고 최종 단백질 용액의 경우는 26.53mg/ml이었다. SDS-PAGE 전기영동상에서 분자량 60~70 KD 및 30~40 KD의 2 band가 나타났으며 non-reducing 전기영동에서는 닭 혈청 IgG와 같은 120~160 KD의 분자량을 보인 band가 각각의 분리용액에서 나타났다. 난황 항체의 개 파보바이러스에 대한 혈구응집억제반응 항체역가는 혈청의 역가에 비해 1주의 차이를 주며 증가했으며 난황 항체는 1:640에서 1:2560, 혈청은 1:640에서 1:5120을 나타내었다.

• Journal of the Korean Society of Groundwater Environment
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• v.7 no.3
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• pp.103-115
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• 2000

The formation of brown-colored precipitates is one of the serious problems frequently encountered in the development and supply of groundwater in Korea, because by it the water exceeds the drinking water standard in terms of color. taste. turbidity and dissolved iron concentration and of often results in scaling problem within the water supplying system. In groundwaters from the Pajoo area, brown precipitates are typically formed in a few hours after pumping-out. In this paper we examine the process of the brown precipitates' formation using the equilibrium thermodynamic and kinetic approaches, in order to understand the origin and geochemical pathway of the generation of turbidity in groundwater. The results of this study are used to suggest not only the proper pumping technique to minimize the formation of precipitates but also the optimal design of water treatment methods to improve the water quality. The bed-rock groundwater in the Pajoo area belongs to the Ca-$HCO_3$type that was evolved through water/rock (gneiss) interaction. Based on SEM-EDS and XRD analyses, the precipitates are identified as an amorphous, Fe-bearing oxides or hydroxides. By the use of multi-step filtration with pore sizes of 6, 4, 1, 0.45 and 0.2 $\mu\textrm{m}$, the precipitates mostly fall in the colloidal size (1 to 0.45 $\mu\textrm{m}$) but are concentrated (about 81%) in the range of 1 to 6 $\mu\textrm{m}$in teams of mass (weight) distribution. Large amounts of dissolved iron were possibly originated from dissolution of clinochlore in cataclasite which contains high amounts of Fe (up to 3 wt.%). The calculation of saturation index (using a computer code PHREEQC), as well as the examination of pH-Eh stability relations, also indicate that the final precipitates are Fe-oxy-hydroxide that is formed by the change of water chemistry (mainly, oxidation) due to the exposure to oxygen during the pumping-out of Fe(II)-bearing, reduced groundwater. After pumping-out, the groundwater shows the progressive decreases of pH, DO and alkalinity with elapsed time. However, turbidity increases and then decreases with time. The decrease of dissolved Fe concentration as a function of elapsed time after pumping-out is expressed as a regression equation Fe(II)=10.l exp(-0.0009t). The oxidation reaction due to the influx of free oxygen during the pumping and storage of groundwater results in the formation of brown precipitates, which is dependent on time, $Po_2$and pH. In order to obtain drinkable water quality, therefore, the precipitates should be removed by filtering after the stepwise storage and aeration in tanks with sufficient volume for sufficient time. Particle size distribution data also suggest that step-wise filtration would be cost-effective. To minimize the scaling within wells, the continued (if possible) pumping within the optimum pumping rate is recommended because this technique will be most effective for minimizing the mixing between deep Fe(II)-rich water and shallow $O_2$-rich water. The simultaneous pumping of shallow $O_2$-rich water in different wells is also recommended.

• Journal of Korean Society of Water and Wastewater
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• v.28 no.6
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• pp.623-634
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• 2014

This study examined a feasibility of coagulation as post-treatment to remove sulfide and phosphorus for the effluent of anaerobic fluidized bed reactor (AFBR) treating domestic wastewater. Removal efficiencies of sulfide, phosphorus and COD by coagulation were not affected by pH in the range of 5.9 to 7.2. Alkalinity requirement could be estimated by the amount of $Fe^{3+}$ to form $Fe(OH)_{3(S)}$ and to remove sulfide and phosphorus. At coagulant aid dosage of 2 mg/L, anionic polymer showed best results regarding size and settleability of flocs. Sulfide removal for the AFBR effluent at the $Fe^{3+}/S^{2-}$ ratio of 0.64, close to the theoretical value of 0.67 found with a synthetic wastewater, was only 75.2%. One of the reasons for this high $Fe^{3+}/S^{2-}$ ratio requirement is that the AFBR effluent contains sulfide, phosphorus, hydroxide and bicarbonate which can react with $Fe^{3+}$ competitively. Concentrations of sulfide and phosphorous reduced to below 0.1 and 0.5 mg/L, respectively, at the $Fe^{3+}/S^{2-}$ ratio of 2.0. Average effluent COD of 80 mg/L, mostly soluble COD, was obtained at the dosage 50 mg $Fe^{3+}/L$ ($Fe^{3+}/S^{2-}$ ratio of 2.0) with corresponding COD removal of 55%. For better removal of COD, soluble COD removal at the AFBR should be enhanced. Coagulation with $Fe^{3+}$ removed sulfide, phosphorus and COD simultaneously in the AFBR effluent, and thus could be an alternative process for the conventional wastewater treatment processes where relatively high quality effluent is not required.

• Resources Recycling
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• v.14 no.6 s.68
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• pp.21-27
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• 2005

As one of the hydrometallurgical processes available in the recycling of silver-bearing wastes, the preparation of Ag nano-powder was investigated by a reductive precipitation reaction in silver solution using sodium formaldehydesulfoxylate and ascorbic acid as a reducing agent. Silver solution was prepared by dissolving silver nitrate with distilled water, and Tamol NN8906, PVP, SDS and caprylic acid were also used respectively as the dispersant to avoid the agglomeration of particles during the reductive reaction. Ag particles obtained from the reduction reaction from silver solution were characterized using the particle size analyzer and TEM to determine the particle size distribution and morphology. It was found that about $40\%$ excess of sodium formaldehydesulfoxylate was required to reduce completely silver ions in the solution. It alto appeared that the particle size generated with sodium formaldehydesulfoxylate was much greater than that with ascorbic acid. As far as the effect of dispersant on the Ag particles was concerned, the particle size distribution showed typically bimodal distribution in case of Tamol/FVP while very broad distribution ranged from 0.01 to $100{\mu}m$ appeared in case of SDS/caprylic acid.