• Title/Summary/Keyword: 음이온 분포

Search Result 106, Processing Time 0.025 seconds

Chemical Composition of Rainwater in Suwon and Ansung Area (수원과 안성지역 빗물의 화학성분 조성)

  • Lee, Jong-Sik;Kim, Bok-Young;Kim, Jin-Ho;Hong, Seung-Gil
    • Korean Journal of Environmental Agriculture
    • /
    • v.18 no.2
    • /
    • pp.169-173
    • /
    • 1999
  • To investigate the chemical properties of rainwater in the southern part of gyeonggi Province, the rainwater was collected in Suwon and Ansung for six months from May to October in 1998, and analyzed its chemical composition. The ion balance and electric conductivity balance showed confidence to chemical analyses of rainwater. The most frequent pH range of rainwater was pH $5.0{\sim}5.6$ both in Suwon and Ansung area with distribution ratio of 37.9% and 35.3%, respectively. Among the 1mm fraction for initial 5mm of rainfall, ion concentration of initial rainwater (less than 1mm of rainfall) was higher than those of the later terms. The major ions in rainwater were $NH_4^-,\;Ca^{2+}$and $Na^+$ for cations, and $SO_4^{2-}$ and $NO_3^-$ for anions. Monthly variation of pH of rainwater showed low level of 4.2 to 4.5 in Suwon and 4.6 to 4.7 in Ansung in August and September, respectively. The $nss-SO_4^{2-}/NO_3^-$ ratio of rainwater in Suwon and Ansung area were 2.2 and 2.9 which means nonsea salt $SO_4^{2-}$ contrbuted to acidity of rainwater more in Ansung than Suwon area.

  • PDF

Fabrication of Nano $Y_{2}O_{3}-CeO_{2}$ Sintered Body Using Dispersion Stability (분산 안정성을 이용한 나노 $Y_{2}O_{3}-CeO_{2}$ 소결체의 제조)

  • Kim, Eun-Jung;Lee, Sang-Hoon;Choi, Sung-Churl
    • Journal of the Korean Ceramic Society
    • /
    • v.38 no.9
    • /
    • pp.853-859
    • /
    • 2001
  • The dispersion stability of nano $Y_2O_3-CeO_2$ system was investigated using colloid surface chemistry. Green body of $Y_2O_3$ doped $CeO_2$ was prepared by slip casting in and aqueous system. The dispersion stability of suspension between powders and organic additive was accomplished through electrokinetic behavior of suspension, which was done by ESA apparatus. The dynamic mobility of particles was enhanced when the anionic dispersant of the amount of 1wt% was added. The dissolution of $Y^{3+}$ ion in suspension occurred in the acidic region so that pH value in slurries did not move to below 7.0. In the $CeO_2-Y_2O_3$ system, optimal preparation of suspension was made after adding the anionic dispersant as the amount of 1wt% and pH value of 11.0, and then slip-cast and sintered at 1400$^{\circ}$C, 2 hrs. It appeared relative density of >98% and homogeneous distribution of Y element in depth direction as well as in the microstructure of surface.

  • PDF

The Study on Characteristics of Rainwater in Saemangeum (재난을 대비한 새만금지역의 강우특성에 관한 연구)

  • Lim, Ik Hyun;Hwang, Eui Jin;Ryu, Ji Hyeob
    • Journal of Korean Society of societal Security
    • /
    • v.4 no.2
    • /
    • pp.65-72
    • /
    • 2011
  • This study was carried out to investigate the cause of acidification of rainwater and to evaluate the possibility of alternative water resource in Saemangeum. The rainwater were collected in the kwangwhal-myun, Saemangeum from March to September, 2009. The collected 7 samples were analyzed with pH meter, IC (ion chromatography) and ICP (inductively coupled plasma) about the pH and the major ions ($SO{_4}^{2-}$, $NO_3{^-}$, $Cl^-$, $Ca^{2+}$, $K^+$, $NH^{4+}$, $Na^+$ and $Mg^{2+}$) of rainwater. The order of the major anion concentration and the acidification contribution in the rainwater was $SO{_4}^{2-}$>$NO_3{^-}$>$Cl^-$, and that of the major cation was $Ca^{2+}$>$K^+$>$NH_4{^+}$>$Na^+$>$Mg^{2+}$. In the initial rainwater, the major ions concentration were higher than the middle period. pH of the rainwater was the lowest at May, but similar to the results of the others. And pH of the rainwater were significant correlation with $SO{_4}^{2-}$ and $Cl^-$ in Saemangeum. From this results, the rainwater was slight acidic, and $SO{_4}^{2-}$ was the main factor contributed to the rainwater acidification in Saemangeum.

  • PDF

Characteristics of a Wet Air Cleaning System for Removal of Air Pollutants (습식 공기청정장치의 공기오염물질 제거 특성)

  • Bae, Gwi-Nam;Kim, Yong Pyo;Baik, Nam Jun
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.22 no.1
    • /
    • pp.21-31
    • /
    • 2000
  • Performance characteristics of a wet air cleaning system were investigated experimentally, and discussed in relation with physicochemical properties of the target pollutants. The system is composed of an air cleaner, a separator, and a medium filter. Removal efficiency of the system was measured for ambient particles and gaseous air pollutants: $SO_2$, NO, $NO_2$, HCHO, and $NH_3$. For particle removal test, particles were introduced into the system through a fan, and the particle size distribution was measured at three locations by using two laser particle counters. Particle removal efficiency for each system component was obtained from the particle size distribution. It was found that the separator primarily removed coarse particles greater than $5{\mu}m$ in diameter, and that the medium filter mainly removed fine particles less than $5{\mu}m$ in diameter. For gas removal test, air with gaseous air pollutant was injected into the outlet of the fan, and the concentration was measured both at the upstream of the air cleaner and at the downstream of the separator. It was found that the gaseous species with high Henry's law coefficients, such as $SO_2$, HCHO, and $NH_3$, showed high removal efficiency, but the gaseous species with low Henry's law coefficients, such as NO and $NO_2$, showed low removal efficiencies. It was also found that negative ions were generated from the air cleaner.

  • PDF

A Study on the Ingredients in the Sap of Acer mono MAX. and Betula costata T. in Mt. Jiri Area -On the Components of Mineral and Sugar- (지리산지역 고로쇠나무 및 거제수(거자수) 나무의 수액성분에 관하여 -Mineral과 Sugar성분에 관하여-)

  • 서화중;김충모;정두례
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.20 no.5
    • /
    • pp.479-482
    • /
    • 1991
  • The medical use of Acer mono MAX. and Betula costata T. sap has had the long history in Korea. So the mineral and sugar contents of these sap gathered in Mt. Jiri area at spring were analyzed to investigate the scientific base of folk remedies by using ion liquid chromatography and high performance liquid chromatography. The values of chlorine and sulfate in Acer mono MAX. were 11.5 mg/l and 176.7 mg/l, and in Betula costata T. 26.5 mg/l and 162.4 mg/l, respectively. The values of potassium, sodium, calcium and magnesium in Acer mono MAX. were 67.9 mg/l, 5.6 mg/l, 73.8 mg/l and 4.5 mg/l, and in Betula costata T. were 152.1 mg/l, 9.7 mg/l, 39.2 mg/l and 5.7 mg/l, respectively. The values of copper, zinc and manganese in Acer mono MAX. were 0.057 mg/l, 0.483 mg/l and 5.071 mg/l, and copper, zinc, mangances and iron in Betula costata T. were 0.038 mg/l, 1.584 mg/l, 4.354 mg/l and 2.511 mg/l, respectively. The values of sucrose in Acer mono MAX. were 27.29 mg/l, glucose and fructose in Betula costata T. were 0.97 g/l and 3.05 g/l, respectively.

  • PDF

태화강 주변지역 지하수의 수질특성 및 계절별 수질변화 양상

  • Lee Jong-Seong;Kim Do-Sun;Yun Hye-Jeong;Choi Yeong-A;Choi Yeong-Seon;Im Jong-Seon;Yun Han-Jik;Lee Jin-Yeol;Jeong Su-Geun;Ham Yu-Sik
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 2005.04a
    • /
    • pp.441-445
    • /
    • 2005
  • 태화강 주변지역 지하수의 계절적 수질 변화를 보고자 현장측정 항목(수온, pH, 알칼리도, 전기전도도), 일반 항목(증발잔류물, 총경도, 과망간산칼륨소비량), 음이온물질$(F^-,\;Cl^-,\;{NO_3}^-,\;{SO_4}^{2-})$, 양이온물질$(Ca^{2+},\;Mg^{2+},\;K^+,\;Na^+)$등으로 구분하여 분석하였으며, 총 70개 지점을 대상으로 2004년 5월, 10월 2회에 걸쳐 실시하였다. 지역별 수질특성을 살펴보면 남구지역은 $Ca-Mg-HCO_3,\;Ca-Mg-HCO_3-Cl,\;Ca-Mg-Na-Cl-HCO_3,\;Na-Cl-HCO_3$의 4가지 유형이 전체 시료의 74%를 차지하였으며, $Ca-Mg-HCO_3$형이 가장 우세하게 나타났고, 중구지역 지하수에서는 $Ca-Mg-HCO_3-Cl,\;Ca-Mg-Na-HCO_3-Cl,\;Ca-Mg-HCO_3$의 3가지 유형이 전체 시료의 60%를 차지하는 것으로 나타났으며, 이중에서 $Ca-Mg-HCO_3-Cl$형이 가장 우세하게 나타났다. 두 지역의 수질 변화를 살펴보면. 전기전도도는 남구는 $731.5{\mu}s/m^3$에서 $529.8{\mu}s/m^3$, 중구는 $752.6{\mu}s/m^3$에서 $621.6{\mu}s/m^3$로 201.7, $131.0{\mu}s/m^3$만큼 작아져 두 지역 모두 같은 양상을 보였으나, Hardness 및 TDS의 경우 남구지역은 5월보다 10월에 평균, 최대값이 모두 낮게 나타났다. 또한 $Cl^-$의 경우 지역적, 계절적으로 큰 차이를 보이고 있으며 남구는 5월 68.2mg/l, 10월에는 61.7mg/l로 다소 감소하였으나 중구의 경우 5월 75.5mg/l, 10월 122.1mg/l로 다소 증가한 것으로 나타났다. 양이온 분포 비율 및 농도는 비슷하게 나타났으며, 계절적으로 5월보다 10월에 모두 높게 나타났다. 두 지역 모두 양이온물질 중 나트륨의 분포비율 및 농도가 5월보다 10월에 다소 높게 나타났다. 연구 지역 지하수의 계절적 수질변화를 살펴보면 두 지역간의 지하수질 및 분포특성에 있어 다소 차이를 보이고 있으며, 특히 중구 지역에서 5월보다 10월에 나트륨과 염소이온의 증가가 다소 나타나는 것으로 관찰되었다. 또한 연구지역 중 특이지점($Cl^-$:1,000mg/l이상)은 남구는 5월에 2개에서 10월에는 3개 지점으로 증가하였으며, 중구는 5월, 10월 모두 4개 지점으로 나타났다.

  • PDF

Environmental Assessment for Acid Mine Drainage by Past Coal Mining Activities in the Youngwol, Jungseon and Pyungchang areas, Korea (영월, 정선 및 평창지역 폐 석탄광 산성광산배수의 환경오염 평가)

  • 정명채
    • Economic and Environmental Geology
    • /
    • v.36 no.2
    • /
    • pp.111-121
    • /
    • 2003
  • The objective of this study is to investigate the physical and chemical properties for environmental assessment of water system affected by acid mine drainage (AMD) from coal mining activities in the Youngwol, Jungseon and Pyungchang areas in Korea. During November 2000 to July 2002, 6 times of water samples were collected season-ally from acid mine drainage and nearby streams at 13 coal mines in the study area. The physical and chemical properties including pH, Eh, TDS, salinity, bicarbonates and DO were measured in the field. Eighteen cations includ-ing Al, Ca, Fe, Mg, Mn and Zn, and 6 anions including nitrates and sulfates were also analyzed by ICP-AES and If, respectively. Acid water from the Jungam coal mine has typical characteristics of AMD with very low pH(3∼4) and high TDS(1,000∼5,000 mg/1). Relatively high concentrations(mg/kg) of heavy meals, especially for Al(380), Fe(80), Mn(44) and Zn(8), were found in water samples from the Jungam coal mine area. Water samples from the Seojin, Sebang and Sungjin coal mines also contained over 50 mg/l of Al, >100 mg/1 of Fe and )10 mg/1 of Mn. In addition to anioins, over 1,000 mg/l of sulfate was found in several water samples. Seasonally, the concentrations of metals and sulfates varied; wet season samples were relatively higher in metals and sulfates than dry season samples. It is needed to establish the proper remediation and environmental monitoring of the AMD continuously.

Design of high speed InAlGaAs/InGaAs HBT structure by Hybrid Monte Carlo Simulation (Hybrid Monte Carlo 시뮬레이션에 의한 고속 InAlGaAs/InGaAs HBT의 구조 설계)

  • 황성범;김용규;송정근;홍창희
    • Journal of the Korean Institute of Telematics and Electronics D
    • /
    • v.36D no.3
    • /
    • pp.66-74
    • /
    • 1999
  • InAlGaAs/InGaAs HBTs with the various emitter junction gradings(xf=0.0-1.0) and the modified collector structures (collector- I;n-p-n, collector-II;i-p-n) are simulated and analyzed by HMC (Hybrid Monte Carlo) method in order to find an optimum structure for the shortest transit time. A minimum base transit time($ au$b) of 0.21ps was obtainsed for HBT with the grading layer, which is parabolically graded from $x_f$=1.0 and xf=0.5 at the emitter-base interface. The minimum collector transit time($\tau$c) of 0.31ps was found when the collector was modified by inserting p-p-n layers, because p layer makes it possible to relax the electric field in the i-type collector layer, confining the electrons in the $\Gamma$-valley during transporting across the collector. Thus InAlGaAs/InGaAs HBT in combination with the emitter grading($x_f$=0.5) and the modified collector-III showed the transit times of 0.87 psec and the cut-off frequency (f$\tau$) of 183 GHz.

  • PDF

Preparation of Polycaprolactone Microcapsules by Membrane Emulsification Method and Its Drug Release Properties (막유화법에 의한 생분해성 Polycaprolactone 마이크로캡슐의 제조와 약물방출 특성)

  • Youm, Kyung-Ho;Yun, Tae-Ho;Kim, Kong-Soo;Cho, Suh-Hyeong
    • Membrane Journal
    • /
    • v.17 no.1
    • /
    • pp.67-79
    • /
    • 2007
  • Uniform microcapsules containing ionic model drugs were prepared by controlling various conditions of emulsification procedure using a lab-scale membrane emulsification system with a SPG (Shirasu porous glass) tubular membrane. We observed the effects of various emulsification parameters [concentration and molecular weight of polycaprolatone (PCL) polymer, transmembrane pressure and emulsifier concentration in disperse phase and continuous phase, stirring speed] on the mean size and size ditribution of microcapsules containing lidocaine hydrochloride (cationic drug), sodium salicylate (nonionic drug) and 4-acetaminophen (anionic drug) used as a model drugs. Also, release characteristics of a model drugs from PCL microcapsules were investigated. Controlling membrane emulsification parameters, uniform PCL microcapsules with about $5\;{\mu}m$ of the mean size were finally prepared. The release rate and the burst effect of microcapsules were decreased in condition of the acidic solution, but it was increased in condition of the base solution.

Preparation of Mono-dispersed Polyamide 6(Nylon 6) Micro-particle (단분산린 Polyamide 6(Nylon 6) 미세입자의 제조)

  • Cho, Hangu-Gu;Kim, Hyung-Joong
    • Polymer(Korea)
    • /
    • v.31 no.4
    • /
    • pp.322-328
    • /
    • 2007
  • Mono-dispersed polyamide 6(Nylon 6) micro-particles sized in $4{\sim}5\;{\mu}m$ diameter were prepared by dispersion polymerization of ${\varepsilon}-caprolactam$ in liquid paraffin as a dispersion medium. Potassium metal(K) as a catalyst was separately added twice over the anionic ring-opening polymerization of ${\varepsilon}-caprolactam$. The size, shape, and size-distribution of prepared particles were varied with the concentration of anti-coagulant as well as the amount of initiator and catalyst. As the initiator concentration was in the range of $0.97{\sim}1.17\;wt%$ in monomer, about 90.6% of yield was accomplished. In addition, the highest yield of well-spherically shaped micro-particles was achieved by adding about $1.3{\sim}1.4\;wt%$ of catalyst.