• Title/Summary/Keyword: 유해 gas

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Characteristic Study for Methyl-mercaptain Removal by an Essential Oil (식물추출물을 이용한 메틸멀캡탄 제거 특성 연구)

  • Park, Young-Gyu
    • KSBB Journal
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    • v.22 no.3
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    • pp.151-156
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    • 2007
  • Increasing public concerns over odors and air regulations necessitates the remediation of a wide range of odorous compounds for industrial purpose. Currently, wet scrubbing technique by neutralization using essential oils is utilized to treat methyl mercaptan odor. The chemical analysis is performed to analyze the composition of an essential oil by GC-MS. The objective of this study is to clarify the possibility of the neutralization of odors sprayed in the fixed bed and determine the removal efficiencies in the misty aerosol by different input odor concentration. It is found that methyl mercaptan is significantly removed in the wet scrubber, and their removal efficiency of methyl mercaptan is obtained by 98%.

Numerical simulation of VOC decomposition in an arc plasma reactor (수치해석 기법을 이용한 아크 플라즈마 반응기의 VOCs 분해성능 평가연구)

  • Park, Mi-jeong;Jo, Young-min
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.8
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    • pp.1-7
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    • 2016
  • A range of techniques have been being developed to remove the volatile organic compounds from paining processes. High temperature decomposition of harmful VOCs using arc plasma has recently been proposed, and this work analyzed the extreme hot process by computer-aided fluid dynamics prior to the reactor design. Numerical simulations utilized the conservation equations of mass and momentum. The simulation showed that the fluid flowed down along the inner surface of the centrifugal reactor by forming intensive spiral trajectories. Although the high temperature gas generated by plasma influences the bottom of the reactor, no heat transfer in radial direction appeared. The decomposition efficiency of a typical VOCs, toluene, was found to be a maximum of 67% across the reactor, which was similar to the value (approximately 70%) for the lab-scale test.

The Study on Effect of Exhaust Gas Characteristics according to Aromatic compound Content in Diesel (경유의 방향족 함량 변화가 배출가스에 미치는 영향 연구)

  • Kim, Shin;Min, Kyong-Il;Yim, Eui-Soon;Ha, Jong-Han;Na, Byung-Ki
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.549-561
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    • 2014
  • According to reports in EU and USA, Aromatic ingredient in diesel estimated the causative agent of air pollution. Because reduction of total aromatic and Poly-aromatic compound content are decreasing environmentally harmful emissions HC, NOx, PM. It is necessary to investigate correlationship between automotive technology and fuel quality in Korea. This study examines emission effect of two representative domestic vehicles(2.2 L for emission of Euro 4, 5) and five kinds of domestic diesel fuel (total aromatic compound content 26, 28, 30 wt% and poly-aromatic compound content 3, 5 wt%). Finally, Environmental impact assessment was studied between vehicle and diesel fuel.

Contamination Sources of Several Potentially Hazardous Compounds Found at the Gap Stream and the Miho Stream, Two Major Tributaries of the Geum River (금강 수계 주요지류인 갑천과 미호천에서 잠정유해물질 오염원 확인 연구)

  • Lee, Jun-Bae;Lee, Jay-Jung;Cho, Yoon-Hae;Yoon, Jo-Hee;Hong, Seoun-Hwa;Lee, Dae-Hee;Lee, Dae-Hee;Cho, Young-Hwan;Shin, Ho-Sang
    • Korean Journal of Environmental Agriculture
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    • v.35 no.1
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    • pp.15-23
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    • 2016
  • BACKGROUND: Water quality is of concern to water utility operators, public health officials, and populations using the water. If any contaminant is released from a point of entry, it could be spread rapidly throughout the water stream. So the identification of the location of the points of entry and its release history are critical informations to establish the management strategy.METHODS AND RESULTS: Aniline, nonylphenol, pentachlorophenol and formaldehyde in 39 surface water samples were analysed using Gas chromatography-mass spectrometry (GC-MS) methods. Formaldehyde, aniline and nonylphenol were mainly detected in the near sites where industrial waste water and domestic sewage were discharged into stream. But pentachlorophenol was detected in the downstream samples where pulp manufacturing plants were operated.CONCLUSION: Results indicate that pentachlorophenol found in main stream of Guem river was mainly introduced from pulp manufacture industries. Otherwise, formaldehyde, aniline and nonylphenol were mainly contaminated from the industrial waste water and domestic sewage.

A Study on the Identification of Hazardous Organic Substances for Industrial Classification (업종별 유해성 유기물질의 확인에 대한 연구)

  • Park, Sun Ku;Kim, Sung Soo;Ko, O Suk;Jung, Sung Woong;Park, Jun Dae;Ryu, Seung Do;Ryu, Jae Kyun;Cho, Hyun-Woo
    • Analytical Science and Technology
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    • v.9 no.4
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    • pp.392-398
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    • 1996
  • Eleven organic chemical substances, tetrachloroethylene, ethyl benzene, p-xylene, o-xylene, isopropyl benzene, n-propyl benzene. 1,2,4-trimethyl benzene, 1,3,5-trimethyl benzene, p-isopropyl toluene. see-butyl benzene, and naphthalene, which have hazardously influenced to human, were extracted from untreated wastewater collected at 26 companies of 8 types industry in the basin of Kwangju stream. Their structures were elucidated by Gas Chromatography/Mass Spectrometry(GC/MS) and in comparison with each standard reagents.

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Study of Development of Selective Removal Adsorption Ion Exchange Resin Materials for Fabricated with Chemical-biological Cloth by QFD (QFD 기법을 이용한 특정 유해가스 노출제어 이온선택성 보호복 소재개발연구)

  • Song, Hwa Seon;Koo, Il Seob;Kim, In Sik
    • Journal of Korean Society for Quality Management
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    • v.43 no.3
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    • pp.359-372
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    • 2015
  • Purpose: Through studying the expert's and non-experts panel responses to the questions regarding the attributes of chemical-biological protection cloth quality in terms of the levels of customer demand and technical factors has been studied. We are applied to a QFD matrix with find out the relationship between the selective removal efficiency of chemical-biological cloth and the guidelines of technical approach. Methods: We fabricated several composite of ion-exchange resins with selectively permeable performance designed to facilities water vapor transport and selective adsorption of the harmful gases. With these materials, we characterized on the selectively permeable performance to identify ion-exchange resin with chemical-biological protective cloth. Results: Results showed that ion exchange materials possessed performance with selectively efficiencies as NH3, SOx, NOx and HCl gas. The selective adsorption amount of ammonia and hydrogen gases were $90-80{\mu}g/g$ with TRILITE SCR-BH sulfonated ion exchange resin. The PP non-woven/ion exchange resin adsorbent materials possessed performance with water vapor permeability were 1,100-1,350 g/m2/day, it's was two times high value compare with activated carbon. With these materials, we characterized selectively removal efficiency to identify new ion-exchange material with chemical-biological protective capability. Conclusion: This study shows that a QFD aids in deciding with of the adsorption parameters to optimized with chemical-biological protection cloth manufacturing.

Chemical Composition of Painting Materials used in Some Korean Shipyards (조선업의 도장 작업시 취급하는 도료중 유해물질 성분에 관한 연구)

  • Shin, Yong Chul;Yi, Gwang Yong
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.9 no.1
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    • pp.156-172
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    • 1999
  • Potential chemical hazards encountered in painting operation of four shipyards and a ship-repair shop were investigated through the material safety data sheets (MSDS). Material safety data sheets (MSDS) for 307 paints, 50 thinners and 34 binders were collected and reviewed. It was shown that various organic solvents such as aromatic hydrocarbons, aliphatic hydrocarbons, ketones, alcohols, glycols, glycol ether acetates and esters were contained in painting materials. Of these solvents, xylene was found in the largest number of painting materials. sixty percent of the thinners contained xylene in the contents of 20-100%. Other most frequently found solvents were 1-methoxypropanol, 1-methoxypropyl acetate, n-butanol, methyl isobutyl ketone, toluene, isopropanol, and n-butyl acetate, etc. Glycol ethers such as 2-methoxyethanol (2-ME), 2-methoxyethyl acetate (2-MEA), 2-ethoxyethanol (2-EE), 2-ethoxyethyl acetate (2-EEA) and 2-butoxyethanol (2-BA) were regarded as having the potential to cause adverse reproductive effects, embryotoxic effect and hematotoxic effects, and were found in some epoxy panting materials. Coal tar pitch was included in some paints(13%) where polynuclear aromatic hydrocarbons (PAHs) could be contaminated. Inorganic pigments such as lead chromate and zinc potassium chromate were found in some paints (8%). The epoxy resin based paints, which may contain isocyanates such as toluene diisocyanates and hexamethylene diisocyanates causing potential sensitization and asthma to upper respiratory organ, were mostly used in the shipyards. The constituents in the MSDS were significantly different from the results analyzed using gas chromatography/mass detector: minor constituents or impurities were omitted in many MSDS. In conclusion, xylene was the most frequent organic solvent in painting materials, and glycol ethers, including 2-ME, 2-MEA, 2-EE, 2-EEA and 2-BA, were found some products. Also, painting workers may be exposed to PAHs, lead, chromate, isocyanates, organic tin and other various chemicals. The compositions of chemicals in painting materials were variable significantly, and the hazards were changed. These facts should be considered in environmental monitoring and control of the hazards.

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Environmental and economic life cycle analysis of hydrogen as Transportation fuels (자동차 연료로서 수소의 전과정 환경성/경제성 분석)

  • Lee, Ji-Yong;Cha, Kyoung-Hoon;Yu, Moo-Sang;Lee, Soo-Yeon;Hur, Tak;Lim, Tae-Won
    • New & Renewable Energy
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    • v.3 no.2 s.10
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    • pp.31-39
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    • 2007
  • 화석연료의 사용으로 인한 자원고갈과 지구온난화 영향 그리고 에너지 안보문제의 해결을 위해 세계 각국들은 대체에너지 개발에 많은 노력을 기울이고 있다. 그 중 수소는 다양한 경로를 통해 생산 가능하고, 수송연료로 사용 시, 유해 물질이 거의 배출되지 않는다는 장점 때문에 가장 주목받는 대체 에너지원이다. 현재는 수소생산 기술개발을 통해 상업화시기를 앞당기려고 하는 수소에너지 시대의 진입시점이라 할 수 있다. 그러나 수소는 생산경로에 따라 다양한 환경성 및 경제성 결과를 도출 할 수 있기 때문에 다양한 평가가 요구된다. 본 연구에서는 국내 수소생산 방식으로 개발/상용화되어있는 Natural Gas Steam Reforming (NGSR), Naphtha Steam Reforming (Naphtha SR), Water Electrolysis (WE)에 대하여, Life Cycle Assessment (LCA)와 Life Cycle Costing Analysis (LCCA) 방법을 사용하여, 수소경로 전반에 대한 즉, 원료채취부터 자동차로 주행하였을 때까지의 각 대상 수소경로의 환경성과 경제성을 평가하였다. LCA와 LCCA 결과는 Naphtha SR과 NGSR 수소경로에서 지구온난화와 화석자원 소모 부문 모두 기존연료 (가솔린, 디젤)와 비교해서 개선효과가 뚜렷하게 나타났으나, WE 수소경로는 오히려 환경부하가 증가되는 것으로 나타났다. 또한 경제성 측면에서는, 수소 판매 시 가솔린과 동일한 연료세율을 부과하더라도 수소가 가솔린에 비해 가격경쟁력을 확보하게 되는데, 이는 주행 시 수소자동차의 연비가 기존 차량에 비해 월등히 좋기 때문에 연료비용의 이점 때문이다. 만약, 수소에 연료세를 부과하지 않는 다면, Naphtha SR로 생산하여 유통한 수소가 수송연료로서 가장 뛰어난 비용효율성을 갖는 것으로 나타났다.

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Implement of Knocking diagnostic algorithm and design of OBD-II Diagnostic system S/W on common-rail engine (커먼레일 엔진에서 노킹 진단 알고리즘 구현 및 OBD-II 진단기 S/W 설계 방안)

  • Kim, Hwa-Seon;Jang, Seong-Jin;Nam, Jae-Hyun;Jang, Jong-Yug
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.16 no.11
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    • pp.2446-2452
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    • 2012
  • In order to meet the recently enhanced emission standards at home and abroad, it is necessary to develop the CRDI ECU control algorithm that users can adjust fuel injection timing and amount in response to their needs. Therefore, this study developed the simulator for knocking analysis that enables knocking discrimination and engine balance correction applicable to the ECU exclusive to the industrial CRDI engine. The purpose of this study is to provide the driver-oriented diagnostic service that enable drivers to diagnose vehicles directly by developing diagnostic devices for vehicles with ths use of the results of the developed simulator for knocing analysis according to the OBD-II standards. For this purpose, this study aims to improve the fuel efficiency of vehicles by proposing the S/W design method of the OBD-II diagnosis device that can provide real-time communcations with the use of wired system and bluetooth module as a wireless system to send and recevice automobile fault diagnosis signal and sensor output signal, and to suggest an improvement for engine efficiency by minimizing the generation of harmful exhaust gas.

Development of a Prototype Equipment for Road Stripe Removing Using High Pressure Water-Jet (워터젯을 이용한 노면표시 제거장비의 프로토타입 개발)

  • Kim, Kyoon-Tai;Han, Jae-Goo;Kwon, Soon-Wook
    • Korean Journal of Construction Engineering and Management
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    • v.7 no.5
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    • pp.149-158
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    • 2006
  • Current removing process is labor intensive and time consuming, employing a conventional grinding type manual machine. This manual tasks trigger various dangers such as unexpected traffic accidents or explosions of propane gas used for finalizing removing process, leading to health damage and environment pollution by dusts and noxious gases. Accordingly, it is necessity for the development of new alternative equipment. In this paper, we have developed a prototype equipment for road stripe removing made up with a high-pressure water-jet system as a mobile type system. The following shows the results. First, an analysis of the current road stripe removal process showed that it can be divided into a) preparation, b) removal and c) ground finishing. It also showed that the b) removal process requires equipment which can cover the whole process. Second, the study compared between the productivity of the developed equipment and conventional methods, and it obtained 280% productivity improvement compared to the conventional equipment.