• Title/Summary/Keyword: 유해 gas

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Fabrication and Properties of Piezoelectric Microcantilever for Gas Sensor Application (가스 센서 응용을 위한 압전 마이크로 칸티레버의 제작 및 특성)

  • 신상훈;송상근;백준규;박효덕;이재찬
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.75-75
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    • 2003
  • 본 연구에서는 대기 중 극 미량으로 존재하는 환경 유해 가스 성분을 검출할 수 있는 미세 소자로의 응용을 위해 마이크로 칸티레버를 제작하고 가스 센서로의 활용 가능성을 검토하였다. 마이크로 칸티레버는 크게 구동층 캐패시터로서 대표적인 압전 재료인 Pb(Zr,Ti)O$_3$ (PZT)를 사용하고 SiNx 박막을 지지층으로 하는 형태로 제작되었다. 제작된 마이크로 칸티레버는 치수 및 형상에 따라 17~29 KHz 의 기본 공진 주파수 값을 나타내었다. Electron beam evaporator를 이용한 copper (Cu) 박막의 단계적인 증착을 통해 칸티 레버 표면에 질량을 증가시키고 그에 따른 마이크로 칸티레버의 공진주파수 변화를 관찰한 결과 질량 증가에 대해 34 Hz/ng의 선형적인 주파수 감소를 나타내었으며, 이로부터 694.4 $\textrm{cm}^2$/g 의 gravimetric sensitivity factor를 얼을 수 있었다. 마이크로칸티레버의 가스 감지능력 시험을 위해 가스 흡착층으로 일차 알콜류의 vapor를 흡착 하는 것으로 보고된 poly methyl metacrytate (PMMA)를 마이크로 칸티레버 표면에 코팅하였다. 마이크로칸티 레버의 기본 공진 주파수 및 PMMA 흡착층 형성과 가스의 흡착에 따른 주파수 변화는 마이크로 칸티 레버로부터 의 전기적 신호를 이용하는 복소 임피던스 분석에 의해 측정되었다. PMMA가 코팅된 마이크로 칸티레버는 ethanol 및 methanol vapor 의 농도가 증가함에 따라 선형적인 공진주파수 감소를 나타내었으며, methanol vapor 의 경우 0.06 Hz/ppm 의 가스 검출 감도를 얻을 수 있었다.

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A Compact Pulse Corona Plasma System with Photocatalyst for an Air Conditioner (광촉매와 조합된 코로나 방전 플라즈마 필터의 유해 가스 및 입자 제거 특성)

  • Shin, Soo-Youn;Moon, Jae-Duk
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.1
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    • pp.151-155
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    • 2007
  • A compact discharge plasma system with a photocatalyst has been proposed and investigated experimentally for application to air conditioners. It was found that there was intense ultra violet radiation with high energy of 3.2 eV from the corona discharge due to the DC-biased pulse voltage applied on a wire. An electrophotochemical reaction took place apparently on the surfaces of the photocatalyst of $TiO_2$ irradiated ultra violet front the discharge plasma in the proposed plasma system. The proposed discharge plasma system with the photocatalyst of $TiO_2$ showed very high removal efficiency of VOCs by tile additional electrophotochemical reactions on the photocatalyst. The proposed discharge plasma system also showed very high removal efficiency of particles such as smokes, suspended bacteria, and pollen and mite allergens by the electrostatic precipitation part. This type of corona discharge plasma system with a photocatalyst can be used as an effective means of removing both indoor pollutant gases and particles including suspended allergens.

Pathophysiology of Chronic Obstructive Pulmonary Disease (만성폐쇄성폐질환의 병태생리)

  • Kim, Hyun Kuk;Lee, Sang-Do
    • Tuberculosis and Respiratory Diseases
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    • v.59 no.1
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    • pp.5-13
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    • 2005
  • Chronic obstructive pulmonary disease (COPD) is a chronic progressive disease, characterized by irreversible airflow limitation, with a partially reversible component. The pathological abnormalities of COPD are associated with lung inflammation, imbalances of proteinase and antiproteinase, and oxidative stress, which are induced by noxious particles and gases in susceptible individuals. The physiological changes of COPD are mucus hypersecretion, ciliary dysfunction, airflow limitation, pulmonary hyperinflation, gas exchange abnormalities, pulmonary hypertension, cor pulmonale and systemic effects. The airflow limitation principally results from an increase in the resistance of the small conducting airways and a decrease in pulmonary elastic recoil due to emphysematous lung destruction. This article provides a general overview of the pathophysiology of COPD.

The Characteristics of Spray and Exhaust Emissions Environmental Assessment of Adulteration and Convention Diesel (유사경유 및 정상경유 미립화특성과 배출가스 환경성평가)

  • Lee, Jong-Tae;Moon, Sun-Hee;Kim, Jeong-Soo;Kim, Sun-Moon;Park, Gyu-Tae;Lim, Yun-Sung
    • Journal of ILASS-Korea
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    • v.18 no.2
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    • pp.106-111
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    • 2013
  • Adulterations fuel have been using in the vehicle in these days. Because gasoline, diesel prices are rising every day. so people find more cheap price fuel. Adulterations fuel caused a serious air pollution problems. Adulteration fuel were made from waste engine oil, waste paint. According to Government regulations permit to be used recycle fuel(adulteration fuel) only in industrial boiler. Unburned fuel pollutants are effected to human health. In this paper, the hazardous air pollutants characteristics in the diesel vehicles according to adulterations of vehicle fuels were carried out in the NEDC test mode in chassis dynamometer. It is revealed that the all of the regulation pollutants (THC, NOx, CO and PM) emission in the adulterations of vehicle fuels was increased also the green house gas, $CO_2$ was increased. In the hazardous air pollutants characteristics, the VOCs(Volitile Organic Compounds) BTEX(Benzene, Toluene, Ethylbenzene, Xylene) emissions in the adulterations of vehicle fuels showed higher level than these in the diesel fuels.

A Study on Development of On-line Condition Monitoring Program of a Turboshaft Engine (터보샤프트 엔진의 온라인 상태감시 프로그램 개발에 관한 연구)

  • Kong, Chang-Duk;Kho, Seong-Hee;Ki, Ja-Young;Gu, Young-Joo;Jun, Yong-Min
    • Journal of the Korean Society of Propulsion Engineers
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    • v.12 no.6
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    • pp.7-11
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    • 2008
  • The helicopter flies at low level flight mode in its own operational range comparing to other aircraft categories. The low level flight means that the engine operates at variable atmospheric condition such as hot and cold temperature, snow, heavy rain, etc. Furthermore it may increase the entering possibility of engine foreign object damage particles like sand, dust, etc., i.e. this operating condition gives rise to damages of engine gas path components. An on-line condition monitoring program was developed by using SIMULINK, where measurement signals were simulated as an input module. The reliability and capability of the developed on-line condition monitoring were confirmed through application to a real helicopter engine health monitoring.

Pyrolysis Reaction for the Treatment of Hazardous Halogenated Hydrocarbon Waste (유해 할로겐화 탄화수소 폐기물 처리를 위한 열분해 반응)

  • 조완근
    • Journal of Environmental Science International
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    • v.6 no.4
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    • pp.399-407
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    • 1997
  • The pyrolysis reactions of atomic hydrogen with chloroform were studied In a 4 cm 1.6. tubular flow reactor with low flow velocity 1518 cm/sec and a 2.6 cm 1.4. tubular flow reactor with high flow velocity (1227 cm/sec). The hydrogen atom concentration was measured by chemiluminescence titration with nitrogen dioxide, and the chloroform concentrations were determined using a gas chromatography. The chloroform conversion efficiency depended on both the chloroform flow rate and linear flow velocity, but 416 not depend on the flow rate of hydrogen atom. A computer model was employed to estimate a rate constant for the initial reaction of atomic hydrogen with chloroform. The model consisted of a scheme for chloroform-hydrogen atom reaction, Runge-Kutta 4th-order method for Integration of first-order differential equations describing the time dependence of the concentrations of various chemical species, and Rosenbrock method for optimization to match model and experimental results. The scheme for chloroform-hydrogen atom reaction Included 22 elementary reactions. The rate constant estimated using the data obtained from the 2.6 cm 1.4. reactor was to be 8.1 $\times$ $10^{-14}$ $cm^3$/molecule-sec and 3.8 $\times$ $10^{-15}$ cms/molecule-sec, and the deviations of computer model from experimental results were 9% and 12% , for the each reaction time of 0.028 sec and 0.072 sec, respectively.

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Plasma Immersion Ion Implantation을 적용한 알루미늄합금의 방열 및 내부식특성에 관한 연구

  • Kim, Jeong-Hyo;Kim, Seung-Jin;Cha, Byeong-Cheol;Kim, Seon-Gwang;Son, Geun-Yong;Gwon, A-Ram
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.247-247
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    • 2012
  • 기존형광등보다 에너지소비가 적고, 수명이 길다는 장점을 가진 LED소자는 조명분야뿐만 아니라 선박 및 해양플랜트시장에까지 적용분야가 확대되고 있다. 그러나 LED소자의 수명연장 및 제품신뢰성을 위해서 방열에 관한 연구가 필수적이며 특히, 해양환경적용을 위해서는 내부식성을 요구하는 방열 재료개발에 대한 연구가 필요하다. 일반적으로 방열판소재로 사용되는 알루미늄의 경우 열전도도가 우수하며, 대기 중에서 쉽게 생기는 자연산화막보다 내부식특성을 향상시키기 위해 현재 국내 외의 표면처리 방법으로 전기화학적 방법을 이용한 Anodizing기술을 적용하고 있다. 하지만, Anodizing에 사용되는 질산과 황산액을 처리하는 과정에서 유독물질을 발생시킴으로 유해물질사용제한 등 국제적으로 환경규제가 강화되고 있어 Anodizing기술의 적용이 제한적인 단점이 있다. 본 연구에서는 친환경적 기술인 Plasma Immersion Ion Implantation (PIII)방식을 사용하여 알루미늄표면에 $Al_2O_3$을 형성하였다. 최적의 산화막증착 조건을 찾기 위해 Gas Flow양, Pulse Voltage, 공정온도, 시간 등을 변수로 실험을 진행하였다. SIMS (Secondary ion mass spectroscopy)를 통해 $Al_2O_3$ 박막두께 및 Oxygen의 정량분석을 하였으며, Anodizing처리된 알루미늄시편과 열전도특성과 내부식특성을 비교하기 위해 각각 Hot Disk 열전도율측정기와 Salt water tester chamber를 사용하였다.

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The study to measure of the BTX concentration using ANN (인공신경망을 이용한 BTX 농도 측정에 관한 연구)

  • 정영창;김동진;홍철호;이장훈;권혁구
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.5 no.1
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    • pp.1-6
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    • 2004
  • Air qualify monitoring if a primary activity for industrial and social environment. Especially, the VOCs(Volatile Organic Compounds) are very harmful for human and environment. Throughout this research. we designed sensor array with various kinds of gas sensor, and the recognition algorithm with ANN(Artificial Neural Network : BP), respectively. We have designed system to recognize various kinds and quantities of VOCs, such as benzene, tolylene, and xylene.

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Atomization Characteristics Experiment of Hole Type Nozzle for the Reduction of Harmful Exhausted Gas (유해배기가스 저감을 위한 Hole형 노즐의 미립화 특성실험)

  • Chung, Jin-Do;Yu, Byoung-Gu
    • Journal of ILASS-Korea
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    • v.2 no.3
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    • pp.17-24
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    • 1997
  • A simplified experiment was performed to figure out the atomization characteristics of rice-bran oil which it is highly viscous liquid by applying ultrasonic energy. A spray system, an ultrasonic system, and three kinds of hole-type nozzles(hole diameter: 0.31, 0.34, 0.37mm) were manufactured. To investigate the effects of ultrasonic energy on the atomization of a highly viscous liquid, a phase doppler particle analyzer was used for measurement and calculation of spray droplets data. Nozzle opening pressures were chosen of 3 levels, i.e, 16, 20, and 24MPa. As a result, it could be concluded that the ultrasonic energy was effective to improve the spray atomization when it applied to the fuel by means of 3 different nozzles because of the effects of the liquid fuel cavitation and relaxation between molecules caused by ultrasonic energy. The improvement rate of the spray atomization by the ultrasonic method compared with the conventional spray increased about 15% in the case of hole type nozzles. By increasing of the nozzle opening pressure and decreasing of the hole diameter, the atomization of spray droplets was improved.

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A study on importance of MSDS education (MSDS 교육의 중요성에 관한 연구)

  • Choi, Sung-Jai
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.15 no.6
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    • pp.209-215
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    • 2015
  • Following the semiconductor industry's growing, various types of toxic gases and caustic chemicals, HF(Hydrofluoric acid), HCI (Hydochloric acid), $H_2O_2$ (Hydrogen peroxide), $H_2SO_4$ (Sulfuric acid), and Piranha, were using on the semiconductor manufacturing process. Therefore many gas leakage accidents that produce huge losses of lives were caused by the processes. This research deeply considers two basic solutions that the necessity of MSDS education on university for reducing damage of lives and protecting life from chemical leak accidents such as a HF accident in Gumi, Korea and the use of GHS, REACH and the comprehension of propriety about using MSDS for keeping safety from conflagrations by released poison chemical materials.