• Applied Chemistry for Engineering
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• v.7 no.1
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• pp.162-170
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• 1996

Light cycle Oil(LCO) contains 2,6-dimethylnaphthalene (2,6-DMNA) which is used as the basic material for high performance engineering plastics and liquid crystal polymer. This study was experimentally investigated to concentrate a mixture of dimethylnaphthalene(DMNA) isomers in the LCO by extraction-distillation combination as a pretreatment for separation and purification of 2,6-DMNA in the LCO. Furthermore, concentration of a mixture of DMNA isomers in the LCO compared between distillation and extraction-distillation combination. The recovery of aromatics in the LCO was performed by batch cocurrent multistage extraction with dimethylsulfoxide and water mixture as solvent. The concentration of naphthalene group(carbon number 10-12) in the extracted mixture is higher than that in the LCO. The yield for naphthalene group increased with decreasing carbon number. The yield for a mixture of DMNA isomers obtained in 5 equilibrium extration runs was about 65%. the separation of individual components with extractedmixture was tested by batch distillation. Futhermore, for recovery of a mixture of DMNA isomers of high concentration, distillate containing DMNA was distilled. As a result, a mixture of DMNA isomers with high concentration such as 60wt% was recovered. The extraction-distillation combination was more effective than the distillation to concentration a mixture of DMNA isomer in the LCO.

• Journal of Wetlands Research
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• v.18 no.4
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• pp.357-362
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• 2016

Improvement of the solid-liquid separation efficiency in the secondary sedimentation tank of the biological treatment process, is known to be increasing effectiveness of the overall system operation. Sewage treatment plant effluent SS is composed of most organic substances. In order to reduce the SS component in the secondary sedimentation tank discharge, fine SS components constituting the heterogeneous should be increased by its own aggregation (self flocculation), so that can be deleted through their precipitation. So, it is improved through using the installation of double rectification wall in this secondary tank. In case, sewage is rapidly increased due to the daily change of the influent water, it was confirmed that suspended solids caused by the impact load are processed stably. Therefore, there is a need for a facility installation which can be its own aggregation for reduction suspended solids in secondary sedimentation tank.

• Resources Recycling
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• v.20 no.2
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• pp.60-66
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• 2011

Solvent extraction experiments were carried out to recover and separate Ru(III) from aqueous hydrochloric acid media using TBP and Cyanex923. The efficiency of the extraction was studied under various experimental conditions, such as concentration of HCl and NaCl, concentration of extractant in the organic phase and temperature. The extraction behavior of metal impurities, such as Pt, Bi, Sn, Fe, Pb and Cu in mixed solutions was examined. From the experimental studies, it was found that the Cyanex923 resulted in higher extraction percentage of Ru than TBP. However TBP was more effective for the separation of Ru and Pt, Bi, Sn in mixed solutions than Cyanex923.

• Journal of Korea Water Resources Association
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• v.35 no.3
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• pp.331-344
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• 2002

This study is aimed at the development of a deterministic runoff model which can be used for flood runoff. The model is formulated by the watershed runoff model. Based on the assumptions that runoff system is nonlinear, the proposed watershed runoff model is the conceptual model. In the model structure, the conceptual model divides the runoff system into a surface structure and a subsurface structure corresponding to the surface flow, and inter flow and ground water flow respectively. The lag time effect of surface can be represented by the sub-tank of surface structure in the conceptual model. The parameter calibration of inter flow and ground water flow in the subsurface structure of the conceptual model is performed by separating the components with numeric filter The runoff coefficient($\alpha$$_2$) is expressed as the function of antecedent precipitation index(API). The parameters with the surface flow can be calibrated with the runoff coefficient($\alpha$$_1$ and $\alpha$/$_{11}$) in the conceptual model. In the conceptual model, an algorithm is developed to calibrate the parameters automatically based on efficiency criteria. The comparative study shows that simulated value from the conceptual model well agreed to observed value.

• Applied Chemistry for Engineering
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• v.18 no.2
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• pp.168-172
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• 2007

The separation of indole from a model mixture comprising four kinds of nitrogen heterocyclic compounds [indole (In), quinoline (Q), iso-quinoline (iQ), quinaldine (Qu)], three kinds of bicyclic aromatic compounds [1-methylnaphthalene (1MN), 2-methylnaphthalene (2MN), dimethylnaphthalene (DMN)], biphenyl (Bp) and phenyl ether (Pe) was examined by batch cocurrent 4 stages equilibrium extraction. The model mixture used as a raw material in this work was prepared according to the components and compositions contained in coal tar fraction (the temperature ranges of fraction: $240{\sim}265^{\circ}C$). An aqueous solution of formamide was used as a solvent. Indole was recovered more than 99% through 4 stages of the equilibrium extraction. The range of selectivity of indole in reference to DMN obtained through the 5 stages equilibrium extraction was found to be 63~118. The process for separation and recovery of indole contained in coal tar was studied by using the experimental results obtained from this work and the previous work.

• Applied Chemistry for Engineering
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• v.21 no.2
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• pp.238-241
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• 2010

The purification of indole from 54.3wt% indole fraction (temperature range of distillate: $250{\sim}255^{\circ}C$) recovered by extraction-distillation combination of coal tar fraction (temperature range of distillate: $240{\sim}265^{\circ}C$) was examined by solute crystallization. The feed consists of eight components such as quinoline, iso-quinoline, indole, quinaldine, 1-methylnaphthalene, 2-methylnaphthalene, biphenyl and phenyl ether. Hexane and an aqueous solution of methanol (50 : 50 vol%) were used as the crystallization solvent and the coolant, respectively. A batch stirred tank of glass material was used as a crystallization apparatus. By increasing the operation temperature and the volume ratio of solvent to feed at initial, the purity of indole increas ed, but yields of indole showed a decreasing tendency. Solute crystallization method using hexane as a solvent was excellent because the purity of 99.3 wt% indole was recovered at the yield of 50% without washing operation.

• Korean Journal of Food Science and Technology
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• v.31 no.2
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• pp.522-526
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• 1999

Bactericidal effects of chitosans with varying molecular weight $(10,000{\sim}170,000)$ were investigated for Streptococcus mutans, a primary causative bacterium of dental caries. The molecular weight of chitosan was a significant contributor to the bactericidal effect, and a chitosan having approximately 30,000 of molecular weight exhibited the highest bactericidal effects on S. mutans. Treatment of chitosan resulted in leaking intracellular protein and nucleic acid out of S. mutans cells. In addition, the divalent cations such as $Ca^{2+}\;and\;Mg^{2+}$ were also significantly released out of the cell. Visible damage of chitosan treated cells was observed by transmission electron microscopy (TEM), in which the cell wall was notably distorted and cytoplasmic membrane was separated from the cell wall. The results suggested that the bactericidal effect of chitosan on S. mutans was attributable to both leakage of intracellular materials and structural disintegration of cell wall.

• Proceedings of the Korea Water Resources Association Conference
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• 2010.05a
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• pp.2016-2020
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• 2010

기존에 국내외에서 적용되는 지하수 함양량 추정방법인 기저유출 분리법, 연단위 물수지 분석법, 지하수위변동법 등은 집중형 개념을 기반으로 하거나 국지적인 규모로 다뤄지기 때문에 함양량의 시공간적 변동성을 나타내기에는 한계가 있다. 따라서 본 연구에서는 시공간적으로 변하는 지하수 함양량을 정량적으로 추정할 수 있는 기법을 이용, 실제 유역에 적용하였다. 이를 위해 강우-유출 모형은 수문성분 해석 이론이 잘 정립된 SWAT모형과 SWAT모형의 지하수 부분을 MODFLOW모형으로 대체한 SWAT-MODFLOW모형을 선택하였고, 분석 대상유역인 정읍지역을 대상으로 각 소유역 및 수문학적 반응단위(Hydrologic Response Unit: HRU)별로 토지이용과 토양통 특성을 반영하여 지하수 함양량의 시공간적인 변화를 산정하였다. 2001년부터 2008년까지의 소유역별 일단위 지하수 함양량을 산정하였으며, 함양량의 시 공간적 변동성을 분석한 결과 월평균 함양량의 경우 대략 280mm 범위 내에서 유역의 토지이용 및 토양특성, 경사 등에 따라 매우 비 균질하게 분포하는 것을 확인할 수 있었다. 이렇게 산정한 함양량은 지역지하수 관리계획에 유연하고 합리적으로 적용될 수 있을 것으로 판단된다.

• Journal of The Geomorphological Association of Korea
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• v.23 no.1
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• pp.77-85
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• 2016

To understand the difference of runoff discharge processes between Gwangneung deciduous and coniferous forest catchments, we collected hydrological data (e.g., precipitation, soil moisture, runoff discharge) and conducted hydrochemical analyses in the deciduous and coniferous forest catchments in Gwangneung National Arboretum in the northwest part of South Korea. Based on the end-member mixing analysis of the three storm events during the summer monsoon in 2005, the hillslope runoff in the deciduous forest catchment was higher 20% than the coniferousforest catchment during the firststorm event. Howerver, hillslope runoff increased from the second storm event in the coniferous catchment. We conclude that low soil water contents and topographical gradient characteristics highly influence runoff in the coniferous forest catchment during the first storm events. In general, coniferous forests are shown high interception loss and low soil moisture compared to the deciduous forests. It may also be more likely to be a reduction in soil porosity development when artificial coniferous forests reduced soil biodiversity. The forest soil porosity is an important indicator to determine the water recharge of the forest. Therefore, in order to secure the water resources, it should be managed coniferous forests for improving soil biodiversity and porosity.

• Korean Journal of Food Science and Technology
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• v.20 no.2
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• pp.176-187
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• 1988

Volatile flavor components in the Chinese quince fruits were trapped by simultaneous steam distillation-extraction method, and these were fractionated into the neutral, the basic, the phenolic and the acidic fraction. In the identification of carboxylic acids, the acidic fraction was methylated with diazomethane. Volatile flavor components in these fractions were analyzed by the high-resolution GC and GC-MS equipped with a fused silica capillary column. The total of one hundred and forty-five compounds from the steam volatile concentrate of the Chinese quince fruits were identified: they were 3 aliphatic hydrocarbons, 1 cyclic hydrocarbon, 4 aromatic hydrocarbons, 9 terpene hydrocarbons, 17 alcohols, 3 terpene alcohols, 6 phenols, 21 aldehydes, 7 ketones, 28 esters, 27 acids, 3 furans, 2 thiazoles, 2 acetals, 3 lactones and 9 miscellaneous ones. The greater part of the components except for carboxylic acids were identified from the neutral fraction. The neutral fraction gave a much higher yield than others and was assumed to be indispensable for the reproduction of the aroma of the Chinese quince fruits in a sensory evaluation. According to the results of the GC-sniff evaluation, 1-hexanal, cis-3-hexenal, trans-2-hexenal, 2-methyl-2-hepten-6-one, 1-hexanol, cis-3-hexenol, trans, trans-2, 4-hexadienal and trans-2-hexenol were considered to be the key compounds of grassy odor. On the other hand, esters seemed to be the main constituents of a fruity aroma in the Chinese quince fruits.