• Title/Summary/Keyword: 유인물질

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Synthesis and Biological Activity Test of the Sex Pheromone of the Diamond Back Moth (배추좀나방의 성 페로몬의 합성과 생물활성시험)

  • Suk-Ku Kang;Chul-Hee Lee;Jung Han Kim;Jeong-Oon Lee
    • Journal of the Korean Chemical Society
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    • v.32 no.1
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    • pp.60-64
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    • 1988
  • Synthesis and biological activity test are described for the (Z)-11-hexadecen-1-ol, (Z)-11-hexadecen-1-yl acetate, and (Z)-11-hexadecen-l-al, the sex pheromone of the diamond back moth, Plutella xylostella L.. Lithium acetylide was alkylated with 10-bromodecan-1-ol THP ether to give 11-hexadecyn-l-ol THP ether. 11-Hexadecyn-l-ol THP ether was stereoselectively reduced over Pd/BaSO4to yield (Z)-11-hexadecen-l-ol THP ether, which was in turn deprotected to provide (Z)-11-hexadecen-l-ol. (Z)-11-Hexadecen-l-ol was acetylated and oxidized to afford (Z)-11-hexadecen-1-yl acetate and (Z)-11-hexadecen-l-al, respectively. Biological activity test of the synthetic compounds, (Z)-11-hexadecen-l-ol, (Z)-11-hexadecen-1-yl acetate, and (Z)-11-hexadecen-l-al in the ratio of 0.1 : 5 : 5 was tested in the field using polyethylene capsules as containers. The numbers of moth trapped with pheromone vials were counted.

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Mechanisms for the Initiation of Sperm Motility (정자운동 개시 기구)

  • Kho Kang Hee;Kang Kyoung Ho;Chang Young Jin
    • Development and Reproduction
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    • v.7 no.2
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    • pp.81-88
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    • 2003
  • Initiation and activation of sperm motility are prerequisite processes for the contact and fusion of male and female gametes at fertilization. The phenomena are under the regulation of CAMP and $Ca^{2+}$ in vertebrates and invertebrates. Mammalian sperm requires $Ca^{2+}$and cyclic AMP for the activation of sperm motility. Cell signaling for the initiation and activation of sperm motility has been well studied in the ascidians, Ciona intestinalis and C. savignyi and salmonid fishes. In Ciona, whose cell signaling for activation of sperm motility has been established, the sperm-activating and -attracting factor released from unfertilized egg requires extracellular $Ca^{2+}$ for activating sperm motility and eliciting chemotactic behavior of the activated sperm toward the egg. On the other hand, the cyclic AMP-dependent phosphorylation of protein is essential for the initiation of sperm motility in salmonid fishes. A decrease in the environmental Ti concentration surrounding the spawned sperm causes a li efflux and $Ca^{2+}$ influx through the specific $K^{+}$ channel and dihydropyridine-sensitive L-/T- type $Ca^{2+}$ channel, respectively, thereby leading to the membrane hyperpolarization and $Ca^{2+}$ influx. The membrane hyperpolarization synthesizes cyclic AMP, which triggers the luther Process of cell signaling, i.e., cyclic AMP-dependent protein phosphorylation, to initiate sperm motility in salmond fishes.almond fishes.

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Survey on a Research for Fire Safety in Space with the Understanding of Combustion Characteristics in Microgravity based on NASA's Space Research Program (NASA의 우주 연구 프로그램에 따른 미소 중력하에서의 연소 특성 및 화재 안전 연구 개괄)

  • Sohn, Chae-Hoon;Son, Young-Jin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.11 no.3
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    • pp.65-72
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    • 2007
  • Fire is one of important checkpoints in crewed exploration systems, where men inhabit in space. In space, astronaut can't escape from fire out of a spacecraft and not expect any help of fire fighters, either. Accordingly, the best way to stand against fire is to prevent it. But, when fire occurs in space, flame behaviors are quite different from those observed on earth because of micro- or zero-gravity in space. The present paper introduces major research results on flame behaviors under microgravity and fire prevention, detection, and suppression in crewed exploration spacecrafts and international space station based on NASA's FPDS research program.

Study of Separation of carbon dioxide through hollow fiber membrane contactor (중공사막 접촉장치를 통한 이산화탄소 분리에 관한 연구)

  • 염봉열;김민수;이용택;박유인;이규호
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.61-64
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    • 1997
  • 1. 서론 : 적절한 이산화탄소의 분리는 지구온난화의 가속현상을 늦출 수 있을 뿐만 아니라 각종 탄화수소가스의 원료로 분리 정제된 이산화탄소를 재이용할 수 있으므로 경제적으로 매우 중요하다. 이산화탄소 분리에 사용되던 기존 공정들의 단점을 보완할 수 있는 대체방안으로 최근에 개발되기 시작한 것이 소수성의 다공성 고분자 분리막(hydrophobic porous ploymeric membrane) 방법인데, 이는 모듈의 유효 막 표면적이 상대적으로 크고 기체와 액체의 흐름을 독립적으로 제어할 수 있으므로 범람 등의 현상이 없으나 막 자체의 저항이 비교적 큰 단점을 가지고 있다. Qi와 Cussler는 이러한 특성을 가지는 중공사막 모듈에서의 기-액 흐름에 대한 물질전달 상관관계식을 얻었으며[1], Karoor 등은 여러 가지 중공사막 모듈을 사용하여 순수물과 diethanolamine(DEA) 등의 흡수제에 대한 이산화탄소의 물질전달 거동을 수치모델과 실험을 통하여 고찰하였다[3]. 또한 중공사막 접촉기의 실제적 응용에 대하여 Matsumoto 등은 화력발전소에서 발생하는 연소가스 내의 이산화탄소 흠수에 대한 연구를 수행하였다[4]. 본 연구에서는 중공사막 접촉장치를 사용하여 흡수제를 순수물과 탄산칼륨($K_2CO_3$)을 사용했을 경우의 이산화탄소의 분리 거동을 수치모델과 실험을 통하여 고찰하였다. 수치모델의 경우 이전까지의 연구가 반응이 없는 경우나 반응식을 간략화시킨 경우에 한정되었는데 비하여, 반으이 있는 경우 각각의 반응물질들의 거동을 고려한 반응식을 유도하여 해를 구하고자 하녔다.

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Associated Nitrogen Fixation in the Rhizosphere of Rice in Saline and Reclaimed Saline Paddy Soil -IV. Chemotaxis of Associative N2-fixing Bacteria to Single or Combined Sugars and Root Exudates (간척지토양(干拓地土壤)의 수도근권(水稻根圈)에서 협생질소고정(協生窒素固定)에 관(關)한 연구(硏究) -제사보(第四報). 협생질소고정균(協生窒素固定菌)의 단당(單糖) 및 복합당류(複合糖類)와 근분비물질(根分泌物質)에 대(對)한 화학주화성(化學走化性))

  • Lee, Sang-Kyu;Suh, Jang-Sun;Ko, Jae-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.20 no.4
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    • pp.359-367
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    • 1987
  • A method for evaluating bacterial chemotactic responses toward several single of combined sugars and sterile mucilage from the different rice cultivars had been tested. Bacterial genus of Azospirillum, Pseudomonas and Agrobacterium were specially identified from the histosphere of different rice cultivars and graminea grasses in saline and reclaimed saline paddy soil. To evaluate chemotaxis of these strains a modification of Fendrik channel method was used. Under this condition Azospirillum lipoferum Ecc 3-1 reacted stereoisomerically fomulating the single migration ring while Agrobacterium radiobacter Ecc 1-1 and Pseudomonas sp Ecc 4-1 did not. Strains specificities of chemotaxis to the single sugar such as D(+)-glucose and D(+)-fructose were less prominent than malic and citric acid. Chemotactic responses to the combined sugar such as D-galacturonic acid and the L-aspartate were found high attracting reaction than other combined sugars. Chemotaxis of associative $N_2$-fixing bacteria to the root exudates of different rice cultivars were differed among bacterial strains and rice cultivars.

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Responses of Phyllotreta striolata and Athalia rosae ruficornis to Colored-sticky Traps and Aggregation Pheromone and Seasonal Fluctuations in Radish Fields on Jeju Island (제주지역 무에서 벼룩잎벌레와 무잎벌의 색트랩과 집합페로몬에 대한 반응과 연중 발생특성)

  • Song, Jeong Heub;Yang, Young Taek;Yang, Cheol Jun;Choi, Byeong Ryul;Jwa, Chang Sook
    • Korean journal of applied entomology
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    • v.54 no.4
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    • pp.289-294
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    • 2015
  • Striped flea beetle, Phyllotreta striolata (SFB) and turnip sawfly, Athalia rosae ruficornis (TSF) are two economically important sporadic pests in radish fields on Jeju island. The response of adult SFB and TSF to a mixture of aggregation pheromone, (+)-(6R,7S)-himachala-9,11-diene and host plant volatile, allyl isothiocyanate (HAI), as well as to yellow and blue sticky traps was examined in radish fields. Adult SFB was more attracted to the sticky trap with HAI, regardless of the color of the sticky trap; however, adult TSF was more attracted on the yellow sticky trap than blue, and no effect of HAI was observed. The adult SFB and TSF can be effectively monitored using yellow sticky traps placed 10 cm above the plant canopy. SFB and TSF had 3 and 5 peak times in a year, respectively. The first peak occurred in the middle of March for SFB and mid-late of April for TSF. We expect that the results of the present study can facilitate minimizing the damage caused by the two important pests in commercial radish fields.

Identification of Greyish White Material Adhered to Shrouds from Tombs Covered with Lime of the Chosun Dynasty (조선시대 회곽 묘 출토 염습의에 부착된 회백색 물질의 동정)

  • OH, Joon-Suk;Yu, Hei-Sun;Yun, Eun-Young
    • Journal of Conservation Science
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    • v.16 s.16
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    • pp.21-26
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    • 2004
  • A lot of waterlogged shrouds and mummies have been found in tombs revered with lime of the Chosun Dynasty(1392-1910) of Korea. Shrouds were heavily polluted with greyish white material. Greyish white material, which adhered to shrouds excavated from tombs(16C and 17C), was submitted to FT-IR qualitative analysis and fatty acid analysis for cleaning. The results of the FT-IR qualitative analysis identified the main ingredient of the greyish white material as calcium salt of fatty acid, including a little of the fatty acids, lipids and proteins. Therefore the greyish white material fumed out adipocere which was formed from the degradation of the lipids in a dead body. From the fatty acid analysis, hydroxy fatty acids(10-Hydroxyhexadecanoic acid and 10-Hydroxyoctadecanoic acid), which were found in adipocere, were detected. The distribution of contents of fatty acids was also rimilar to that of adipocere which have a high proportion of palmitic acid of saturated fatty acid and a low proportion of oleic arid of unsaturated fatty acid. In view of the results of analyses, it was revealed that greyish white material adhered to shrouds was adipocere moved from a mummy.

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플라즈마를 이용한 폴리머합성과 특성

  • Yu, In-Geun;Park, Seung-Il;Yu, Seung-Min;Kim, Seong-Bong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.144.2-144.2
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    • 2015
  • 폴리머는 물건 포장, 산업재, 자동차 등 다양하게 사용되는 물질이다. 그런데 이러한 폴리머 제품을 제조하기 위해서는 일정 규모의 생산시설이 필요하다. 최근, 플라즈마를 이용한 여러 가지 폴리머 합성법들이 개발되면서 보다 편리하고 간편한 생산법이 제시되고 있으며, 다양한 분야에서 그 응용가능성을 타진하고 있다. 본 연구에서는 비교적 간단하게 플라즈마를 발생시킬 수 있는 대기압 AC 플라즈마 장치를 이용해 가장 많이 응용되고 있는 methyl methacrylate($C^5H^8O^2$)와 ethyl methacrylate($C^6H^{10}O^2$)를 폴리머로 합성했다. 이렇게 합성된 각 폴리머의 여러 가지 특성평가와 합성과정에서 부각된 여러 변수 및 합성 메커니즘에 대해서 살펴본다. 그리고 향후 플라즈마를 이용한 다양한 폴리머합성 가능성과 농업, 식품, 환경개선, 바이오 등의 응용 가능성에 대해서도 살펴볼 예정이다.

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An Antibacterial Compound against Pasteurella haemolytica Poduced by Streptomyces sp. 51086 (반추동물 급성기관지폐렴균 Pasteurella haemolytica에 항균활성을 갖는 물질의 특성규명)

  • 강희철;유인자;윤봉식;전용수;유익동
    • Microbiology and Biotechnology Letters
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    • v.27 no.4
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    • pp.339-343
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    • 1999
  • Pasteurella haemolytica is well known to cause severe pneumonia, consolidation and oedema of the lung, and fibrinous pleurisy under the stress and infection of virus in the cattle. In the course of our screening for antimicrobial agents against P.haemloytica, compound 51086 has been isolated from the fermentation broth of Streptimyces sp. 51086. The compound 51086 was purified by SiO2, Sephadex LH-20 and ODS column chromatographies and HPLC, subsequently. The structure of compound 51086 was determined as hygromycin A by combination of 1H NMR, 13C NMR, HMBC, and ESI-MS. This compound showed significant antibacterial activity against P.haemolytica and P.multocida.

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Properties of MFS capacitors using $YMnO_3$ film ($YMnO_3$를 이용한 MFS 커패시터의 특성)

  • 김채규;김진규;정순원;김용성;이남열;김광호;유병곤;이원재;유인규
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.425-428
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    • 1999
  • In this paper, the electrical properties of Pt/YMnO$_3$/Si(100) structures with difference rapid thermal annealing (RTA) treatment were investigated. YMnO$_3$films were obtained without buffer layers, introducing oxygen. A typical value of the dielectric constant was about 20 derived from 1MHz capacitance-voltage (C-V) measurement and the resistivity of the film at the field of 150kV/cm was about 1.34$\times$10$^{12}$ $\Omega$ . cm. The minimum interface state density around midgap was estimated to be about 5$\times$10$^{11}$ cm$^2$. eV.

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