• Title/Summary/Keyword: 유용금속

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A Simple Shell Model Approach to Lattice Dynamics of Cr, Mo, and W

  • Kim, Chang-Hyo;Chang, Jong-Hwa
    • Nuclear Engineering and Technology
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    • v.7 no.2
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    • pp.107-118
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    • 1975
  • The lattice dynamics of Cr, Mo, and W are formulated in terms of a simple shell model in which the transition metal ions in the crystals are treated as deformable ions. The model involves a total of seven parameters; two charge parameters and five force constant parameters. The numerical values of the model parameters are determined by fitting to three elastic constants and the lattice vibrational frequencies measured by the neutron inelastic scattering experiments. Attempts are made to compute the phonon dispersion relations, the frequency distribution functions, and the lattice specific heats of three metals. The results are compared with experiments. It is found that the simple shell model can give a satisfactory account for the lattice vibrational characteristics of transition metals. The usefulness of the model is then discussed in comparison With other lattice dynamical models.

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Operative Treatment of the Displaced Midshaft Clavicle Fracture Using Precontoured Locking Compression Plate (Precontoured Locking Compression Plate를 이용한 전위성 쇄골 간부 골절의 수술적 치료)

  • Kim, Jeong Woo;Kang, Hong Je;No, Sung Hyun
    • Clinics in Shoulder and Elbow
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    • v.15 no.2
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    • pp.117-122
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    • 2012
  • Purpose: To assess the effectiveness of internal fixation using a precontoured locking compression plate for the treatment of the displaced clavicle fracture by analyzing both radiological and clinical outcomes. Materials and Methods: We reviewed 34 cases of displaced clavicle shaft fracture treated by internal fixation using precontoured locking compression plates between May 2009 and February 2010. Radiological outcomes were analized on the basis of bone union and the differences between the time for bone union depending on sex and age. Clinical outcomes were analyzed on the basis of quick DASH Scores and the differences in the range of motion of the affected shoulder compared to the contralateral shoulder. Results: In the radiological evaluation, all fractures showed bone union, and the average time for bone union was 12.3 weeks, without delayed unions. Time for bone union did not differ significantly with respect to sex and age (p=0.87). In the clinical evaluation, the average final quick DASH Score was 23.5 (range, 12~42). At final follow up, the range of motion after bone union in the affected shoulder was not significantly different from that of the contralateral shoulder (p=0.69). Conclusion: The internal fixation achieved using precontoured locking compression plate in displaced clavicle shaft fracture showed effective bone union and can be considered as a reliable method with fine clinical results showing early range of motion at the shoulder joint.

The Study of Surface Plasmonic Bands Using Block Copolymer Nanopatterns (블록공중합체 나노패턴을 이용한 표면 플라즈몬 연구)

  • Yoo, Seung Min
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.11
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    • pp.88-93
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    • 2017
  • It is important to develop a simple method oftuning localized surface plasmon resonance(LSPR) properties, due to their numerous applications. In addition, the careful examination of the shape, size and combination of metal nanoparticles is useful for understanding the relation between the LSPR properties and metal nanostructures. This article describes the dependence of theLSPR properties on the arrays of metal nanoparticles obtained from a block copolymer(BCP) micellar thin film. Firstly, two different Au nanostructures, having a dot and ring shape, were fabricated using conventional block copolymer micelle lithography. Then, Ag was plated on the Au nanostructures through the silver mirror reaction technique to obtain Au/Ag bimetallic nanostructures. During the production of these metallic nanostructures, the processing factors, such as the pre-treatment by ethanol, silver mirror reaction time and removal or not of the BCP, were varied. Once the Au nanoparticles were synthesized, Ag was properly plated on the Au, providing two distinguishable characteristic plasmonic bands at around 525nm for Au and around 420nm for Ag, as confirmed bythe UV-vis measurements. However, when a small amount of Au seed nanoparticles, which accelerate the Ag plating speed,was formed by usinga block copolymer with a relatively highmolecular weight, all of the Au surfaces were fully covered by Ag during the silver mirror reaction, showing only the characteristic peak for Ag at around 420nm. The Ag plating technique on Au nanoparticles pre-synthesized from a block copolymer is useful to study the LSPR properties carefully.

A Study of the Metal Artifact Reduction using Dual Energy CT : Clinical Applications of Dual Energy and MAR Algorithm (Dual Energy CT를 이용한 금속물질 인공물 감소방법 : Dual Energy와 MAR알고리즘의 임상적 응용)

  • Park, Ki Seok;Choi, Woo Jeon;Kim, Dong Hyun
    • Journal of the Korean Society of Radiology
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    • v.15 no.3
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    • pp.273-279
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    • 2021
  • Metal material inserted into the body have a large difference in density from human tissues or bones around the Metal during CT scans.. Therefore, the Metal material inserted into the body produces Artifact. Metal Artifact, which occurs around Metals, can degrade the quality of CT images, causing confusion when medical team diagnose lesions. Through this experiment, we confirm that the occurrence of Artifacts decrease by using Dual energy CT and MAR algorithm in Single source Dual energy CT. We also want to present basic data on clinical application methods by comparing and analyzing the characteristics of images obtained by each method. Using GE 750HD CT, artificial implants were scanned using general method and Dual energy. Then we apply the MAR algorithm to each image obtained. And all previously acquired images were compared and analyzed the characteristics of the examination, such as image quality evaluation and dose evaluation. Images with MAR algorithm and Dual Energy confirmed a decrease in Metal Artifact. Images with MAR algorithm have reduced Metal Artifact, but have the disadvantage of distorting the details of artificial joint implants. On the other hand images teseted with Dual Energy have the advantage of being able to implement details than those applied with MAR algorithms, it takes longer to reconstruct the image and the exposure dose was about four times higher than those applied with MAR algorithm. In order to locate Metals, such as the post-operative follow-up period, it is useful to apply MAR algorithm to obtain images. And it is more useful to examine with Dual Energy when micro lesion identification, such as cardiac examination, and surgical planning or when tests are performed in diagnostic way.

The Leaching of Valuable Metal from Mine Waste Rock by the Adaptation Effect and the Direct Oxidation with Indigenous Bacteria (토착박테리아의 중금속 적응효과와 직접산화작용에 의한 폐광석으로부터 유용금속 용출)

  • Kim, Bong-Ju;Cho, Kang-Hee;Choi, Nag-Choul;Park, Cheon-Young
    • Journal of the Mineralogical Society of Korea
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    • v.28 no.3
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    • pp.209-220
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    • 2015
  • The aim of this study was leaching valuable metal ions from mine waste rocks which were abandoned mine site using indigenous aerobic bacteria. In order to tolerate the the indigenous aerobic bacteria to the heavy metal ions they were repeatedly adapted in $CuSO_4{\cdot}5H_2O$ environment. As the repeated generation-adaptation progressed, the pH values of the growth-medium were gradually decreased. During bio-leaching experiments with indigenous aerobic bacteria raised in a heavy metal ion environment for 42 days, the pH of the leaching solution was decreased while increasing the adaptation period. The indigeous bacteria were much more active on the surface of Younhwa waste rocks which contained relatively few the chalcopyrite and Cu content than the Goseong mine waste rocks, and also the amount of Cu and Fe ions were leached more in the Younhwa sample(leaching rate of 92.79% and 55.88%, respectively) than the Goseong sample(leaching rate of 66.77% and 21.83%, respectively). Accordingly, it is confirmed that valuable metal ions can be leached from the mine waste rocks, if any indigenous bacteria which inhabits a mine environment site for a long time with heavy metal ions can be used, and these bacteria can be progressively adapted in the growth-solutions containing the target heavy metals.

A Study on the Discrimination of Materials Corrosion States Using the Acoustic Signal Data (음향신호 데이터를 이용한 재료 부식 상태 판별에 관한 연구)

  • Moon, Gun
    • Journal of Advanced Navigation Technology
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    • v.9 no.2
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    • pp.131-139
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    • 2005
  • On this study, I constructed the reflective acoustic signal detecting system using 15MHz acoustic transducer. The most difficult problems discriminating the characteristics of the metal substance are the discriminating the corrosion state and seeking hidden defects by using none destructive testing. For solving these problems, at first, theoretic analysis has been proceeded on the acoustic V(z) characteristics which is very important on discriminating the material characteristics. For application the V(z) theory to discriminating corrosion state, the 100 and 500 won metal coins which are issued on the different years are used as the test samples. The experimental results showed the distinct differences among the coin's acoustic signals accorded to its issued years. I catched the common regulation by analysing the acquisited acoustic signals and convinced this technique to be very useful on corrosion discrimination of the metal substances by none destructive testing and also can be used to inspect on the aeronautical materials for safety navigation.

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Characterization of Metal Composition in Spent Printed Circuit Boards of Mobile Phones (폐휴대폰 내의 인쇄회로기판에 함유된 금속 성분의 변화)

  • Jeong, jinki;Lee, Jae-chun;Choi, Jun-chul
    • Resources Recycling
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    • v.24 no.3
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    • pp.76-80
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    • 2015
  • Mobile phone has become one of the essential items in our daily life. In Korea, it is estimated that more than 20 million cell phones are discarded each year due to advancement in technology, thus creating disposal and environmental pollution. In order to conserve the resources, their proper recycling is essential as it contains both valuable and toxic metals. The economics of the recycling will depend on the amount and value of the metals. Therefore, it is necessary to determine the composition of the metals present in the different cell phones. In the present study, a report is presented on the variation of metal content per year of waste mobile phones. A review has been made for the mobile phones manufactured during the period 2000-2009 and metal content of the printed circuit boards (PCBs) by analyzing their metals. An example of the precious metal palladium and of the heavy metal lead shows the decreasing trend.

Use of Minimally Invasive Plate Osteosynthesis for Tibial Diaphyseal Fracture in Three Dogs (경골 골간 골절에서의 최소 침습적 금속판 고정술의 이용 3례)

  • Heo, Su-Young;Lee, Ki-Chang;Lee, Hae-Beom
    • Journal of Veterinary Clinics
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    • v.29 no.4
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    • pp.339-343
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    • 2012
  • Three dogs were presented with diaphyseal fracture of the tibia following separate motor vehicle accidents. On physical and orthopedic examinations, the dogs were noted to have soft-tissue swelling and a closed fracture in these tibia sites. Radiographs revealed a simple, short oblique fracture (case 1), a comminuted, spiral fracture (case 2), and a simple, spiral fracture (case 3) in tibia. Minimally invasive percutaneous plate osteosynthesis (MIPO) using a veterinary cuttable plate or locking plate was applied for the treatment of these fractures. The surgery was successful, and the fractures healed without any complications by 7 weeks (case 1), 10 weeks (case 2) and 8 weeks (case 3) after surgery. Our patients showed fast bone healing times and early weight-bearing during the treatment of their tibia fractures. Therefore, MIPO was a useful procedure for diaphyseal fracture of the tibia in veterinary orthopedics.

R&D Trends of Rare Metals Recovery from Seawater (해수(海水)로부터 희유금속(稀有金屬) 회수(回收) 연구동향(硏究動向))

  • Kim, Jong-Heon;Noh, Kyung-Ran;Kim, Sang-Woo;Choi, Sung-Bae;Kil, Sang-Cheol
    • Resources Recycling
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    • v.22 no.6
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    • pp.73-80
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    • 2013
  • Marine mineral resources are classified into submarine and seawater mineral resources. In seawater, huge amounts of useful minerals, such as uranium, lithium, magnesium, aluminum, zinc, iron, silver, copper, vanadium, nickel, titanium and cobalt are present. If the rare metals recovery technology from seawater is developed, the commercialization of the precess will be possible. For the 21st century, countries rich in resoures tend to weaponize the resources, according to the depletion of reserves and quality degradation of metal resources in the land. Therefore, Korea that relies on imports for most of the metal resources, should focus on the research and development of the rare metals recovery technology from seawater by using the geographical characteristics of the country that is on three sea-sides.

냉음극형 X-선 튜브의 제작을 위한 CNT 페이스트의 무기 충전제에 대한 연구

  • Kim, Jae-U;Gang, Jun-Tae;Jeong, Jin-U;Choe, Seong-Yeol;Choe, Jeong-Yong;An, Seung-Jun;Song, Yun-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.290.2-290.2
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    • 2013
  • X-선 튜브는 의료 영상 및 치료, 산업용 제전 장치, 비파괴 X-선 영상 장치 등에서 사용되는데 기존의 열전자원을 이용한 X-선 튜브와는 달리, 냉음극형 X-선 튜브는 빠른 속도의 디지털 구동이 가능하며 전력 소비가 낮은 장점이 있다. 따라서, 최근 많은 연구자들에 의해서 냉음극형 X-선 튜브에 관한 연구가 활발하게 진행되고 있다. 냉음극형 X-선 튜브는 전계 방출을 이용한 전자원을 사용하며, 탄소나노튜브 (CNT), Si, 다양한 종류의 나노선 등이 대표적이다. 그 중에서 CNT는 높은 종횡비로 인해 전계 방출 특성이 우수하여 가장 대표적인 물질이다. CNT를 이용한 전자원을 제작하기 위해서는 직접 성장법, 전기영동법, 스크린 프린팅법, 디핑법 등 다양한 방법이 존재한다. 직접 성장법을 제외한 방법들은 모재료인 CNT와 용매, 금속재료들을 섞어 페이스트나 수용액의 상태를 제작하여야 한다. 이 때, 금속 재료는 기판과 CNT간의 접착 및 전자 전도 통로의 역할을 하는 무기 충전제이며 일반적으로 나노 혹은 수 마이크로미터 크기의 상태로 존재하는 것을 주로 사용한다. X-선 튜브 제작은 일반적으로 외벽을 유리 혹은 세라믹을 주로 사용하는데 아노드 전극 및 캐소드 전극 등과 결합하여 진공 밀봉된 형태가 되어야 한다. 브레이징 방법은 금속과 세라믹을 결합하는데 매우 유용한 방법이며, 그 중에서도 진공 브레이징 방법은 다량의 부품을 한 번에 결합시킬 수 있다. 하지만 진공 브레이징 공정의 온도는 약 $700{\sim}1,000^{\circ}C$이며 이는 금속 재료가 충분히 증발할 수 있는 온도가 된다. 본 발표에서는 고온 진공 상태에서의 무기 충전제의 증발에 대한 현상을 관찰하고 고온진공 상태에서 증발없이 무기 충전제로의 역할을 할 수 있도록 다양한 금속 및 합금에 대한 연구를 수행하였다. 또한, 이 연구를 통해 선택된 무기 충전제를 포함하여 CNT 페이스트를 볼밀링 방법을 이용하여 제작하였으며, 이를 이용한 CNT 에미터가 X-선 튜브의 전자원으로 사용될 수 있는지 확인하기 위해 전계 방출 실험을 함께 실시하였다. 제작된 CNT 에미터가 우수한 전계 방출 특성을 가지고 있음을 확인하였으며, 이는 본 연구를 통해 선택된 금속 및 합금 재료가 무기 충전제로의 역할을 잘 수행하고 있음을 보여준다.

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